In this research, a comparative analysis of plug-in hybrid electric vehicle (PHEV) engine was conducted with two advanced low temperature combustion (LTC) techniques viz. Homogeneous charge with direct injection (HCDI) and reactivity-controlled compression ignition (RCCI), utilizing alternative fuels diethyl ether (DEE) and ethanol. This was attempted to exhibit the promising potential of LTC based PHEV to achieve the highest efficiency and low emissions. The experimental results disclosed that DEE powered HCDI can achieve superior thermal efficiency with an impressive peak torque of 14 Nm. On the other hand, ethanol powered RCCI produced a peak torque of 17.5 Nm with remarkable emission reduction characteristics, especially CO2. It was vindicated that HCDI-PHEV outperformed the RCCI-PHEV in terms of fuel economy despite both HCDI and RCCI being lower than the conventional diesel PHEV. The NOx emissions from HCDI were almost negligible. About 20 % lower nitrogen oxide (NOx) emissions were recorded for RCCI respectively as compared to diesel (36 g/s). HCDI and RCCI showcased about 2 and 1.3 times higher soot emissions than diesel (7.12 g/s). Fuel economy was improved by 15 % and 43 % respectively under HCDI and RCCI modes over the conventional diesel mode of PHEV operation. When the PHEV was operated continuously for about 3.5 h, the battery's SOC dropped from 80 % to 45 % under diesel operation, whereas it only reached 50 % and 60 % under RCCI and HCDI mode operation. Low fuel consumption characteristics, acceptable torque production capabilities and ultralow NOx reduction potential established HCDI as the preferable choice for PHEV over RCCI.