Copper Network Research Articles

Ultrasensitive and highly flexible nonenzymatic glucose biosensor based on laser-scribed carbon paper substrate

Owing to the high specific surface area and easy accessability to targeting biomolecules, emerging non-noble-metal networks are developed as an ultra-active catalyst for molecular detection. In this work, a facile flexible enzyme-free glucose sensor with superior sensing performance has been successfully constructed by integrating laser-scribed carbon paper (LSCP) with copper network (CN). Remarkably, operation parameters are modeled and optimized by Central Composite Design (CCD) to obtain an optimal conductivity of 4.783 × 107 S·m−1 for CN. Due to the great electronic/ionic pathway between LSCP of ample active sites and CN of excellent conductivity, the disposable biosensor exhibits fast electron transfer kinetics. For glucose detection, LSCP/CN exhibits an excellent sensitivity of 3626.6 μA mM−1 cm−2, a wide linear range from 1 μM to 7.96 mM, an ultra-low detection limit of 30 nM (S/N = 3) as well as favorable reusability. Satisfactory anti-interference capacity to electro-active oxides and selectivity against carbohydrates studied for concentrations up to normal physiologic levels and higher concentrations are systematically investigated. The applications of glucose determination in human serum and perspiration samples are also successful, with recoveries of 100.8% (± 2.28%) and 92.1% (±3.61%), respectively. Experimentally, the current response of the LSCP/CN biosensor is resilient to mechanical deformation with less than 8% decay even after 1000 cycles of 1 mm repeated bending and 180° cyclical folding tests. As such, LSCP/CN can be applicable for flexible, attachable and potentially wearable biosensors to attain real-time physiological monitoring.

Synthesis, Crystal Structure, and Properties of Three-Dimensional Network Copper Coordination Polymer Based on 1,5-Naphthalenedisulfonic Acid and 2,2′-Bipyridine

The novel Cu(II) coordination polymer [Cu(1,5-nds)(bipy)(H2O)2]n·2nH2O (I) (1,5-nds = 1,5-naphthalenedisulfonate anion, bipy = 2,2′-bipyridine) with one-dimensional chain structure was synthesized in water by the reflux method. The complex was characterized by X-ray single-crystal diffraction, elemental analysis, infrared spectrum, UV-vis spectrum, and thermogravimetric analysis. The characterization results of X-ray single-crystal diffraction show that the both of sulfonate groups in the 1,5-naphthalenedisulfonate anion coordinate with two copper ions. The copper ion also coordinates with two nitrogen atoms from a 2,2′-bipyridine molecule and two oxygen atoms from two water molecules, respectively. The both of the uncoordinated water molecules like the nodes of a network connect to the complex molecules to form the three-dimensional network by the hydrogen bonds.