In order to enhance the thermal performance of the phase change material (PCM) wall during winter, a novel PCM and double-layer capillary bundles (PCM-DLCB) coupling wall is proposed. The PCM-DLCB wall utilizes the capillary bundle near the outer surface to capture solar energy during sunny winter days. The heat is then transferred to the capillary bundle near the inner surface through a circulating pump, promoting the melting of the PCM. Optimization and long-term operation comparison research were conducted using numerical simulation to investigate the potential of the PCM-DLCB wall to improve energy efficiency during winter. Five structural parameters, including the type of PCM, the position of the capillary bundle, the position and thickness of the PCM layer, the spacing of the capillary bundles, and the flow velocity in the capillary bundle, were selected as variables for structural and operation optimization. The optimization target was the accumulated heat gain from the inner surface of the wall. The research results indicate that: (1) The most suitable PCM is RT-18HC; (2) Placing the PCM layer between the double-layer capillary bundle yields better results compared to other arrangements; (3) Optimal energy saving is achieved when the outer capillary bundle is positioned 6 mm away from the outer surface and the inner capillary bundle is positioned 8 mm away from the inner surface; (4) The optimal thickness of the PCM layer is 10 mm; (5) The optimal flow velocity in the capillary bundle is approximately 0.04 m/s. Furthermore, long-term operation results based on a typical hot summer and cold winter climate zone reveal that the optimized PCM-DLCB wall provides a 7.80 % increase in indoor heat gain compared to an ordinary PCM wall during winter, and an 18.4 % increase compared to a wall without PCM.