Core-sheath Structure Research Articles

Fibrous Conductive Metallogels with Hybrid Electron/Ion Networks for Boosted Extreme Sensitivity and High Linearity Strain Sensor.

Fibrous strain sensing materials with both high sensitivity and high linearity are of significant importance for wearable sensors, yet they still face great challenges. Herein, a photo-spun reaction encapsulation strategy is proposed for the continuous fabrication of fibrous strain sensor materials (AMGF) with a core-sheath structure. Metallogels (MOGs) formed by bacterial cellulose (BC) nanofibers and Ag nanoparticles (AgNPs), and thermoplastic elastomers (TPE) are employed as the core and sheath, respectively. The in situ ultraviolet light reduction of Ag+ ensured AgNPs to maintain the interconnections between the BC nanofibers and form electron conductive networks (0.31 S m-1 ). Under applied strain, the BC nanofibers experience separation, bringing AMGF a high sensitivity (gauge factor 4.36). The concentration of free ions in the MOGs uniformly varies with applied deformation, endowing AMGF with high linearity and a goodness-of-fit of 0.98. The sheath TPE provided AMGF sensor with stable working life (>10000 s). Furthermore, the AMGF sensors are demonstrated to monitor complex deformations of the dummy joints in real-time as a wearable sensor. Therefore, the fibrous hybrid conductive network fibers fabricated via the photo-spun reaction encapsulation strategy provide a new route for addressing the challenge of achieving both high sensitivity and high linearity.

Transparent core-sheath composite fibers as flexible temperature sensor based on liquid crystal color change for smart sportswear

The characteristic of color changes in response to external temperature stimuli has made thermochromic fibers a subject of widespread research interest. However, for practical applications, improvements are still needed in terms of color rendering and the prevention of temperature-sensitive material leakage. This study utilized an optimized thermally induced coaxial dry spinning process to prepare a transparent temperature sensing fiber (PCCF) with a core-sheath structure. The sheath layer and the core layer of the PCCF were polydimethylsiloxane (PDMS) and cholesteric liquid crystal (CLC), respectively. The high transmittance exhibited by PCCF was attributed to the pellucid PDMS, which quickly cured in oil bath to form a complete core-sheath structure. The research results indicated that PCCF displayed uniform morphology (average diameter ∼539 μm), excellent tensile properties (elongation at break up to 183 %), as well as good mechanical, thermal, and sweat resistance stability. In addition, the PCCF showed a colorful variation of hues including yellow, green, blue and purple at a very narrow temperature change from 34 °C to 38 °C, attributing to that the molecular pitch was altered to selectively reflect visible light when the CLC was stimulated by temperature. Meanwhile, high sensitivity and short response time were obtained. When the PCCF was directly integrated into sportswear, the remarkable color changes could be observed as the wearer's body temperature increases. PCCF demonstrates a great potential application in smart sportswear and healthcare area.

Study on microwave absorption performance of nickel cobalt bimetallic nanosheet arrays @ hydrophilic carbon cloth composite with core-sheath structure

Magnetic metal/carbon matrix composites have gained significant attention as vital microwave absorption materials (MAMs) in recent years, owing to their multifarious microwave loss mechanisms, adjustable chemical composition, and microstructure. In this study, we describe the successful synthesis of nickel-cobalt bimetallic nanosheet arrays @ hydrophilic carbon cloth (NiCo-BNSAs @ HCC) composites with a distinctive core-sheath structure, low density, and high toughness using a solvothermal method followed by a high-temperature pyrolysis process. Despite their low density and high toughness, these composites exhibit outstanding MA properties at low matching thicknesses. Among them, S2 exhibited the minimum reflection loss (RLmin) of −75.4 dB at 1.35 mm, with its optimal effective absorption bandwidth (EAB, RL＜−10 dB) extending to 3.6 GHz at 1.10 mm. Our analysis indicates that the incorporation of NiCo-BNSAs nanosheets not only enhances the multiple scattering of EM waves but also improves interfacial polarization loss and dipole polarization loss. This study provides valuable insights into the rational construction of high-performance magnetic metal/ carbon matrix MAMs with a core-sheath structure.

Coaxial bioprinting of cellulose nanocrystal-reinforced core-sheath strands for alginate hydrogel construct fabrication

Alginate is among the most popular bioinks for 3D bioprinting because it is biocompatible, biodegradable, and is easily crosslinked using divalent cations. Here, we investigate the addition of cellulose nanocrystals (CNCs) to an alginate-based bioink to strengthen bioprinted structures. Using coaxial 3D bioprinting, alginate strands were constructed with a core-sheath structure reinforced by CNCs within the core. The addition of CNCs resulted in an increase in the storage modulus. Formulations containing CNCs resulted in more stable strands with uniformity factors and printability numbers close to 1. Based on the uniformity factor, the formulations containing 1.5 wt% CNCs deviated the least from a theoretically flawless strand. The alginate strands displayed microporous internal structures that were evident by scanning electron microscopy of the strand cross-sections. The addition of CNCs to the core compartment doubled both the modulus and the tensile strength, and the material was able to resist a strain above 50% before failure, thus demonstrating that the addition of the CNCs to the core of the strand leads to resilient printed structures.

Continuous fabrication of core-sheath fiber for strain sensing and self-powered application

Fiber-based sensor based on the core-sheath structure has drawn increasing attention in the strain sensing and self-powered fields because of its various advantages (e.g., lightweight, small size, flexibility and ease of weavability into soft textile, etc.). However, it still has been challenging to continuously fabricate core-sheath fiber with good interfacial interaction. Herein, a core-sheath fiber was continuously fabricated by melt co-extrusion molding method, whose sheath layer and core layer are respectively pure polystyrene polybutadiene polystyrene (SBS) and SBS/multi-walled carbon nanotubes (SBS/MWCNTs) composite. In view of this, exhibits good compatibility occurs between core layer and sheath layer because they share the same SBS phase. Moreover, with the help of sheath layer, core layer can be effectively prevented the environmental damage. Fiber strain sensor based on such core-sheath fiber exhibits a higher sensitivity (i.e., GF = 106341), wider working range (strain of 0–200 %) and shorter response time (50 ms), which can further perform underwater communication and underwater motion monitoring. Furthermore, based on such core-sheath fiber, fiber triboelectric generator (F-TENG) and textile triboelectric generator (T-TENG) have been successfully developed and they can respectively serve as self-powered bionic whisker (SPBW) and mechanical energy harvester (MEH). This study provides a facile, low-cost, continuous and environmentally friendly method to fabricate core-sheath fiber, paving a new pathway to develop fiber with strain sensing and self-powered sensing performance.

Divergent Deborah number-dependent transition from homogeneity to heterogeneity

Heterogeneous structures are ubiquitous in natural organisms. Native heterogeneous structures inspire many artificial structures that are playing important roles in modern society, while it is challenging to identify the relevant factors in forming these structures due to the complexity of living systems. Here, hybrid hydrogels consisting of flexible polymer networks with embedded stiff cellulose nanocrystals (CNCs) are considered an open system to simulate the generalized formation of heterogeneous core-sheath structures. As the result of the modified air drying process of hybrid hydrogels, the formation of heterogeneous core-sheath structure is found to be correlated to the relative evaporation speed. Specifically, the formation of such heterogeneity in xerogel fibers is found to be correlated with the divergence of Deborah number (De). During the transition of De from large to small values with accompanying morphologies, the turning point is around De = 1. The mechanism can be considered a relative humidity-dependent glass transition behavior. These unique heterogeneous structures play a key role in tuning water permeation and water sorption capacity. Insights into these aspects can prospectively contribute to a better understanding of the native heterogeneous structures for bionics design.

Core-Sheath Fiber-Based Triboelectric Nanogenerators for Energy Harvesting and Self-Powered Straight-Arm Sit-Up Sensing.

Fiber-based triboelectric nanogenerators (F-TENGs), a green and sustainable energy-harvesting and transformation technology, hold great potential in the areas of portable energy harvesters and smart wearable sensors. Herein, the core-sheath structure F-TENGs (CF-TENGs) are developed by using continuous production equipment. The CF-TENGs, consisting of an elastic conductive fiber (core layer) and silicone rubber (sheath layer), can simultaneously accomplish stable reversible strain and excellent electrical output performance. High outputs (an open-circuit voltage of 17.5 V and a short-circuit current of 0.1 μA at a frequency of 1 Hz) can be attained when the CF-TENGs (a length of 5 cm) are contacted with a nylon fabric. The CF-TENGs not only act as self-powered sensors for applications in motion monitoring but also efficiently transfer mechanical energy into electric energy. As self-powered wearable sensors, the CF-TENGs can accurately indicate various human physiological movements. Moreover, they can be applied on straight-arm sit-up sensing to achieve standardized sport testing. Importantly, a CF-TENG-based weaved fabric presents high electrical performance to meet requirements as an energy harvester. These CF-TENGs provide a significant insight to facilitate the development of fiber-based triboelectric applications.

Electrospun core-sheath PCL nanofibers loaded with nHA and simvastatin and their potential bone regeneration applications.

Introduction: Drugs and biocompatible nanoparticles have raised significant potential in advancing the bone regeneration. Electrospinning technology enables the full realization of the value of drugs and nanoparticles. Methods: In this study, we have successfully fabricated core-sheath nanofibers solely composed of polycaprolactone (PCL) polymer. Simvastatin (SIM) was confined to the core of the nanofibers while nanohydroxyapatite (nHA) was loaded on the nanofiber surface. Results: All the prepared nanofibers exhibited a cylindrical micromorphology, and the core-sheath structure was exploited using a Transmission Electron Microscope. X-ray pattern results indicated that SIM was in an amorphous state within nanofibers, while Fourier Transform InfraRed spectroscopy showed excellent chemical compatibility among SIM, nHA, and PCL. The actual loading of nHA within the nanofiber was determined by a thermogravimetric test due to the high melting point of nHA. Core-sheath nanofibers could release SIM for 672h, which was attributed to the core-sheath structure. Furthermore, nanofibers loaded with SIM or nHA had a positive impact on cell proliferation, with the core-sheath nanofibers displaying the most favorable cell proliferation behavior. Discussion: Such a synergistic facilitation strategy based on materials and nanostructure may encourage researchers to exploit new biomedical materials in future.

Formation of various cell-aggregated structures in the core of hydrogel filament using a microfluidic device and its application as an in vitro neuromuscular junction model

Microfluidic systems have been widely used in various in vitro tissue engineering models. In this paper, we present a new microfluidic system for manufacturing cell filaments laden with cell aggregates of various shapes (beads, rosaries, and filaments) in the core region. The structures were obtained using the Rayleigh-Plateau instability of the two-phase flow of the injected bioinks (continuous phase of collagen/poly[ethylene glycol] diacrylate [PEGDA] and a dispersed phase of methacrylated gelatin (GelMA)). To demonstrate the potential of the system at the neuromuscular junction in vitro model, we injected a C2C12-laden collagen/PEGDA bioink into the sheath region and GelMA mixed with motor neuron cells (NSC-34) into the core region of the fabricated cell aggregates. The rosary-shaped NSC-34 aggregate in the core exhibited higher cell viability and more developed neurogenic gene expression than the cell aggregates of beads and filaments in the core region, owing to much greater mechanotransduction. Furthermore, when comparing the cell-laden struts (C2C12 in the sheath region and NSC34 in the rosary core region) with normally bioprinted struts with the same cell density, the expressions of myogenesis-, neuromuscular junction (NMJ)-, and neurogenesis-related genes in struts laden with rosary-shaped cell aggregates were significantly upregulated. The results of these experiments demonstrate the potential for the fabrication of new cell-laden core-sheath structures, which could be used for designing various in vitro models.

Novel smart coaxial electrospinning textiles for efficient thermal interface management and electromagnetic compatibility in electronics

Phase change materials (PCMs) have attracted considerable attention for their energy storage and thermoregulatory properties. However, the solid–liquid leakage, low thermal conductivity, and single functionality of PCMs hinder their applications to electronic equipment. In this study, polyvinyl alcohol (PVA) and polyethylene oxide/ferric oxide (PEO/Fe3O4)-based core–sheath textiles are prepared using an eco-friendly coaxial electrospinning technique and simple steam crosslinking. The composite phase change fibers (CPCFs) and magnetic composite phase change fibers (MCPCFs) produced in this way show ultrahigh encapsulation ratios of 78.02 wt% and 69.11 wt%, respectively, and high phase change enthalpies of 106.96 J g−1 and 94.75 J g−1, respectively. The addition of Fe3O4 (20 wt%) introduces a saturation magnetization of 9.5 emu g−1, thereby realizing 3 dB electromagnetic shielding performance. The textiles exhibit excellent flexibility and can be formed into complex shapes. Owing to their core–sheath structure, the CPCFs and MCPCFs exhibit outstanding structural and thermal stabilities during 100 thermal cycles. Furthermore, the mechanical properties of the CPCF and MCPCF textiles can be enhanced by crosslinking.

Fabrication of Nanocomposites with High Elasticity and Strength for the Load-Bearing Layer of Small-Diameter Vascular Grafts.

Compliance mismatch of commercially available artificial grafts, where the artificial graft and the native vessel are subject to different radial expansions, is a major issue that results in graft occlusion after implantation. A human artery possesses a nonlinear mechanical response to pulsatile pressure due to its nonlinear viscoelastic nature, which is difficult to replicate in artificial graft fabrication. Here, we fabricated nanocomposites with nonlinear mechanical responses for potential application as the load-bearing layer of vascular grafts, based on a poly(dimethylsiloxane) (PDMS)-casted nanofibrous film. The nanofibers consisted of a core-sheath structure with a PDMS elastomer reinforced with poly(methyl methacrylate) (PMMA) nanofibers as the sheath and thermoplastic polyurethane (TPU) elastomer as the core. The surface morphology and chemical composition together with the crystalline structure of the nanocomposites were characterized, and dynamic mechanical analysis was performed to select the graft with the most suitable properties as the load-bearing layer of a small-diameter vascular graft. The presence of the stiff polymer PMMA and elastic polymer TPU in the PMMA/PDMS/TPU combination resulted in a delayed dissipation of energy after exposure to a force corresponding to 180 mm Hg. Casting the PDMS/PMMA/TPU nanofibrous mat into a nanocomposite film improved the ultimate tensile strength of PDMS without compromising its elasticity. The compliance values of the nanocomposites were also found to be a close match to those of the greater saphenous vein, demonstrating a great potential of the nanocomposites as the load-bearing layer in a biostable vascular graft.

Muscular Kevlar aerogel fibers appealing to thermal insulation with a symbiotic core-sheath structure

High-performance aerogels offer a broad application prospect owing to their various features such as high specific surface area and attractive thermal insulation. However, their porous structure confers weak mechanical properties to aerogels. The strategy of coaxial wet-spinning was implemented to strengthen Kevlar aerogel fibers and improve their usability. Prepared Kevlar aerogel fibers have a symbiotic core–sheath structure, with a blurred division between core and sheath. In addition, the breaking stress of Kevlar aerogel fibers can reach 2.6 MPa, which is four times that of the core, presenting a significant improvement in tensile strength compared to those in previous studies. Moreover, Kevlar aerogel fibers exhibit superior thermal stability, which is inherited from Kevlar fibers, and decomposed after 480 °C. Moreover, their high porosity and high specific area (∼400.5 m2·g−1) endow them with outstanding thermal insulation properties. When fabrics woven from these fibers are exposed to a 300 °C hot plate, the temperature on the surface can be 110 °C lower, resulting in a significant temperature gradient of 83 °C·mm−1. In total, the resultant Kevlar aerogel fibers with a symbiotic core–sheath structure are used as fillers for protective clothing or fire insulation blankets and similar items.

Rhombus-patterned flexible self-supported PVDF-based humidity sensor for respiratory monitoring

Humidity sensors are crucial in sectors such as environmental sustainability, industrial production, and healthcare. The fabrication of sandwich-type humidity sensors that can serve as substrates, sensing materials, and electrodes remains a focus of effort in the healthcare sector now. This research entails the synthesis of rhombus-patterned flexible nanofiber membranes (PPZN) utilizing polyvinylidene fluoride (PVDF) and zinc oxide nanoparticles (ZnO NPs) as the foundational substrates, while employing polyvinylpyrrolidone (PVP) as a structural modulator and hydrophilic modifier. The fabrication process involved the utilization of electrospinning technique for membrane production. Furthermore, polyaniline (PANI) is in-situ polymerized onto rhombus-patterned nanofiber membrane to form a core-sheath structure (PPZN), which serves as an electrode to produce a rhombus-patterned flexible self-supported PVDF-based humidity sensor (YPPZN). The combination of hydrophilic and hydrophobic properties facilitates the transfer of water molecules. At the same time, the unique diamond structure and high surface area provide favorable channels for the transportation of water molecules. YPPZN offers a broad range of relative humidity for operation (13%–93% RH), excellent sensitivity, and quick response and recovery times (20s/75s). The YPPZN humidity sensor likewise provides excellent flexibility and dependability, which can be configured into an arch inside a mask for ongoing real-time monitoring of human respiratory parameters.

Hollow Co0.85Se@MoSe2 with Core–Sheath Structures Derived from Co Microchains for High Efficiency Electromagnetic Wave Absorption

Hollow and hierarchical structures are the desirable features for high-performance electromagnetic wave absorbing (EWA) materials. In this study, Co microchains were used as a matrix and a layer of MoSe2 nanosheets and nanospheres was loaded onto their surface through a one-step hydrothermal reaction. During this process, Co cations migrated from the inside to the outside of the nanowire and combined with Se anions to form hollow Co0.85Se microchains and the MoSe2 on the surface contributed to a hierarchical structure. The prepared Co0.85Se@MoSe2 composites showed dielectric and magnetic losses simultaneously, achieving a minimum reflection loss (RLmin) of −42.6 dB and an effective absorbing bandwidth (EAB) of 10 GHz (6.8–10.6 and 11.8–18 GHz) at the thickness of 2.3 mm. Co0.85Se@MoSe2 microchains were successfully synthesized for the first time using a cost-effective and simple solvothermal reaction. This work sheds light on the large-scale synthesis of Co-based microchains as well as a promising EWA material with a specific structure and multiple loss modes.

Nanofibers with an Adjustable Core-Sheath Structure Constructed from Hyperbranched Polyester for Efficient Loading of ZnO Nanoparticles

Loading nanoparticles is a valuable way to construct functional fiber materials, yet the lack of homogeneity and easy agglomeration hinder its functional effect. Hyper-branched polyester (HBPE) has been identified as the ideal delivery vehicle for nanoparticles. Its application in nanofibers can be a promising approach to enhancing the loading efficiency. In this study, adjustable core-sheath structured polyacrylonitrile (PAN)/HBPE nanofibers were fabricated owing to the phase separation of two components during centrifugal spinning, and zinc oxide nanoparticles (ZnO NPs) were further introduced into the sheath. Scanning electron microscopy, transmission electron microscopy, energy-dispersive spectroscopy, and so forth were utilized to characterize the morphology of the obtained nanofibers. Results indicated that the thickness of sheath in PAN/HBPE nanofibers could expand from 33.33 to 57.14% as the mass ratio of PAN/HBPE decreased from 8:2 to 5:5. Additionally, the ZnO NPs were encapsulated and dispersed by HBPE and successfully delivered to the sheath layer of the nanofibers. Therefore, the Zn content on the surface of PAN/HBPE/ZnO NP nanofibers can reach 17.86 wt % with only 6 wt % ZnO NPs doped, representing a 90% increase compared with HBPE-free nanofibers. Besides, the PAN/HBPE/ZnO NP nanofibers exhibited excellent air permeability and qualified biocompatibility, as well as outstanding functional release. The antibacterial rates against Escherichia coli and Staphylococcus aureus reached 96.62 ± 0.34 and 99.55 ± 0.78%, respectively. This facile processing strategy subtly combines the advantages of material and structure, providing insights to better achieve efficient loading of nanoparticles on nanofibers, enabling more researchers to customize functional materials.

Mechanochromic photonic fibers composed of strain responsive colloidal crystals and spandex yarns

Mechanochromic photonic fibers can realize a visual dynamic color response to external stimuli, and are widely used in colorimetric sensing, smart display, and medical care. At present, colloidal crystals-based mechanochromic photonic fibers with a core-sheath structure have been successfully prepared by electrophoretic deposition and dip-coating. However, problems such as the complicated preparation process and the limited range of color change are still unsolved and hinder the applications of mechanochromic photonic fibers. Here, a mechanochromic photonic fiber with a wide color shift range is prepared by a simple and effective strategy. The fiber is fabricated by coating elastic rubber containing a non-close-packed array of silica particles onto spandex yarn. The obtained photonic fiber displays a structural color that can be controlled by adjusting the diameter and volume fraction of silica particles. Under stretching, the fiber shifts from red to blue with a color change range of 127 nm. More importantly, it achieves reversible color change in the visible range under mechanical strain. These mechanochromic photonic fibers based on colloidal crystals and spandex yarns are promising for smart wearables, display textiles, and visual sensors.

Engineered Shellac Beads-on-the-String Fibers Using Triaxial Electrospinning for Improved Colon-Targeted Drug Delivery.

Colon-targeted drug delivery is gradually attracting attention because it can effectively treat colon diseases. Furthermore, electrospun fibers have great potential application value in the field of drug delivery because of their unique external shape and internal structure. In this study, a core layer of hydrophilic polyethylene oxide (PEO) and the anti-colon-cancer drug curcumin (CUR), a middle layer of ethanol, and a sheath layer of the natural pH-sensitive biomaterial shellac were used in a modified triaxial electrospinning process to prepare beads-on-the-string (BOTS) microfibers. A series of characterizations were carried out on the obtained fibers to verify the process-shape/structure-application relationship. The results of scanning electron microscopy and transmission electron microscopy indicated a BOTS shape and core-sheath structure. X-ray diffraction results indicated that the drug in the fibers was in an amorphous form. Infrared spectroscopy revealed the good compatibility of the components in the fibers. In vitro drug release revealed that the BOTS microfibers provide colon-targeted drug delivery and zero-order drug release. Compared to linear cylindrical microfibers, the obtained BOTS microfibers can prevent the leakage of drugs in simulated gastric fluid, and they provide zero-order release in simulated intestinal fluid because the beads in BOTS microfibers can act as drug reservoirs.

Piezoelectric Enhancement of Piezoceramic Nanoparticle-Doped PVDF/PCL Core-Sheath Fibers

Electrospinning is considered to be an efficient method to prepare piezoelectric thin films because of its ability to transform the phase of the polymers. A core-sheath structure can endow fibers with more functions and properties. In this study, fibers with a core-sheath structure were prepared using polyvinylidene fluoride (PVDF) included with nanoparticles (NPs) as the shell layer and polycaprolactone (PCL) as the core layer. Their mechanical and piezoelectric properties were studied in detail. During the course of the electrospinning process, PVDF was demonstrated to increase the amount of its polar phase, with the help of nanoparticles acting as a nucleating agent to facilitate the change. PCL was chosen as a core material because of its good mechanical properties and its compatibility with PVDF. Transmission electron microscope (TEM) assessments revealed that the fibers have a core-sheath structure, and shell layers were loaded with nanoparticles. Mechanical testing showed that the core layer can significantly improve mechanical properties. The XRD patterns of the core-sheath structure fibers indicated the β phase domain the main component. Piezoelectric testing showed that the doped nanoparticles were able to enhance piezoelectric performances. The increases of mechanical and piezoelectric properties of core-sheath structure fibers provide a feasible application for wearable electronics, which require flexibility and good mechanical properties.

A wearable dual-mode strain sensing yarn: Based on the conductive carbon composites and mechanoluminescent layer with core-sheath structures

Yarn or fiber has the advantages of flexible processing, comfortable wearing, good service life, high feasibility of mass production. In recent years, the wearable strain sensor based on yarn or fiber has attracted wide attention. However, most of the previous research work is based on a single electrical signal or energy conversion sensor, which greatly reduces the application range of strain sensor. Therefore, multi-mode sensing under stress application conditions is particularly important promoting the development of new materials. By combining resistive stress sensing with mechanical luminescence sensing, the two-mode strain sensing yarn is prepared and applied in wearable applications. The results show that the tensile strength of core-shell yarn can reach 180% and the surface brightness can reach the visual level. When the carbon concentration in the core yarn is 40%, the corresponding range is small and the resistance increases from 3 MΩ to 5MΩ. The doped luminescent powder has a strong luminescent peak at 578 nm and a small luminescent peak at 493 nm under the action of stress. These properties solve the problem of non-stretching of conductive yarns and can better reflect the magnitude of stress. It also has good application prospects in motion detection, health care, human-computer interaction, artificial intelligence and so on.

Multiple dimension-component designed Co/Co9S8/Ti3C2Tx MXene composite for enhanced microwave absorption

The two-dimensional (2D) transition metal carbide Ti3C2Tx MXene is a potential candidate for efficient electromagnetic wave absorbers due to its excellent intrinsic conductivity and structural machinability. However, Ti3C2Tx MXene also has some problems (such as self-stacking and single loss mechanism) that limit its practical electromagnetic wave absorption. Based on the electromagnetic wave absorption mechanism, electromagnetic responsiveness of absorbers can be modulated by designing the composition and structure. Herein, a 1D/2D Co/Co9S8/Ti3C2Tx composite has been synthesized by assembling 2D Ti3C2Tx MXene with the designed 1D magnetic structure. The 1D Co/Co9S8 was designed as a core-sheath structure that avoids magnetic agglomeration, and the assembly with 2D Ti3C2Tx sheets alleviates the self-stacking problem of Ti3C2Tx MXene sheets. More importantly, the magnetic component enriches the electromagnetic wave dissipation mechanism, and the multiple heterojunction surfaces provide strong polarization loss capability for the Ti3C2Tx MXene-based absorber. Benefiting from the unique structure and dielectric-magnetic synergistic loss, the Co/Co9S8/Ti3C2Tx composite shows an effective absorption bandwidth of 5.36 GHz (10.08–15.44 GHz) at 2.1 mm and the optimal RLmin value of −52.02 dB at 1.8 mm. This work provides an innovative idea for the design of effective Ti3C2Tx MXene-based absorbers.