Effect Of Corrosion Research Articles

Effect of corrosion on bond between reinforcement and concrete-an experimental study

The presence of cracks in concrete structures can lead to corrosion as it exposes the steel reinforcement to environmental factors. When moisture and oxygen reach the steel, corrosion weakens the bond between the steel and the surrounding concrete. This weakening can reduce the load-carrying capacity and, in severe cases, lead to failure. Understanding the relationship between corrosion and bond strength is vital for reinforced concrete structures. This paper investigates the impact of corrosion on bond strength in reinforced concrete structures by examining the bond performance of concrete with both corroded and uncorroded reinforcement bars. The study considers concrete grades M20, M25, and M30, as well as corrosion levels varying from 0 to 20% in intervals of 5%. To conduct the study, cylindrical samples with different levels of corrosion were created using the corrosion acceleration process with the impressed current technique. Pull-out tests were then carried out to determine the bond-slip relationship and the degradation of bond strength due to corrosion. The test results show that lower-grade concrete (M20) experiences a significant decrease in bond strength compared to higher grades (M25 and M30), with M20 showing a 30.7% reduction and M25 showing a 25.8% reduction in bond strength relative to M30 in controlled specimens. The bond stress-slip relationship reveals a non-linear response, with reduced bond stress and slips for all grades of concrete as corrosion levels increase. Additionally, the reduction in bar diameter due to corrosion ranged from 11.3 to 11.6 mm at 5% corrosion and from 9.4 to 9.7 mm at 20% corrosion, significantly impacting the load-carrying capacity of the reinforced concrete structures. These findings underscore the importance of considering concrete grade and corrosion levels when assessing and maintaining bond performance in reinforced concrete structures.

Evaluation of N80 Carbon Steel Corrosion in 15 wt.% HCl Using Isatin-hydrazones: A Comprehensive Approach with Chemical, Electrochemical Techniques, and DFTB Calculations

The adverse effects of corrosion on industrial metals, particularly N80 carbon steel under acidic conditions, call for developing effective corrosion inhibitors. Due to their structural and electrical properties, isatine-hydrazones have emerged as possible corrosion inhibitors. This study investigates the corrosion inhibition capabilities of two specific Isatin-hydrazones, (E)-1-octyl-3-(2-(5-oxo-4,4-diphenyl)-4,5-dihydro-1H-imidazol-2-yl)hydrazono)indolin-2-one (OPHIHI) and (E)-3-(2-(5-oxo-4,4-diphenyl)-4,5-dihydro-1H-imidazol-2-yl)hydrazono)indolin-2-one (OIHIHI), on N80 carbon steel in a highly acidic medium. The study assessed the corrosion inhibition efficacy of OIHIHI and OPHIHI using both computational and experimental approaches. Weight loss measurements, potentiodynamic polarization, and electrochemical impedance spectroscopy were used in the experiments. In contrast, density functional theory (DFT), molecular dynamics (MD), and tight-binding density functional theory (DFTB) were used in the computational analyses to elucidate the interaction mechanisms between the inhibitors and metal surfaces. The experiment demonstrated that both OPHIHI and OIHIHI effectively reduce corrosion rates in a 15 wt.% HCl solution at 303 K, achieving an inhibition efficiency of 96 % and 92 %, respectively, at an optimal 5 × 10−3 mol/L concentration. These inhibitors were discovered to form protective layers on the N80 carbon steel surface, offering mixed protective qualities (cathodic and anodic protection) with a preponderance of cathodic protection against carbon steel corrosion in 15 wt.% HCl. Computational studies supported the experiment's findings by demonstrating that isatin-hydrazones' superior electronic properties enabled them to form robust covalent bonds with the Fe (110) surface. Based on these results, OPHIHI and OIHIHI could be used as corrosion inhibitors in the oil and gas industry, particularly under highly acidic conditions.

Biomass Derived Self-Doped Carbon Nanosheets Enable Robust Hole Transport Layers with Ion Buffer for Perovskite Solar Cells.

The diffusion of iodine species and lead leakage during device degradation represent the main obstacles restricting the commercial application of perovskite solar cells (PSCs). Cobalt loaded ultrathin carbon nanosheets (Co(III)-CNS) derived from biomass are prepared as ion buffer material to construct robust hole transport layers (HTLs). The carbon nanosheets containing trivalent cobalt ions can facilitate the oxidation of the hole transport material while preserving the structural integrity and electrical properties of HTLs under thermal stress, thereby ensuring efficient carrier transport. The two-dimensional ultrathin graphitized lamellar structure of Co(III)-CNS is conducive to alleviate the corrosive effects of the outward diffusion of iodine species on HTLs and silver electrodes, while avoiding irreversible degradation of PSCs. With the improvement of HTL composition and the related interfaces, Co(III)-CNS doped devices can maintain intact device structure under thermal stress and remain above 80% of the original power conversion efficiency (PCE) after thermal aging at 85 oC for 720 h. Notably, the chemical interactions between heteroatoms of self-doped carbon nanosheets and the mobile lead ions can effectively alleviate lead leakage and avoid the potential impacts of device degradation on ecosystem. Ultimately, the Co(III)-CNS doped PSCs with enhanced thermal stability exhibit a champion PCE of 22.32%.

Experimental research of corroded concrete beams with natural cooling after fire considering the bond deterioration

The residual bearing capacity after fire is of great significance for safety assessment and repair of building structures. To accurately evaluate the residual strength of corroded beam after natural cooling, this study investigated the residual bearing capacity of corroded beam considering the bond deterioration after fire exposure. First, the bond behavior and flexural-deformation capacity was conducted by pullout test and bending test after corrosion erosion and fire temperatures damage. The bond deterioration test shows that when the temperature rises above 200℃ and the corrosion level exceeds 4.3%, the bond strength decreases by 16.5%. At the temperature reaches 600℃ or the corrosion degree reaches 13.8%, the bond behavior damage exceeds 50%. The bending test indicates that corrosion and high temperature damage both decrease the bending bearing capacity of the beam, but the influence of high temperature damage on the residual bearing capacity is greater than that of corrosion. The bond property deterioration decreases the strain value of the tensile rebar during the bending process, and decreases the bending capacity of the beam. Finally, a bond-slip constitutive model suitable for corroded beams after fire is proposed, which is applied to the calculation of the ultimate moment of the beam. The modified value of beam bearing capacity considering bond deterioration has better collimation and higher safety margin. The bond-slip constitutive model and the modified calculation method of bending moment of beam are helpful to provide more accurate performance assessment of beam after the coupling effect of corrosion and fire damage.

Corrosion Resistance Improvement of Mild Steel

Abstract Corrosion’s devastating consequences have become a big issue all over the world. One of the corrosion damage aspects are related to decontamination solutions which are essential for rapid degradation of toxic agents. The decontamination solutions should be non-corrosive to avoid deterioration of steel container. Decontamination solutions comprising have high chlorinating activity so they have a corrosive effect on mild which are used in fabrication of storage tanks. In this case, using inhibitors is one of the most effective strategies to limit the rate of corrosion. This work describes the effect of different compounds; (zinc chromate, cinnamaldehyde, sodium tripolyphosphate, zinc ortho-phosphate, ammonium molybdate and thiourea) on the rate of corrosion of mild steel within dichloroisocyanuric acid decontamination solution. Meanwhile, these inhibitors should not affect active chlorine content which is responsible for the decontamination process. By using kelthoff and AquaChec® methods for measuring active chlorine, it was found that only zinc chromate passed the tests. For measuring electrochemical behaviour of mild steel in decontamination solutions, different techniques were used. Zinc chromate inhibition on mild steel in a 0.5% dichloroisocyanuric acid solution at different temperatures (298–313 K) were studied utilising electrochemical impedance spectroscopy, weight loss, and potentiodynamic polarisation. The results reveal that zinc chromate is an excellent mild steel corrosion inhibitor in dichloroisocyanuric acid, with an inhibition efficacy of 96% at a concentration of 0.005 M. Finally, surface morphology of mild was also investigated using SEM.

Microbiological evaluation of ultraviolet C light-emitting diodes for disinfection of medical instruments

BackgroundDespite the many guidelines for reprocessing of medical instruments, challenges persist such as microbial resistance to biocides, corrosive effects on materials, and time-consuming reprocessing procedures. Ultraviolet (UV) C light-emitting diode (LED) chambers might provide a solution but the integration in healthcare is still in its infancy. Here, we evaluated the efficacy of a novel ZAPARAY™ UVC LED chamber as a time and energy-efficient alternative for reprocessing of medical instruments for which current disinfection protocols exhibit limitations. MethodsWe verified the disinfection efficacy of the UVC LED chamber on a Petri dish and contaminated several medical devices with Staphylococcus aureus ATCC 25923. The bacterial reduction was assessed after 5 min of UVC LED exposure. Additionally, we investigated the impact of rinsing before UVC exposure. ResultsWe demonstrated a bacterial reduction of 9 log10 on a Petri dish. Non-rinsed dental tools exhibited varied reduction levels ranging from a 3.23 log10 to a 6.25 log10 reduction. Rinsing alone yielded an average reduction of 2.7 log10 and additional UVC exposure further reduced the bacterial load by an average of 3.65 log10. We showed an average 4.90 log10 reduction on thermistors, 2 log10 or less on orthodontic pliers, and no reduction on handpieces. ConclusionsThis study demonstrates that UVC LED chambers may be used as a standardized substitute for specific (manual) disinfection procedures of certain medical devices, offering a time-efficient and more sustainable alternative. However, its use should be preceded by efficacy testing for each specific type of instrument.

Effect of temperature and oxidative atmosphere on the oxidation behavior of yttrium-containing ceramics

Yttrium-containing ceramics exhibit excellent resistance to water-oxygen corrosion, making them an attractive choice as the modified matrix for SiCf/SiC composites. However, the oxidation products of yttrium-containing ceramics are complex and vary widely in performance. In this study, YSOC ceramics, which are composed of yttrium silicate, SiO2, and SiC, were prepared using Y2O3, SiO2, SiC, and Li2CO3. This research investigated the effects of high temperatures, air oxidation, and water-oxygen corrosion on the phase compositions of YSOC ceramics. The influence of environmental factors on the synthesis and decomposition of yttrium silicate was analyzed. Moreover, the study explored the compatibility of different oxidation products with SiC. The results suggest that Y2SiO5 and Y2Si2O7 are formed through the low eutectic of SiO2, Y2O3, and Li2CO3. The high SiO2 content likely contributes to the relatively low formation temperature of Y2Si2O7. In the oxidizing environment, Y2SiO5 reacts with SiO2 to produce Y2Si2O7. Conversely, in the water vapor-containing atmosphere, Y2Si2O7 undergoes hydrolysis to form Y2SiO5. Y2Si2O7 displays a reduced elastic modulus in comparison to SiC fibers and exhibits favorable physical and chemical compatibility with SiC fibers. However, the hydrolysis of Y2Si2O7 may potentially affect the water-oxygen corrosion resistance of the ceramics. These findings will significantly advance research and enhance understanding of the water-oxygen corrosion behaviors of yttrium-containing matrix-modified composites.

Corrosion study and microscopic analysis of X65 specimen by sulfate reducing bacteria

Abstract In this work, the corrosion effects of seawater and production water on X65 specimens with or without bacteria were studied, and weight loss analysis, scanning electron microscopy analysis, EDXA analysis, fluorescence analysis and bacterial content analysis were carried out. The results show that seawater corrosion of X65 is greater than production water. Compared with the sterilized water sample, the SRB in the bacterialized water sample slightly promoted the corrosion of X65, but the promotion effect of SRB on the corrosion of X65 within 7 days was rather limited. The high pressure or high temperature environment is not conducive to the growth and reproduction of SRB, and the remaining small amount of SRB promotes the development of surface pitting of X65 test pieces.

Parenting a New Moral Panic: Anti-Queer Digital Activism and Reactionary Media Ecologies

This article looks at the appropriation of cancel-culture activism by anti-queer parental rights activists online. By examining their digitally mediated anti-queer rhetoric, this paper studies how these activists drive public outrage to promote cultural censorship. Surveying digital campaigns by Libs of TikTok and Moms for Liberty, this paper analyzes how their media amplifies “grooming” and “pedophilia” discourses to dynamize older anti-queer stereotypes. Drawing upon the language of child protectionism from 1970s educational debates, this mediated rhetoric demonstrates how anti-queer activists have appropriated the social justice origins of cancel-culture online. By using social media to frame conservative activists as marginalized, these campaigns invert the history of anti-LGBTQ+ media and educational environments to rationalize anti-LGBTQ+ censorship. By looking at how this rhetoric flows from social media into conservative TV journalism, this paper uncovers how this digital activism shapes a broader reactionary media ecology with corrosive democratic effects in the United States.

Numerical Modeling of Uniaxial Corroded Reinforced Concrete Columns Exposed to Fire

Corroded concrete structures remain at risk of fire damage throughout their lifespan. This study explores the fire resistance of reinforced concrete columns, considering the simultaneous impact of corrosion and high temperatures. Thermal–structural models of the corroded concrete columns are developed using SAFIR software (2022). The numerical results are compared with published test data on temperature distributions and axial displacement–time curves. Then, parametric analyses are conducted to investigate the influence of various factors, such as corrosion degree, concrete compressive strength, cover thickness, and fire exposure models, on the fire performance of the concrete columns. The findings reveal that corrosion significantly undermines fire resistance: notably, columns with severe corrosion exhibited a 47% reduction in fire resistance. Conversely, increased concrete strength can bolster the fire resistance of intact columns, particularly when the concrete cover is minimal. Enhancing the cover thickness proves to be an effective strategy to mitigate the thermal degradation of steel reinforcements, thereby extending the columns’ fire resistance by as much as 23%. The study introduces coefficients to quantify the effects of corrosion, fire exposure, material strength, and cover thickness, culminating in a practical formula to calculate the fire endurance of corroded reinforced concrete columns. This formula could complement existing fire safety regulations.

Dependence of molybdenum content on the cavitation corrosion synergy and wear failure of laser cladded CoCrFeNiMnMo high entropy alloy coatings

The CoCrFeNiMnMo high entropy alloy (HEA) coatings with various Mo contents (0.1, 0.5, 0.8, 1.0 in atomic ratio) were prepared by laser cladding, aiming at determining the optimum Mo content and the effect of Mo on the microstructure and properties of CoCrFeNiMnMox HEA. The synergistic cavitation failure-corrosion impact of the coatings was also studied in 3.5 wt% NaCl solution. Experimental results showed that HEA coatings were only composed of FCC matrix and the grains were refined gradually with the increase of Mo contents. Meanwhile, the corrosion resistance of the coatings increased first and then decreased. The CoCrFeNiMnMo05 possessed the highest corrosion resistance as indicated by the highest polarization resistance, strongest passivation tendency and lowest carrier concentration. The wear resistance of the coatings was significantly higher than that of the substract. The enhanced wear resistance was contributed to the grain refinement and solid solution strengthening. After 8h cavitation failure, the CoCrFeNiMnMo05 showed the lowest mean depth failure of 0.05 μm as it maintains the highest self-healing ability and integrity of passive film during the synergistic effect of cavitation failure and corrosion. In this study, the optimum Mo content was determined and the effect of Mo on the microstructure and properties of CoCrFeNiMnMox HEA was described.

Tribocorrosion in nitric acid of Zr alloy, Ti alloy, and 310 SS used for reprocessing of spent nuclear fuel

The tribocorrosion behavior of the three representative dissolver materials, namely zirconium (Zr) alloy, 310 stainless steel (SS), and titanium (Ti) alloy in HNO3 was systematically investigated by SEM, XPS, and Nanoindentation. The results revealed that Zr alloy possesses high corrosion resistance but a less favorable tribocorrosion resistance, whereas 310 SS presents a comparatively better tribocorrosion resistance but insufficient corrosion resistance. Moreover, both the coefficient of friction and wear loss of all three alloys were decreased at 0.8 V compared to −0.8 V, demonstrating an antagonistic effect of corrosion on wear, attributed to the lubrication and hardness enhancement of oxide layers. The present work offers a new perspective on the tribocorrosion behavior of continuous dissolvers used for reprocessing spent nuclear fuel.

Nonflammable Fluorinated Electrolyte Realizing High Voltage Anode-Free Zn Dual-Ion Batteries.

Due to the low decomposition potential of H2O and its corrosive effect to Zn foil, the Zn metal battery with aqueous electrolytes operates within a narrow electrochemical window and exhibits low anode utilization ratio. Fluorinated carbonate ester, exhibiting low highest occupied molecular orbital (HOMO) energy level, is suitable for constructing high-voltage batteries, yet its application in Zn metal battery has been scarcely explored. Herein, we propose an electrolyte based on fluorinated solvents and ethoxy (pentafluoro) cyclotriphosphazene (PFPN) additive, which exhibits a high decomposition voltage of 2.75 V in Zn batteries. The fluorinated carbonate esters possess non-flammability and exhibit reduced solvation capacity which in turn promotes the incorporation of anions into Zn2+ solvation shell. Consequently, an anion-derived interface layer is formed on Zn anode, aiding the compact and planar growth of deposited Zn. Therefore, the Zn//Zn cell exhibits an impressive Zn utilization of 91% for 140 h, a level seldom reported previously. Benefitting from the oxidation resistant solvents and cathode-electrolyte interface layer formed by PFPN additive, the Zn//graphite dual-ions battery shows an extended cycling life of 1000 cycles. Furthermore, an anode-free cell was constructed and stably operated for 100 cycles, with a notably high average discharge midpoint voltage of 1.84 V.

Experimental study on flexural behavior of corroded post-tensioned T- shaped beam

A comprehensive literature review on pre-stressed concrete beams subjected to corrosion reveals that most experimental studies are on rectangular sections even though T-shaped and box sections are more widely used in engineering practice with post-tensioned prestress, in particular for heavy structures like bridges. In this paper, five post-tensioned T-shaped beams were prepared, four of which were subjected to accelerated corrosion, and then all the beams were subjected to the four-point bending test. Special attention was directed to the cracking propagation and failure patterns, load-deflection, load-strain of concrete and steel strand, ductility and flexural capacity of the test beams. The experimental results show that the flexural behavior of the test beams deteriorates with the corrosion degree of prestressed strands, especially when the corrosion degree exceeds 2 %. When the corrosion degree is 8.42 %, the failure pattern of crushing of compressed concrete is changed to the rupture of the wires. The corrosion effects on the load-strain of steel strands depend on corrosion loss, strand position and loading stress state. Corrosion of steel strands reduces the compressive strain of concrete at the same compression position and the ultimate strain of the prestressed strands at the position of beam end. Finally, a numerical model is proposed, which can provide accurate and effective predictions of the failure pattern and flexural capacity of the corroded post-tensioned T-shaped beam.

Effect of cold expansion on the fatigue life of multi-hole 7075-T6 aluminum alloy structures under the pre-corrosion condition

The multi-hole structures with cold expansion are extensively utilized in the various joint parts of aircraft. However, the synergistic effect of stress concentration and atmospheric corrosion will cause severe deterioration of structural loading capabilities. Thus, it is crucial to investigate the fatigue life degradation mechanism of these structures under pre-corrosion conditions. In this paper, three-hole specimens with cold expansion (CE) and non-cold expansion (NCE) were used to investigate the effect of cold expansion on the fatigue performance of multi-hole structures of 7075-T6 aluminum alloy under pre-corrosion conditions. The life degradation law and damage mechanism of these two types of specimens under pre-corrosion conditions were analyzed. Furthermore, the cold expansion strengthening factor was proposed through the curve-fitting of the fatigue life attenuation ratio of these two types of specimens. Finally, a competition mechanism for the contribution ratio to the final fracture of the specimens in corrosive environments was proposed based on the SEM morphology analysis of the fatigue fracture of the specimens.

Seawater submersion for cylindrical lithium-ion batteries thermal runaway prevention

Lithium-ion batteries (LIBs) are currently used in various electric vehicles, including electric boats. To assess the risk of fire due to thermal runaway of the LIB during the operation of ferries, seawater can be used as a cooling fluid for the LIB to prevent thermal runaway as it is abundant. However, the seawater could corrode the electrodes of the battery, which would lead to toxic wastewater. Prevention of thermal runaway of lithium-ion batteries by submersion in seawater needs to be investigated to clarify the corrosion that could lead to toxic wastewater. In this study, fully charged, pristine 18650 NMC Li-ion cells were submerged in synthetic seawater (SSW) to investigate the corrosion effect compared to deionized (DI) water. The results showed that SSW induced rapid voltage discharge, leading to corrosion on the electrodes and toxic effluents, while DI water maintained the stability of the cells and did not cause any corrosion effect. In addition, the prevention of thermal runaway was investigated by exposing fully charged LIB to extreme overheating conditions. The liquid submersion system was activated by rapid voltage drop monitoring to evaluate its effectiveness in preventing thermal runaway (TR). The investigation of TR prevention by SSW submersion showed that the TR process can be effectively prevented. In addition, no corrosion effect was observed during submersion in SSW as the battery voltage was not applied. This study shows that seawater can be used to prevent TR in LIB and does not cause environmental problems comparable to water.

Investigating corrosion-induced deterioration in bolted steel plate joints using guided wave ultrasonic inspection

AbstractBolted steel plate joints encounter challenges posed by joint corrosion, which impact the quality of interfacial contact among the bolted components. Unfortunately, no correlation between corrosion-induced joint damage and preload, nor an existing numerical model capable of capturing such effects, has been identified. This study aims to utilize guided wave ultrasonic investigation to examine the deterioration of interfacial contact caused by corrosion in bolted joints. Additionally, a contact modification-based numerical approach is presented to capture the effects of changing interfacial stress during joint corrosion. Guided wave mode selection was conducted with some preliminary experiments supplemented with the theory of wave mode dispersion, hence leading to the selection of S0 and A0 mode existing at 300 kHz. The joint was then corroded in a controlled manner using an electrochemical process while simultaneous ultrasonic measurements were taken. The experimental observations highlighted the progressive dispersion in the transmitted A0 mode across the bolted joint, potentially due to changing interfacial stress boundaries between the plates. A damage parameter, termed the dispersion index, was developed based on the energy ratio of different signal sections. A linear change in the dispersion index was observed with the increase in corrosion-induced mass loss. The insight was further established through a numerical investigation by studying the effect of changing bolt preload and the corresponding interfacial stress distribution. The findings revealed that monitoring the changes in the stress distribution at the bolted interface can provide insight into interfacial corrosion. Eventually, destructive tension test results confirmed the effect of joint corrosion on the load-bearing capacity of the joint. The change in failure mode of the pristine and corroded specimen is observed. The reported approach establishes the potential of ultrasonic inspection to investigate the interfacial health of a bolted joint in corroding conditions.

Polyoxometalate-Ionic Liquids for Mitigating the Effects of Iron Gall Ink Corrosion on Cellulosic Supports.

Iron gall ink (IGI), renowned for its indelibility, was the most important writing ink in the Western world from the 15th to the late 19th century. However, it is now known that IGIs induce acid-catalyzed hydrolysis and iron-catalyzed oxidation of the cellulose in historical paper documents. These mechanisms of deterioration cause significant damage to the writing support materials, including color alteration and burn-through appearance, and in the worst scenarios, physical disintegration of the supports. Minimally invasive, long-term effective conservation treatments that tackle the underlying mechanisms of IGI degradation and their corrosion effects are yet to be developed. This study introduces the deployment of hydrophobic and anticorrosive polyoxometalate-ionic liquids (POM-ILs) as colorless coatings to counteract IGI-corrosion of cellulosic supports. Model IGI-containing papers (mockups) were prepared, coated with POM-ILs, and artificially aged to assess the compatibility of POM-ILs with IGI-containing documents. Comprehensive monitoring using colorimetric and scanning electron microscopy-energy-dispersive X-ray spectroscopy (SEM/EDS) analyses showed minimal interference with the aesthetic properties and morphology of the IGI mockups. In addition, polyoxometalates (POMs) with vacant metal atom sites in the cluster shell can be used to coordinate free transition metal ions. The ability of a monolacunary Keggin-type polyoxotungstate to coordinate free Fe(II) from IGI solution was demonstrated using UV-vis analysis. This led to the formation of a dimeric species, [(SiW11O39Fe)2O]K12·28H2O, which was characterized by single-crystal X-ray diffraction. Altogether, this study points to POM-ILs as promising protective coatings for effectively preserving historical IGI-written heritage.

Prediction model for the bond behaviour of low-corrosion reinforced concrete considering corrosion time variability

Corrosion greatly affects the bond behaviour of reinforced concrete. In the case of reinforcing low-corrosion reinforced concrete, the bond strength of steel bars and concrete is at an enhanced stage. Accurate prediction of bond behaviour at this stage is crucial for the rational reinforcement. This study designed ten groups, totalling 30 pull-out specimens, were accelerated corroded with various current densities and electrification times. Through 3D scanning and image analysis technology, we observed that increasing the current density yielded less homogeneous corrosion, creating pit-like rust marks. Meanwhile, we developed a model for predicting the corrosion level. The model is applicable to the corrosion level design of accelerated corrosion. Pull-out tests showed that as corrosion increased, the specimen failure mode changed from pull-out to splitting and back to pull-out, with the bond strength first increasing and then decreasing. A bond-slip prediction model for corroded reinforced concrete was also established, considering the effects of corrosion on bond strength in different stages, especially the enhancement stage. The model performs well in predicting the bond behaviour of low-corrosion reinforced concrete and can be used in conjunction with corrosion prediction models and provides guidance for reinforcement.

True-triaxial strength characteristics of cement stone subjected to sulfuric acid corrosion: An experimental and theoretical study

True triaxial tests were conducted to investigate the effect of sulfuric acid corrosion on the true triaxial strength of cement stone under different acid immersion times, including the common loading path and novel loading path with constant Lode angle. The chemical composition and microstructure of cement stone under different acid immersion times (0, 7, 14, and 28 d) were examined via X-ray diffraction and scanning electron microscopy. As the duration of acid immersion increases, the concentrations of portlandite (Ca(OH)2) and calcium silicate hydrate (C-S-H) within the cement stone exhibit a gradual decline, while the presence of calcium sulfate (CaSO4) progressively rises. The microstructure of the cement stone was primarily affected by two factors: the damaging and strengthening effects of sulfuric acid and CaSO4, respectively. The damaging effects of the acid were dominant for days 0–14 of immersion, with continuous increase in microstructure damage. Subsequently, the strengthening effect of CaSO4 became apparent for days 14–28 of immersion, with continuous improvement in microstructure integrity. Consequently, the strength of cement stone exhibited a diminishing trend during the initial immersion period of 0–14 days, followed by an enhancement in strength from 14 to 28 days of immersion. Furthermore, a three-dimensional strength criterion was proposed by combining the Hoek–Brown and Matsuoka–Nakai criteria. The failure envelope first shrank and then expanded with increasing immersion time, accurately describing the variation in strength in the three-dimensional principal stress space.