Eleven glass compositions were prepared by melt and quench method with progressive substitution of SrO for PbO (0 ≤ x ≤ 1·0) with a step-wise increment of 0·10 in the glass [(Pb x Sr1 − x )OTiO2]–[(2SiO2B2O3)]–[BaO·K2O]·Nb2O5 (mol percentage) system. The infrared spectra (IR) of various glass compositions in the above mentioned glass system was recorded over a continuous spectral range 400–4000 cm − 1 to study their different oxides structure systematically. Differential thermal analysis (DTA) was recorded from room temperature (~27 °C) to 1400 °C employing a heating rate of 10 °C /min to determine glass transition temperature, T g and crystallization temperature, T c. The melting temperature, T m, of these glass compositions was found to be in the range 597–1060 °C depending on the composition under normal atmospheric conditions. T g and T m of glasses were found to increase with increasing SrO content. X-ray diffraction analysis of these glass–ceramic samples shows that major crystalline phase of the glass–ceramic sample with x ≤ 0·5 was found to have cubic structure similar to SrTiO3 ceramic. Scanning electron microscopy has been carried out to see the surface morphology of the crystallites dispersed in the glassy matrix.