Continental Subduction Research Articles

Geochemical characteristics and water quality assessment of trace elements in geothermal springs in the Gulu-Yadong rift, Tibetan Plateau

Thermal springs are enriched in many trace elements that are closely related to environmental and human health. The occurrence of trace elements in groundwater systems is one of the most significant environmental and public health concerns. The northward subduction of the Indian continental lithosphere beneath the Asian continent has produced an ongoing continental subduction zone. The Tibetan Plateau serves as the ‘Water Tower of Asia’, supplying drinking water to more than one billion residents in Asia. In this study, eighteen geothermal springs in the Gulu-Yadong Rrift (GYR) were selected for investigation of the geochemical characteristics of their trace elements. The geological process–related geochemical characteristics of trace elements in geothermal springs in the GYR were quantitatively assessed. The results indicated that there were high concentrations of Cr, As, B, and F in the geothermal waters in the GYR. The concentrations of Cr, As and B greatly exceeded the World Health Organization (WHO) guidelines for drinking water. The water quality throughout the whole rift was spatially heterogeneous. The concentrations of trace elements in only six geothermal springs were within the guidelines of the WHO, while the concentrations of trace elements in eleven geothermal springs considerably exceeded the WHO guidelines. Continental subduction–related magmatic processes, leaching and water-rock interactions may be the main factors controlling trace elements in the geothermal water. The deep circulation of the thermal water facilitated the addition of upwelling hot materials and magmatic fluids into the shallow aquifers, as well as enhancing the water-rock interactions. The results of this study indicate that geological processes have a large influence on the geochemical characteristics of trace elements in geothermal springs in the Tibetan Plateau. It is a non-negligible environmental and health issue in the plateau.

Petrogenesis of Late Campanian Alkaline Igneous Rocks in Eastern Anatolia: Magmatism related to a subduction transform edge propagator (STEP) fault?

ABSTRACT In eastern Anatolia, the Divriği-Hekimhan Magmatic Province (DHMP) includes ~77–69 Ma alkaline rock units which are located to the NW of the Baskil Arc of ~85–74 Ma. The magmatic rocks are composed of nepheline (Ne)–to quartz (Q)–normative alkaline basaltic to trachytic/syenitic units. Among them, the basaltic rocks are composed of plagioclase (Or2–11Ab32–51An39–64) + clinopyroxene (Wo47–51En35–42Fs9–16) + Fe-Ti oxide ± alkali feldspar (Or57–98Ab2–42An1) ± biotite ± olivine. Their 87Sr/86Sr(I) ratios and ɛNd(I) values vary in the ranges of 0.70591–0.70871 and−3.2–1.6, respectively. The subvolcanic trachytic rocks are composed of perthitic alkali feldspar phenocryst in a matrix of feldspar (Or45–61Ab38–54An0–2), biotite, and Fe-Ti oxides. The trachytic volcanic rocks are made up of feldspar (Or38–63Ab34–59An1–4) in a fine-grained matrix. Their 87Sr/86Sr(I) ratios and ɛNd(I) values vary in the ranges of 0.70532–0.70952 and−3.2–0.7, respectively. The syenitic rocks in the region contain both quartz- and nepheline-sodalite-bearing syenites. Geochemical features reveal that the Ne-normative basaltic magmas have undergone mafic mineral fractionation coupled with crustal contamination to produce the Q-normative derivatives. Enhanced differentiation of the Ne- and Q-normative fractionated magmas via feldspar-dominated fractionation created the silica-undersaturated and -oversaturated trachytic magmas, respectively. During the feldspar-dominated differentiation, the re-melting of accumulated alkali feldspars in the magma chamber likely gave rise to the formation of trachytic rocks with alkali feldspar-like whole rock compositions. The final products of the Ne-normative magmas are represented by the phonolites and foid-syenites with silica-undersaturated eutectic compositions. A geochemical evaluation of the basaltic rocks revealed that the alkaline magmatism mainly originated from a shallow asthenospheric mantle source which had previously been metasomatized by oceanic to continental subduction. We suggest that the DHMP was formed in response to STEP fault-controlled rolling back of the northward subducting slab of the Baskil Arc, which created a localized gap for asthenospheric upwelling.

Lithospheric evolution of eastern Arabia based on surface wave and receiver function analyses

The geodynamic evolution of Eastern Arabia comprises three major events that must have acted on the entire lithosphere below the present-day passive continental margin. Starting with the Pan-African plate assembly during the Late Proterozoic, NNE-oriented structural trends were established which were reactivated during Infracambrian and Ordovician extension. Permian Pangean breakup and rifting created two rift axes to form the present-day geometry of the eastern and northern passive margins of Eastern Arabia. SW-directed obduction of the Semail Ophiolite during the Late Cretaceous was the latest major tectonic event that shapes the present-day geology of northern Oman. Recent anisotropic ambient noise tomography, surface wave analysis of earthquake data and receiver function analysis reveal the present-day lithospheric thickness of ∼100 km, and the previously unknown, highly variable internal structure of the East Arabian continental crust. We integrate all newly available seismological observations into a consistent geodynamic model that describes the evolution of lithospheric thickness and crustal heterogeneity, identifies crustal segmentation and relates inherited structures to lateral variations within the dynamics of ophiolite obduction.A sharp, NNE-striking contrast of ∼10% in shear wave velocity (VS) in the lower crust separates felsic Arabian continental crust in the NW from intermediate lithologies in the NE of Oman. This crustal segmentation is interpreted as being established during the Pan-African orogeny. High VS in the lower crust of northeastern Oman is likely due to Permian mafic intrusions related to the Pangean breakup. Mild crustal thickening below todays high topography is attributed to Late Cretaceous time, where northward continental subduction below the Neo-Tethys led to underthrusting and thickening of the continental crust and ultimately to obduction of the Semail Ophiolite.After post-obduction relaxation, we argue that lithospheric thickness, margin perpendicular fast directions of anisotropy and contemporaneous mid- to late Eocene basanite intrusions are indicative of an overall relaxed state of stress of the lithosphere at that time. In consequence, we propose marginal erosion of the base lithosphere on the passive Arabian plate margin during the Late Eocene as a geodynamic process that facilitated margin-wide emergence of the Oman Mountains. Altogether, the present configuration of the lithosphere in northeastern Arabia preserves imprints from Late Proterozoic Pan-African assemblage, Permian Pangean break-up, Late Cretaceous subduction and ophiolite obduction, and Cenozoic post-obduction evolution.

Assembly of the Variscan Orogenic Wedge in the Bohemian Massif: Monazite U‐Pb Geochronology of the Tectonic Events Recorded in Saxothuringian Metasediments

AbstractThe geochronology of metasediments incorporated to orogenic wedges provides an important key in understanding the early evolution of collisional systems. This study reveals the timing of Variscan processes in the Saxothuringian orogenic wedge, reflecting transition from oceanic to continental subduction and collision. In situ monazite U‐Pb geochronology and Rare Earth Elements (REE) geochemistry were performed in the Erzgebirge Crystalline Complex on phyllites and micaschists surrounding the ultra‐high‐pressure (UHP) core of the Erzgebirge dome. The resulting ages and REE patterns were linked to the individual tectonometamorphic events and revealed that the hanging‐wall phyllites experienced prograde metamorphism around ∼350 Ma, followed by exhumation at ∼345–340 Ma. The oldest age (∼339 Ma) recorded in garnet cores in the foot‐wall micaschists is considered as an upper age limit for their prograde metamorphism, while matrix monazite ages of ∼330 Ma reflect a significant resetting of the monazite age system. Spatial distribution of metamorphic isograds and ages indicates a phase of accretion of continental material resulting in an inverted metamorphic field gradient in the wedge between ∼360 and ∼340 Ma. This phase was followed by exhumation of a significant portion of buoyant subducted continental material leading to massive ductile thinning of the wedge around ∼335 Ma. Finally, a late Variscan intracontinental deformation was responsible for heterogeneous reactivation and final exhumation of the wedge at ∼330 Ma. It is newly shown that the Saxothuringian wedge can be divided into a younger inner part, formed by micaschists and UHP rocks, and an older outer part, formed by phyllites.

Water transport in continental subduction zones: Constraints from eclogite from the Dabie orogen, east-central China

Water transport in continental subduction zones: Constraints from eclogite from the Dabie orogen, east-central China

Hot, Wide, Continental Back-arcs Explain Earth’s Enigmatic mid-Proterozoic Magmatic and Metamorphic Record

Higher than average thermobaric ratios (temperature/pressure) of metamorphic rocks and abundant ‘dry’ ferroan magmatism including massif anorthosite suites are two enigmatic features of the mid-Proterozoic (1.85–0.85 Ga) that have unclear origins. It has been proposed that elevated mantle temperatures due to insulation under the Columbia supercontinent, and/or to plate slowdown, combined with thin lithosphere, led to high continental geothermal gradients, high-temperature metamorphism, and an increase in dry, ferroan magmatism. Geodynamic modelling predicts that continental subduction zones at mid-Proterozoic mantle potential temperatures (80–150 °C hotter than at present) would exhibit key differences to the Phanerozoic, critically, extensive slab rollback combined with greater volumes of decompression melting of the asthenosphere would lead to wide regions of back-arc magmatism. We posit that these hot, wide continental back-arcs can effectively explain the abundance of ferroan magmatism, anorthosite suites, and high T/P metamorphism. Our model negates the need for extra mantle heating from supercontinental insulation or plate slowdown and shows that the tectonic regime of the mid-Proterozoic was a transitional phase between those of the Archean (likely comprising peel-back tectonics and episodic subduction) and the Phanerozoic (comprising deep continental subduction), and which could have resulted solely from secular cooling of the mantle.

Sediment recycling by continental subduction indicated by B-Hf-Pb-Nd isotopes from Miocene–Quaternary lavas in the northern margin of Tibet

Although it has been argued that sediment recycling plays an important role in the differentiation of the continental crust, boron (B) isotopic data does not support a direct input of subducted sediments into arc magmas. This raises questions about the viability of sediment recycling as a process in the differentiation of continental crust. Here, we report B isotopic data from Miocene–Quaternary lavas derived from different sources in the northern margin of Tibet. These lavas have high B contents and negative δ11B values close to those of continental sediments. Strongly peraluminous rhyolites have the highest B (93 to 1559 ppm) contents with negative δ11B (−9.7 to −17.9) values. Adakitic dacites and trachyandesites exhibit the lowest B (18 to 29 ppm) contents with markedly negative δ11B (−12.0 to −35.7) values whereas olivine leucitites have B (37.2 to 59.3 ppm) contents with negative δ11B (−8.3 to −15.6) values. These lavas also have enriched Hf-Pb-Nd isotopic compositions similar to those of sediments. This data, combined with numerical modelling and geophysical and tectonic data for Cenozoic continental subduction in the northern margin of Tibet, indicates that: (1) the strongly peraluminous rhyolites were generated by partial melting of mica-bearing continental sedimentary rocks subducted to the depth of mid-to-lower crust; (2) adakitic lavas were derived by partial melting of sediment-bearing thickened lower crust underwent dehydration and eclogites-facies metamorphism; and (3) olivine leucitites were generated by partial melting of enriched mantle metasomatized by sediment-bearing eclogite-facies crust-derived melts. Thus, at continental convergent margins, continental subduction is an important mechanism for sediment recycling and the evolution of continental crust.

Serpentinization and Deserpentinization of the Mantle Wedge at a Convergent Plate Margin: Evidence of Orogenic Peridotites from a Composite Oceanic–Continental Subduction Zone

AbstractSerpentinites of the mantle wedge were identified from a composite oceanic–continental subduction zone that occurs as the Hong’an orogen in east–central China. They were comprehensively investigated by an integrated approach of whole-rock major and trace elements, mineral major and trace elements, whole-rock and olivine O isotopes, and phase equilibrium modeling as well as zircon U–Pb ages, trace elements, and Hf-O isotopes. These serpentinites show high Mg# and MgO/SiO2 ratios but low Al2O3/SiO2 ratios as well as low Ti contents, resembling those from the mantle wedge rather than the subducting oceanic slab. Petrographic observations were combined with CIPW norm calculations to suggest that the protoliths of these serpentinites are refractory peridotites in the mantle wedge. Whole-rock and mineral compositions indicate that these serpentinites experienced multiple episodes of metamorphism and metasomatism during the tectonic development from oceanic subduction in the Carboniferous to continental collision in the Triassic. The enrichments of Th, U, light rare earth elements and high field strength elements in the whole rock and the finding of zircon inside them indicate their formation through metasomatism of the mantle wedge peridotites by subducting crust-derived fluids. The ca. 310 Ma zircon domains exhibit positive εHf(t) values of 4.5 to 19.1 and variable δ18O values similar to those of oceanic-type eclogites in the Hong’an orogen but different trace element compositions, indicating their formation through metasomatism by fluids from the subducting Paleotethyan oceanic crust. The ca. 430 Ma zircons exhibit U–Pb ages, trace elements and Hf-O isotopes similar to those of the protolith magmatic zircons in the oceanic-type eclogites. The older zircon domains also exhibit similar element and isotope compositions to inherited zircons from the high- to ultrahigh-pressure metamorphic rocks in the Hong’an orogen. Thus, these relict zircons would be physically transferred into the serpentinites by metasomatic fluids originating from the subducting Paleotethyan oceanic crust. High Th/U ratios for the ca. 310 Ma zircons imply their formation through the metasomatic reaction rather than direct precipitation from the subducting oceanic crust-derived fluids. The metasomatic zircons of Triassic age show negative εHf(t) values of −16.0 to −2.7, indicating their formation through metasomatic overprinting by deeply subducting continental crust-derived fluids in the continental subduction channel during the Triassic continental collision. In this context, the mantle wedge peridotites were first metasomatized in the Carboniferous by the subducting oceanic crust-derived fluids. Afterwards, part of the metasomatized peridotites were off-scrapped into the oceanic subduction channel, where they were hydrated by further subducting oceanic crust-derived fluids to form antigorite serpentinite at forearc depths. The antigorite serpentinite was carried to deeper depths during subsequent continental subduction and underwent dehydration there. This gave rise to metamorphic olivine with extremely high Fo values of 96.7 to 97.6 and higher MnO but lower NiO contents than common mantle olivine. The coexistence of lizardite, brucite and magnesite in the serpentinites indicates their retrograde processes of serpentinization and carbonation on the subsurface. Therefore, the present observations and interpretations of orogenic serpentinites provide insights into the multistage fluid metasomatism at different depths during the tectonic transition from oceanic subduction to continental collision.

Petrology and phase equilibria of HP/LT eclogite at Gaoqiao, western Dabie and implications for lawsonite development in continental subduction zones

Lawsonite is of great significance for understanding fluid activity, element migration and crust–mantle interactions in subduction zones. Though studies have predicted lawsonite to be present under theP–Tregime during continental subduction, no lawsonite has been documented from natural (U) HP rocks in continental orogenic belt. In this study, we work on HP–LT eclogite (GQ–1 and GQ–2) at Gaoqiao, western Dabie to explore lawsonite formation and preservation during continental subduction and exhumation. Both samples have ubiquitous polymineralic aggregates of epidote/clinozoisite + paragonite/albite ± other minerals showing distinct rectangular or rhombic shapes developed as inclusions in garnet or in the matrix. Combined with recalculated bulk compositions similar to that of ideal lawsonite, we interpret these polymineralic aggregates to be pseudomorphs after lawsonite. Phase equilibrium modelling combined with compositional isopleth thermobarometry have constrained a segment of the prograde to peak stages to evolve from 19.0 to 19.5 kbar, ∼470°C to ∼20.0 kbar, 500C–505°C, then to ∼25 kbar, 530C–555°C in lawsonite stability fields. The progradeP–Tpath shows a two-stageP–Tevolution, with the first stage following a geothermal gradient of ∼7°C/km and the second stage decreasing to ∼6°C/km. Initial exhumation was inferred to follow an isothermal decompression process leading to lawsonite breakdown to form epidote/clinozosite ± paragoniteviathe reaction lawsonite + omphacite→ epidote + glaucophane ± paragonite + H2O at ∼19 kbar, 550°C. ModeledP/T–Xpseudosections calculated atT= 550°C andp= 25 kbar show that, when H2O content in bulk composition is more than 1.1 wt%, a certain amount of lawsonite (>13 mode%) should be present in eclogite. On the other hand, in the compositional range of natural intracontinental plate basalts, variations on O (Fe3+),XMgO[MgO/(MgO+FeO)],XCaO[CaO/(CaO+MgO+FeO+MnO+Na2O)],XNa2O[(Na2O/(CaO+Na2O)] andXAl2O3[Al2O3/(Al2O3+CaO+Na2O)] in bulk compositions have little influence on lawsonite development. In combination with previous studies, we conclude that during continent subduction along low geothermal gradient (<8°C/km), lawsonite could be formed under H2O present conditions. The absence of lawsonite in natural eclogite might be ascribed to retrograde overprint during exhumation.

The role of continental subduction in mantle metasomatism and carbon recycling revealed by melt inclusions in UHP eclogites.

Subduction is the main process that recycles surface material into the mantle. Fluids and melts derived by dehydration and partial melting reactions of subducted continental crust, a major reservoir of volatiles (i.e., H2O and CO2) and incompatible elements, can substantially metasomatize and refertilize the mantle. Here, we investigate glassy inclusions of silicate melt of continental origin found in Variscan ultrahigh-pressure eclogites to assess the continental crust contribution to mantle metasomatism and the journey of volatiles, carbon in particular, to the deep roots of mountain belts. We argue that the melt preserved in these inclusions is the agent responsible for mantle metasomatism and subsequent ultrapotassic magmatism in the Variscides. We propose that continental subduction can redistribute a substantial volume of carbon in the continental lithosphere, which is subsequently transferred to the continental crust during postcollisional magmatism and stored for a time length longer than that of the modern carbon cycle.

Supplemental Material for GRL paper of Dabie continental subduction

Supplemental Material for GRL paper of Dabie continental subduction

The transition from oceanic to continental subduction and collision: A case study of the North Qaidam ultrahigh-pressure metamorphic belt, northern Tibetan Plateau

The transition from oceanic to continental subduction and collision: A case study of the North Qaidam ultrahigh-pressure metamorphic belt, northern Tibetan Plateau

Protracted eclogite‐facies metamorphism of the Dulan area, North Qaidam ultrahigh‐pressure terrane: Insights on zircon growth during continental subduction and collision

AbstractContinental subduction and collision are recorded by ultrahigh‐pressure (UHP) terranes; UHP terranes that form at early stages of an orogeny tend to be small and experience short residence at eclogite‐facies depths, whereas terranes that form at mature stages of an orogeny tend to be larger and experience longer residence at these depths, but accurately determining eclogite‐facies residence time requires a large geochronologic dataset tied to metamorphic conditions (via trace elements and/or inclusions). In the Dulan area, North Qaidam UHP terrane, China, it remains unclear whether the terrane experienced a long residence at eclogite‐facies depths, marking the mature stage of an orogeny or two distinct (ultra)high pressure ([U]HP) events (with short residence times), interpreted as the transition from oceanic subduction to continental collision, where one (U)HP event is related to the former and second (U)HP event to the latter. To address this issue, we report new zircon U–Pb ages and trace‐element data from eclogite and host paragneiss from the Dulan area and show that this terrane records ~42 Myr of eclogite‐facies metamorphism at (U)HP conditions, similar to other large UHP terranes. Zircon from 11 eclogite and 2 gneiss samples yields weighted mean ages of 463–425 Ma, flat heavy rare earth element (HREE) patterns without negative Eu anomalies, and eclogitic mineral inclusions, indicating eclogite‐facies conditions. Paragneiss metamorphic ages overlap with ages from eclogite but are generally younger, suggesting that a lack of internally generated fluids may have inhibited zircon growth and/or recrystallization until early decompression and white mica consumption in felsic gneiss generated fluids; thus, we interpret that these felsic rocks record the later stages of continental collision. Dataset patterns from all new and previously published analyses for the Dulan area (34 eclogite and 14 gneiss) suggest that metamorphic zircon in eclogite records prograde, peak and possibly early retrograde conditions, in contrast to the prediction from mass balance models that metamorphic zircon should only grow during exhumation and cooling. We reconcile our observations with these model predictions by recognizing that differential solubility can lead to grain‐scale zircon growth or recrystallization over a large segment of the pressure–temperature (P–T) path even where zircon abundance decreases at the whole‐rock scale.

Discovery of the mid-Cretaceous sedimentary rocks from the ultrahigh-pressure terrane, Dabie Orogenic Belt, and its tectono-paleogeographic implications

The Dabie Orogenic Belt, located in east-central China, is known for the greatest outcrop area of the ultrahigh-pressure metamorphic rocks in the world and is typical for studying deep continental subduction and continent–continent collision. However, since lower-grade metamorphic rock occurrence in the core of the ultrahigh-pressure terrane was reported, it has become a new point of concern. This study reported new results. The so-called lower-grade metamorphic rocks are divided into sedimentary rocks and meta-volcanics. The sedimentary rocks consist mainly of fine-grained turbidites formed under an anoxic deep-water lacustrine basin. Laser Ablation–Inductively Coupled Plasma–Mass Spectrometry U–Pb detrital zircon dating indicates that their maximum deposit age is 119.0 ± 1.1 Ma belonging to the mid-Cretaceous Aptian. U–Pb detrital zircon ages from the sedimentary rocks cluster in three age groups: 1) 2773.8–1550.0 Ma (45.0%); 2) 868.8–622.3 Ma (23.0%); 3) 147.0–100.0 Ma (31.5%). And the provenance and tectonic settings of these sedimentary rocks are discussed by synthesizing U–Pb detrital zircon ages, initial Hf isotope ratios, and trace elements of the zircons. Source rocks of the first group were mainly composed of the Paleoproterozoic basement derived from the reworking of the Paleoarchean–Neoarchean Yangtze continental crust. For the second group, its source rocks consisted of Neoproterozoic volcanics mainly from an island arc system, which derived from the reworking of older continental crust in the northern Yangtze Block. The third group's source rocks were chiefly composed of Cretaceous rift igneous rocks derived from the derivation through melting of middle-aged continental crust in the Dabie Orogenic Belt. The meta-volcanics have weighted mean U–Pb ages from 751.0 ± 16 Ma to 786.3 ± 5.9 Ma, and their protoliths formed under a Middle Neoproterozoic island arc system in the northern Yangtze Block. The meta-volcanics underwent a Triassic subduction of different depths and then an exhumation, but the sedimentary rocks did not. The findings suggest that the ultrahigh-pressure terrane had suffered violent subsidence during the mid-Cretaceous, and a four-stage evolution model of the Dabie Orogenic Belt was established accordingly.

Partial melting of subducted continental crust during the exhumation: Insights from Palaeozoic granitic rocks in South Altyn, western China

The early Palaeozoic continental subduction–collisional belt in South Altyn (SA) western China distributes a large amount of (ultra)-high-pressure ((U)HP) metamorphic and granitic rocks associated with subduction, collision, and exhumation. In this study, four granitic rocks were collected from Bashenwake located in eastern SA. The ages of the garnet-bearing alkali-feldspar granite (GAFG), garnet-bearing granitic gneiss (GGG), alkali-feldspar granite (AFG), and syenogranite (SG) are 458.0 ± 4.1, 483.0 ± 4.1, 450.0 ± 2.4, and 482.0 ± 4.9 Ma, respectively. Whole-rock major and trace elements and Sr–Nd–Pb isotope, and zircon Hf isotope compositions for all samples exhibit characteristics of a continental crustal source. Based on partial melting modeling, the source temperature of the GGG, GAFG, AFG and SG was concluded as 750–780 °C, 730–760 °C, 730–770 °C and ca. 800 °C, respectively. The source pressure was estimated as ca. 0.8 GPa for the GGG, GAFG and AFG, and ca.1.2 GPa for SG. Combined with studies on (U)HP metamorphic rocks in SA, this study reveals that GGG is formed by metamorphism while SG is formed from partial melting of upper crustal rocks heated by upwelling mantle during the initial stage of exhumation (ca. 480 Ma) of subducted continental crust in SA. During further stage of exhumation of the subducted continental crust at ca. 450 Ma, the GAFG and AFG were formed from partial melting of GGG as a result of decreased pressure and further mantle upwelling. Consequently, the exhumation age of subducted continental crust in eastern SA is ca. 30 Myr earlier than that in western SA. Thus, the geochronology and petrogenesis of four granitic samples in this study exhibit one of very few evidence for partial melting of subducted continental crust during the exhumation and also provide magmatism exhibits evidence for the differential exhumation model of eastern SA in Palaeozoic.

Mantle refertilization in high-pressure conditions of continental subduction channel:Evidence from orogenic peridotite in the Sulu ultrahigh pressure terrane, eastern China

Mantle refertilization in high-pressure conditions of continental subduction channel:Evidence from orogenic peridotite in the Sulu ultrahigh pressure terrane, eastern China

Mantle refertilization in high-pressure conditions of continental subduction channel:Evidence from orogenic peridotite in the Sulu ultrahigh pressure terrane, eastern China

Mantle refertilization in high-pressure conditions of continental subduction channel:Evidence from orogenic peridotite in the Sulu ultrahigh pressure terrane, eastern China

Post-Collisional Silica-Undersaturated Bamaoqiongzong Volcanic Rocks from Northern Qiangtang: Indicators of the Mantle Heterogeneity and Geodynamic Evolution of Central Tibet

AbstractThe formation of post-collisional mantle-derived rocks in the Tibetan Plateau has been linked to the deep geodynamic processes that cause surface uplift. Co-existing silica-oversaturated to silica-undersaturated mantle-derived rocks have been identified in the northern Qiangtang Terrane (NQT). However, the origins of silica-undersaturated magmas are controversial, and the mechanisms responsible for variable silica activity in the mantle-derived rocks are unclear. Here, we present 40Ar/39Ar chronology, mineral chemistry, and whole-rock geochemical data for the Bamaoqiongzong (BMQZ) volcanic rocks of the NQT. The BMQZ volcanic rocks consist of olivine leucitites, trachybasalts, and phonolites and were erupted at ca. 29 Ma. All samples are unsaturated in silica and characterized by enrichment in light rare earth elements and large-ion lithophile elements, depletion in high-field-strength elements, and the presence of negative Nb–Ta–Ti anomalies and positive Pb anomalies. All samples show limited variation in (87Sr/86Sr)i (0.7079–0.7085) and εNd(t) values (−6.9 to −5.3). The geochemical compositions of the BMQZ volcanic rocks indicate that they were produced by partial melting of carbonated phlogopite–lherzolite within the lithospheric mantle. The formation of the olivine leucitites-trachybasalts-phonolites suite was controlled by fractional crystallization and magma mixing in a magmatic plumbing system. This plumbing system included several independent reservoirs and conduits within the crust. The enriched mantle sources of the BMQZ volcanic rocks were formed by the addition of carbonate-rich melts released from the southward-subducted Songpan–Ganzi Terrane after the Late Cretaceous. Our new results, together with published data, reveal systematic variations in geochemical compositions between silica-undersaturated and silica-oversaturated rocks in the NQT, which are ascribed to variations in the nature of the subducted continental materials added during intracontinental subduction. Carbonate-rich melts that were formed by the breakdown of carbonate minerals helped to generate the mantle sources of silica-undersaturated rocks, whereas silicate melts produced by the partial melting of sediment diapirs contributed to the generation of the silica-oversaturated rocks. On the basis of published numerical modelling of continental subduction and crustal deformation records in the NQT, we suggest that intracontinental subduction and lithospheric thinning together contributed to the generation of post-collisional mantle-derived rocks in the Tibetan Plateau.

Tourmaline chemistry, boron, and strontium isotope systematics trace multiple melt–fluid–rock interaction stages in deeply subducted continental crust

The generation, transport, and recrystallization of slab-derived melts/fluids play a critical role in the deep recycling of elements in subduction zones. While boron (B) isotope systematics have been invoked as an important tracer of these processes, its behavior during metamorphic dehydration and partial melting of deeply subducted continental slabs, and the partitioning of B isotopes between minerals and melts/fluids is not fully understood. Here, we investigate these processes through an in situ study of the major, trace-element, and B-Sr isotope variations in different occurrences of tourmaline in migmatite from the Yuka terrane, North Qaidam orogen (China), which resulted from partial melting of a continental slab at different stages during subduction and exhumation. Based on textural and detailed high-resolution X-ray mapping studies, tourmaline was classified into four paragenetic generations (Tur-I, Tur-II, Tur-III, and Tur-IV). Dravitic Tur-I occurs in melanosomes and shows increasing Fe, Ca, and Ti contents from the core to the outer rim. In addition, it has relatively homogeneous Sr isotope values (0.7407–0.7416) and decreasing δ11B values (-3.8 to −8.6 ‰) and XMg (Mg/(Mg + Fe)) ratios, indicating formation in a rock buffered by an aqueous fluid during the prograde to peak metamorphism. Schorlitic Tur-II occurs within selvage zones between melanosomes and leucosomes, and yields high-Fe values and low δ11B (-13.5 to −10.9 ‰) and more variable 87Sr/86Sr (0.7343–0.7418) values, indicating crystallization in the presence of a hydrous melt external derived from breakdown of Fe-rich mineral(s) during partial melting of the subducted slab. Dravitic Tur-III formed in the matrix and also enveloped Tur-II. It shows homogeneous 87Sr/86Sr values (0.7411–0.7420) and decreasing δ11B values (-6.8 to −9.9 ‰) and XMg ratios as well as increasing Fe and Ti contents from core to outer rim. Formation of Tur-III reflects a transitional stage from hydrous melt to aqueous fluid during exhumation. Tur-IV in the leucosomes is essentially a schorl-dravite solid solution with small amounts of Ca. Its 87Sr/86Sr values (0.7402–0.7416) and δ11B values (-11.4 to −8.5 ‰) are intermediate between the respective values of Tur-II and Tur-III. The formation of Tur-IV likely results from interaction between melt and fluid and, based on its chronological sequence, and is interpreted to have formed during the exhumation stage of the Yuka terrane.Overall, the variable XMg ratios and δ11B values in the different generations of tourmalines are a consequence of the evolution of the melt/fluid at different depths within the deeply subducted slab. Decreasing δ11B values from Tur-I to Tur-II and Tur-III are controlled by the breakdown of different minerals during partial melting or metamorphic dehydration of the subducted slab, while the co-variations of the elemental geochemistry and B isotopic compositions of tourmaline reflect different depths of formation during subduction and exhumation of the lithosphere. These observations suggest tourmaline may serve as a useful tracer of multiple melt/fluid–rock interactions and of boron cycling in continental subduction zones. The heterogeneity of δ11B in melts/fluids at different depth levels of the continental subducted slab may also result in locally variable B isotope values in syn- and post-collisional magmas.

Heterogeneous orogenic lithospheric mantle beneath the North Qaidam orogen: Geochemical evidence from syn-exhumation and post-collisional mafic magmatic rocks

Syn-exhumation and post-collisional mafic magmatic rocks are generally exposed in continental collision orogens. Their geochemical compositions can not only reflect the nature of orogenic lithospheric mantle but also provide a window to trace crust-mantle interaction in continental collision zones. Herein, we present a combined study of whole-rock major-trace elements and Sr-Nd-Hf isotopes as well as zircon U Pb ages and Hf O isotopes for the Paleozoic mafic magmatic rocks from the North Qaidam orogen, northeastern Tibet. Zircon U Pb dating for the rocks yields two groups of ages of 420 ± 8 to 395 ± 2 Ma and 383 ± 5 to 368 ± 3 Ma, corresponding to the syn -exhumation and post-collisional stages, respectively. These mafic magmatic rocks are characterized by arc-like trace element distribution patterns, enriched to depleted radiogenic Sr-Nd-Hf isotope compositions and high zircon δ 18 O values, which are comparable to those of the orthogneiss and continental eclogite in this orogen. This indicates their derivation from the orogenic lithospheric mantle modified by the subducted continental crust during the continental collision. Significant differences in radiogenic isotope compositions between the syn -exhumation and post-collisional mafic magmatic rocks suggest their mantle sources were mainly metasomatized by the orthogneiss- and continental eclogite-derived melts, respectively. Quantitative modelling of trace element compositions shows that about 93.0:6.0:1.0 and 91.7:2.8:5.5 mixture of the mantle peridotite, orthogneiss- and continental eclogite-derived melts with 23% and 28% aggregated fractional melting can closely match the syn -exhumation and post-collisional mafic magmatic rocks, respectively. The reaction of the continental crust-derived melts with mantle peridotite would result in the heterogeneous orogenic lithospheric mantle. Therefore, the syn -exhumation and post-collisional mafic magmatic rocks provide a snapshot of the compositional variations in the orogenic lithospheric mantle and the crust-mantle interaction in the continental collision zone. • Syn-exhumation/post-collisional mafic magmatic rocks in the North Qiadam orogen. • They were derived from a heterogeneous orogenic lithospheric mantle. • The mantle source was metasomatized by melts from the subducted continental crust. • These rocks record crust-mantle interaction in the continental subduction channel.