The dual challenges of additive safety and environmental sustainability in the current cosmetics market have attracted significant attention. In this study, we obtained raw materials from natural Chinese medicine, combined with electrospinning technology, developed a new type of environmentally friendly dry nanofiber multifunctional mask with Bletilla striata polysaccharide (BSP) as the material and loaded with the sodium ferulate (SF). The optimal manufacturing process was screened by scanning electron microscopy (SEM), and the diameters of the dry nanofiber facial mask (DNFM) were mainly distributed in the range of 180–240 nm. Volunteer experiments and water contact angle assessments showed that the DNFM had good moisture retention and solubility. The experimental findings showcased that the water vapor transmission rate of the PVA/BSP/SF DNFM was 4607.77 ± 74.12 g/m2/day, and the tyrosinase inhibition rate was 52.88 %, over 98 % inhibition rates against Propionibacterium acnes (P. acnes), and a 94.99 ± 0.24 % DPPH free radical scavenging rate. The mouse group treated with the DNFM displayed stronger resistance to UV damage. Cell Counting Kit-8 (CCK8) and Live/Dead staining experiments verified its safety and biocompatibility. The combined application of electrospinning technology and natural Chinese medicine components provides a new strategy for the development of an environmentally friendly and convenient mask product.