Copper Carbonyl Complexes Research Articles

Copper(I) Carbonyl Complex of a Trifluoromethylated Tris(pyrazolyl)borate Ligand

Copper(I) Carbonyl Complex of a Trifluoromethylated Tris(pyrazolyl)borate Ligand

Preparation and characterization of copper(I) complexes with unsaturated small molecules. Crystal structure determination of a copper carbonyl complex stabilized by a tris-chelating oxygen ligand

Preparation de [LCu(CO)] et [LCu(ethylene)] et [LCu(anhydride maleique)]. Structure cristalline de [(C 5 H 5 )Co{P(O)(OMe) 2 } 3 Cu(CO)]

Tropocoronands: a versatile macrocyclic ligand system for mononuclear and binuclear metal complexes

Abstract

An experimental ESCA investigation of some copper complexes involving CO

An ESCA investigation of 7 copper carbonyl complexes is presented to complement a previous theoretical study. The spectra reveal that the copper is essentially in a +1 oxidation state, although for dinuclear complexes there is evidence for slightly lower than a d 10 electron population on the copper.

Preparation of copper(I) carbonyl complexes derived from sulfonic acids. Crystal structure of carbonylcopper ethanesulfonate (Cu(CO)C2H5SO3)

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTPreparation of copper(I) carbonyl complexes derived from sulfonic acids. Crystal structure of carbonylcopper ethanesulfonate (Cu(CO)C2H5SO3)G. Doyle, K. A. Eriksen, and D. Van EngenCite this: Inorg. Chem. 1983, 22, 20, 2892–2895Publication Date (Print):September 1, 1983Publication History Published online1 May 2002Published inissue 1 September 1983https://doi.org/10.1021/ic00162a025RIGHTS & PERMISSIONSArticle Views223Altmetric-Citations25LEARN ABOUT THESE METRICSArticle Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated. Share Add toView InAdd Full Text with ReferenceAdd Description ExportRISCitationCitation and abstractCitation and referencesMore Options Share onFacebookTwitterWechatLinked InReddit PDF (560 KB) Get e-AlertsSupporting Info (1)»Supporting Information Supporting Information Get e-Alerts

Copper(I) binds carbon monoxide in a cubane-like structure: chemistry and X-ray crystal structure of tetrakis[(2-methylquinolin-8-olato)-carbonylcopper(I)

Copper(I) chloride reacts with a solution of sodium 2-methylquinolin-8-olate (qNa) in tetrahydrofuran under a pressure of 60 atm of CO at 65 °C to give a tetranuclear copper(I) carbonyl complex [Cu(q)(CO)]4, (1), [ν(C–O), 2050 cm–1], having a cubane-like structure, with S4 symmetry, in which the copper atoms are bridged by the oxygen atom of the quinolinolato ligand.

Reaction of molecular oxygen with copper(I). Structural characterization of dimeric .mu.-carbonato and tetrameric .mu.-hydroxo complexes resulting from the autoxidation of a copper(I) carbonyl complex

Reaction of molecular oxygen with copper(I). Structural characterization of dimeric .mu.-carbonato and tetrameric .mu.-hydroxo complexes resulting from the autoxidation of a copper(I) carbonyl complex

Solid Copper(I)carbonyl Complex. Composition and Equilibria.

Solid Copper(I)carbonyl Complex. Composition and Equilibria.

Group IB metal chemistry. Part I. Preparation and reactions of the carbonyl(hydrotripyrazol-1-ylborato)copper(I) complex

The reaction between copper(I) chloride and K[HB(pz)3](pz = pyrazol-1-yl) in the presence of CO affords white, crystalline [{HB(pz)3}Cu(CO)](I) as an air- and heat-stable copper carbonyl complex. Reactions between (I) and ligands L [L = PPh3, PMePh2, P(OMe)3, P(OPh)3, Ph2PCH2CH2PPh2(dppe), AsPh3, SbPh3, or ButNC] afford the complexes [{HB(pz)3}CuL]. On heating, (I) first decarbonylates to [Cu2{HB(pz)3}2](II) which then disproportionates to copper metal and Cu[HB(pz)3]2.

A stable copper carbonyl complex

The preparation and properties of the first air- and heat-stable copper carbonyl complex, [HB(pz)3]Cu-(CO), are described.

The Formation of Copper( I ) Carbonyl Complexes in S ulfuric Acid Solution

常温,常圧で,銅(I)化合物は酸溶液中において,銅(I)lgイオンにつき1分子の一酸化炭素を吸収し,透明で安定なCuCO+を生成する。CH+ H+,CO→CuCO+硫酸中で銅(I)イオンに一酸化炭素を導入するとCuCO+に混ざってCu(CO)3+ が平衡混合物として生成し,-10℃,7atmのもとでは,ほとんど全部がCu(CO)3+となり,Cu(CO)3+は-10℃,7atm以上で安定である。温度,圧力の条件が70℃から-10℃,Iatmから7atmの範囲では,温度,圧力の変化により可逆的につぎの平衡関係が考えられる。Cu(CO)3+→←CuCO+ +2CO

Copper( I ) Carbonyl Complexes in the Mixed Solvents with Sulfuric Acid

硫酸中においては,Cu+ は一酸化炭素を吸収してCuCO+および部分的にCu(CO)3+を生成し,CO/cu(1)比はIを越える。この硫酸中に少量の他の溶媒を加えると,CO/Cu(1)比はすぐに1まで降下する。溶媒がH2SO4+S=SH++HSO4-のようにプロトン受容体として働く能力がある場合は,硫酸との等モル混合溶媒において,CO/Cu(1)比は1となる。これらの結果から,Cu+に対してHSOベイオンは硫酸分子よりも配位力が強く,そのためCu(CO)3+ 錯体中の一酸化炭素分子を追い出してCuCO+・nHSO4-を生成するものと考えられる