Continental Margin Environment Research Articles

Origin and paleo-oceanic conditions of Guadalupian bedded chert in the northern margin of the Upper Yangtze region: Implication for marine anoxia and the Permian Chert Event

Unusual accumulations of chert developed worldwide over tens of millions of years during the Permian Period, and they are referred to as the Permian Chert Event. Middle Permian cherts, in the forms of nodules and bedded cherts, are widely distributed in the Yangtze region. A comprehensive study was conducted on middle Permian cherts from the Xibeixiang section on the northern margin of the Upper Yangtze region. This study combined micropaleontology and geochemical analyses to determine the ages, paleo-oceanic conditions, and implications of the Permian Chert Event. Identification of conodonts and brachiopods showed that the Xibeixiang cherts belong to the late Capitanian Jinogondolella granti zone. The Xibeixiang cherts can be divided into two subunits. The lower section (Sc1) consists of a thin interbedded layer of bedded chert, shale, and limestone, which were strongly influenced by upwelling with relatively low temperatures. The upper section (Sc2) comprises a thin interbedded layer of bedded chert and shale. The intermediate chemical index of alteration (CIA) values of Sc2 suggest a temperature increase compared to Sc1 and a weakening of upwelling activity. The Sc2 section of the Xibeixiang cherts is consistent with the end-Capitanian oceanic anoxic event and coincides in time with the end-Guadalupian biotic crisis, supporting a connection between the biotic crisis and marine anoxia. The Permian Chert Event distributions in the Guadalupian Epoch exhibit substantial temporal and spatial heterogeneity on a global scale. Alterations in the oceanic environment likely caused the shoaling of the lysocline and calcite compensation depth (CCD). This allowed cherts to be deposited instead of carbonates, even in relatively shallow-marine areas, such as continental margin environments.

The Early Neoproterozoic Andean-Type Orogenic and Within-Plate Magmatic Events in the Northern Margin of the Yangtze Craton during the Convergence of the Rodinia Supercontinent

Although considered a crucial component of the Rodinia supercontinent, it remains uncertain how the Yangtze craton relates to the accretion and breakup of Rodinia. Here, the Huanglingmiao granitic complex (HGC), an intermediate-acid rock series that intruded on the southern Kongling terrane of the northern Yangtze craton margin, is investigated to help resolve this conundrum. Our analysis indicates that these rocks consist of tonalite, trondhjemite, granodiorite, oligoporphyritic granodiorite, porphyric biotite granodiorite, and fine- to medium-grained granodiorite dyke compositions. Collectively, this assemblage is further subdivided into two categories by their temporal, spatial, and geochemical features into early TTG-like and later granitic–dioritic units, which are composed of tonalite, trondhjemite, granodiorite, porphyritic granodiorite, and the fine- to medium-grained granodiorite dykes, respectively. Zircon U-Pb dating yields ages of 865~850 Ma for the TTG-like rocks, 844~825 Ma for the porphyritic granodiorites, and ~800 Ma for the granodiorite dykes. Combined with geochemical evidence, the data suggest that the early- and late-series rocks were formed by a partial melting of Mesoproterozoic and Paleoproterozoic crustal materials, respectively, suggesting that the vertical layering of the crust controlled the composition of the independent units. In addition, isotopic evidence points to different sources for the various rocks in the Kongling terrane and that mantle-derived materials influenced the early-series lithologies. Combined with previous studies on the northern margin of the Yangtze craton, it is inferred that the early-series rocks formed in an active continental margin environment, while the late-series rocks display within-plate boundary formation characteristics. The multiple magmatic activities revealed by this study record sequential partial melting with tectonic transition characteristics from an Andean-type to within-plate magmatism in the northern margin of the Yangtze craton. Taken together, these observations point to a strong association between these rocks, convergence, and incorporation of the northern Yangtze craton margin into the Rodinia supercontinent during the Tonian Period.

Geology, geochemistry, mineralization and fluid inclusion characteristics of the SW of Hormuz Island banded iron formations, southern Iran

The Hormuz Island banded iron formations (HIBIFs) are situated at the Zagros Folded Zone in southern Iran. The BIFs occur intercalated with the Neoproterozoic Hormuz series, an evaporite and siliciclastic succession with pyroclastic rocks, and were deposited on the continental rift margin of the Arabian plate. The HIBIFs are banded rocks consisting of the alternation of dark Fe-rich and reddish-brown Si-rich layers, and belong to oxide facies iron formations. The post-Archean Australian shale normalized rare earth elements and yttrium patterns of HIBIFs have the characteristics of both hydrothermal solutions and seawater. The sharp positive Eu anomaly (2.10–6.90) may be inherited from high-temperature hydrothermal solutions, while slightly negative Ce anomalies (0.57–0.82) are inherited from seawater. The homogenization temperature and salinity of primary fluid inclusions range from 180.7 to 474.3°C and from 2.24 to 12.85 wt% NaCl, respectively, which suggests that intermediate- to high-temperature hydrothermal fluids and seawater contributed to the formation of the HIBIFs. The Eu/Sm and Sm/Yb ratios in BIFs are between the values of hydrothermal fluids and seawater. In summary, all geological and geochemical data suggest that the HIBIFs are a post-great oxidation event iron formation pulse at the end of the Ediacaran period. However, this is actually not similar to Neoproterozoic syn-glacial iron formations. Instead, this is a new occurrence of iron formation in an overlooked/understudied time period when either global or local conditions were conducive to iron deposition. The iron deposition on Hormuz Island does not appear to be triggered by fluctuating atmospheric oxygen or sea-level variations, but instead may be related to syn-basinal volcanism in the active continental rift margin environment in anoxic submarine condition. Thematic collection: This article is part of the Geochemical processes related to mined, milled, or natural metal deposits collection available at: https://www.lyellcollection.org/topic/collections/geochemical-processes-related-to-mined-milled-or-natural-metal-deposits

Unraveling the early Paleozoic tectonic history of the South Qinling Belt: Evidence from geochronology, geochemistry, and Sm-Nd isotopes of meta-sedimentary rocks

The determination of the petrogenesis and age of meta-sedimentary rocks plays a crucial role in enhancing our understanding of regional tectonic evolution. In this study, we conducted comprehensive geochemical, zircon U-Pb, and Sm-Nd isotope dating analyses of the biotite gneiss of the Changjiaoba group to investigate the tectonic evolution of the South Qinling belt. The age range of detrital zircons from the biotite gneiss was estimated to be 446–2798 Ma, with prominent peaks observed at approximately 454, 660, 790, 1998, and 2770 Ma. The earliest data indicate that the final sedimentary age of the Changjiaoba group corresponds to the late Ordovician. The protoliths of the biotite gneiss were argillaceous rocks, classified as parametamorphic rock. The chondrite-normalized rare earth element (REE) diagram exhibited right-inclined patterns with negative Eu anomalies. The upper continental crust (UCC)-normalized trace element patterns exhibited insignificant enrichment of Ba, Sr, and K; negative anomalies of Hf, Th, U, and Ti; and depletion of Cr and Ni. Geochemical indicators suggest that the precursor sediments are felsic rocks that have undergone moderate weathering. The εNd (t) values of the biotite gneiss (−10.2 to −3.4) suggest a mixture of a few juvenile crust components and abundant ancient material, indicating an arc-realted setting. Collectively, our findings suggest that the primary material sources of the Changjiaoba group were predominantly the North Qinling belt during the Paleozoic and the Yangtze block during the Neoproterozoic. The tectonic setting discrimination diagrams imply that the biotite gneiss were formed in an active continental margin environment, supporting the notion of the northward oceanic subduction during the early Paleozoic. In conclusion, our study provides valuable insights into the composition and deposition history of the Changjiaoba group in the South Qinling belt, contributing to our understanding of the regional geology.

Purple soil inheritance and source of parent rock material and tectonic background in the Sichuan Basin, China

ABSTRACT The parent rock inheritance of the purple soils in the Sichuan Basin is evident, and this is due to factors that are directly related to the parent rocks’ characteristics. Fundamentally, the nature of purple soils is determined by the lithology, chemical composition, weathering, and soil formation of parent rocks, whereas the provenance, and tectonic context of rocks during their diagenesis have a significant influence on their rock attributes. In this study, rocks from four sedimentary layers of the Cretaceous and Jurassic eras – k1c, J3p, J3s, J2s in the Sichuan Basin – as well as the overlying soils were examined, and experimental determinations of the samples’ physical characteristics and chemical elemental composition were made to confirm the parent rock inheritance of purple soils. The essential weathering indices ICV, CIAcorr, WIP, and Na/K were used to study the weathering characteristics of the rocks and soils, and the A-CN-K ternary diagram was used to assess the weathering trends of the rocks. The findings demonstrate that purple soil exhibits significant parent rock inheritance due to its rapid physical soil formation process and weak chemical weathering process. That the rocks of the four sedimentary layers in the study area have all reached a moderate degree of weathering, their original source components are quartzose sedimentary which may have been derived from feldspar source rocks. The tectonic background of the source rocks may be mainly continental arc and active continental margin environment, there may be an oceanic arc tectonic environment.

Lithology, Geochemistry of the Middle Devonian Sediments and the Influence of Volcanism on Sedimentation in the Southeast of West Siberia

Abstract —Dataset on the Middle Devonian volcanic-carbonate–terrigenous sediments of Salair and the Kuznetsk trough, submerged northward under the Mesozoic–Cenozoic West Siberian geosyneclise (WSG) cover, have been presented. Mainly deep water sediments composed of thin- and fine-grained clastic material (with predominance of tephroids) and thin-, fine-clastic biodetrital limestones with slope slide breccia, as well as turbidites and peculiar “conglomerate-like” limestones (paleoseismites) were found. Sedimentary and geodynamic environments have been reconstructed for the Middle Devonian strata. Predominantly andesitic composition of pyroclastic ashes with fewer values of felsic and basic volcanic components have been determined. The structures related to the continental margin environments of the Siberian continent, the continental slope and its basement have been found. According to sedimentary and geochemical data, the paleogeodynamic environment within the studied region was relatively stable and generally corresponded to the island arc conditions. The paleoclimate of the source area changed from semi-humid in the late Emsian–early Eifelian (Malaya Salairka age) to aridic in the middle Givetian (Kerlegesh age). Basin sediments formed in the deep water oxic environments with good water aeration, excepting euxinic environments found in the lowermost part of studied succession.

Provenance, Sedimentary Environment, Tectonic Setting, and Uranium Mineralization Implications of the Yaojia Formation, SW Songliao Basin, NE China

The SW Songliao Basin is an extremely significant part of the giant sandstone uranium metallogenic belt in northern China. The Yaojia Formation is the most significant ore-bearing layer in the region. However, the poorly constrained sedimentology of the Yaojia Formation has substantially hindered the understanding of the basin and the exploration of uranium deposits within it. To determine the sedimentology, provenance, and tectonic setting of the Yaojia Formation in the study area, we conducted petrography, whole-rock geochemical analysis, and electron probe research. Based on the results of the study, it appears that the Yaojia Formation sandstone is predominantly composed of lithic sandstone and feldspar lithic sandstone. Uranium exists in two forms: as independent minerals and as adsorption uranium. Pitchblende is the most common independent uranium mineral, with small amounts of coffinite also occurring. The ratios of Sr/Ba, V/(V+Ni), V/Cr, Ni/Co, and (Cu+Mo)/Zn of the samples indicate that the Yaojia Formation was deposited in a sub- to oxygen-rich freshwater environment with a moderately stratified bottom water body and smooth circulation. The geochemical characteristics of the Yaojia Formation sandstones imply that they are primarily derived from felsic igneous rocks in the upper continental crust in active continental margin and continental island arc environments. According to geochemistry and previous detrital zircon U-Pb chronology studies, the Mesozoic and Late Paleozoic felsic igneous rocks of the southern Great Xing’an Mountains are the principal sources of the Yaojia Formation in the SW Songliao Basin. Besides providing sediments for the study area, the uranium-rich felsic igneous rocks in the source areas also represent a long-term, stable, and ideal source of uranium, suggesting substantial potential for uranium exploration in the study area.

Insights on the Formation Conditions of Manganese Oxides from Crimora, VA (USA)

Many regions of the United States contain manganese deposits economically valuable in New England, Appalachian, and Piedmont regions in the Eastern United States, in Northern Arkansas, and, to a small extent, in Central–Western California. Mn oxide/hydroxide (commonly referred to as Mn oxide minerals) are found in a wide variety of geological settings and occur as fine-grained aggregates, veins, marine and freshwater nodules and concretions, crusts, dendrites, and coatings on rock surfaces (e.g., desert varnish). How manganese oxides form and what mechanisms determine which oxides are likely to form are limited and still debated. This paper focuses on Mn oxides collected at the southern bound of the abandoned open-pit site called Crimora Mine (Augusta County, Virginia). This study uses mineralogical and chemical features to shed light on the origin of manganese deposits in Crimora along the western foot of the Blue Ridge in South–West Virginia. We report the first detailed study on the genesis of the Crimora manganese deposit conducted since the mine was closed in the 1950s. Crimora Mine sample is dark black fine- to medium-grained round and oblong nodules coated with a fine-grained intermix of yellowish earthy limonite, clays, and quartz. Scanning electron microscopy (SEM) revealed that the Crimora Mn-oxides exhibit concentric layering, breccia-like matrices, and veins. X-ray powder diffraction (XRPD) identified the set of Mn minerals as hollandite and birnessite. The concentration and range of dissolved chemical species in freshwater, seawater, and hydrothermal depositional fluids impart a geochemical signature to the Mn-oxides, providing a diagnostic tool to shed light on their genetic origin. Inductively coupled plasma optical emission spectroscopy (ICP-OES) analysis of the Crimora manganese oxides shows Mn, Fe, and Ti, as well as trace elements such as Co, Ba, Y, Zn, Cr, Ni, Tl, La, V, and Li. A bivariate analysis based on the geochemical correlation of Mn and other common substituting cations (e.g., Fe, Co, Ti) shows a mixed genesis in different environments with varying biological and sedimentary supergene (freshwater and marine) conditions. These data suggest that the Mn-rich deposit in Crimora, VA, was formed in a continental margin environment of surficial deposits and reprecipitated in mixed biogenic and supergene conditions.

Dominance of benthic fluxes in the oceanic beryllium budget and implications for paleo-denudation records.

The ratio of atmosphere-derived 10Be to continent-derived 9Be in marine sediments has been used to probe the long-term relationship between continental denudation and climate. However, its application is complicated by uncertainty in 9Be transfer through the land-ocean interface. The riverine dissolved load alone is insufficient to close the marine 9Be budget, largely due to substantial removal of riverine 9Be to continental margin sediments. We focus on the ultimate fate of this latter Be. We present sediment pore-water Be profiles from diverse continental margin environments to quantify the diagenetic Be release to the ocean. Our results suggest that pore-water Be cycling is mainly controlled by particulate supply and Mn-Fe cycling, leading to higher benthic fluxes on shelves. Benthic fluxes may help close the 9Be budget and are at least comparable to, or higher (~2-fold) than, the riverine dissolved input. These observations demand a revised model framework, which considers the potentially dominant benthic source, to robustly interpret marine Be isotopic records.

Geochemistry, Detrital Zircon U-Pb Geochronology, and Lu-Hf Isotopes of the Metasedimentary Rocks (Xinghongpu Formation, Late Devonian) in the Central South Qinling Orogenic Belt: Implications for Provenance and Tectonics

The Xinghongpu Formation is very important for understanding the Devonian tectonic evolution of the South Qinling orogenic belt. Geochemical, detrital zircon U-Pb-Hf isotopic studies were carried out on the Late Devonian metasedimentary rocks of the Xinghongpu Formation to constrain the depositional age, the provenance, and the tectonic setting. The detrital zircon U-Pb dating results revealed that the depositional age of the Xinghongpu Formation of the Late Devonian was not earlier than 363.2 Ma. The whole-rock geochemistry suggested that (1) this suite of metasedimentary rocks was mainly derived from quartzose sediments of mature continental provenance, with a small contribution from mafic and intermediate igneous provenance, and (2) the metasedimentary sandstone of the Xinghongpu Formation from the Late Devonian was deposited in an active continental margin to continental arc setting. The detailed detrital zircon U-Pb dating showed that the age spectra of detrital zircon could be divided into four groups: (1) 416–480 Ma, accounting for about 23%; (2) 740–850 Ma, accounting for about 19%; (3) 889–1017 Ma, accounting for about 19%; and (4) 1072–1146 Ma, accounting for about 12%. It also contained a group of Early Proterozoic zircons. The age and Hf isotope of the detrital zircons suggested that the clastic sediment deposited in the Xinghongpu Formation mainly came from the South Qinling Orogenic Belt and the North Qinling Orogenic Belt. The detrital zircon Lu-Hf isotopes indicated that most zircons were the products of the ancient crustal remelting, and the mantle-derived magmatic sources contributed to the provenance. The Xinghongpu Fm. formed in an oceanic basin in a continental margin environment with arc systems.

Early Cretaceous monsoonal upwelling along the northern margin of the Gondwana continent: Evidence from radiolarian cherts

Radiolarian-bearing cherts are widely exposed in the volcanic-sedimentary sequences associated with the Purang ophiolitic mélange in the western segment of the Yarlung Tsangpo suture zone. Highly diverse and well preserved Lower Cretaceous (Valanginian–Hauterivian) radiolarian assemblages that correlate to the Cecrops septemporatus Zone occur in bedded cherts in the Peiersanggangmu section of the southern Purang ophiolitic mélange. Fifty-five species belonging to 38 genera, including characteristic species: Archaeodictyomitra apiarium (Rüst), Cecrops septemporatus (Parona), Hemicryptocapsa capita Tan, Pseudodictyomitra carpatica (Lozyniak), and Svinitzium pseudopuga Dumitrica, have been recognized.Geochemistry of the cherts reveals high SiO2 contents (average: 92.23 wt%), Al/(Al + Fe + Mn) ratios, and low LaN/CeN ratios. Post Archean Australian Shale (PAAS) normalized rare earth element (REE) abundance patterns exhibit moderately positive Ce anomalies (mean Ce/Ce* =1.35) with relative enrichment in light rare earth elements (LREEs). These features are indicative of deposition in an oceanic basin close to a continental margin environment. Lithological characteristics and geochemical results suggest that the paleogeographical location for these radiolarian-bearing bedded cherts closely matches northern regions of the Indian continent, where existed enhanced upwelling activity and surface mixing resulting from monsoon activities.

Major, trace and rare earth element geochemistry of the Permian Lucaogou oil shales, eastern Junggar Basin, NW China: implications for weathering, provenance and tectonic setting

The Permian Lucaogou oil shales in the eastern Junggar Basin have long been regarded as important source rocks and reservoirs for tight oil exploration. The oil shales can also be used to assess the provenance and tectonic setting of the East Junggar region using major, trace and rare earth element geochemistry. The low chemical index of alteration ratios (37.36–64.18, 45.54 on average), low plagioclase index of alteration ratios (26.99–62.95, 42.99 on average), and high index of compositional variability ratios (0.64–1.66, 1.10 on average) suggest that the Permian Lucaogou oil shales mostly consist of immature sediments that have experienced a weak weathering intensity. The samples have low TiO2/Al2O3 and TiO2/Zr ratios that indicate a felsic origin with minor intermediate igneous rocks. The high Th/Sc and Zr/Sc ratios suggest a felsic origin without sediment recycling. The samples show fractionated light rare earth elements and relatively flat heavy rare earth elements patterns with weak negative Eu anomalies, which implies that the main provenance is lower Carboniferous intermediate–acid volcanic rocks. In addition, multiple major- and trace-element‐based discrimination diagrams show that the parent rock of clastic sediments formed mainly in a continental island arc and active continental margin environment, consistent with previous studies on the tectonic background of the East Junggar region during the late early Carboniferous. Key Points Immature sediments are present in the Permian Lucaogou oil shales and have a weak weathering intensity. The provenance of the clastic sediments of the Permian Lucaogou oil shales was predominantly early Carboniferous intermediate–acid volcanic rocks. The clastic sediments of the Permian Lucaogou oil shales were developed in a continental island arc and active continental margin environments. The Permian Lucaogou oil shales provide crucial information for tectonic setting and evolution of the northern Xinjiang during the Carboniferous–Permian.

Study on the Provenance and Tectonic Setting of Mudstone in the Lower Silurian Longmaxi Formation of the Yanyuan Basin on the Western Margin of the Yangtze Platform

This study investigates the provenance and tectonic background of the lower Silurian Longmaxi Formation black shale of the Yanyuan Basin in the western Kangdian ancient land and provides guidance for shale gas exploration and development in the area. The mineral petrological and geochemical characteristics of the Longmaxi Formation black shale in this area have been studied in detail. The study area is mainly a passive continental margin environment, but also has the attributes of an active continental margin and island arc environment due to the collision between the western oceanic crust and the Yangtze continental crust. The source rocks are mainly felsic igneous rocks, with a small contribution of intermediate–basic rocks. It is inferred that the Kangdian ancient land in the eastern part of the area could be the main provenance area, but with the contribution of sediments derived from oceanic island arc located in the west. During the whole Longmaxi period, the tectonic movement was intense, the climate was cold, the degree of chemical weathering was low, and it was a highly volatile geological sedimentary basin. Therefore, the highly siliceous organic-rich mudstone, which was different from the Sichuan Basin, was deposited.

Nature of Paleozoic Basement of the Catalan Coastal Ranges (Spain) and Tectonic Setting of the Priorat DOQ Wine Terroir: Evidence from Volcanic and Sedimentary Rocks

The Paleozoic volcano-sedimentary rocks within the structural basement of the horst-and-graben system of the Catalan Coastal Ranges (CCR) are composed of black shale, volcaniclastic sediments, lava flows, sills and lithocrystalloclastic tuffs. Paleozoic sediments are depleted in high-field strength elements (HFSE) such as Nb, Ta, Zr, Hf and Ti, suggesting their accumulation within the Andean-type active continental margin environment. Volcanic rocks within the Paleozoic CCR sequence belong to shoshonitic and high-K volcanic series and are enriched in Cs, Rb and Ba and depleted in HFSE, which is consistent with their derivation from metasomatized (possibly through deep recycling of pelagic sediments) subduction-related mantle source. The presence of sills (sill-sediment complex) suggests that Paleozoic basement of the CCR was formed within the rifted active continental margin or an arc-back-arc basin system akin to the modern Western Pacific subduction configuration. This complex volcanic terroir hosts world-class wines of the Priorat DOQ region. The presence of framboidal pyrite and magnetite, siderite, sphalerite xenotime, (La–Ce–Nd)-monazite, zircon and baddeleyite, as well as cuprite, tenorite and cupriferous and native silver in volcanic-derived black shale (and consequently in the world-famous “llicorella” soil overlying it) may have had dramatic effects on wine quality and sensory characteristics. These mineral features, together with strong enrichment of Priorat shale in Au, Ag and, to a lesser extent, Pt could have pronounced effects on (1) rates and specific types of chemical reactions; (2) plant metabolism; (3) response to nutrient components and (4) determination of grape flavor. Volcanic wine terroirs, such as the Priorat DOQ region, are special geologic environments for wine growth, capable of producing unique wine aromatic and gustatory characteristics.

Chronological and geochemical characteristics of metavolcanic rocks in the Nanping‐Ninghua tectonic belt: Constraints on the formation of the Cathaysia block

AbstractThe tectonic properties of the Nanping‐Ninghua tectonic belt (NNTB) play a crucial role in understanding the tectonic evolution of the Wuyi orogenic belt, which is related to the Neoproterozoic‐Paleozoic tectonic evolution of the Cathaysian Block. In this study, We present comprehensive petrological, geochronological, and geochemical data on the metavolcanic rocks from the Louqian Formation in Changting, Fujian Province. Our results show that volcanism in Changting occurred between 740.4 and 723.5 Ma, based on zircon U–Pb data for the metavolcanic rocks. The metavolcanic rocks have SiO2 contents ranging from 68.22 to 71.56 wt %, high Al2O3 and Na2O + K2O contents (13.30–15.19 wt % and 7.56–8.25 wt %, respectively), and low CaO, MgO, and FeOT contents (0.09–1.25 wt %, 0.72–0.96 wt %, and 1.57–3.16 wt %, respectively). These samples are enriched in large‐ion lithophile elements (LILEs) such as Ba and Rb, and depleted in high‐field‐strength elements (HFSEs) including Nb, Ta, and Ti, with significant negative Eu anomalies, indicating an affinity for arc igneous rocks. Based on previous geological studies, we suggest that the NNTB formed in an active continental margin environment during the Nanhua Period. The subduction of oceanic crust led to the formation of the volcanic belt along the Nanping‐Ninghua continental margin, which was active until 696 Ma. During the Neoproterozoic, the North and South Wuyi terranes did not merge to form a single Wuyi terrane, and the Cathaysia Block was composed of several terranes.

Mesoarchean banded iron-formation from the northern Yangtze Craton, South China and its geological and paleoenvironmental implications

Banded iron formations (BIFs) are important sedimentary rocks used for reconstructing the geochemical and environmental evolution of Precambrian Earth surface conditions. Here, we describe the oldest BIFs of Mesoarchean age in the Yemadong Formation, and their implications for paleo-environmental evolution of the Mesoarchean Ocean in the northern Yangtze Craton, South China. U-Pb dating of metamorphic zircons obtained from metavolcanic rocks interbedded within the Yemadong Complex, record two major tecto-thermal events at 2901 ± 8 Ma, in agreement with a Mesoarchean origin of the Dujiagou BIFs, and as recently as 775 Ma. A high SiO2 + total Fe2O3 content of 90.95–94.62 wt%, moderate 0.54–1.42 wt% Al2O3 + TiO2, and broadly elevated levels of incompatible elements, point to a predominantly chemical origin of the BIF deposit, with a minor but influential terrigenous input. Rare Earth Element (REE) plus Yttrium patterns normalized against Post Archean Average Shale composition are characterized by the depletion of light REE relative to heavy REE. However, extremely weak Eu and Ce anomalies, together with low average chondrite Y/Ho ratios compared to average Mesoarchean BIF values, indicate that the primary REE composition of the rocks may have been diluted to some extent by terrigenous input, pointing to proximity or connection of the depositional setting to a continental margin environment. Despite potential terrigenous dilution of the syngenetic seawater-hydrothermal chemical composition, the preservation of an inherited hydrothermal REE signal in some samples, point to submarine hydrothermal provenance of the Dujiagou BIFs, as is the case for most Precambrian BIFs. Positive δ56Fe values, ranging from 0.25 to 0.45 ‰, characteristic of primary Archean BIFs, suggest partial oxidation of reduced Fe(II) to divalent (Fe(II)/Fe(III)) magnetite-rich BIFs in a broadly reducing Archean Ocean lacking a persistent and pervasive redoxcline before the rise of atmospheric oxygen.

Multi dating approach of long marine core sediments from the south-eastern continental shelf of Korea: Comparison of SAR OSL, TT-OSL and pIRIR dates

Marine sediments constitute important archives of past oceanic, climate, and sea-level changes. However, it is difficult to derive accurate chronological models due to the absence of long sediment cores and limitations of dating methods. To investigate the feasibility of applying optically stimulated luminescence (OSL) ages to establish high-resolution chronologies in the East Sea of Korea, we obtained three cores with lengths up to 120 m from the eastern continental shelf of Korea. Most of the core sediments were homogeneous or crudely laminated mud, with some sand and gravel bed. Multiple dating methods, including fine-grained quartz single-aliquot regenerative-dose (SAR) OSL, thermally transferred OSL (TT-OSL) from fine-grained quartz, and single-grain K-feldspar post-infrared (IR) infrared stimulated luminescence (IRSL) (pIRIR), following the above description, were applied to overcome the age limitation and create an accurate age model through cross-checking among the different dating methods. We also investigated the applicability of the standardised growth curve (SGC) to TT-OSL signals in continental shelf environments. The equivalent dose (D e ) values from the SGC were consistent with those from the SAR TT-OSL procedure, which suggests that the SGC is valid for long core sediments on the continental shelf. A detailed chronology derived from the radiocarbon, U/Th, and multiple OSL age dating methods was compared. Especially, in core 19ESDP-101, a comparison between TT-OSL ages from fine-grained quartz and pIRIR ages from coarse K-feldspar showed agreement to within 10% at most depths for which ages were measured. We demonstrated that OSL dating from long marine core sediments in a continental shelf margin environment can provide an accurate and precise chronology in undatable regions.

High-Precision CA-ID-TIMS U-Pb Zircon Geochronology of Felsic Rocks in the Finlayson Lake VMS District, Yukon: Linking Paleozoic Basin-Scale Accumulation Rates to the Occurrence of Subseafloor Replacement-Style Mineralization

Abstract Felsic igneous complexes and associated volcano-sedimentary rocks in continental back-arc environments host large-tonnage and/or high-grade volcanogenic massive sulfide (VMS) deposits. The emplacement mechanisms, style, and preservation of these deposits is thought to be partially dependent on depositional rates of the host lithofacies (i.e., discrete volcanic eruptions) relative to the setting of massive sulfide genesis on the seafloor as mounds and/or via subseafloor replacement of existing strata. The localization and occurrence of subseafloor replacement-style VMS deposits is therefore strongly influenced by the characteristics of the volcano-sedimentary facies in the hosting basin and the rates of their emplacement; the latter are poorly constrained in the literature due to the difficulty of obtaining high-precision dates that make this possible in Phanerozoic and older rocks. New high-resolution U-Pb geochronology and detailed regional stratigraphic investigation indicate that Devonian-Mississippian volcanic rocks and associated VMS mineralization in the Yukon-Tanana terrane in the Finlayson Lake district, Yukon, Canada, were erupted or emplaced during distinct time periods (ca. 363.3, 362.8, and 355.2 Ma) in two discrete submarine basins: the Kudz Ze Kayah formation and the Wolverine Lake group. The VMS deposits in both settings are contained within intrabasinal rocks that accumulated at rapid rates of ~350 to 2,000 m/m.y. over 0.6 to 1.4 m.y. Locally, these rates reach peak rates up to 7,500 m/m.y. in the Wolverine Lake group, which are interpreted to reflect facies deposition by mass transport complexes or turbidity currents. These new dates indicate that rapid accumulation of volcanic rocks in the back-arc basins was critical for localizing subseafloor replacement-style mineralization and the development of the Zn-enriched GP4F, Kudz Ze Kayah, and Wolverine VMS deposits. Rapid depositional processes observed in these deposits and their host basins are interpreted to have an important role in developing highly porous and permeable, water-saturated lithofacies that provide optimal conditions for enhancing zone refining processes and subsequent preservation of massive sulfide mineralization, which are key in the development of high-grade and large-tonnage VMS deposits. It is herein suggested that quantitative basin-scale accumulation rates, as a result of new U-Pb geochronological methods and increased precision combined with detailed stratigraphic and facies analysis, may provide important perspectives on the formation of continental back-arc basins and the localization of VMS deposits in other continental margin environments globally.

Geochemical characteristics of Jurassic sandstones on the southern margin of the Junggar Basin: Constraints on provenance and sandstone-type uranium mineralization

Jurassic strata in the southern margin of the Junggar Basin are located in the piedmont zone of the North Tianshan Mountains in Xinjiang, China. Due to multiple tectonic movements, the basin has a complicated history of structural deformation. Accurate reconstructions of the tectonic setting, provenance attributes and paleoclimatic characteristics of the Jurassic strata in the area are vital to facilitate mineral resources prospecting (such as coal, oil, natural gas and uranium) in the basin. Here we used scanning electron microscopy, major and trace elements analyses (including rare earth elements; REE), clay mineralogy and heavy mineral composition in outcrop samples, to analyze the paleoclimate, tectonic setting, source rock properties and provenance characteristics in the southern margin of the Junggar Basin during the Jurassic period. The results are as follows: (1) according to major and trace elements and clay mineral assemblages, the degree of drought increased slightly from the Early Jurassic to the Late Jurassic concomitant increase. (2) Major and minor element discrimination and REE patterns indicate that the material was sourced from continental island arc and active continental margin environments, primarily from upper crustal felsic source rocks (mainly greywacke and arkose). (3) Heavy mineral and whole rock analyses show that the provenances of the Lower Jurassic sandstones were mainly from the primarily Zaire Mountain, North Tianshan Mt.-Middle Tianshan Mt., while the Upper Jurassic sediments were sourced from the primarily North Tianshan Mountain, Zaire Mountain, Middle Tianshan Mountain.

Geochemical characterisation of offshore New Zealand phosphorites, and mechanisms for their formation

Phosphate deposits can form in a range of environments, and despite similar P contents, their mineralogy, and hence major and trace element chemistry, can vary substantially. Continental margins with high surface-water productivity are recognised as a major environment for the formation of extensive phosphate deposits. The geochemical characterisation of continental-margin-derived phosphorites from Chatham Rise and south-eastern offshore New Zealand, as well as newly discovered seamount phosphorites from Bollons Seamount (first documented here), offer insights into the different mechanisms of phosphorite formation from these two different environments. Though less studied, seamounts are increasingly recognised for their phosphorite deposits as well as Fe-Mn crusts and Mn nodules. We propose the first model for the formation of nodules at Bollons Seamount, and an updated model for Chatham Rise nodules (and south-eastern offshore NZ phosphorites) is presented. Suboxic-to-anoxic enrichments of U and V are observed in Chatham Rise and south-eastern offshore phosphorites that contrast with oxic enrichments of Mn, Ce, Co, and Cr in Bollons Seamount phosphorites. Differences in uptake of Light Rare Earth Elements (LREE) vs. Heavy Rare Earth Elements (HREE) and variations in mineralogy (e.g., presence of glauconite vs. Fe-Mn crusts), allow phosphate deposits that formed in organic-rich, upwelling continental-margin environments to be distinguished from those that formed in oxic-suboxic organic-poor seamount environments.