Copper Oxide Research Articles

Boosting photoelectrochemical water splitting performance via nanostructured Ag-CuO thin films

Undoped and doped copper oxide (CuO) with silver (Ag) was prepared using the SILAR technique on the ITO substrate to generate green hydrogen from the water-splitting process. The (−111) and (111) were the most intense reflections of crystallographic planes observed in pure and Ag-doped CuO thin films. Ag doping within the crystal structure of pristine leads to increasing the crystallite size. FESEM images show homogeneity and uniform distribution for the pure and Ag-doped CuO thin films that confirm the particles have small sizes, give more features and are responsible for the target application. The doping process affected the energy band gap where it was 2.2 eV for the pure sample then descended to 1.9 eV as doping reached 5 % concentration of Ag element. The photoelectrochemical testing showed that the Ag 5 % content photoelectrode has a high value of photocurrent density approximately ∼ - 5 mA/cm2.

Synergistic degradation of toxic azo dyes using Mn-CuO@Biochar: An efficient adsorptive and photocatalytic approach for wastewater treatment

Congo red (CR) and Eriochrome Black T (EBT) is a toxic azo dye with a complex structure which represents a serious Ecotoxicological hazards for aquatic bodies. This research investigates the synergistic effects of Corn plants biochar and manganese (Mn)-composited copper oxide (CuO) in the adsorptive and photocatalytic degradation of toxic anionic dyes i.e. CR and EBT. The acquired materials were characterized by FTIR, XRD, SEM-EDX, XPS, TEM, BET, ZP, and pHZc test. The experiment demonstrated that Mn-CuO@BC composite exhibited a remarkable adsorption of ∼ 98 % and ∼ 95 % and photocatalytic degradation of 92 % and 88 % for CR and EBT respectively. It was further found that coupling of the H2O2 with Mn-CuO@BC enhances the photocatalytic efficiency of catalyst for CR and EBT i.e. upto ∼ 98 % and 96 % respectively possibly owing to the efficient ●OH radical. Adsorption kinetics followed a pseudo 2nd order model, indicating predominant chemisorption, and adsorption isotherms fit well with the Langmuir model. Further, toxicity degradation products of EBT were examined through ECOSAR indicated a reduced ecological impact. In general, this work highlight the dual functional advantages of the Mn-CuO@BC composite, providing an efficient and versatile approach for wastewater treatment involving complex dye pollutants.

Copper-Nickel/SiC composites for applications on contact electrodes

Novel copper-nickel matrix composites reinforced with silicon carbide (SiC) micro particles for metal contact applications were manufactured by powder metallurgy technology and were experimentally characterized. Cu and Cu alloys are commonly used as metal contact for either vacuum, oil, or SF6 in low-voltage circuit breaker devices, but their application in environments with the presence of oxygen is limited due to their tendency to form high-resistance copper oxides. Thus, the addition of Ni as an alloying element provides resistance to both humidity and several corrosive environments and increases the composites' hardness, mechanical strength, and wear resistance. Moreover, SiC was chosen due to its contribution to mechanical strength, mouldability, low production cost, and non-reactive nature at ordinary temperatures. Here, three SiC particle size distributions were considered, and it was found that the composites' physical properties are also dependent on the ceramic loading. After evaluating these properties, two specific SiC concentrations were potentially considered for electrode applications: 10 wt% and 20 wt%. The obtained hardness values are in the range of 55 – 65 HR30T which guarantees the necessary strength without detriment of the contact area whereas the welding is minimized. In addition to a homogeneous particle distribution in the solid material, specific wear resistance of ∼10-5 mm3N-1m-1 and electrical conductivities of ∼20 %IACS were obtained. Considering these parameters, Cu-Ni/SiC composites' performance is not compromised compared to commercial Ag/WC materials commonly used in metal contact applications.

Photodetector application of CuO nanoparticles on porous silicon fabricated by laser ablation in liquid at diverse laser energies

Abstract This paper describes the synthesis and analysis of a photodetector made of copper oxide nanoparticles (CuONPs) embedded in a porous silicon (PS) matrix. CuONPs were generated utilizing pulsed laser ablation in ethanol (PLAL), while a porous silicon-(PS) substrate was created via photo-assisted electrochemical etching. An investigation is conducted on the optical, structural, and electrical characteristics of CuONPs/PS devices, with a focus on their dependence on laser energy. The X-ray diffraction analysis reveals the presence of distinct peaks associated with a copper cubic structure, demonstrating the successful synthesis of CuONPs that have been deposited onto PS. The study using field emission scanning electron microscopy revealed that the particles exhibited spherical form. The CuO-nanocolloids exhibited a linear relationship between laser power and absorption, and their surface plasmon resonance peaks were clearly visible at 570–590 nm. Band gaps of 1.70, 1.61, 1.81, and 1.90 eV were found for CuONPs produced at 500, 600, 700, and 800 mJ of laser energy, respectively, according to the optical characteristics. The greatest responsivity of the CuO-NPs/PS photodetector, manufactured at an energy level of 700 mJ, was 0.135345 A/W at 450 nm, as determined by the optoelectronic characteristics. As a result of combining PS with CuONPs, the devices shown in this work have the ability to function as highly efficient photodetectors.

Diverse energy laser ablation in liquid for indium oxide nanoparticles on porous silicon: enhancing photodetector performance

Abstract The fabrication and analysis of a photodetector using copper oxide nanoparticles (In2O3-NPs) embedded in a porous silicon (PS) structure are detailed in this study. One method used to create In2O3 NPs was pulsed laser ablation in ethanol (PLAL), while another was photo-assisted electrochemical etching to create a porous silicon substrate. The optical, structural, and electrical features of In2O3-NPs/PS devices are investigated, with a particular emphasis on their variations with laser energy. After successfully applying In2O3 nanoparticles onto PS, the X-ray diffraction analysis revealed the presence of distinct peaks that correlate to a copper cubic structure. Using field emission scanning electron microscopy, the researchers determined that the particles had a spherical shape. Absorption increased with increasing laser intensity, and the In2O3-nanocolloids showed clear surface plasmon resonance peaks between 570 and 590 nm in wavelength range. Band gaps of 3.5, 3.4, 3.2, and 3.1 eV were found for the In2O3-NPs generated at 500, 600, 700, and 800 mJ of laser energy, according to the optical properties. According to the optoelectronic properties of the In2O3-NPs/PS photodetector, it was built with an energy level of 700 mJ and had a maximum responsivity of 0.2766 A/W at 650 nm. The In2O3NPs/PS devices discussed in this study have excellent photodetecting performance because they integrate In2O3-NPs with PS.

The impairment of joint tetracycline and copper oxide nanoparticle exposure on activated sludge

The increasing usage of two emerging contaminants (i.e., tetracycline (TET) and copper oxide nanoparticles (CuO-NPs)) has raised wide concerns about their potential impacts on the efficiency of wastewater treatment. However, the joint effects of TET and CuO-NPs on activated sludge processes have rarely been documented. This study investigated the sludge characteristics and bioactivities under both individual and joint exposure to TET (1 mg/L) and CuO-NPs (2 mg/L) for 60 days. The results demonstrated that both individual and joint exposures of TET and CuO-NPs deteriorated the flocculation ability and dewatering of sludge by inducing non-filamentous bacteria. The joint exposure showed higher effects on sludge when compared with individual exposure. Sludge characterization analysis attributed this deterioration partly to the increased extracellular polymeric substance (EPS) secretion (especially loose-bound EPS). In addition, exposure to CuO-NPs would result in an inhibition of total nitrogen removal due to impairment of the denitrification process (i.e., nitrate reductase, nitrous reductase, and electron-transfer associated enzyme), but not for TET. The inhibition of nitrogen removal could be exacerbated when simultaneously exposed to CuO-NPs and TET. 16S rRNA analysis further revealed that the long-term joint exposure to TET and CuO-NPs resulted in a significant decrease in microbial community richness, diversity, and associated functional bacteria abundance. The results of this study suggest that joint exposure to TET and CuO-NPs results in the deterioration of sludge function efficiency.

Degradation of Dyes Using Biologically Synthesized Nanoparticles by Aloe barbadensis Leaves Extract

AbstractNanotechnology has enormous, economic, social, and environmental ramifications. Due to their capacity to survive in complex processes, inorganic nanomaterials like metal/metal oxides have received substantial study during the past decade. Nanoparticles have antibacterial, magnetic, electrical, and catalytic characteristics due to their greater surface area. There are several methods to develop nanoparticles but environment friendly behavior with no toxic byproducts attracts researchers toward biological process of nanoparticles. This work synthesizes copper oxide (CuO) nanoparticles and zinc oxide (ZnO) with Aloe barbadensis (Aloe vera) leaves extract and successfully characterizes them with different analytical techniques. The catalytic activity of such nanoparticles tests over different cationic and anionic dyes like methylene blue (MB), methyl orange (MO), and methyl red (MR) for different intervals of time and reveals. The degradation efficiency of CuO nanoparticles for MB, MO, and MR dyes are 59.92%, 73.48%, and 73.10% respectively, and for ZnO nanoparticles it is 81.44%, 76.46%, and 63.30% for MB, MO, and MR dyes respectively under the exposure of sunlight for 8 h. The present work successfully develops an ecofriendly process of dye degradation by biologically synthesized nanoparticles.

Advancements in CuO nanoparticle technology: synthesis, characterization of copper oxide nanoflowers

Abstract Nanostructured materials, including metal and metal oxide nanoparticles, play a crucial role in advancing diverse scientific and technological areas. Transition metal oxides such as CuO are integral to developments in fields like antibacterial treatments, solar energy conversion, sensing technologies, catalysis, magnetic storage, supercapacitors, and semiconductor devices. This research is centered on the hydrothermal synthesis of pure copper oxide nanoflowers, which are noted for their extensive surface areas. Zeta potential analysis, ultraviolet-visible spectrophotometry, field-emission scanning electron microscopy, and Fourier-transform infrared spectroscopy were some of the methods utilized to characterize these nanoparticles. The results showed that band gap energies, crystallite size, and lattice characteristics are all greatly affected by CuO. XRD results indicated a covellite monoclinic polycrystalline structure predominantly orientation with average crystallite sizes around 15.84 nm. FE-SEM imagery depicted the hierarchical, cauliflower-like structure of the CuO nanoparticles. Optical assessments revealed band gap values ranging from 2.58 eV. The findings underscore the broad potential of CuO nanoflowers across various technological applications.

The Effect of Preparation Conditions on the Characteristics of Anodized Copper Oxide

The Effect of Preparation Conditions on the Characteristics of Anodized Copper Oxide

Sequential DBD plasma-assisted tandem tri-electrodes Fenton process for enhanced antibiotics treatment and denitrification

Ozone generated by dielectric barrier discharge (DBD) plasma has the potential for water treatment; however, its limitations, including water solubility, performance in complex matrices, and resistance to some pollutants. This study explored a sequential DBD plasma assisted by a tandem tri-electrode Fenton (S-PEF) process, using a three-stage treatment approach for degrading antibiotics (sulfamethoxazole, SMX; amoxicillin, AMX; and norfloxacin, NOF) in continuous flow mode for 220-bed volumes. Initially, antibiotics such as SMX and AMX underwent degradation in DBD plasma gas, which housed the mixing chamber. The more resilient NOF was removed by hydroxyl radicals (OH) in the following anodic chamber of the tandem trielectrodes by Fenton assisted oxidation. The continuous cyclic redox regeneration of Fe in tandem trielectrodes prevents secondary Fe sludge pollution. Finally, NO3-N and NO2-N were denitrified into N2 with 95 % selectivity in a cathodic chamber using copper oxide nanowires. This sequential treatment is crucial to mitigating the competitive effects of CO32− and humic acid in wastewater since O3 is less susceptible to them compared to OH. The S-PEF completely degraded all antibiotics regardless of water temperature (10 and 25 °C) compared to sole plasma treatment. Finally, toxicity assessments using an ecological structure–activity relationship (ECOSAR) and E. coli disinfection assays showed a significant reduction in toxicity. This study highlights the promising potential of the S-PEF as an advanced technology for wastewater treatment.

Synthesis of Luminescent Copper Nanoparticles Using Couroupita guianensis Flower Extract: Evaluation of Antibacterial and Anticancer Activities.

The biosynthesis of nanoparticles is a crucial research area aimed at developing innovative, cost-effective, and eco-friendly synthesis techniques for various applications. Herein, we synthesized copper oxide nanoparticles (CuNPs) using Couroupita guianensis flower extract via a simple green synthesis method. These green CuNPs demonstrate promising antimicrobial activity and anticancer activity against A549 nonsmall cell lung cancer (NSCLC) cells. We comprehensively characterized the CuNPs using UV spectrum, XRD, FTIR, SEM, and EDS analyses. The antibacterial and anticancerous performance is attributed to their spherical-like morphology, which enhances effective interaction with bacterial and cancer cells. Moreover, CuNPs proved effective in inactivating Escherichia coli, achieving 2%, 52%, and 99% inactivation at 0, 30, and 60 min, respectively, and Listeria monocytogenes, achieving 1%, 48%, and 98% inactivation at 0, 30, and 60 min, respectively, under visible light. Furthermore, the CuNPs exhibited significant anticancer activity against A549 NSCLC cells, achieving cell viability reductions of 10%, 30%, 50%, 70%, 83%, and 91% at concentrations of 25, 50, 100, 150, 200, and 250 μg/mL, respectively. The green synthesized CuNPs demonstrate their potential in biomedical applications.

Green chemistry approach for the synthesis of CrxCu1-xO nanoparticles: An investigation of the structural and dielectric properties

Chromium (Cr)-doped copper oxide (CrxCu1-xO, x = 0, 0.02, 0.04, 0.06, 0.10) nanoparticles were prepared by a green chemistry approach using Juglans regia fruit extract. The characteristics of pristine and Cr-doped CuO were examined in relation to the concentration of the dopant (2, 4, 6, and 10mol%) using X-ray diffraction (XRD), Fourier Transform Infrared Spectroscopy (FTIR) Scanning electron microscopy (SEM), Energy dispersive analysis (EDX), and UV-Vis. spectroscopy (UV-Vis). According to the XRD results, the synthesized samples exhibited a polycrystalline nature and monoclinic crystal structure. It was discovered that the average grain size varies from 22.4nm to 17.82nm because of the addition of dopants. The optical analysis revealed an increase in the band gap from 1.62 to 3.10eV. We performed the dielectric analysis of pure and Cr-doped CuO nanoparticles and analyzed the behavior of dielectric parameters like dielectric constant, dielectric loss, and ac conductivity with frequency. The dielectric constant and loss exhibit a decreasing trend with frequency whereas ac conductivity demonstrates an increasing trend with frequency and composition.

The structural characteristics of nano-copper thin films produced via laser-assisted electric wire explosion process

Abstract Due to the wide range of important applications, the metal and metal oxide nanoparticles have increasing demand, so that many methods and technologies attempted to produce it. The Electric Wire Explosion (EWE) method is the most established method to produce nanometals and metal oxides in the form of either powders or thin films. In this study, copper and copper oxide films were prepared via electric wire explosion method with a developed laser igniting spark gap switch. The Cu thin films were prepared at different explosion voltages (4, 5 and 7kV) and then their structural properties were studied. The results show that the produced copper/copper oxides nanoparticles of thin films increased as the exploding voltage increased. The XRD test shows that the films crystallite size increased as the exploding voltage increased. FE-scanning electron microscope (FE-SEM) images, are shows the decrease of grain size of thin films as the explosion voltage increase.

Fundamentals of copper(II) adsorption on phyllosilicate minerals relevant to crud formation in solvent extraction from heap leach liquors

Because of the common presence of different silicate minerals, like kaolinite, montmorillonite and muscovite as gangue minerals in the beneficiation of copper oxide ores, the interaction between copper(II) ions in solution and each of these minerals is a field of strong interest, considering their implications on the aggregation of these minerals in the extreme pH conditions typical of hydrometallurgical unit operations for copper production. After copper adsorption isotherms determination at pH 2 and 4, specific adsorption data were fitted to both Langmuir and Freundlich models. It was found that adsorption is systematically larger at pH 4, and that montmorillonite is the mineral that displays a larger adsorption capacity, as in principle expected by its larger cation exchange capacity, CEC. A good fitting to the Langmuir model was obtained for the three samples, and montmorillonite also appears to conform to Freundlich isotherm predictions, as the tested concentrations of copper(II) do not allow to reach saturation. Furthermore, some desorption is measured for kaolinite and muscovite at the highest copper concentrations, probably because of significant interactions between the adsorbed ions. No such desorption was detected in montmorillonite samples. An XPS analysis of the surfaces of the three minerals suggests that copper adsorption in kaolinite is not associated to a cation exchange process but rather to electrostatic interactions between silica-like faces of the clay. In contrast, ionic exchange of structural calcium (for montmorillonite) or potassium (in the case of muscovite) seems to be the predominant mechanism of Cu(II) adsorption in the other two samples. Electrophoretic mobility determinations agree with this hypothesis: the mobility (always negative, with no traces of charge inversion) decreases in absolute value when kaolinite particles are in contact with solutions of increasing copper concentration at pH 2 or pH 4. On the other hand, the electrophoretic mobility values of muscovite and montmorillonite showed a weak pH and copper concentration dependence, a result that matches well with the ion exchange processes detected in the XPS measurements.

Development and characterization of carboxylated copper oxide conjugated polymeric nanocomposites and correlating with computational techniques

The quality and effectiveness of composite-based components are influenced by their mechanical characteristics. Hence, a structured approach is essential to identify the key factors that contribute to achieving superior mechanical characteristics. This study investigates the utilization of an artificial neural network (ANN) to predict the mechanical characteristics, explicitly density, and hardness, of carboxyl copper oxide nanoparticle (CCONP)/DL-lactide and glycolide copolymer (PDLG) nanocomposites fabricated through microwave-assisted sintering. The research explores the effects of numerous microwave sintering conditions on the microstructure and mechanical properties of the nanocomposites. Physical characterization techniques including FTIR and TEM analysis are employed to confirm physical interactions and nanocomposite size. A back-propagation neural network with a 2–10-2 architecture was developed to predict density and hardness. The network was trained using the Levenberg-Marquardt algorithm and the Scaled Conjugate Gradient method. The predicted values are compared with experimental results, showing good agreement with correlation coefficients (R) of 0.883 for density and 0.9737 for hardness. This demonstrates the effectiveness of the ANN approach in evaluating the mechanical properties of CCONP/PDLG nanocomposites, providing a reliable tool for decision-making and potentially reducing experimental characterization costs.

One-pot bioinspired synthesis of PbO/CuO/FeO trimetallic oxide nanocomposite using Vitis vinifera fruit juice for highly sensitive electrochemical detection of 4-Nitrotoluene

The determination of explosive nitroaromatic chemicals has prompted concerns about human safety around the world. In this work, we demonstrate an electrochemical sensor based on trimetallic oxide nanocomposites modified screen-printed carbon electrode (SPCE) for the detection of nitroaromatic compounds. Trimetallic oxide nanocomposites are multiphase materials containing ternary metal oxides. Because of their high specific surface area, superior electron transport capabilities, and favourable catalytic behaviour, they are frequently employed as antibacterial materials, catalysts, and sensors. In order to combat the problems associated with high manufacturing costs, low selectivity, and low sensitivity of conventional sensors, this paper reports on the construction of an electrochemical sensor for 4-nitrotoluene (4-NT) using a trimetallic oxide nano-sensor. The nano-sensor is composed of transition metal oxides copper and iron combined with post-transition lead metal oxide. In this study, we prepared a PbO/CuO/FeO TMO NCs sample with different individual metal oxides synthesized by a green reduction method using Vitis vinifera fruit juice. SEM was used to observe and validate structural and morphological variations brought on by various metal compositions. The four bio-synthesized materials comprise dispersed multiphase matrices containing varying shapes of nanoparticles with different morphologies. The elemental and phase arrangements of the synthesized samples were investigated employing UV, FT-IR, XRD, and EDAX approaches. The findings of the electrochemical measurements indicate that the SPCE modified with PbO/CuO/FeO TMO NCs has enhanced sensing capabilities over CuO, FeO, and PbO NPs for 4-NT; the limit of detection is 4.512 nM and sensitivity is −0.531 μA nM−1 for the developed sensor. Notably, recovery values (99.2–101.7 %) in water samples showed that evaluating interfering species from different contaminants had no effect on the sensing of 4-NT. All of these findings show that the newly developed sensor performs well in terms of reproducibility, selectivity, and sensitivity for the detection of 4-NT

Robust superhydrophobic copper oxide layer with high-low staggered structure on polymers for strong anti-icing and all-day de-icing

Recently, superhydrophobic materials with photothermal and electrothermal conversion functions have received much attention in solving icing problems. However, the currently emerging methods still suffer from the complexity of the preparation method, poor hydrophobicity, or poor abrasion resistance. Herein, a robust copper oxide layer with a high-low staggered structure was prepared on the polymer surface by laser-induced selective metallization (LISM), which can be used for anti-icing and all-day (daytime and night) de-icing. The high-low staggered structure of the superhydrophobic copper oxide surface gives the surface excellent hydrophobicity, light trapping capability, and high electrical resistance, resulting in the surface with superior delayed icing, photothermal de-icing, and electrothermal de-icing capabilities. The copper oxide layer has a water contact angle (CA) of up to 161.3° and a surface delayed icing time of 1374 s, which is 8.23 times longer than the conventional copper layer prepared by LISM. In addition, the surface temperatures of the copper oxide layer are 67.6 °C and 57.3 °C, respectively, under 1.0 sun irradiation or at 5 V applied voltage. Under these conditions, the copper oxide surface’s photothermal and electrothermal de-icing times are 159 and 186 s. In addition, the high-low staggered structure of the prepared superhydrophobic copper oxide surface makes the surface less susceptible to abrasion, resulting in excellent mechanical robustness of the copper oxide layer surface. The proposed method is suitable for low-cost large-scale manufacturing, which guides the preparation of copper oxide superhydrophobic materials for anti-icing and all-day de-icing, and has good application prospects.

Ambient Stability of Sodium-Doped Copper Oxide Obtained through Thermal Oxidation.

The ambient stability of copper oxide layers produced through thermal oxidation is a critical factor for their application in advanced photovoltaic devices. This study investigates the long-term stability of thermally grown sodium-doped copper oxides fabricated at 300 °C, 500 °C, and 700 °C. The structural, optical, and electronic properties of these oxide layers were examined after a 30-day period to understand how thermal oxidation temperature and sodium doping influence the durability and properties of copper oxide films. The results indicate that the stability of thermal copper oxide increases with oxidation temperature. The film produced at 700 °C maintained consistent optical properties, work function value, and structural integrity over time, demonstrating their robustness against environmental degradation. In contrast, the layers produced at lower temperatures (300 °C and 500 °C) showed more significant changes due to continued oxidation and adsorption from ambient.

Biosynthesis of Selenium and Copper Oxide Nanoparticles using Probiotic Bacteria against Food Spoilage Microorganisms

The study’s aim is to synthesize selenium (SeNPs) and copper oxide (CuONPs) nanoparticles using probiotic Lactobacillus acidophilus as a reducing agent. The biosynthesized probiotic Lactobacillus acidophilus selenium and copper oxide nanoparticles were known by color change. The characterization of SeNPs and CuoNPs was completed by Ultraviolet-visible (UV-VIS) spectroscopy, Field Emission Scanning electron microscope (FESEM), Atomic force microscope (AFM), X-Ray diffraction analysis (XRD) and Fourier transform infrared spectroscopy (FTIR). These tests are utilized for detecting stability, morphology, size, crystalline nature and functional groups on nanoparticles prepared surface. Outcomes revealed appearance of the brick-red and green color, representing a specific color of selenium and copper oxide nanoparticles. It was also disclosed that UV-VIS spectroscopy indicated band absorbance at 236 and 264 nanometer of intense surface Plasmon resonance, manifesting the formation and stability of prepared SeNPs and CuONPs. The FESEM image displayed mulit-shapes between spherical and vaulted for selenium and copper oxide nanosized. XRD at 2 theta revealed crystalline selenium and copper oxide nanoparticles where the average size is 75.52-153.22 nm. FTIR revealed the presence of functional groups of the supernatant that act as stabilizing and reducing agents. The antibacterial activity of synthesized nanoparticles was studied against five different bacteria causing food spoilage. As a result of this study, selenium nanoparticle and copper nanoparticles were biosynthized successfully in less time and easy consuming way by green synthesis of the supernatant probiotic Lactobacillus acidophilus.

Synergistic catalysis of dual-sites promoted cycloaddition of CO2 with epoxides

This study explores the catalytic efficacy of fluorine-modified 1 wt% copper oxide on MCM-41 (F-1Cu/MCM-41) in carbon dioxide cycloaddition reactions. It delves into reaction mechanisms, active sites, and the practical applicability of the catalyst. Comprehensive examination through in situ diffuse reflectance infrared Fourier transform spectroscopy and other analytical methods substantiated the role of halogen-modified mono-dispersed copper species in carbon dioxide activation and silicon hydroxide sites in epoxide activation, while underscoring the role of Lewis bases and Brønsted acids. Kinetic studies and density functional theory calculations pinpointed carbon dioxide activation as the pivotal step. Furthermore, the catalyst exhibited robust stability and efficiency in continuous flow experiments, sustaining a 99% selectivity towards cyclic carbonate over 150 h. An eco-friendly evaluation confirmed the sustainability of the process, emphasizing its minimal environmental footprint and high efficiency. These results establish fluorine-modified 1 wt% copper oxide on MCM-41 as a formidable candidate for industrial-scale cyclic carbonate production, due to its promising performance and sustainability.