The article presents the results of a study of the effect of slab thickness on the element segregation of during continuous casting of billets. The process of accumulation of elements on the surface of dendrites during crystallization of steel slabs for various thicknesses is considered. The theoretical dependence of the process of accumulation of elements on the dendrite surface during the crystallization of steel slabs for various thicknesses has been established. It is shown that the efficiency of accumulation of elements on the dendrite surface depends significantly from the crystallization and cooling rate of the slab. The established dependence makes it possible to determine the permissible increased element content in strips, which is equivalent to their content in thick slabs during continuous casting of billets. The element segregation searching shows that at pouring of thin steel strips, an increasing of the element content is possible compared to continuous casting of thick slabs with an identical level of segregation. The elements are arranged as possible to maximize the impurities content in AISI 1006 carbon steel in the following decreasing sequence: S, O, N, P, H. Another sequence is observed for stainless steel AISI 304: O, S, P, H, N. The following sequences are observed in the case of residual elements: for steel AISI 1006 - Pb, Bi, Sn, As, Zn, Sb, Cu; for steel AISI 304 - Cu, Sb, Sn, Bi, Pb, As, Zn. The sequences are as follows for the alloying elements: for steel AISI 1006 - B, Se, Al, Te, Ca, Mg, Ce, C, La, Nb, Ti, Mn, Ni, Si, Cr; for steel AISI 304 - Ca, Te, Al, Ti, Mg, C, La, Ce, Nb, Se, V, B, Si, Cr, Mn.