AbstractThe charge structure in thunderstorms may be strongly affected by different secondary ice production (SIP) processes, but has not been well understood. In this study, the impacts of three SIP mechanisms on microphysics and electrification in a squall line are investigated using model simulation, including the rime‐splintering, ice‐ice collisional breakup, and shattering of freezing drops. The parameterization of the three SIP mechanisms, a noninductive and an inductive charging parameterization are implemented in the spectral bin microphysics. The results show that with SIP processes included, the modeled radar reflectivity is more consistent with observation. It is found that both the mass and concentrations of graupel/hail are enhanced by SIP processes, while the diameter decreases. The mixing ratio of ice/snow decreases due to the rime‐splintering, and increases in mixing ratio are due to the shattering of freezing drops. Particle charging is significantly affected by SIP, leading to a dipole structure of the total charge density, which includes a lower negative and an upper positive charge region. With both the noninductive and inductive charging considered, the charge carried by graupel/hail changes from negative to a bipolar structure, and the charge sign carried by ice/snow is inverted due to the SIP. The modeled lightning activity is enhanced by implementing all three SIP processes, while if only considering the rime‐splintering process, the flash rate would be suppressed. The insights obtained from this study highlight the importance of considering different mechanisms of SIP in modeling the charge structure and lightning activity in thunderstorms.