Continental Island Arc Research Articles

Mineralogical and geochemical studies of shales from Kopili Formation, Dima Hasao district Assam, North East India: Insights into diagenesis, deposition and provenance

The Eocene Kopili Formation in the Assam foreland basin records sediment sources, tectonic activity and depositional environments following the India-Eurasia collision. Mineralogical and geochemical analysis of these shales exposed near Garampani, Assam, NE India was conducted to study the diagenesis, palaeoweathering, palaeosalinity, redox conditions, tectonic settings and provenance. The Kopili Formation is composed of mainly shale with thin beds of limestone, black shale and sandstone and these units overlie the Upper Sylhet Limestone. The presence of goethite-rich phosphatic nodules, secondary precipitation within the fissile planes of shale and the occurrence of anatase, talc, smectite and chlorite suggest diagenesis. The prevalence of kaolinite and mean Chemical Index of Alteration (CIA), Chemical Index of Weathering (CIW), Al2O3/MgO and Rb/Sr values of 86.73, 97.26, 16.36 and 1.32, respectively indicates extensive source rock weathering in humid tropical climate. The Index of Compositional Variation (ICV) values ranging between 0.47 and 2.38 also signify high weathering and tectonically active basin. The Sr/Ba ratio 0.34 ± 0.27 (mean±2σ) suggest overall freshwater basin. The Ni/Co (2.84 ± 2.29), V/Cr (1.65 ± 0.45) and Ce/Ce∗ (0.97 ± 0.63) suggest fluctuating redox environment. The samples predominantly cluster in continental island arc domain on the Th-Sc-Zr/10, La-Th-Sc and Th-Co-Zr/10 discriminant diagrams. Elemental ratios of Th/Sc, La/Sc, Cr/Th with average 0.91, 3.18, 10.13 respectively and La/Th-Hf plot suggest a felsic source rock. The Kopili shale was deposited in freshwater, continental island arc basin with fluctuating redox conditions, receiving sediments from weathered Himalayan granites and gneisses under a warm and humid climate. Subsequently, they underwent diagenetic alteration by low-pH fluid(s).

Spatiotemporal evolution of the early Permian multi-source-to-sink system in the northwestern margin of the North China Block: Implications for the paleogeographic reconstruction along the southern margin of the Paleo-Asian Ocean

The northwestern margin of the North China Block, situated at the intersection of multiple tectonic units, presents a complex geological setting that challenges paleogeographic reconstructions. The subduction and closure of the Paleo-Asian Ocean have further complicated the understanding of sediment provenance during the Early Permian. In this study, we integrated sedimentological, geochemical, and UPb dating methods to delineate the Early Permian source-to-sink systems along the northwestern margin of the North China Block. The identification of four key source-to-sink systems—the Alxa, Langshan, Serteng–Wula, and Jining–Daqing—reveals a pronounced east–west provenance differentiation, indicative of the regional tectonic and sedimentary responses to subduction of the Paleo-Asian Ocean.During the Shanxi Formation deposition, the western regions were dominated by the Inner Mongolian continental island arc as a principal sediment source, fostering distal meandering river deltas. Conversely, the eastern regions were predominantly influenced by the North China Block basement, leading to the deposition of proximal, shallow meandering river deltas. As the Shihezi Formation deposition ensued, the western source-to-sink systems continued to receive sediments from the uplifted Inner Mongolian Arc, transitioning to distal braided river deltas amidst an orogenic setting. Meanwhile, the eastern systems, particularly Jining–Daqing, showed increased contributions from the North China Block basement, forming mixed-source, shallow braided river deltas.This research provides a refined understanding of the spatiotemporal evolution of source-to-sink systems and their responses to the tectonic setting, offering valuable insights into the paleogeographic evolution along the southern margin of the Paleo-Asian Ocean.

Geochemical and detrital zircon U[sbnd]Pb geochronology of the qigequan formation in the yuejin 2 area: Implications for tectonics and uranium sources

The Yuejin 2 mining area lies within the Mangya region, situated on the northwestern periphery of the Qaidam Basin. Recently discovered, it harbors a medium-sized uranium deposit within the basin. Nonetheless, investigations into the sedimentary provenance and paleoclimate of the Neogene Qigequan Formation in this locale have been sparse. This study delves into a meticulous examination of petrogeochemical attributes and the detrital zircon UPb geochronology of sandstones from the Qigequan Formation within the mining area, aiming to discern their origins and tectonic context. By scrutinizing the trace and rare earth element signatures of the rocks, we discern that the lower strata of the Qigequan Formation primarily originate from felsic sedimentary sources, indicative of a continental island arc tectonic. Detrital zircon ages from the Qigequan Formation manifest primarily in three distinct periods: 169–292 Ma, 327–505 Ma, and > 670 Ma, corresponding with geological ages documented in the Altyn Tagh and East Kunlun Mountains orogenic belts. Predominantly, the Altyn Tagh orogenic belt and the Qimantag Mountains in the eastern Kunlun Mountains serve as the principal source of the Qigequan Formation. The chemical weathering index (CIA*) is 70.54, suggesting a moderate level of chemical weathering within the source region. Additionally, the angular morphology of the detrital zircon implies proximity between the source area and the basin. During the late sedimentary epoch of the Qigequan Formation, rapid uplift of the Altyn Tagh led to a notable rise in temperature within the Yuejin 2 area, transitioning from a reducing to an oxidizing environment. Surface water enriched with uranium and eroded source rocks gradually infiltrated the sand bodies of the lower Qigequan Formation. Interaction with reducing agents facilitated the enrichment and formation of ore. Paleoclimatic shifts instigated the oxidation–reduction sequence necessary for uranium mineralization. Favorable conditions, characterized by oxygen-rich paleo-water, facilitated the activation, migration, and re-enrichment of uranium. Moreover, the Himalayan movement acted as a driving force and a pivotal factor in creating the conducive conditions imperative for large-scale uranium mineralization in the area.

Late Carboniferous–Early Permian sedimentary–tectonic evolution in the eastern Qaidam Basin, Western China: Insight into the zircon U–Pb geochronology of ash-fall tuffs and sandstones

The Late Carboniferous–Early Permian period is a significant transitional phase within the late Paleozoic ice age and to investigate the sedimentary–tectonic evolution of the Qaidam Basin in this period is crucial for comprehensively understanding the tectonic history of the northeastern Paleo-Tethys Ocean and the related response to energy and mineral resources. This paper focuses on the Carboniferous–Permian strata of the Wanggaxiu-Dongdagou outcrop that was taken to represent the southern Oulongbruk terrane in the eastern Qaidam Basin. We determined the ages of tuff interbeds within the Zhabusagaxiu Formation originally identified as the upper Carboniferous and obtained the crystallization age spectra of detrital zircon grains from Carboniferous to lower Permian sandstones using laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) isotope geochemical techniques. The origin of the volcanic ash and the sedimentary–tectonic evolution in this period were analyzed. The results indicate that the original Zhabusagaxiu Formation can be divided into two chronostratigraphic units: the upper Carboniferous Zhabusagaxiu Formation and the lower Permian. The earliest age obtained from tuffaceous layers within the dark shale interval is 297.8 ± 3.0 Ma (mean square weighted deviation (MSWD) = 0.87), which suggests a stratigraphic boundary between the Carboniferous and Permian periods. Detrital zircons from Carboniferous–Permian samples in the southern Oulongbruk terrane predominantly originated from the Qaidam block-North Qaidam ultrahigh-pressure belt continental island arc to the south. The ultrahigh-pressure belt had a significantly increased contribution to the detrital source supply system from the Late Carboniferous to Early Permian, while the Qaidam block experienced frequent volcanic eruptions from 298 to 293 Ma, dispersing volcanic ash only northward to the Oulongbruk back-arc basin and the Zongwulong Trough. The upper Carboniferous Zhabusagaxiu Formation was marked by siliceous clastic rock–carbonate rock interbedding in an epicontinental sea, while the lower Permian was characterized by shallow to bathyal marine shelf to subaqueous sedimentation. The Early Permian transgression potentially represents the largest transgression during the late Paleozoic ice age, indicating an enriched hydrocarbon-generating interval.

Provenance signature and tectono–sedimentary setting of the Permian Shihezi formation (Ordos basin, China): Insights from geochemistry and detrital zircon U–Pb dating

During the depositional period of the Permian Shihezi Formation, the southern margin of the Ordos Basin was a key location for studying the tectonic movement of the North China Craton (NCC) and South China Blocks. The sedimentary environment was the first period of complete transition from marine to continental. However, the distribution of sediments controlled by a multi–provenance supply and the response of deposition to tectonics remain ambiguous, and the restoration of paleogeography remains in the qualitative stage, restricting the study of larger-scale tectono–sedimentary patterns. Based on field profiles and core observations, the paleocurrent direction, lithic fragments, heavy mineral assemblages, rare earth element distribution patterns, 11 detrital zircon U–Pb age datasets, and discrimination diagram of major and trace elements, the provenance signature and tectono–sedimentary setting were revealed. The results indicated that there are three main provenances in the southern margin of the Ordos Basin: North Qilian and western and eastern sections of the North Qinling Orogenic Belt. The tectonic setting of the North Qilian was a continental island arc, and the North Qinling was transformed from a passive to an active continental margin. Owing to the continued intense tectonic activities of the North Qilian, a braided river delta with a large sedimentary range developed in the west, and it was mixed with detrital sediments from the western section of the North Qinling with weak tectonic activity in the central. Affected by the uplift of the southern North China Craton, the sedimentary environment in the eastern range was unstable, and the thickness distribution of sandy sediments in the braided river delta was uneven. Refinement of provenance and deposition has important implications for the study of basin–mountain coupling relationships and paleogeographic reconstruction in the southern Ordos Basin and provides a basis for the study of collision evolution of the North and South China Blocks in the Permian.

Geochemical Characteristics and Sedimentary Paleoenvironment of the Coal-Bearing Strata in the Xishanyao Formation: A Case Study of the Yihua Coal Mine in the Zhundong Coalfield, Xinjiang

The eastern Junggar Basin in Xinjiang harbors abundant coal resources within the Middle Jurassic Xishanyao Formation. However, the formation environment associated with these coal-bearing strata remains unclear. Geochemical characteristics serve as crucial geological indicators of the sedimentary period. Therefore, it is imperative to explore the geochemical attributes and sedimentary context of the coal-rich layers within the Middle Jurassic Xishanyao Formation in the Zhundong region to enhance the prospects of coal extraction and utilization. The elemental compositions, both major and trace, of the Xishanyao Formation were analyzed through X-ray fluorescence spectrometry (XRF) and inductively coupled plasma mass spectrometry (ICP-MS). A comprehensive analysis was conducted on the sediment provenance, tectonic background, and depositional environment of the coal-bearing strata in the Xishanyao Formation. Moreover, through the utilization of a range of discrimination indices, including Sr/Cu, B/Ga, Sr/Ba, V/Cr, Ni/Co, and δCe, the paleo-depositional setting of the coal-containing layers was reconstructed. The findings suggest that the primary source rocks of the coal-bearing beds in the Xishanyao Formation consist of continental tholeiites, with the predominant material composition in the source region being felsic volcanic rocks originating from the upper crust. The tectonic backdrop of the source region is marked by a continental island arc environment. During the sedimentation period of the Xishanyao Formation, the depositional environment was characterized by a freshwater oxidizing setting. Additionally, it experienced a transition from arid-hot to humid-hot before returning to arid-hot conditions.

A multi-source proxies approach to identifying local processes in lower Permian black shale impacting on the sedimentary environment of eastern Palaeo-Tethys Ocean

Foreland basin tectonics along the eastern Palaeo-Tethys Ocean produced a complex and dynamic pattern of sediment delivery to adjacent basins. Environmental processes at the local scale significantly disrupt regional ones, making the analysis of sedimentary evolution difficult. This study investigated the Lower Permian Liangshan Formation black shale formed in such geological setting, rich in cherts with exceptionally high silica and fluctuating major and trace element concentrations, detected using XRD, XRF, and ICP-MS techniques. Different types of silica, including detrital quartz, recrystallised radiolaria, microcrystalline quartz, and quartz veins, were identified using SEM and SEM-CL imaging. Geochemical characterisation and enrichment pattern analyses indicated that the structural setting was characterised by proximity to the oceanic island arc, continental island arc, and passive margin, and the major zone of sediment accumulation was a semi-restricted back-arc basin under the subduction zone. The processes controlling sediment accumulation included hydrothermal activity, upwelling, biogenic silica, and terrestrial inputs. Although upwelling interfered with the mobility and migration of hydrothermal elements, it introduced abundant nutrients, and together with hydrothermal fluids, it contributed to the subsequent boom in siliceous organisms. Terrigenous inputs induced by land uplift significantly diluted the components from other sources. This multi-source proxies approach not only enables researchers to disentangle local from regional processes but also sheds light on how these diverse environmental forces interact within intricate earth systems, which enhance our comprehension of geologic history and inform ongoing studies focused on climate change mitigation strategies.

Study on Sedimentary Environment and Organic Matter Enrichment Model of Carboniferous–Permian Marine–Continental Transitional Shale in Northern Margin of North China Basin

The shales of the Taiyuan Formation and Shanxi Formation in the North China Basin have good prospects for shale gas exploration and development. In this study, Well KP1 at the northern margin of the North China Basin was used as the research object for rock mineral, organic geochemical, and elemental geochemical analyses. The results show that brittle minerals in the shales of the Taiyuan Formation and Shanxi Formation are relatively rare (<40%) and that the clay mineral content is high (>50%). The average TOC content is 3.68%. The organic matter is mainly mixed and sapropelic. The source rocks of the Taiyuan Formation and Shanxi Formation are mainly felsic, and the tectonic background lies in the continental island arc area. The primary variables that influenced the enrichment of organic materials during the sedimentary stage of the Taiyuan Formation were paleosalinity and paleoproductivity. Paleosalinity acted as the primary regulator of organic matter enrichment during the sedimentary stage of the Shanxi Formation.

Geochemical indicators to constrain weathering, provenance and tectonic setting of the Pisha Sandstone (Early–Middle Triassic) in Northeast Ordos Basin, China

The Pisha Sandstone is widely exposed in the northeastern margin of the Ordos basin. Since the Mesozoic the basin was subjected to uneven uplift several times, strong weathering and erosion have been occurring and a large amount of sediments derived from these erosional strata are input into the lower Yellow River, posing a fragile ecological environment along the river. However, the geochemical characteristics of the Pisha Sandstone have remained poorly understood. In this study, we focus on the Pisha Sandstone from Early–Middle Triassic Liujiagou, Heshanggou and Ermaying Formation, present a very first petrographic and geochemical data together with detailed field geological characteristics, aiming to place geochemical indicators on weathering, provenance and tectonic setting of the Pisha Sandstone. The results show that sandstones in Pisha Sandstone are classified as arkose, litharenite and wacke. The geochemical proxies including Chemical Index of Alteration (CIA = 67.2), Chemical Index of Weathering (CIW = 80.1), Plagioclase Index of Alteration (PIA = 75.6) and Index of Compositional Variability (ICV = 1.6) indicate Pisha Sandstone experienced first–cycle deposit and moderate to strong chemical weathering. Trace element and rare earth element concentrations together with their ratios (La/Sc, La/Co, Th/Sc, Th/Co, Cr/Th) reveal a felsic provenance, and source rock compositions are predominantly granodiorite and granite from the north margin of the Inner Mongolia Paleo–Uplift (IMPU), with a small amount of mafic or intermediate components. The geochemical signatures and tectonic discrimination diagrams display a collision setting for the Pisha Sandstone and further reveal the sediments had been deposited in a continental island arc setting. The results of this work may provide new theoretical basis for environmental protection in the Pisha Sandstone area.

The Ordovician Arc–Basin System in the Northern Great Xing’an Range (Northeast China): Constraints from Provenance Analysis of the Luohe Formation

The Northeast China Block is a major component of the Central Asian Orogenic Belt, and its tectonic evolution has attracted much research attention. Ordovician strata are important in reconstructing the tectonic evolution of the Northeast China Block. This paper presents the results of sedimentological, zircon U–Pb, and geochemical analyses of sandstones of the Luohe Formation in the Wunuer area, Northern Great Xing’an Range, Northeast China. Lithological data, sedimentary structures, and grain-size analysis indicate that the Luohe Formation was deposited in a shallow marine environment. Detrital zircon U–Pb dating yields age peaks of 463, 504, 783, 826, 973, and 1882 Ma for sandstones from the Luohe Formation. The youngest zircon grain age of 451 ± 6 Ma represents the maximum depositional age of the Luohe Formation. The peak age at 463 Ma is consistent with the timing of post-collisional magmatism and the formation of the Duobaoshan island arc, while the peak at 504 Ma is consistent with the timing of magmatic activity related to the collision between the Erguna and Xing’an blocks. The peaks at 788, 826, 973, and 1882 Ma correspond to magmatism in the Erguna block, these ages indicate that the sandstones of the Luohe Formation were derived mainly from the Erguna block. Sandstone modal compositional analysis indicates that the provenance of the Luohe Formation was mainly a magmatic arc. The geochemical compositions of the sandstones suggest that the source rocks have continental island arc signatures. Based on the depositional age, sedimentary environment, provenance, and regional geology, it is concluded that the Luohe Formation was deposited in a back-arc basin setting during the formation of the Duobaoshan island arc–basin system in response to subduction of the Paleo-Asian oceanic plate.

Trace element geochemistry of sediments in the Pearl River Estuary and its implication for provenance

The Pearl River system is China’s third longest river and the Pearl River Estuary is a major estuary in China. In the paper, a sediment core collected from the coastal zone in the Pearl River Estuary was analyzed for trace element concentrations and grain size to identify provenance during the past decades. In addition, the tectonic framework of the study area has also been studied using reliable geochemical tracers, including rare earth elements (REEs) and trace elements. The results reveal a significant contribution of reworked sediment from multiple sources. Discrimination diagrams suggest that the sediments display felsic characteristics with recycled components, and therefore, the source rock types of the sediments are presumed to be granitic rocks. The REE patterns observed in the samples primarily reflect the influence of an ancient continental crust that contains felsic materials on the sediments with an LREE/HREE ratio of 7.94–9.56 (mean 8.46) and a δ Eu value of 0.61–0.70 (mean 0.65). The sediments are plotted into a zone of continental island arcs, which was formed during the late Mesozoic subduction of the ancient Pacific. The study on the source of sediment cores shows that the main source of sediments in this area excludes the possibility of the upper middle river from the Pearl River Watered, which reflects the importance of the lower Pearl River Basin, especially the Dongjiang River, for material transport in the study area. Our results demonstrate that the geochemical characteristics of trace elements in sediment could provide an efficient approach to identify sediment provenance in estuaries worldwide.

Dispersion of sandy sediments during marine–continental transition: An integrated study from the Late Paleozoic western Ordos Basin

The western Ordos Basin is located at the intersection of multiple tectonic units and is a key area in the restoration of the palaeogeographic pattern of the East Asia region. The stability of the area and well-developed Paleozoic strata in the basin provide ideal conditions for revealing the relationships among the tectonic processes apparent there. However, within the constraints of extensive post-depositional modification, poor-quality seismic data, and a lack of wells, sediment dispersion differences, source attribution, and source-to-sink processes are still unclear. In this study, we integrated sedimentology, mineral, and geochemical data obtained from marine, continental, and marine-continental transition sedimentary environments in the study area in order to reveal the evolution from source-to-sink. The results show that the western Ordos Basin was predominantly supplied by the Alxa block, Yinshan orogenic belt, Qilian orogenic belt, and the North Qinling orogenic belt during the Late Paleozoic era. As a result of the closure of the Paleo Asian Ocean, the Alxa block and Yinshan orogenic belt became the primary source areas to the north, being composed of granite and alkaline basalt and some sedimentary rocks. In the southern area, the Qilian and the Northern Qinling orogenic belts were subjected to the PaleoTethys remnant ocean basin subduction during the Early Permian. Granite and alkaline basalt were the source rocks of the North Qinling orogenic belt, which became the source area during the Shanxi period. The Qilian orogenic belt contains some sedimentary rocks. The continuous uplift of the southern and northern orogenic belts. The tectonic setting of the northern source area transitions from a passive continental margin to an active continental margin with a mixture of continental arc. The tectonic setting of the southern source area transitions from a mixture of passive continental margin and active continental margin to an active continental margin and continental island arc. The climate changes gradually from humid to semi-arid and then to arid, and meanwhile, the sea level shows a decreasing trend, leading to an increasing distance of advancement for each source-to-sink system, and gradually converged in the central and eastern regions of the basin. Tidal and fan delta sandy sediments in the study area were transformed into fluvial delta sandy sediments in the northern two source-to-sink systems. The southern source-to-sink systems gradually changed from scattered sandbarrier and coastal sandy sediment to fluvial sandy sediment after the Shanxi Formation.

Geochronology, provenance, and tectonic setting of the meta-sedimentary rocks from the North Shahrekord metamorphic Complex, Iran

ABSTRACT The meta-sedimentary rocks from the North Shahrekord metamorphic Complex (NSMC) comprise micaschists, paragneisses, quartz-feldspathic schists, and marbles. Detrital zircons from the paragneisses yield ages of ca. 2811–507 Ma with most of the dated grains belonging to the Late Neoproterozoic to Cambrian, suggesting a maximum depositional age of the sedimentary protolith during the Late Ediacaran to the Early Cambrian times (543 ± 12 Ma). In contrast, detrital zircons from the quartz-feldspathic schists are mostly dominantly 692–577 Ma and a few at ca. 2369–703 Ma, suggesting that the maximum depositional age of 577 ± 9 Ma, Late Neoproterozoic. The age distribution of detrital zircons suggests that their main provenance was located within the Arabian-Nubian Shield and adjacent terranes. Rutiles from a paragneiss give a U-Pb lower-intercept age of 181 ± 3 Ma, indicating the occurrence of a high-pressure metamorphic event during the Early Jurassic. The trace element contents of the two rock units show enrichment in LREE relative to HREE and negative Eu anomalies, indicating upper continental crustal sources. The geochemical evidence (e.g. low to moderate Chemical Index of Alteration (CIA) and Plagioclase Index of Alteration, high Index of Compositional Variability (PIA), and low Th/U) suggests that the quartz-feldspathic schists and paragneisses originated from an immature, and immature to less mature, respectively, intermediate-felsic igneous source and their protolith experienced a simple sedimentary recycling history with relatively weak to moderate chemical weathering. Geochemical and petrographic data also suggest that the precursor to the quartz-feldspathic schists and paragneisses were deposited in a continental island arc and a back-arc basin setting, respectively. Our new data, including depositional age, provenance, and geochemical evidence, provide perspectives on palaeogeographic affinities (provenance of sediments with different weathering and recycling materials), and paleotectonic reconstructions (from arc to back-arc) of the Iranian basement, exposed in the Sanandaj-Sirjan Zone, during Ediacaran.

Elemental composition and metal pollution in Egyptian Red Sea mangrove sediments: Characterization and origin

The present work was conducted to characterize the mangrove sediments along the Egyptian Red Sea in terms of elemental composition and to assess the extent of pollution and its sources. A total of 26 samples of mangrove sediments were collected from three different areas: Sharm El Madfea, Sowmaa Mangrove and Abu Fasi. The samples were analyzed using the inductively coupled plasma – mass spectrometry ICP–MS and atomic-emission spectrometry ICP-AES. Mass fractions of a total of 58 major and trace elements were determined in the mangrove samples. Univariate and multivariate statistical analyses were performed to determine the origin of trace and major elements in the mangrove sediments. The normalized values show that the elements above the background can be indicated in descending order as follows: P > Cd > Sr > Ca > U > Se > As > Sn > Cu > Sb > Pb > Mo > Ag. Several pollution indices were also calculated. Principal component analysis revealed three clusters of the studied sediment samples. The analysis of the ratio indicators shows that the origin of the sediments mostly falls near continental island arcs (CIA). The pollution indices show remarkable pollution levels and enriched elements. The data obtained can serve as baseline data for the sediments of the mangrove environment and can be used to study possible changes in the future.

Investigating the mineralogical and geochemical composition of fluvial sediments of Watari river system, Kano, Nigeria

A key objective of this research is to conduct a mineralogical and geochemical screening of the fluvial sediments in Watari river. Data collected from this study can be used to further enhance scientific understanding of the fluvial processes in the Watari basin as well as the larger Hadejia-Jama' are basin. The geological data can also be used as input information for the prediction of sedimentation rates in the Watari dam, Kano. An intensive field was conducted to explore thebedforms (sand bars, ripples, and sand filled channel or dunes) of the proximal channel environments, platform geometry and sinuosity.X-ray diffraction (XRD) and X-ray fluorescence (XRF) analyses were used to study the mineralogy and chemical composition of the collected samples, respectively. The Watari river can be considered as braided due to the presence of smaller multi-threaded channels, braid or channel bars. The lithology of exposures observed at the river bank show a series of depositional cycles that comprise mudrocks (light and dark), sandstone, conglomerate and a basal quartzitic gravel deposit. The wacke and sub-litheranite rocks were sourced from mafic and intermediate igneous rocks. The relatively high La and Ce in the mudrocks can be attributed mainly to the adsorption of Ce onto Fe-oxides which are abundant in the fluvial sediments eroded from lateritic soils. From the bivariate plot of Al2O3/SiO2 against Fe2O3+MgO, the sandstone facies fall under the passive continental margin, while the quartzite and conglomerate facies are grouped under the foreland basin, and the light mudrock facies is classified under the continental island arc. In addition, the plot of Al2O3/(CaO + Na2O) against Fe2O3+MgO shows the sandstone and quartzite facies fall under the foreland basin. The relatively high concentration of feldspar and muscovite mica in the siliciclastic facies is indicative of close proximity to parent material, and low degree of weathering and diagenesis. The variability in the mineral composition points toward different cycles of fluvial sedimentation, diverse provenance, and wide range of source materials.The geochemical data further buttresses the variability in provenance, wider geographic area of the sediments or re-deposition and reworking by fluvial actions.

The influences of sedimentary environments on carbon accumulation in lacustrine deposits: Evidences from elemental geochemistry

The carbon dynamics of lacustrine deposits play an important role in controlling the atmospheric carbon cycle. However, the influences of various sedimentary factors on carbon accumulation in lacustrine deposits are rarely known. In this study, the petrological and geochemistry analyses of organic-rich (average total organic content = 24.22 wt%) lacustrine deposits and organic-poor (average total organic content = 2.48 wt%) lacustrine deposits buried under a peatland (the Zhibian peatland) in Northeast Asia are used to explore the above issues. Results suggest that the concentrations of major oxides, trace elements and rare earth elements in the organic-poor lacustrine deposits are higher than those in the organic-rich lacustrine deposits. Furthermore, these lacustrine deposits were sourced from felsic rocks. The tectonic background was continental island arc and active continental margin. Additionally, the sedimentary models of lacustrine deposits buried under peat sequence were also concluded. Organic-poor lacustrine deposits were developed in a deep-water area, that was freshwater and oxygenic condition. This type of lacustrine deposit was influenced by the frequent input of coarse-grained terrigenous debris and low productivity. In contrast, the organic-rich lacustrine deposits were developed in a shallow-water area, that was saline and anaerobic condition. This type of lacustrine deposit was influenced by a rare input of fine-grained terrigenous debris and high productivity. These findings should assist future studies on the carbon dynamics of buried lacustrine deposits. This study would provide a representative example of carbon accumulation processes and mechanisms in buried paleolake system in Northeast China.

Mineralogical and elemental geochemical characteristics of Taodonggou Group mudstone in the Taibei Sag, Turpan–Hami Basin: implication for its formation mechanism

Abstract. Organic matter types in the Taodonggou Group mudstone exhibit significant differences with depth. In order to understand the formation mechanism of this special phenomenon, we analyzed the mineralogy and geochemistry of the mudstone, as well as the source rocks, depositional environment, and depositional processes of the Taodonggou Group. Based on this, we have gained the following insights. (1) The Taodonggou Group mudstone was deposited in an intermediate-depth or deep, dysoxic, freshwater–brackish lake environment under warm and humid paleoclimatic conditions. The input of terrestrial debris was stable, but the sedimentation rate was slow. In addition, the sedimentation in the middle stage was influenced by hydrothermal activities, and the changes in the depositional environment corresponded to variations in organic matter types. (2) The source rocks of the Taodonggou Group mudstone are mainly andesitic and feldspathic volcanic rocks. Sediment sorting and recycling were weak, and hydrocarbon source information was well preserved. The tectonic background of the source area was a continental island arc and an oceanic island arc. Furthermore, changes in the provenance of the Taodonggou Group also had a significant impact on the variations in organic matter types. (3) The sedimentation of the Taodonggou Group involved both traction and gravity flows. The variations in source area, depositional environment, and depositional processes during different depositional periods led to changes in the organic matter types of the Taodonggou mudstone. (4) Based on the depositional environment, provenance, and depositional processes, the sedimentation of the Taodonggou Group can be divided into three stages. In the early stages, the sedimentation center was in the Bogda area. At this time, the Bogda Mountain region was not exposed, and the depositional processes inherited the characteristics of early Permian gravity flow sedimentation, resulting in the widespread deposition of a series of high-quality Type III source rocks in the basin. In the middle stage of the Taodonggou Group sedimentation, the sedimentation center gradually migrated to the Taibei Sag. During this period, the Bogda Mountain region experienced uplift and hydrothermal activity, and the depositional processes gradually transitioned to traction flows, resulting in the widespread deposition of a series of Type II source rocks in the basin. In the late stage of the Taodonggou Group, the uplift of the Bogda Mountain region ceased, and the sedimentation center completely shifted to the Taibei Sag. Meanwhile, under the influence of gravity flows, the organic matter types of the Taodonggou mudstone changed to Type III.

Provenance, Sedimentary Environment, Tectonic Setting, and Uranium Mineralization Implications of the Yaojia Formation, SW Songliao Basin, NE China

The SW Songliao Basin is an extremely significant part of the giant sandstone uranium metallogenic belt in northern China. The Yaojia Formation is the most significant ore-bearing layer in the region. However, the poorly constrained sedimentology of the Yaojia Formation has substantially hindered the understanding of the basin and the exploration of uranium deposits within it. To determine the sedimentology, provenance, and tectonic setting of the Yaojia Formation in the study area, we conducted petrography, whole-rock geochemical analysis, and electron probe research. Based on the results of the study, it appears that the Yaojia Formation sandstone is predominantly composed of lithic sandstone and feldspar lithic sandstone. Uranium exists in two forms: as independent minerals and as adsorption uranium. Pitchblende is the most common independent uranium mineral, with small amounts of coffinite also occurring. The ratios of Sr/Ba, V/(V+Ni), V/Cr, Ni/Co, and (Cu+Mo)/Zn of the samples indicate that the Yaojia Formation was deposited in a sub- to oxygen-rich freshwater environment with a moderately stratified bottom water body and smooth circulation. The geochemical characteristics of the Yaojia Formation sandstones imply that they are primarily derived from felsic igneous rocks in the upper continental crust in active continental margin and continental island arc environments. According to geochemistry and previous detrital zircon U-Pb chronology studies, the Mesozoic and Late Paleozoic felsic igneous rocks of the southern Great Xing’an Mountains are the principal sources of the Yaojia Formation in the SW Songliao Basin. Besides providing sediments for the study area, the uranium-rich felsic igneous rocks in the source areas also represent a long-term, stable, and ideal source of uranium, suggesting substantial potential for uranium exploration in the study area.

Late Triassic Tectonic Setting in Northeastern Margin of North China Craton: Insight into Sedimentary and Apatite Fission Tracks

The closure timing of the Paleo-Asian Ocean and the terminal stage of the Central Asian Orogenic Belt have been widely debated in the geological community. It’s known that the gradual scissor-like closure of the Paleo-Asian Ocean occurred from west to east during the Paleozoic period. However, it was not until the Triassic period that the complete closure of the ocean occurred at the northeastern margin of the North China Craton. Nevertheless, there is still much uncertainty regarding the Late Triassic tectonic setting in Northeast China. In this study, we focused on the Upper Triassic Dajianggang Formation, located in the Shuangyang area of central Jilin Province, which is situated on the northeastern margin of the North China Plate. Our aim was to determine the formation age of the Dajianggang Formation by analyzing the detrital particle composition, petrogeochemistry, detrital zircon U-Pb isotope dating, and apatite fission track thermochronology. Our results indicated that the primary sandstone provenance area of the Dajianggang Formation in the Shuangyang area is the island arc orogenic belt. The tectonic background of the sandstone provenance area is mainly a continental island arc environment. The provenance area is mostly composed of felsic rocks with sedimentary tendencies, and some of its material may have originated from the northern margin of the North China Craton or the eroded recycle orogenic belt. LA-ICP-MS U-Pb dating of detrital zircons shows that the Dajianggang Formation formed after 226.8 ± 5 Ma. Moreover, analysis of the thermal evolution history modelling shows that the Dajianggang Formation in the Shuangyang area continued to be deposited and heated in the early stage, and then experienced rapid exhumation around 30 Ma. This suggests that the study area underwent an orogenic process during the early stage of formation, but then transitioned into a post-orogenic extension period, which constrained the final closure of the Paleo-Asian Ocean prior to the Late Triassic period. In addition, our study indicates that the remote effect of the Pacific subduction did not reach the study area until 30 Ma. The central age of the detrital apatite fission track of sample 19DJ-1 is 94.2 ± 8.3 Ma, which is younger than its corresponding stratigraphic age. The two peak ages of the fission track analysis are 62.9 ± 5.4 Ma and 126 ± 11 Ma. These findings provide new evidence for the tectonic evolution of Northeast China and shed light on the Late Triassic tectonic setting, as well as the influence time of subsequent tectonic domains in the southern part of Northeast China.

Provenance and reconstruction of the tectonic setting in the Famatinian belt - Geochemistry of the late Cambrian – early Ordovician metasedimentary units of the Famatina system, Sierras Pampeanas, Argentina

In order to evaluate depositional environment, provenance and tectonic setting, 19 samples of the metasedimentary rocks of the late Cambrian – early Tremadocian from the north of the Sierra de Narváez, developed at the upper-crustal section of the Famatinian Orogen, together with units of the same ages present at the central portion of the Famatina System (s.l.), the Volcancito and Bordo Atravesado Formations, were petrographic and geochemical analyzed.Although the analyzed metasedimentary rocks were affected by a low grade metamorphic event and locally by thermal metamorphism, the relatively uniform pattern of the REE and trace-element concentrations for the different samples attest nearly isochemical processes related to the metamorphic events, without significant remobilization.The metasandstone from the Sierra de Narváez, with abundance of quartz, feldspar and mainly volcanic fragments, are comparable with those related to a signature of magmatic arc influence. The plagioclase and the typical volcanic quartz point to the dominated volcanic inputs.Taking into account geochemical data, the metasedimentary successions (metapsammite and metapelite) display similar characteristics to those from recent deep-sea turbidite developed in continental arc margins. The presence of black shales facies in the succession, record deepening of the depositional environment due to an overall sea-level rise, denoting an oxygen depletion characteristic of them. The remarkable involvement of volcanic components in the north of the Sierra de Narváez deposits, interbedded as riodacitic to basaltic effusions and as lithic clastic components with the same nature in the metasandstone, allow to indicate that they represent the beginning of the volcanic activity along the Famatina System (s.l.), under the tectonic regime of a continental island arc.