Sediment Contribution Research Articles

Storm sediment contribution to salt marsh accretion and expansion

Storm sediment contribution to salt marsh accretion and expansion

Storm sediment contribution to salt marsh accretion and expansion

Storm sediment contribution to salt marsh accretion and expansion

Mid-Miocene uplift and tectonic-sedimentary evolution of the Taiwan accretionary prism: Constraints from sedimentary records in the Hengchun Peninsula, southern Taiwan

The young Taiwan orogenic belt is a classic example of a modern arc–continent convergence zone, which displays a longitudinal transition from active collision in the north to oceanic subduction in the south. However, the timing of its initial exposure above the sea level and the early-stage uplift mechanism has been a point of much debate. Here we applied major and trace element, Nd isotope and heavy minerals analysis on the Miocene sedimentary rocks from the Hengchun Peninsula to trace sediment provenance and to further constrain the tectonic-sedimentary evolution of the Taiwan accretionary prism. Results show that the Hengchun mudstones (∼11.6–6.5 Ma) are characterized by higher CaO (1.42 wt %) and MgO (2.57 wt %) contents, Cr/Zr (0.52) and Co/Th (1.58) ratios, and less negative ϵNd (t) values (−12 to −7) than those from the Chinese passive continental margin sediments. It indicates that the Chinese mainland was not exclusive sediment contributor for the Hengchun sediments. Combined with the high content of Cr-spinel heavy mineral (mean value ∼ 28.2%) in the Hengchun Miocene sandstones, and the presence of mafic lithic grains and N-MORB-type mafic rocks of 26-22 Ma in the Hengchun Peninsula, it is clear that the subducting South China Sea oceanic lithosphere should be also considered for the origin of the Hengchun sediments. The most likely source of these oceanic clasts being transported to the Hengchun Peninsula is the equivalent prism to the north, which had involved oceanic fragments during the subduction process. Consequently, Taiwan accretionary prism should have been already partly exposed prior to ∼11.6 Ma, considerably earlier than most previous estimates and the onset of arc-continent collision. Underplating of seamounts and/or the thinned Chinese continental margin beneath the overlying Taiwan accretionary prism, together with wedge extrusion tectonics, may have played an important role for this early-stage uplift, which now is also observed in the sandbox experiments, marine observation and analogue modeling. Our study not only better integrates the subduction and then erosion history of the South China Sea oceanic crust with sedimentary records in Taiwan, but also signifies a modern example from Taiwan that highlights the importance of soft exhumation mechanism in worldwide plate convergence zones relative to hard collision.

Using check dam deposits to reconstruct changes in the sediment response of a small catchment on the Loess Plateau in China, during the period 1960–1990

AbstractInformation on both the magnitude and relative contributions of inter‐gully and gully areas to the sediment yield from small catchments in the Loess Plateau of China represents an important requirement for understanding catchment sediment dynamics, assessing the sensitivity of catchment sediment budgets to environmental change and developing effective soil and water conservation strategies. Contemporary catchment monitoring programmes can provide such information, but there is also a need to consider past behaviour. Where long‐term records are lacking, attention has been directed to the potential for using the sediment deposits behind check dams to reconstruct the sediment response of the upstream catchment. This contribution reports a study of the 0.181 km2 Nianyangou catchment located in the hilly region of the Chinese Loess Plateau, in Shaanxi Province, China, which has extended a previous study aimed at using individual flood couplets preserved in the check dam deposits to reconstruct the record of annual sediment yield, to include the use of sediment source fingerprinting techniques to document changes in the annual sediment contribution from inter‐gully and gully areas for the period 1960–1990. The sediment response of the catchment provided evidence of two change points in 1964 (Period 1–Period 2) and 1983 (Period 2–Period 3), which reflect the introduction of soil and water conservation measures in the mid 1960s through to the 1970s and a change in the land tenure system in 1983. The annual sediment yields from inter‐gully and gully areas follow the trend P1 > P3 > P2, whereas the equivalent information on the relative contribution of inter‐gully and gully areas follow different trends P3 > P1 > P2 and P2 > P1 > P3, respectively.

Contrasting particle fluxes and composition in a submarine canyon affected by natural sediment transport events and bottom trawling

Submarine canyons are important conduits of sediment and organic matter to deep-sea environments, mainly during high-energy natural events such as storms, river floods, or dense shelf water cascading, but also due to human activities such as bottom trawling. The contributions of natural and trawling-induced sediment and organic matter inputs into Palamós Canyon (NW Mediterranean) were assessed from three instrumented moorings deployed in the axis and northern flank of the canyon covering the trawling closure (February) and the trawling season (March-December) of 2017. During the trawling closure, large sediment fluxes with high contents of labile marine organic matter content were registered in the canyon axis, associated to storm resuspension on the shelf that coincided with dense shelf water cascading and high surface water productivity. Although no major natural sediment transport events occurred during the following spring and summer months, near-daily trawling-induced sediment gravity flows were recorded in the northern flank mooring, placed directly below a fishing ground, which sometimes reached the canyon axis. Compositionally, the organic matter transferred by trawling resuspension was impoverished in the most labile biomarkers (fatty acids, amino acids, and dicarboxylic acids) and had a high degree of degradation, which was similar to surficial sediment from the adjacent fishing ground. Trawling resuspended particles masked the transfer of organic matter enriched in labile biomarkers that naturally occur during the quiescent summer months. Overall, bottom trawling enhances the magnitude of particle fluxes while modifying its organic carbon composition, increasing the re-exposure and transfer of degraded organic carbon and potentially affecting benthic communities that rely on the arrival of fresh organic matter.

An experimental investigation of the erosion process and morphological characteristics of the tile-back type slope with non-uniform slopes based on a 3D reconstruction method

Tile-back type slopes comprise ephemeral gullies (EGs) and hillslopes; they are a unique and widely distributed micro-landform in the Loess Plateau region of China. Gully erosion from these landforms is a serious issue, but the micro-landform makes the erosion process and its estimation complex. Quantifying soil erosion processes and their distribution characteristics at different positions on tile-back type slopes will provide a clearer picture for ecological restoration to control further soil degradation. This study investigated the erosion process of tile-back type slope with non-uniform slopes using a 3D photo-reconstruction method during eight successive simulated rainfall events. The results showed that EG erosion began with a chain of intermittent headcuts. When the accumulated rainfall reached 76 mm, serious collapses dramatically increased the amount of sediment by 216% after the first rainfall (cumulative rainfall was about 15 mm). We quantified the sediment contribution of EG erosion (46.20%), rill erosion (35.62%), and inter-rill erosion (18.18%) to total soil loss. The erosion area of the steep slope section and extremely steep slope section accounted for 33.26% and 66.74% of the total erosion area, respectively. Moreover, sediment amounts significantly correlated with morphological parameters, particularly the amount of EG erosion and maximum gully depth, with a correlation coefficient of 0.98. Cumulative gully length and erosion area had the greatest effect on rill erosion, with a correlation coefficient of 0.97. These results provide insight into the qualitative and quantitative understanding of EG erosion process on Loess Plateau of China and an important reference for the rational arrangement of EG control measures.

Late Quaternary sedimentary record of estuarine incised-valley filling and interfluve flooding: The Manfredonia paleovalley system (southern Italy)

Multiple paleovalley systems of late Quaternary age have been widely explored in previous research from the Gulf of Manfredonia on the basis of seismic data, but only limited information is available on their proximal (onshore) segments. Through an integration of sedimentary, paleoecological (mollusks, benthic foraminifers, ostracods), and geochemical analyses from three 30-50 m-long onshore cores and a sequence-stratigraphic framework chronologically constrained by 25 radiocarbon data, we document the stratigraphic architecture of three contiguous paleovalley systems (Candelaro, Cervaro and Carapelle rivers) and their sedimentary response to Late Pleistocene valley excavation, Holocene filling and basinwide interfluve flooding. Above a prominent sequence boundary formed during the Late Pleistocene relative sea-level fall, fluvial-channel gravels and sands (lowstand systems tract) are overlain by a deepening-upward, valley-fill succession of inner-estuarine (freshwater) to outer-estuarine (brackish) muds (lower transgressive systems tract – TST). The individual valley fills are overlain by laterally extensive bay deposits (upper TST) and by a progradational succession of prodelta/delta front and offshore/shoreface deposits that reflect normal regression under highstand conditions (HST). The transition from fluvial to inner-estuary (fluvial-dominated) and outer-estuary (wave-influenced) deposits records the progressive shift in sediment provenance from Southern Apennine source rocks to a mixed composition that reflects increasing alongshore sediment contribution from northern sources via the SE-directed Western Adriatic Current. The stratigraphic surface that demarcates the transition from estuarine to bay depositional systems (lower/upper TST boundary) represents the physical prolongation of interfluvial terrace surfaces, as valley margins were flooded during the Early Holocene transgression. This surface, typically recognizable on seismic profiles at the boundary between low-amplitude and overlying high-amplitude reflectors, has no obvious lithologic signature in core. However, it can be readily identified on the basis of paleoecologic features (sharp increase in species diversity and in the proportion of marine taxa) that reveal the abrupt transition from laterally confined to unconfined settings.

Sediment load crisis in the Mekong River Basin: Severe reductions over the decades

The boom in water infrastructure in the Mekong Basin has raised concerns over the annual supply of water and sediment among its riparian communities. By consolidating various datasets, continuous series of sediment load data were estimated for several stations located within the Lower Mekong Basin. At Chiang Saen in Thailand, the nearest station to the Chinese dams, the average sediment load was 79 ± 32 Mt./yr during the pre-dam period of 1965–1991. However, from 2010 to 2019 – during which a series of mega-dams were built in China – the sediment load decreased drastically by 84 % to only 12.5 ± 4.6 Mt./yr. This phenomenon of reduced annual sediment load during the mega-dam era (2010–2019) as compared to during the pre-dam era (1965–1991) can be observed at stations downstream from Luang Prabang (−53 %) to Nong Khai (−62 %) to Khong Chiam (−33 %).One of the drivers of this sediment load crisis is the rapid development of upstream dams. Especially after 2003, Chinese dams have reduced sediment supply to the downstream Mekong Basin severely. Concurrently, there was an increase in sediment contribution from the stretch of the Mekong River from Chiang Saen to Khong Chiam. A positive outcome of this increased sediment contribution was its buffering effect against the reduction in sediment load from the Chinese part of the Mekong Basin. Although sediment load at Kratie – the gateway station before the alluvial stretch comprising the Cambodian floodplains and Vietnam Mekong Delta – decreased from 78 ± 22 Mt./yr (1995–2009) to only 60 ± 21 Mt./yr (2010–2019), the reduction would have been higher without the increased sediment from the Chiang Saen – Khong Chiam stretch. However, with upcoming planned dams in Laos and Cambodia, this buffering effect is likely to be temporary, implying that the sediment load crisis as already experienced by the downstream communities can only become more severe.

Using particle size distributions to fingerprint suspended sediment sources—Evaluation at laboratory and catchment scales

AbstractApplications of sediment source fingerprinting studies are growing globally despite the high costs and workloads associated with the analyses of conventional fingerprint properties on target sediment samples collected using traditional methods. To this end, there is a need to test new fingerprint properties that can overcome these challenges. Sediment particle size could potentially contribute here since it is relatively easy to measure but, until now, has rarely been deployed as a fingerprint itself. Instead, particle size has been used to ensure that source and target sediment samples are more directly comparable on the basis of the fingerprints used. Accordingly, this work examined whether particle size distributions (PSDs) could be used as a reliable fingerprint for apportioning sediment sources, in combination with a grain size un‐mixing model. Application of PSDs as a fingerprint was tested at two scales: (i) in a laboratory setting where soil samples with known PSDs were used to generate artificial mixtures to evaluate un‐mixing model results, and (ii) a catchment setting comparing PSDs in a confluence‐based approach to test if downstream target sediment PSDs could be un‐mixed into the contributions of sediment coming from an upstream and a tributary sampling site. Laboratory results showed that the known proportions of the two, three and four soil samples in the artificial mixtures were predicted accurately using the AnalySize grain size un‐mixing model, giving average absolute errors of 9%, 8% and 6%, respectively. Catchment results showed variable performances when comparing un‐mixing results with sediment budget estimations, with the best results obtained at higher discharge values during storm runoff events. Overall, our results suggest the potential of using PSDs for estimating contributions of sediment sources delivering SS with distinct PSDs when sources are located at short distance to the downstream sampling site.

Evolution of the Northern Part of the Lesser Antilles Arc—Geochemical Constraints From St. Barthélemy Island Lavas

AbstractThis study presents an extensive geochemical data set of 23 samples from St. Barthélemy Island, which belongs to the extinct branch of the Lesser Antilles arc and is currently exposed in the northern part of the subduction forearc. Samples were selected to represent all lithologies and main periods of magmatism, that is, Middle‐Late Eocene, Early Oligocene and Late Oligocene. They show enrichment in light rare earth element/medium rare earth element, large ion lithophile elements (Rb and Ba) and isotopic characteristics, suggesting mixing between the mantle and a subduction component (oceanic crust + sediments). Trace element ratios suggest that primary magmas were generated in a normal mid‐oceanic ridge basalt‐type mantle‐wedge that underwent 8%–18% partial melting in the spinel‐stability field. The sediment contribution was low (0.1%–1%) irrespective of the age of the samples. This is similar to what is observed for the northern Lesser Antilles active branch. St. Barthélemy Island shares strong similarities with St. Martin Island, located on the same extinct arc branch, which suggests a similar geodynamic evolution. Oligocene samples displayed an increase in incompatible elements in the magma source, suggesting an increase in sediment melts, which could be correlated with a drastic change in the tectonic regime at that time, characterized by stretching perpendicular to the trench and subsequent basin opening. On Δ7/4Pb versus206Pb/204Pb, the samples showed a similar trend for both active and extinct islands of the northern Lesser Antilles, suggesting negligible changes in the nature of the magma sources.

Effects of Agricultural Intensity on Nutrient and Sediment Contributions within the Cache River Watershed, Arkansas

Streams in agricultural lands tend to serve as a conduit for nutrient pollution. These streams are often modified and have reduced riparian zones, resulting in agriculture being the leading cause of nonpoint source pollution into streams of the United States. Eutrophication within the Gulf of Mexico has been attributed to nutrient and sediment contributions from watersheds within the greater Mississippi River Basin. One such watershed, the Cache River Watershed (CRW) located in northeast Arkansas, was assessed to determine the impacts of agricultural intensity on water quality at a local scale. The objective of this study was to determine the influence of agricultural activity on nutrient and sediment contributions to the CRW. Following American Public Health Association guidelines, physicochemical parameters, turbidity, and total nutrients (nitrogen and phosphorus) were analyzed weekly from October 2017–September 2020 at 12 subwatersheds of four varying agricultural intensities (low, low moderate, moderate high, high). Results indicate that physicochemical parameters increase (pH, conductivity, temperature) or decrease (dissolved oxygen) with increased agricultural intensity. Similarly, turbidity and total nutrients also increase (significantly for turbidity and total phosphorus) with increased intensity. Contributions of sediment and nutrients in the CRW not only influence local stream health but also contribute to hypoxia in the Gulf of Mexico.

Sources and temporal dynamics of suspended sediment transport along the middle Paraná River

The Paraná River is one of the world's largest fluvial systems due to its discharge. During the last 30 years, water discharge has averaged 18,389 m3 s−1 downstream of the Paraguay-Paraná confluence, where its most important tributaries, the Paraguay and the upper Paraná rivers contribute 22% and 78% of its total discharge, respectively. However, the sedimentological dynamics of this system behaves peculiarly due to the influence of the Bermejo River, a tributary of the Paraguay River. Even though the contribution of the Bermejo River discharge represents only 2% of the Paraná River discharge, its input of suspended sediments is significant due to the erosive processes in the upper Bermejo basin.Most earlier studies have primarily focused on the contributions and dynamics of the wash load (silt and clay) from the Bermejo River through the Paraguay River to the Paraná River, and neglected the relevance of fine and very fine sands (coarser than 63 μm). These sediment fractions play a key role in bed sediment composition, roughness, and bed forms, ultimately modifying the flow resistance and the morphodynamic processes, among other environmental and biological parameters.This study seeks to quantify the suspended sediment contribution of the main tributaries of the middle Paraná River during the last three decades. In particular, water discharge, sediment transport and grain size data measured at gage stations located at the Paraguay River upper reach, the Bermejo River, and the upper and middle reaches of the Paraná River are analyzed. Focus is placed on the coarse suspended sediment fraction. Additionally, the authors collected sediment samples at different river cross-sections and water discharges.The temporal analysis revealed the dynamic behavior of the sediments along the system. The results show different behaviors of the wash load and suspended sand transport provided by the Bermejo River. Along the middle Paraná reach, results suggest a significant suspended coarse fraction deposition during the highest sediment input period. Bed sediments, in turn, are re-suspended during the months with low contributions from the Bermejo and/or during the high water levels stages of the Paraná. This sediment dynamics produces a complex pattern of coarse sediment transport in the Paraná River at its middle reach, also modifying the sedimentological characteristics of the river bed.

Effects of coastal aquaculture on sediment organic matter: Assessed with multiple spectral and isotopic indices

Sediment organic matter (SOM) is important in the biogeochemical cycling of carbon, nutrients, and pollutants in the coastal environment, which is increasingly disturbed by aquaculture that is particularly intense in China. However, the identification of aquaculture signals in SOM is rather challenging in the complex coastal environment that receives materials from a variety of sources. This was studied in a typical culture area of shellfish and algae in SE China from July 2019 to October 2020, using a combination of elemental (OC, TN, N/C), isotopic (δ13C and δ15N), spectral (absorption spectroscopy and fluorescence EEMs-PARAFAC), and statistical analysis (principal component analysis, PCA). All indices of SOM quantity and several spectral indices for the SOM composition correlated significantly with grain size, with lower SOM quantity and higher autochthonous contribution in coarse sediments. The strong correlations between elemental and spectral indices suggested that optical analysis could provide valuable indices for assessing the quantity of bulk organic matter. The comparison of SOM indices between different zones and between different months showed an overall limited influence of shellfish and laver culture. This indicated the sustainability of these types of aquaculture that require no manual addition of feeds and thus are generally clean. The further applications of end-member mixing analysis using the IsoSource program and PCA were more sensitive, which identified the removal of SOM by shellfish in the growing season and the contribution from shellfish residuals after the harvest and the cultured laver at some locations. Overall, our results have implications for a better understanding of the biogeochemical processes and ecosystem sustainability in the coastal environment under intense aquaculture activities.

An Ordovician ophiolitic complex in West Junggar, NW China: Implications for subduction initiation and oceanic arc evolution of the Paleo-Asian Ocean

As a key step of the Wilson cycle, subduction initiation is regarded as a start hallmark of the ocean-continent transformation. However, the crust-mantle interaction and crustal growth processes related to subduction initiation remain enigmatic. Here we report a newly recognized complete magmatic sequence containing three rock assemblages in the Hongguleleng ophiolitic complex (HOC) in West Junggar, NW China. Group I contains typical Mid-Oceanic Ridge (MOR)-derived rocks including abyssal peridotite, gabbro, plagiogranite, and basalt. Group II consists of forearc basalt (FAB) and boninitic gabbro and has a high continentality index (CI > 130), similar to the rock assemblages in the Mariana proto-arc. Group III composed of calc-alkaline andesite and arc tholeiite basaltic andesite exhibits middle CI values (50 < CI < 100), suggesting that they form in a transitional oceanic arc. Zircon U-Pb ages show that the N-MORB gabbro and plagiogranite samples are emplaced at 483–481 Ma, and the boninitic rocks, calc-alkaline andesites, and arc tholeiite basaltic andesites have the crystalline ages of 472–467 Ma, 456 Ma, and 452 Ma, respectively. An increasing trend of Ba/Th and V/Ti ratios from Group I to Group II suggests the addition of aqueous fluid and elevated oxidation in the mantle source during subduction initiation. However, it exhibits an uptrend in Th/Nb and (La/Sm)cn ratios but a downtrend in Ba/Th ratios from Group II to Group III, indicating a significant contribution of slab-derived sediments to the mantle during oceanic arc evolution. Combined with regional data, we consider that there developed an E-W–trending sub-ocean basin of the Paleo-Asian Ocean spanning northern West Junggar and East Kazakhstan during the Middle Cambrian–Ordovician. The MOR-type and forearc ophiolites in northern West Junggar as well as our results suggest that the ocean happened mid-ocean ridge spreading at ca. 512–478 Ma and subduction initiation at ca. 476–467 Ma, and developed a transitional oceanic arc at ca. 456–452 Ma.

Implementing landscape connectivity with topographic filtering model: A simulation of suspended sediment delivery in an agricultural watershed.

The widespread availability of high-fidelity topography combined with advances in geospatial analysis offer the opportunity to reimagine approaches to the difficult problem of predicting sediment delivery from watersheds. Here we present a model that uses high-resolution topography to filter sediment sources to quantify sediment delivery to the watershed outlet. It is a reduced-complexity, top-down model that defines transfer functions-topographic filters-between spatially distributed sediment sources and spatially integrated sediment delivery. The goal of the model is to forecast changes in watershed suspended sediment delivery in response to spatially distributed changes in sediment source magnitude or delivery, whether a result of watershed drivers or intentional management actions. Such an application requires the context of a watershed model that accounts for all sediment sources, enforces sediment mass balance throughout the spatial domain, and accommodates sediment storage and delivery over time. The model is developed for a HUC-8 watershed with a flat upland dominated by corn-soybean agriculture and deeply incised valleys near the watershed outlet with large sediment contributions from near-channel sources. Topofilter computes delivery and storage of field-derived sediment according to its spatial and structural connectivity to the stream channel network; subsequently, delivery of both field- and near-channel-derived sediment along with floodplain storage are computed in the stream channel network to the watershed outlet. The model outputs provide a spatially rich representation of sediment delivery and storage on field and along the stream that is consistent with available independent information on sediment accumulations and fluxes. Rather than a single best-calibrated solution, Topofilter uses the Generalized Likelihood Uncertainty Estimate (GLUE) approach to develop many possible solutions with sediment delivery rates expressed as probability distributions across the watershed. The ensemble of simulation outputs provides a useful basis for estimating uncertainty in sediment delivery and the effectiveness of different landscape management allocation across a watershed.

Targeting the source of fine sediment and associated geochemical elements by using novel fingerprinting methods in proglacial tropical highlands (Cordillera Blanca, Perú)

AbstractIn the Cordillera Blanca, the glaciers delineated by some of the highest peaks in the tropical Peruvian Andes have experienced a fast retreat over the last few decades. At the foot of Artesonraju Peak, the glacier‐fed river conveys fine sediments to Parón Lake, which is enclosed in the proglacial area created by the retreating glaciers of the unique confluence of the Huandoy, Chacraraju, Nevado Caraz and Artesonraju peaks (above 6000 m.a.s.l.). This research addresses the sediment contributions of main glacial landforms to sediment mixtures delivered to the river and lake system (1.6 km2) by applying novel conservativeness and consistency methods for tracer selection and a frequentist unmixing model. A total of 27 surface soil and sediment sources (0–3 cm) were sampled from moraines, alluvial fans and recent colluvium, and 10 composite sediment mixtures, including suspended sediments, were collected to identify the sediment provenance. The unmixing results reveal large variability of the contributing sources related to their predominance and the locations of the mixtures. The largest contributions were from moraines, in percentages varying from 28% to as much as 77%. Alluvial fans contributed between 23% and 47% of the sediments, and colluvium material contributed the least, between 6% and 28%. At the time of sampling, ice melt discharge incising moraines and alluvial fans and eroding riverbanks were the main mechanisms of fine sediment delivery. Runoff over the bare surfaces of recently exposed moraines and the lack of vegetation cover in very active landforms also control sediment mobilization. Overall, highly dynamic changes in this paraglacial environment involve active sediment fluxes accompanying snow and ice melt. Our results indicate that in high tropical mountains, shrinking glaciers expose new surfaces of glacial materials, which deliver fine sediments. Identifying the contributing sources is of interest for water and sediment evaluation and management programs.

Paleoproterozoic Mineralization of the Lijiapuzi Gold Deposit in the Liaodong Peninsula, NE China: Constraints from 40Ar-39Ar Age, S-Pb Isotopes, and In Situ Analyses

A Paleoproterozoic 40Ar/39Ar age, interpreted as the gold metallogenic epoch of the Lijiapuzi deposit in NE China, is reported in this paper. The ore body of this deposit is hosted in the marbles and schists of the Paleoproterozoic Dashiqiao Formation and exhibits parallel development to the foliation of the country rocks. Coexisting auriferous pyrite and tremolite can be observed both in the field and under a microscope, revealing the presence of hydrothermal activity in the deposit. The δ34S composition of the auriferous pyrite varies from +8‰ to +12.3‰, indicating a sedimentary origin. The auriferous pyrite and host marble have similar Pb isotopic ratios, indicating the contribution of Paleoproterozoic sediments to gold mineralization. Furthermore, in situ S and trace element analyses of the auriferous pyrite reveal that the main gold mineralization stage was Py2, which coexists with radial tremolite. 40Ar/39Ar dating of these tremolite samples yields a plateau age of ~1851.23 Ma, with similar isochronal and inverse isochronal ages. The Paleoproterozoic gold metallogenesis, together with the contemporary Pb-Zn, boron, graphite, and magnetite mineralization, constitute an important mineralogenetic series during the evolution of the Jiao-Liao-Ji orogeny in the Liaodong Peninsula.

Bioturbation supplying young carbon into West Antarctic continental margin sediment

Accelerator Mass Spectrometry (AMS) 14C dating is a widely applied method for establishing high-precision chronologies used to underpin late Quaternary paleoclimatic studies. Feedbacks associated with Antarctic Ice Sheets (AIS) and Southern Ocean variance are thought to have played a critical role in regulating past global climate changes since the Last Glacial Maximum. However, determining the exact role of the AIS and Southern Ocean in these changes has proven difficult because of the sparse occurrence of biogenic carbonate suitable for AMS 14C dating in Antarctica. Consequently, AMS 14C dating is often measured on acid insoluble organic matter (AIOM) from bulk sediment samples, which are often biased towards ages that are older than the depositional age, due to pervasive reworking of old carbon. In this scenario, ages can still potentially provide maximum deposition ages, but such interpretations need to be assessed carefully. Here, we document AIOM and foraminifer AMS 14C dates at the same depth intervals from Antarctic continental margin cores, and we find AIOM AMS 14C dates can range between 2000 and 16,000 years younger than those of foraminifera samples. The younger AIOM 14C dates were found in bioturbated sedimentary facies, which often have extremely low sedimentation rates in Antarctica. In cores with low sedimentation rates, the down sediment contribution of organic carbon from macro-benthos can be quite significant in the sediment column with low organic carbon concentration. After considering possibilities of contamination, foraminifer reworking, and remineralization of secondary carbonate to explain this offset, we conclude that bioturbation plays an important role in the Antarctic carbon cycle as a young carbon supplier to depth into the sediment column. This has clear implications for using condensed sedimentary sections to date post-LGM records in Antarctica. These bioturbation processes also have implications for novel radiocarbon dating methods that have recently been developed to overcome sediment reworking processes and more accurately constrain timing of past AIS retreat, including ramped pyrolysis and compound specific isotopes methods.

Hydroclimatic variability in Northeast India during the last two millennia: Sedimentological and geochemical record from Shilloi Lake, Nagaland

The evolution of the monsoonal climate in the Indian Himalayan region remains poorly understood due to the sparse coverage of paleoclimatic datasets. In the present paper, elemental concentrations and grain size parameters are measured for a radiocarbon-dated sediment core retrieved from Shilloi Lake (Nagaland, India) to understand climate variability over north-eastern India during the past two thousand years. The end-member modeling of grain-size distribution along with the elemental composition and ratios (Mg/Al, Sr/Al, Ti/Al) are used to identify changes in clastic input and authigenic carbonate precipitation as well as lake level changes. In addition, the REE distribution pattern and elemental ratios (U/Th, Europium anomaly – Eu*) are evaluated to understand provenance and redox conditions. We identify two main hydrological events: (i) wet conditions during ~1900 to ~1000 cal yrs. BP characterised by high clastic sediment input (as indicated by increased Mg, Al, Mg/Al) and dominant contribution of fine-grained sediments as represented by end member (EM) 1 in zone 1, and (ii) an increase in aridity as signified by decreasing detrital content and increased coarse-grained sediments (EM3) in zone 2 (~1000 cal yrs. BP to present). The regional comparison of paleoclimatic records from NE Himalaya and central India shows an opposing trend in precipitation patterns. However, a synthesis of hydrological proxy records from the tropical Pacific region does not point to an active role of ENSO in the study region. Comparative analysis of modern precipitation data and paleo-records shows that the opposing behaviour resembles an “active-break” pattern that produces an east-west precipitation dipole in central and northeast India.

Identifying Tethys oceanic fingerprint in post-collisional potassium-rich lavas in Tibet using thallium isotopes

Following the Indian-Asian continental collision, the Tibetan Plateau experienced continuous magmatism from south to north, most of which is characterized by high potassium (K) content and negative niobium‑tantalum‑titanium (Nb-Ta-Ti) anomalies. We performed the first exploration using thallium (Tl) isotopes as potential tracers of the source of post-collisional K-rich magmatism. A case study on Tl isotope systematics of K-rich lavas in Ashikule volcanic basin (AVB) in northwestern Tibet is provided, which represents the youngest volcanism in Tibet. Thallium abundances of the AVB lavas are significantly enriched compared to other magmatic settings, with concentrations from 148 to 8259 ng/g. Thallium isotope ratios (reported as ε205Tl) extend to some of the heaviest yet measured in igneous materials, with a range of ε205Tl between −2.7 and + 6.4 ε-units. We evaluate if secondary processes can account for the range in Tl isotope ratios, systematically examining the influences of alteration, degassing, fractional crystallization, and assimilation. Only two samples appear to be influenced by secondary processes, interpreted as kinetic fractionation during degassing, and one sample may be contaminated by sulfides with coupled elevated Tl and Pb contents. The remainder of the Tl isotope ratio range (−2.0 to +5.1 ε-units) we interpret to reflect the source region(s) from which the magmas are derived. The AVB lavas have restricted strontium and neodymium isotopes, suggestive of a homogeneous source, and therefore an apparent decoupling of radiogenic and stable isotope systems is apparent in these lavas. The variation in Tl isotope ratios is interpreted to reflect the contribution of oceanic sediments, which may be associated with ancient Paleo- and Neo-Tethys subductions.