Corrosion Of Pipes Research Articles

Mechanistic investigation of ferric ion and ferriferous oxide on M. barkeri-mediated copper corrosion

Methanosarcina barkeri (M. barkeri) can cause microbiologically influenced corrosion (MIC) of copper in heat exchangers, where ferric ion (Fe3+) and ferriferous oxide (Fe3O4) also exist due to the corrosion of iron pipes with flowing water. It is worth noting that M. barkeri can reduce Fe3+ to Fe2+ or Fe, which may exhibit an unknown effect on copper corrosion. In this study, the molecular mechanism of copper corrosion by M. barkeri with Fe3+ and Fe3O4 was explored. In the presence of Fe3+, the corrosion was enhanced by 82.5 %, and M. barkeri and Fe3+ exhibited a synergistic effect on copper corrosion. It is attributed to that Fe3+ oxidized the copper and promoted the growth of M. barkeri and biofilm formation, thus promoting corrosion. Moreover, the corrosion by M. barkeri with Fe3O4 increased by only 27.7 %, and M. barkeri and Fe3O4 exhibited an antagonistic effect on the corrosion. Fe3O4 covered the coupon surface, which reduced the contact between the cells and the coupon, and thus inhibited electrochemical corrosion. This study provides new insights for methanogens-induced MIC, and also has far-reaching implication for the mitigation of MIC in heat exchangers.

Can molecular oscillation technology be used as an alternative to acid injection to prevent the clogging of emitters in drip irrigation systems?

AbstractIn this study, molecular oscillation technology (Merus ring), developed to prevent calcification, biofilm formation and corrosion in piping in industrial water treatment systems, was compared as an alternative to acid injection to prevent the clogging of emitters by chemicals, and fresh and saline water were compared on the basis of system performance parameters (coefficient of variation, distribution uniformity, Christiansen uniformity, emission uniformity) and economic aspects. The results revealed that both acid injection and the Merus ring in saline and fresh water resulted in significantly higher average emitter flow rates than the control treatment. Both the Merus ring and the acid injection achieved higher performance parameters with fresh water than with saline water. Acid injection was found to be more effective in preventing clogging of the emitters than the Merus ring when saline water was used. Compared with fresh water, saline water increases emitter clogging. The economic analysis revealed that the Merus ring was more economical ($204.3 ha−1) than acid injection with both fresh water ($318.2 ha−1) and saline water ($578.6 ha−1). Therefore, the Merus ring could be a reliable and environmentally friendly alternative to acid injection to prevent the clogging of emitters in drip systems when saline water is used.

Experimental modal analysis of in-plane bending vibration mode using actual water main network

Accidents of water leakage and bursting due to deterioration of water pipes cause water outages and economic losses in the surrounding areas. We are conducting research to develop measurement and diagnostic methods for buried water pipes. The graphitic corrosion of water pipes in a buried environment causes a reduction in pipe thickness which leads to strength problems. For this reason, methods for detecting pipe thickness are necessary for evaluating pipe deterioration, however, there is no effective way to analyze pipe thickness today because it cannot be visually observed in a buried environment. In this study, we focused on the shift in eigenfrequencies of in-plane bending vibration of rings due to deterioration. At first, we performed an experimental modal analysis by using a water pipe network which is used in a practical water utility. In addition, we conducted a theoretical analysis based on a model of a two-dimensional ring with coupled incidental attachment. As a result, in-plane bending vibration was observed in the water pipe of actual size. Furthermore, in-plane bending vibration was observed when excited through fire hydrants and it is also observed in pipes that are different material and diameters.

Evaluation of Electrochemical Properties and Life Prediction of Sensor Wire in Leak Detection Systems of Underground Heating Pipelines

Abstract In this study, we investigated the electrochemical properties and lifespan of the NiCr (NiCr 8020) sensor wire of a resistance leaking detection (LD) system to detect pipe corrosion and leakage in an actual district heating (DH) system. The temperature and applied stress of the sensor wire during the actual operation of the resistance LD system of the DH system were derived through simulations and calculations. The anodic dissolution of the sensor wire was accelerated with the increased temperature and the applied current. The corrosion type changed from localized corrosion, such as pitting, to uniform corrosion. The applied stress caused ductile fracture of the thinned sensor wire by anodic dissolution. In conclusion, we confirmed that in the resistance LD system of a DH system, where current and stress are applied at high temperatures, the sensor wire becomes thin due to the anodic dissolution and subsequent ductile fracture. In addition, the lifespan of the sensor wire was derived according to the resistance level measured in the resistance LD system of the DH system. Our findings contribute to preventing failure and improving the reliability of the resistance LD systems of DH systems.

Experimental study on high temperature gaseous hydrogen fluoride corrosion of boiler water-cooled wall pipes

ABSTRACT Hydrogen fluoride (HF) corrosion of boiler water-cooled wall pipes at high temperature hinders the co-disposal of fluorinated hazardous wastes and coal by combustion. In this paper, common water-cooled wall pipes (15CrMoG and 20G) were utilized to perform gaseous HF corrosion experiments at high temperature on a horizontal tube furnace. The effects of temperature on HF corrosion of different water-cooled wall pipes in 0.2% HF were investigated. Corrosion kinetics curve was obtained by calculating the mass increase due to corrosion. The microscopic morphology and physical phase composition of water-cooled wall pipes after HF corrosion were analyzed. The corrosion resistances of the two water-cooled wall pipes decrease with increasing the temperature. The corrosion weight gain curves of 15CrMoG and 20G at 550 ℃ are ΔW 1.9144 = 0.2100t and ΔW 1.8356 = 0.1344t, respectively. The average corrosion rates of 15CrMoG and 20G are 0.0177 and 0.0125 mg/(cm2·h), respectively. The corrosion resistance of 15CrMoG is superior compared to 20G. The HF corrosion at high temperature consists of non-alternating fluorination and oxidation of the metal matrix. This study is of great significance for the protection of boilers with HF corrosion at high temperature.

Persistent free radicals in natural organic matter activated by iron particles enhanced disinfection byproduct formation

The widespread presence of iron (Fe) particles and natural organic matter (NOM) in drinking water distribution systems (DWDS) can significantly affect tap water quality, contributing to aesthetic issues and potentially generating harmful disinfection byproducts (DBPs). This study revealed that Fe particles, when combined with humic acid (HA), substantially increased DBP formation during chlorination. Fe particles (particularly preformed Fe particles) significantly increased haloacetic acid (HAA) formation by activating the persistent free radicals (PFRs) in the HA. Compared with the control system without Fe particles, greater than 2 times of HAA increase were observed for the system with Fe pariticles. PFRs accumulated on Fe particle surface could generate hydroxyl radicals, facilitating the decomposition of HA into smaller molecules, which were more reactive with chlorine disinfectants, thus elevated the DBP formation including both known and unknown N-DBPs and Cl-DBPs. The DBP promotion effect of in-situ formed Fe particles was much less than that of preformed Fe particles although both in-situ formed and preformed Fe particles could accumulate PFRs from HA. In-situ formed particles primarily accumulated carbon-centered PFRs, while preformed particles accumulated oxygen-centered PFRs. To mitigate the Fe particle induced water quality risks, it is crucial to control iron pipe corrosion and iron release in DWDS. In addtion, the optimization of treatment processes such as coagulation and filtration to more completely remove NOM and Fe particles could help minimize the DBP formation.

Experimental Study on the Chlorine-Induced Corrosion and Blister Formation of Steel Pipes Coated with Modified Polyethylene Powder.

In this study, chlorine-induced corrosion and blister formation on steel pipes (SPs) coated with modified polyethylene powder (MPP) were evaluated through various tests, including chlorine exposure, wet immersion, and temperature gradient experiments. The results confirmed that the extent of corrosion and iron leaching varied with the coating type as expected. In batch leaching tests, no corrosion was observed on modified polyethylene-coated steel pipes (MPCSPs) within a chlorine concentration range of 0 mg/L to 10 mg/L; similarly, there were no significant changes in specimen weight or iron levels. In contrast, the control group with uncoated SPs exhibited significant iron leaching and corrosion, a trend consistent in sequential leaching experiments. SEM analysis after a month of chlorine exposure revealed no significant corrosion on MPCSPs, and SEM-EDX confirmed no major changes in the carbon bond structure, indicating resistance to high chlorine concentrations. Comparative analysis of wet immersion and temperature gradient tests between MPCSP and conventional epoxy-coated SP (ECSP) specimens revealed that MPCSPs did not develop blisters even after 100 days of immersion, whereas ECSPs began showing blisters as early as 50 days. In temperature gradient tests, MPCSPs showed no blisters after 100 days, while ECSPs exhibited severe internal coating layer blisters.

Pitting Corrosion of Steel Pipes in Water Supply Systems: An Influence of Shell-like Layer

Pitting Corrosion of Steel Pipes in Water Supply Systems: An Influence of Shell-like Layer

Research on Acid Aging and Damage Pattern Recognition of Glass Fiber-Reinforced Plastic Oil and Gas Gathering Pipelines Based on Acoustic Emission.

Pipelines extend thousands of kilometers to transport and distribute oil and gas. Given the challenges often faced with corrosion, fatigue, and other issues in steel pipes, the demand for glass fiber-reinforced plastic (GFRP) pipes is increasing in oil and gas gathering and transmission systems. However, the medium that is transported through these pipelines contains multiple acid gases such as CO2 and H2S, as well as ions including Cl-, Ca2+, Mg2+, SO42-, CO32-, and HCO3-. These substances can cause a series of problems, such as aging, debonding, delamination, and fracture. In this study, a series of aging damage experiments were conducted on V-shaped defect GFRP pipes with depths of 2 mm and 5 mm. The aging and failure of GFRP were studied under the combined effects of external force and acidic solution using acoustic emission (AE) techniques. It was found that the acidic aging solution promoted matrix damage, fiber/matrix desorption, and delamination damage in GFRP pipes over a short period. However, the overall aging effect was relatively weak. Based on the experimental data, the SSA-LSSVM algorithm was proposed and applied to the damage pattern recognition of GFRP. An average recognition rate of up to 90% was achieved, indicating that this method is highly suitable for analyzing AE signals related to GFRP damage.

N-vinylcaprolactam-acrylamide copolymer inhibition performance against 304L stainless steel corrosion in a simulated sweet-sour corrosive environment

Internal corrosion of oilfield pipes in the presence of CO2 and H2S is a significant problem in the oil and gas industry. The financial and material ramifications are immense, given that transportation pipelines are vital to the energy and gas industry. In typical oilfield industries, the prevailing approach to address corrosion issues affecting steel-based structural elements involves the incorporation of corrosion inhibitors into the corrosion system. In this study we evaluated the effectiveness of an N-vinylcaprolactam-acrylamide copolymer (NVAM) in inhibiting the corrosion of stainless steel in a 3.5% NaCl solution saturated with CO2 and containing 100 ppm H2S, which simulates a sweet/sour corrosive environment typical of oilfields Several experimental methods, such as weight loss, electrochemical techniques and surface characterization methodologies (SEM, EDS, & AFM) were used to assess the inhibitor's efficacy. The inhibitor demonstrated remarkable performance, attaining an approximately 90 % inhibition efficiency at a 100 ppm concentration. Adsorption of Poly(NVAM) adhered to the Langmuir adsorption model and functioned primarily as a cathodic inhibitor. The results obtained from the analysis of SEM, EDS, and AFM indicate that poly(NVAM) forms a protective film on the surface of the steel, thereby impeding the access of corrosive species. The protective film efficiently prevented corrosive chemicals from reaching the steel's surface.

Leakage Quantification in Metallic Pipes under Different Corrosion Exposure Times

The combined effects of aqueous corrosion, stress factors, and seeded cracks on leakage in cast iron pipes have not been thoroughly examined due to the complexity and difficulty in predicting their interactions. This study seeks to address this gap by investigating the interdependencies between corrosion, stress, and cracks in cast iron pipes to optimise the material selection and design in corrosive environments. Leakage experiments were conducted under simulated localised corrosive conditions and internal pressure, revealing that leakage increased from 0 to 25 mL with crack sizes of 0.5 mm, 0.8 mm, 1 mm, and 1.2 mm, along with corrosion times of 0, 120, 160, and 200 h, and varying stress levels. An empirical model was developed using a curve-fitting approach to map the relationships among corrosion time, crack propagation, and leakage amount. The results demonstrate that the interaction between corrosion, stress, and crack propagation was complex and nonlinear, and the leakage amount increased from 0.7 to 0.10 mm every 15 min, as evidenced by SEM microstructure images and empirical data.

Research on Extrusion Texture and Pitting Corrosion of D16T Drill Pipe in 3.5% KCl Solution

Research on Extrusion Texture and Pitting Corrosion of D16T Drill Pipe in 3.5% KCl Solution

Internal pipe corrosion assessment method in water distribution system using ultrasound and convolutional neural networks

Internal pipe corrosion within water distribution systems leads to iron oxide deposits on pipe walls, potentially contaminating the water supply. Consuming iron oxide-contaminated water can cause significant health issues such as gastrointestinal infections, dermatological problems, and lymph node complications. Therefore, non-destructive and continuous monitoring of pipe corrosion is imperative for water sustainability initiatives. This study introduces a dual-mode methodology utilizing advanced ultrasound technology and convolutional neural networks (CNN) to quantify pipe corrosion. Scanning acoustic microscopy (SAM) employs high-frequency ultrasound to generate high-resolution images of pipe thickness, indicating iron oxide accumulation. SAM also captures internal pipe data to measure iron oxide concentration in the water. This data, analyzed by CNN, achieves an impressive 95% accuracy. This dual-mode system effectively assesses both the extent of pipe corrosion and water contamination, exemplifying the successful integration of SAM and CNN for precise and reliable monitoring.

A numerical analysis of the mechano-electrochemical effects on localised corrosion in pipelines using a multi-physical field coupling approach

In this study, we used a multi-physics coupling approach integrating the electrochemical and solid mechanics fields to develop a three-dimensional finite element model. This model was specifically designed to investigate the effects of mechano-electrochemical (M-E) effects on pipeline corrosion. The boundary conditions for the finite element simulation were established using experimental data, enabling the model to effectively predict the corrosion potential and current density, which aligned well with the experimental findings. Subsequently, the validated model was applied to examine the M-E effects near the pipe corrosion defects, considering various depths of corrosion defects and axial strain. Our results indicate that the stress concentration at the core of the defect increases with increasing axial tensile strain and deepening corrosion. The investigation of the correlation between the corrosion potential and net current density revealed that mechanical forces significantly impact metal corrosion rates, thus influencing pipeline longevity. When the metal structure of the pipeline is deformed within the elastic deformation range, the impact of the M-E effects on corrosion is minimal. However, when a tensile strain is applied or the defect geometry induces plastic deformation at the defect site, a notable increase in the local corrosion activity is observed.

Optimizing the number, locations, and chlorine dosages of booster chlorination stations in water distribution networks

ABSTRACT Safe and reliable drinking water is essential for sustaining life. Chlorination is widely used for disinfection in water distribution networks (WDNs). A higher dose of chlorine is required in an overhead service reservoir to maintain minimum residual chlorine at the farthest end in WDNs. However, delivering high dosages of chlorine from storage tanks can pose public health issues, especially for the residents living near overhead service reservoirs due to the formation of trihalomethanes, haloacetic acids, and chlorophenols. In addition, a higher dosage will lead to increased chlorine consumption and will accelerate pipe corrosion. Booster chlorination (BC) stations with smaller dosages are a solution to this problem. However, identifying the optimal number, locations, and dosage of each BC station in a cost-effective manner is challenging. This study proposes a methodology for determining the optimal number, locations, and chlorine dosages of BC stations in WDNs using a mixed integer linear programming problem. The methodology is illustrated through a simplified WDN in Holeta town, Ethiopia. The results indicate that if one adds two BC stations beyond the three dosage stations at the source, it will lead to a 49% reduction in chlorine use and a 27% decrease in the life cycle cost.

Investigation of Garcinia kola Exudates as Corrosion Inhibitor for Mild Steel in Acidic Environment

This study investigated the performance of Garcinia kola exudates in preventing mild steel exposed to acid concentrated water and soil. The study was performed in order to find an alternative coating substance that can reduce the corrosion of mild steel pipes exposed to corrosive water and soil media. Various mild steel specimens were cut into portions and coated with the exudates at 25 - 50µm thickness. To accelerate the rate of corrosion, 0.5M hydrochloric acid (HCl) was added to tap water in a container. Also, the same concentration of HCl was equally added to soil samples. Uncoated mild steel specimens were immersed in the acid concentrated water and soil, servicing as control sample. The rate of corrosion was monitored for 30 days (720 hours). The inhibition efficiency of the exudates for both corrosive media was compared. Results showed that the weight loss and corrosion rate of mild steel decreased with increase in coating thickness. Comparatively, weight loss and corrosion rate in the uncoated specimens were higher than the coated specimens. For uncoated specimens, the corrosion rate was 0.2793mm/yr and 0.4150mm/yr for specimen immersed in water and soil respectively, but at 25µm coating thickness, it decreased to 0.01369mm/yr and 0.2870mm/yr for specimens in water and soil. Also, at 50µm coating thickness, corrosion rate decreased to 0.0052mm/yr and 0.0318mm/yr for specimens in water and soil, respectively. The inhibition efficiency increased with coating thickness, ranging from 51.00 – 98.15% for specimens immersed in water and 30.84 – 92.33% for specimens buried in soil at 25µm – 50µm coating thickness. The results demonstrated that Garcinia kola exudates can be used as corrosion inhibitor for mild steel exposed to corrosive media.

Cement-mortar lining failure and metal release caused by electrochemical corrosion of ductile iron pipes in drinking water distribution systems

The electrochemical corrosion of ductile pipes (DPs) in drinking water distribution systems (DWDS) has a crucial impact on cement-mortar lining (CML) failure and metal release, potentially leading to drinking water quality deterioration and posing a risk to public health. An in-situ scanning vibrating electrode technique (SVET) with micron-scale resolution, microscopic scale detection and water quality analysis were used to investigate the corrosion behavior and metal release from DPs throughout the whole CML failure process. Metal pollutants release occurred at three different stages of CML failure process, and there are potential risks of water quality deterioration exceeding the maximum allowable levels set by national standards in the partial failure stage and lining peeling stage. Furthermore, the effects of water chemistry (Cl−, SO42−, NO3−, and Ca2+) on corrosion scale growth and iron release activity, were investigated during the CML partial failure stage. Results showed that the CML failure process in DPs was accelerated by the autocatalysis of localized corrosion. Cl− was found to damage the uncorroded metal surface, while SO42− mainly dissolved the corrosion scale surface, increasing iron release. Both the oxidation of NO3− and selective sedimentation of Ca2+ were found to enhance the stability of corrosion scales and inhibit iron release.

Corrosion and degradation behavior of bent aluminum and copper pipes for practical use in air conditioning

Corrosion and degradation behavior of bent aluminum and copper pipes for practical use in air conditioning

Effect of immersion time on bacterial community structure and sulfur metabolism in biofilm on concrete surface in sewer environment

This study focuses on an overlooked but critical issue: the composition and functional expression of microbial communities on the concrete surface in different areas of sewer pipes. Three immersion conditions were applied to simulate the duration of concrete in different areas ofsewers exposed to sewage, including short-term (L1), long-term (L2) and permanent immersion (L3). The properties of concrete under different immersion conditions and the bacterial diversity and functional capabilities in biofilms on the concrete surface were analyzed. Results showed that the L1 group was dominated by Halothiobacillus, whereas Desulfomicrobium was prominent in the L3 group. Significant differences in the predominant functional microbial communities and metabolic functional genes further confirmed the strong impact of immersion time on the pathways of microbial sulfur metabolism and concrete performance in sewer environment. Compared with the L2 and L3 groups, the decreased sewage immersion time resulted in an increase in the abundance and metabolic activity of sulfur-oxidizing bacteria in the L1 group. Hence, greater mass loss and gypsum production of concrete was found in the L1 group. The structural and functional differentiation of bacterial communities on the concrete surface observed in this study contributes to a better understanding of the uneven corrosion in real sewer pipes.

A comprehensive literature mining and machine learning to decipher and predict effects of concrete materials on concrete corrosion of sewer pipe

ABSTRACT The concrete composition of different pipelines varies greatly, and a comprehensive analysis of the impact of concrete design on pipeline corrosion is required. Developed an integrated model based on Scikit-Optimize, XGBoost and SHAP to analyze concrete’s carbonation and sulfuric acid resistance from five aspects: binder type, supplementary cementitious material (SCM’s), aggregate, admixture and w/b. Choose Scikit-Optimize for parameter optimization. As an explanation model, the SHAP model can perform analysis well and explain the analysis basis of the XGBoost training model. The established model can accurately predict the corrosion effect (R2 >0.987) without overfitting. Binder should be maintained at 380 to 400 (kg/m3). Water/binder and coarse aggregate/binder are the two main factors that influence the binder, and they should be maintained at a ratio of around 0.4 to 0.6 and 2.5, respectively. Fly ash (FA) should be SCM’s used as at a range of 300 to 350 (kg/m3) to improve corrosion resistance.