Annual Layer Counting Research Articles

Annual accumulation over recent centuries at four sites in central Greenland

Accurate accumulation records are fundamental to understanding mass balance of the Greenland ice sheet. Ice cores can provide multicentury, high‐resolution ground‐based point estimates of water accumulation. In 2003 and 2004, four new ice cores were collected in the central western (D4 and D5) and Summit (Sandy and Katie) regions of Greenland. Annual layer counting based on multiple glaciochemical parameters (primarily hydrogen peroxide, sea salt, and dust proxies) was used to date the ice cores, resulting in annual dating. The bottom depth ages for D4, D5, Sandy, and Katie were estimated at 1738, 1673, 1844, and 1934 A.D., with mean annual accumulation rates of 41.4, 35.2, 22.4, and 22.4 cmweq yr−1, respectively. These new records were in good agreement with previous accumulation maps and four previously published records from nearby multicentury ice cores. Spatial variability was quantified through an analysis of variance, thereby allowing for more meaningful comparisons to atmospheric processes. More regionally representative accumulation records were constructed for the central western and Summit regions spanning recent centuries using a principle component analysis of both the new and previously reported ice core measurements. These regional records exhibited 6–7% interannual variability (1 standard deviation of the mean) and had lower spatial variability uncertainties than individual accumulation records. Correlations indicate that ∼20% of the variance in the central western region was explained by the North Atlantic Oscillation (NAO), and suggests that an array of more northern ice cores may correlate more closely with NAO.

The DO-climate events are probably noise induced: statistical investigation of the claimed 1470 years cycle

Abstract. The significance of the apparent 1470 years cycle in the recurrence of the Dansgaard-Oeschger (DO) events, observed in the Greenland ice cores, is debated. Here we present statistical significance tests of this periodicity. The detection of a periodicity relies strongly on the accuracy of the dating of the DO events. Here we use both the new NGRIP GICC05 time scale based on multi-parameter annual layer counting and the GISP2 time scale where the periodicity is most pronounced. For the NGRIP dating the recurrence times are indistinguishable from a random occurrence. This is also the case for the GISP2 dating, except in the case where the DO9 event is omitted from the record.

The Greenland Ice Core Chronology 2005, 15–42 ka. Part 2: comparison to other records

A new Greenland Ice Core Chronology (GICC05) based on multi-parameter counting of annual layers has been obtained for the last 42 ka. Here we compare the glacial part of the new time scale, which is based entirely on records from the NorthGRIP ice core, to existing time scales and reference horizons covering the same period. These include the GRIP and NorthGRIP modelled time scales, the Meese-Sowers GISP2 counted time scale, the Shackleton–Fairbanks GRIP time scale (SFCP04) based on 14C calibration of a marine core, the Hulu Cave record, three volcanic reference horizons, and the Laschamp geomagnetic excursion event occurring around Greenland Interstadial 10. GICC05 is generally in good long-term agreement with the existing Greenland ice core chronologies and with the Hulu Cave record, but on shorter time scales there are significant discrepancies. Around the Last Glacial Maximum there is a more than 1 ka age difference between GICC05 and SFCP04 and a more than 0.5 ka discrepancy in the same direction between GICC05 and the age of a recently identified tephra layer in the NorthGRIP ice core. Both SFCP04 and the tephra age are based on 14C-dated marine cores and fixed marine reservoir ages. For the Laschamp event, GICC05 agrees with a recent independent dating within the uncertainties.

The Greenland Ice Core Chronology 2005, 15–42 ka. Part 1: constructing the time scale

The Greenland Ice Core Chronology 2005, GICC05, is extended back to 42 ka b2k (before 2000 AD), i.e. to the end of Greenland Stadial 11. The chronology is based on independent multi-parameter counting of annual layers using comprehensive high-resolution measurements available from the North Greenland Ice Core Project, NGRIP. These are measurements of visual stratigraphy, conductivity of the solid ice, electrolytical melt water conductivity and the concentration of Na +, Ca 2+, SO 4 2−, NO 3 −, NH 4 +. An uncertainty estimate of the time scale is obtained from identification of ‘uncertain’ annual layers, which are counted as 0.5±0.5 years. The sum of the uncertain annual layers, the so-called maximum counting error of the presented chronology ranges from 4% in the warm interstadial periods to 7% in the cold stadials. The annual accumulation rates of the stadials and interstadials are on average one-third and half of the present day values, respectively, and the onset of the Greenland Interstadials 2, 3, and 8, based on 20 year averaged δ 18O values, are determined as 23,340, 27,780, and 38,220 yr b2k in GICC05.

A 780-year record of explosive volcanism from DT263 ice core in east Antarctica

Ice cores recovered from polar ice sheet received and preserved sulfuric acid fallout from explosive volcanic eruptions. DT263 ice core was retrieved from an east Antarctic location. The ice core is dated using a combination of annual layer counting and volcanic time stratigraphic horizon as 780 years (1215–1996 A.D.). The ice core record demonstrates that during the period of approximately 1460–1800 A.D., the accumulation is sharply lower than the levels prior to and after this period. This period coincides with the most recent neoglacial climatic episode, the “Little Ice Age (LIA)”, that has been found in numerous Northern Hemisphere proxy and historic records. The non-sea-salt SO 4 2− concentrations indicate seventeen volcanic events in DT263 ice core. Compared with those from previous Antarctic ice cores, significant discrepancies are found between these records in relative volcanic flux of several well-known events. The discrepancies among these records may be explained by the differences in surface topography, accumulation rate, snow drift and distribution which highlight the potential impact of local glaciology on ice core volcanic records, analytical techniques used for sulfate measurement, etc. Volcanic eruptions in middle and high southern latitudes affect volcanic records in Antarctic snow more intensively than those in the low latitudes.

A synchronized dating of three Greenland ice cores throughout the Holocene

As part of the effort to create the new Greenland Ice Core Chronology 2005 (GICC05) a synchronized stratigraphical timescale for the Holocene parts of the DYE‐3, Greenland Ice Core Project (GRIP), and North Greenland Ice Core Project (NGRIP) ice cores is made by using volcanic reference horizons in electrical conductivity measurements to match the cores. The main annual layer counting is carried out on the most suited records only, exploiting that the three ice cores have been drilled at locations with different climatic conditions and differences in ice flow. However, supplemental counting on data from all cores has been performed between each set of reference horizons in order to verify the validity of the match. After the verification, the main dating is transferred to all records using the volcanic reference horizons as tie points. An assessment of the mean annual layer thickness in each core section confirms that the new synchronized dating is consistent for all three cores. The data used for the main annual layer counting of the past 7900 years are the DYE‐3, GRIP, and NGRIP stable isotope records. As the high accumulation rate at the DYE‐3 drill site makes the seasonal cycle in the DYE‐3 stable isotopes very resistant to firn diffusion, an effort has been made to extend the DYE‐3 Holocene record. The new synchronized dating relies heavily on this record of ∼75,000 stable isotope samples. The dating of the early Holocene consists of an already established part of GICC05 for GRIP and NGRIP which has now been transferred to the DYE‐3 core. GICC05 dates the Younger Dryas termination, as defined from deuterium excess, to 11,703 years before A. D. 2000 (b2k), 130 years earlier than the previous GRIP dating.

A new Greenland ice core chronology for the last glacial termination

We present a new common stratigraphic timescale for the North Greenland Ice Core Project (NGRIP) and GRIP ice cores. The timescale covers the period 7.9–14.8 kyr before present and includes the Bølling, Allerød, Younger Dryas, and early Holocene periods. We use a combination of new and previously published data, the most prominent being new high‐resolution Continuous Flow Analysis (CFA) impurity records from the NGRIP ice core. Several investigators have identified and counted annual layers using a multiparameter approach, and the maximum counting error is estimated to be up to 2% in the Holocene part and about 3% for the older parts. These counting error estimates reflect the number of annual layers that were hard to interpret, but not a possible bias in the set of rules used for annual layer identification. As the GRIP and NGRIP ice cores are not optimal for annual layer counting in the middle and late Holocene, the timescale is tied to a prominent volcanic event inside the 8.2 kyr cold event, recently dated in the DYE‐3 ice core to 8236 years before A. D. 2000 (b2k) with a maximum counting error of 47 years. The new timescale dates the Younger Dryas‐Preboreal transition to 11,703 b2k, which is 100–150 years older than according to the present GRIP and NGRIP timescales. The age of the transition matches the GISP2 timescale within a few years, but viewed over the entire 7.9–14.8 kyr section, there are significant differences between the new timescale and the GISP2 timescale. The transition from the glacial into the Bølling interstadial is dated to 14,692 b2k. The presented timescale is a part of a new Greenland ice core chronology common to the DYE‐3, GRIP, and NGRIP ice cores, named the Greenland Ice Core Chronology 2005 (GICC05). The annual layer thicknesses are observed to be log‐normally distributed with good approximation, and compared to the early Holocene, the mean accumulation rates in the Younger Dryas and Bølling periods are found to be 47 ± 2% and 88 ± 2%, respectively.

Seasonal and spatial variations of snow chemistry on Mount Logan, Yukon, Canada

AbstractThree ice cores were recovered on or near Mount Logan, Yukon, Canada, at 3017, 4135 and 5340 ma.s.l. in 2002. Prior to ice-core drilling, we collected snow-pit and shallow core samples from Mount Logan in 2001 to study seasonal and spatial variations of snow chemistry. We dug snow pits at six sites between 2420 and 5340 m a.s.l. before the beginning of the melt season, with the exception of a pit at 3180 m a.s.l., where the melt season had just started but had affected only the near-surface stratigraphy. Three of the pits were extended deeper with a shallow core. The snow-pit and core samples were analyzed for ion chemistry and δ18O. A series of depth profiles of ions and δ18O shows spatial variations, though characteristic peaks can usually be traced across all the profiles. Concentrations and deposition fluxes of Na+ and Cl−, which are mainly of sea-salt origin, decrease with altitude. On the other hand, deposition fluxes of NO3−, SO42–, Ca2+ and NH4+ show a weak positive relationship with elevation below the summit plateau. Stable isotopes (δ18O) decrease with altitude, with a distinctive jump between 3200 and 4500 m a.s.l., as was reported previously. Stable isotopes (δ18O), Cl−, CH3SO3− (MSA), Na+ and Ca2+ show clear seasonal variations, which would enable us to date the cores by annual-layer counting.

A first shallow firn-core record from Glaciar La Ollada, Cerro Mercedario, central Argentine Andes

AbstractIn January 2003, shallow firn cores were recovered from Glaciar Esmeralda on Cerro del Plomo (33°14’S, 70°13’W; 5300 ma.s.l.), central Chile, and from Glaciar La Ollada on Cerro Mercedario (31°58’S, 70°07’W; 6070 ma.s.l.), Argentina, in order to find a suitable archive for paleoclimate reconstruction in a region strongly influenced by the El Nino-Southern Oscillation. In the area between 28°S and 35°S, the amount of winter precipitation is significantly correlated to the Southern Oscillation Index, with higher values during El Nino years. Glaciochemical analysis indicates that the paleo-record at Glaciar La Ollada is well preserved, whereas at Glaciar Esmeralda the record is strongly influenced by meltwater formation and percolation. A preliminary dating of the Mercedario core by annual-layer counting results in a time-span of 17 years (1986-2002), yielding an average annual net accumulation of 0.45 m w.e.

Deconvolution‐based resolution enhancement of chemical ice core records obtained by continuous flow analysis

Continuous flow analysis (CFA) has become a popular measuring technique for obtaining high‐resolution chemical ice core records due to an attractive combination of measuring speed and resolution. However, when analyzing the deeper sections of ice cores or cores from low‐accumulation areas, there is still need for further improvement of the resolution. Here a method for resolution enhancement of CFA data is presented. It is demonstrated that it is possible to improve the resolution of CFA data by restoring some of the detail that was lost in the measuring process, thus improving the usefulness of the data for high‐resolution studies such as annual layer counting. The presented method uses deconvolution techniques and is robust to the presence of noise in the measurements. If integrated into the data processing, it requires no additional data collection. The method is applied to selected ice core data sequences from Greenland and Antarctica, and the results demonstrate that the data quality can be significantly improved.

Dating of seasonal snow/firn accumulation layers using pollen analysis

AbstractReliable chronologies in ice cores and snow pits from many alpine glaciers in latitudes between 60° N and 60° S are often difficult to establish owing to problems with annual-layer counting. Problems arise from melting, wind erosion and the negligible amount of precipitation in some seasons, all of which tend to obscure the seasonal variations in δ18O and chemical concentrations that are typically used to date ice cores. However, alpine glaciers contain many species of pollen grains that peak at particular times of the year. We used the peaks in Betulaceae, Pinus, Artemisia and a combination of Abies and Picea pollen species to determine the four seasonal layers of a snow pit on Belukha glacier in Russia’s Altai Mountains. Comparing the pollen-dated profiles with wind and precipitation records allows us to determine where a seasonal layer is missing. Thus, the pollen-dating method described here may be a useful tool to measure the annual snow deposition on alpine glaciers, even when some seasonal layers are eroded by wind or missing due to negligible precipitation.

High-resolution ice cores from US ITASE (West Antarctica): development and validation of chronologies and determination of precision and accuracy

AbstractShallow ice cores were obtained from widely distributed sites across the West Antarctic ice sheet, as part of the United States portion of the International Trans-Antarctic Scientific Expedition (US ITASE) program. The US ITASE cores have been dated by annual-layer counting, primarily through the identification of summer peaks in non-sea-salt sulfate (nssSO42–) concentration. Absolute dating accuracy of better than 2 years and relative dating accuracy better than 1 year is demonstrated by the identification of multiple volcanic marker horizons in each of the cores, Tambora, Indonesia (1815), being the most prominent. Independent validation is provided by the tracing of isochronal layers from site to site using high-frequency ice-penetrating radar observations, and by the timing of mid-winter warming events in stable-isotope ratios, which demonstrate significantly better than 1 year accuracy in the last 20 years. Dating precision to ±1 month is demonstrated by the occurrence of summer nitrate peaks and stable-isotope ratios in phase with nssSO42–, and winter-time sea-salt peaks out of phase, with phase variation of <1 month. Dating precision and accuracy are uniform with depth, for at least the last 100 years.

The duration of the Bølling-Allerød period (Greenland Interstadial 1) in the GRIP ice core

AbstractA new dating of the Bølling-Allerød period (Greenland Interstadial event 1) in the GRIP ice core is presented. Newly measured profiles of δD and δ18O, as well as existing profiles of Ca2+, NH4+, dust and NO3–, have been used for the dating. As seasonal variations can be observed in all six components, it was possible to simultaneously count annual layers in the profiles in order to obtain a multi-parameter dating. The new data presented in this study include a total of 36.85 m of stable-isotope profiles of 1 cm resolution from five sections of the Bølling-Allerød period in the GRIP ice core. The annual-layer counting suggests a duration of the complete Bølling-Allerød period, as revealed in the GRIP ice core, of 1627 ± 52 years. This estimate contrasts with an earlier finding from the same GRIP ice core, where the Bølling-Allerød was found to span 2168 years (Hammer, in press). This estimate was based on layer counting, using dust concentrations only.

Spatio-temporal variability in volcanic sulphate deposition over the past 2 kyr in snow pits and firn cores from Amundsenisen, Antarctica

AbstractIn the framework of the European Project for Ice Coring in Antarctica (EPICA), a comprehensive glaciological pre-site survey has been carried out on Amundsenisen, Dronning Maud Land, East Antarctica, in the past decade. Within this survey, four intermediate-depth ice cores and 13 snow pits were analyzed for their ionic composition and interpreted with respect to the spatial and temporal variability of volcanic sulphate deposition. The comparison of the non-sea-salt (nss)-sulphate peaks that are related to the well-known eruptions of Pinatubo and Cerro Hudson in AD 1991 revealed sulphate depositions of comparable size (15.8±3.4 kg km–2) in 11 snow pits. There is a tendency to higher annual concentrations for smaller snow-accumulation rates. The combination of seasonal sodium and annually resolved nss-sulphate records allowed the establishment of a time-scale derived by annual-layer counting over the last 2000 years and thus a detailed chronology of annual volcanic sulphate deposition. Using a robust outlier detection algorithm, 49 volcanic eruptions were identified between AD 165 and 1997. The dating uncertainty is ±3 years between AD 1997 and 1601, around ±5 years between AD 1601 and 1257, and increasing to ±24 years at AD 165, improving the accuracy of the volcanic chronology during the penultimate millennium considerably.

Stable isotope records of plant cover change and monsoon variation in the past 2200 years: evidence from laminated stalagmites in Beijing, China

Two stalagmites collected from the Shihua cave in the southwestern suburb of Beijing were dated by annual layer counting. The results are consistent with thermal ionization mass spectrometry 230Th dating. Stable carbon isotope variation of stalagmites is dominated by plant cover change, which largely reflects climate change and monsoon variation. Oxygen isotopes are mainly affected by precipitation, which is related to summer and winter monsoon intensity. The combination of carbon and oxygen isotopes can therefore be a proxy of plant cover change and monsoon variation. Our stable isotope results show that lower carbon isotope values of the stalagmites between 200 BC and AD 1000 probably imply dense plant cover and an episode dominated by humid summer monsoon. From ˜1000 to AD 1450, the dominant monsoon alternated between the winter monsoon and the summer monsoon. Since ˜AD 1450, a significant jump in carbon isotope ratios and increasing oxygen isotope ratios has been demonstrated, indicating less plant cover and the probable dominance of dry winter monsoon. The results are consistent with historical documents of the region.

Dating of two nearby ice cores from the Illimani, Bolivia

In order to establish a chronology of two nearby ice cores from a glacier at Illimani (6438 m), Bolivia, a broad dating approach is presented here, which in particular makes use of the fast, simple, and nearly nondestructive electrical conductivity method (ECM) that provides a highly resolved record. Thus, ECM is suited for counting annual layers in the ice, especially for ice cores extracted from high‐mountain glaciers with a fast layer thinning. Furthermore, ECM can be used for detecting volcanic signals. Annual signals in the ECM record of the Illimani ice core were identified using the 1964 A.D. tritium reference horizon and were counted along 125 m or 90% of the core, representing the time period from 1200 ± 240 A.D. (estimated accumulated error) to 1999 A.D. The resulting age–depth relationship was supported by counting annual peaks in the microparticle record as well as by nuclear dating using the decay of 210Pb. The identification of volcanic signals originating from eruptions such as Pinatubo (1991 A.D.), El Chichón (1982 A.D.), Agung (1963 A.D.), Krakatoa (1883 A.D.), Tambora (1815 A.D.), and the Unknown 1258 A.D. significantly reduced the uncertainty of annual layer counting (ALC) to ±2 years in the vicinity of these events.

Precise dating of Dansgaard-Oeschger climate oscillations in western Europe from stalagmite data.

The signature of Dansgaard-Oeschger events--millennial-scale abrupt climate oscillations during the last glacial period--is well established in ice cores and marine records. But the effects of such events in continental settings are not as clear, and their absolute chronology is uncertain beyond the limit of (14)C dating and annual layer counting for marine records and ice cores, respectively. Here we present carbon and oxygen isotope records from a stalagmite collected in southwest France which have been precisely dated using 234U/230Th ratios. We find rapid climate oscillations coincident with the established Dansgaard-Oeschger events between 83,000 and 32,000 years ago in both isotope records. The oxygen isotope signature is similar to a record from Soreq cave, Israel, and deep-sea records, indicating the large spatial scale of the climate oscillations. The signal in the carbon isotopes gives evidence of drastic and rapid vegetation changes in western Europe, an important site in human cultural evolution. We also find evidence for a long phase of extremely cold climate in southwest France between 61.2 +/- 0.6 and 67.4 +/- 0.9 kyr ago.

Glaciers and Climate in the Andes between the Equator and 30° S: What is Recorded under Extreme Environmental Conditions?

Sublimation and melt disturb the environmental information obtained from ice core records in the Andes. In two case studies we demonstrate to what extent these post-depositional processes may remove major parts of the accumulated snow cover. Dark ash layers from the Tungurahua eruption changed the albedo of surface snow on Chimborazo glacier (6268 m, 1°30′ S,78°36′ W, Ecuador) between two ice core drilling campaigns and forced substantial melt. Re-distribution and washout of the chemical constituents shifted the concentration profiles obtained in December 1999 as compared to an equivalent core drilled in December 2000. The stable isotope records showed that approximately the water equivalent (weq) of an annual layer had melted, and that the percolating melt water penetrated within the firn layer to a depth of at least 16.5 m without refreezing. In the second example, from a site on the dry axis between the tropical and extra-tropical precipitation belts, significant loss of accumulated snow layers occurred by sublimation. A surface experiment at Cerro Tapado glacier (5536 m, 30°08′ S,69°55′ W, Chile) revealed that losses of ≈2 mm weq (≈5 mm snow) per day occurred during the dry period following the 1997/98 El Niño. This loss generally included the entire surface layer enriched in stable isotopes, and thus caused minimal disturbance of the isotopic signature (and hence climatic information) of the net accumulation, yet chemical constituents again experienced considerable changes in concentration. From annual layer counting and direct dating it is obvious that the major part of the accumulated ice on both glaciers is younger than 100 years; however, isotopic and chemical variations at least in the basal ice from Cerro Tapado clearly point to climate conditions different from the recent centuries. This evidence is supported by mass balance considerations derived from a glacier-climate model. The possibility of a third type of disturbance aside from sublimation and melting – in this case a significant hiatus in the environmental chronology – also deserves consideration for other icecore records from this region. Potential disruptions or discontinuities need to be carefully evaluated given the profound changes in climatic and glaciological conditions since the Last Glacial Maximum throughout Holocene times.

A high resolution stable isotope record of the penultimate deglaciation in lake sediments below the city of Amsterdam, The Netherlands

A detailed record of the deglaciation history of the penultimate glacial to interglacial transition is given, mainly based on the stable isotopes of calcium carbonate-containing lake sediments in a glacially excavated depression below the city of Amsterdam. Initially, this depression, the Amsterdam Basin, formed part of a lake covering the western and central part of the Netherlands and extending for an unknown distance into the present North Sea. Annual layer counting shows that the lake drained after about a millennium, leaving shallow pools in the remaining depressions. The latter changed again into larger and deeper lakes including the Holland Lake during the rise of sea level in the early Eemian. Oxygen isotope values of the early lake sediments indicate an interglacial summer climate, but the nearness of dead-ice fields caused severe winters. The isotope record is furthermore characterized by the influx of large amounts of isotopically light water supplied by the river Rhine. A change to much colder conditions occurred simultaneously with the draining of the Holland Lake, as appears from oxygen isotope values and the sudden increase in non-arboreal pollen. This interval is correlated with the Kattegat Stadial and the sea-level standstill of Aladdins Cave on the Huon Peninsula of New Guinea. A short climate wiggle occurs at the end of this interval. The onset of the Eemian is marked by a rapid warming of ∼5°C which extends into local pollen-zone E3. Provided that our correlation of this cold interval with the sea-level standstill of Aladdins Cave is correct, the time interval between the earliest lake sediments in the Amsterdam Basin and the Eemian highstand took about 5–6 millennia.

Annual-layer determinations and 167 year records of past climate of H72 ice core in east Dronning Maud Land, Antarctica

AbstractTo determine annual layers for reconstructing the past environment at annual resolution from ice cores, we employed snow-stake data back to 1972, tritium content, solid electrical conductivity measurements (ECM) and stratigraphic properties for the 73m ice core at the H72 site, east Dronning Maud Land, Antarctica. the average annual surface mass balance at H72 is 307 mma–1w.e. during the last 27 years from continuous accumulation data, 317 mma–1 w.e. according to the densification model and 311 mma–1 w.e. according to the average surface mass balance for 167 years based on annual-layer counting. the ECM age is closely coincident with tritium age, and corresponds with the snow-stake record back to AD 1972 from the surface to 15 m depth. the H72 ice core is dated as AD 1831by ECMat 73.16 mdepth.The time series of yearly surface mass balance at H72 shows an almost constant 311 mm a–1 w.e. for the last 167 years. the oxygen-isotope records indicate a significant trend to lower values, with negative gradient of 1.7% (100 years)–1.