Since the discovery in 1977 of the metallic properties of molecularly doped polyacetylene, there has been rapid growth in the field of electronically conducting polymers [1-5]. The interest in this area is mainly due to the numerous technological applications of conducting polymers as active electrode materials in energy storage [6], opto-electronic devices [7], display devices [8, 9 ] and their envisaged application for the control of electromagnetic radiation (EMR) and dissipation of electrostatic charge [10-12]. Polyaniline (PAn) is particularly interesting because of the presence of the chemically flexible N H group in the polymer backbone which not only takes part in the protonation/deprotonation but also contributes to 7r-band formation [13], thus ensuring greater environmental stability. PAn can be obtained either by chemical or electrochemical method and does not involve any special precautions [14-16[. Although it is easily synthesized in bulk, its use is restricted due to its unprocessibility by normal melt or solution techniques. For many applications, such as in the control of electromagnetic interference (EMI), dissipation of electrostatic charge (ESD) requires a thin conducting coating on a flexible surface. Polyaniline, unlike metallic coating, is free from corrosion and is very suitable under a highly corrosive atmosphere where other conducting coatings fail. Due to the reactivity of synthetic fabrics like Nylon, Terylene and glass fabric towards mineral acids, we have used organic acids like benzenesulfonic acid (BSA), para-toluenesulfonic acid (PTSA), 5-sulfosalicylic acid (SSA) and 4-hydroxybenzenesulfonic acid as media for grafting PAn. The detailed study using these acids on the properties of polyaniline has been reported elsewhere [8, 9, 17]. The effect of these acids on charge transport, optical and magnetic properties which are quite different to those of mineral acids (like persistence