Silver surfaces can be roughened electrochemically by subjecting a polished surface to an oxidation-reduction cycle (ORC) in an electrolyte solution [l]. Instead of studying surface-enhanced Raman scattering (SERS) spectra in a spectroelectrochemical cell, it is also feasible to remove the electrode from the cell after the roughening process and use it as dry, solid SERS substrate [2]. Typically, SERS spectra of adsorbed molecules differ from their conventional Raman spectra, not only in intensity, but also in band shifts. These changes depend strongly on the SERS substrate under examination and for that reason comparison of SERS spectra is often very difficult. Sometimes, changes in the spectra are not only due to the adsorption of the molecule but also to laser induced and, in the case of SERS on electrodes, electrochemically induced reactions on the surface, especially when visible laser light is used as excitation source. That is why a distinction between “real” SERS bands and SERS bands from new molecules generated on the surface is very difficult. One effort to overcome these problems is to rotate the SERS substrate. This paper reports on SERS on silver surfaces, which have been roughened electrochemically in electrolyte solution, but then removed from the cell. SERS spectra have been recorded with and without rotation of the solid SERS substrate, so that laser induced changes in the spectra should be easy to identify. The studied molecules were p-aminobenzoic acid (PABA) and aniline.