Sediment Contamination Research Articles

Sonneratia sp. as a phytoremediator potential of selected heavy metal contamination on mangrove sediment along Selangor River in Peninsular Malaysia

This study aimed to examine Sonneratia sp as a potential plant for phytoremediation of selected heavy metal contamination of mangrove sediment in Peninsular Malaysia. Five stations were established along Selangor riverbanks under Sonneratia sp trees zone. Five sub-plots (2 m x 2 m) were established for samples collection each plot. Collected samples were prepared and analysed in the laboratory. There was a significant difference of selected heavy metal concentration on sediment and on Sonneratia sp (roots, barks and leaves) between five stations for Zn and Cr, while it was not significant difference for Cu, Pb and Cd. Bio-concentration Factors (BCF) also revealed the species ability to contain elements absorbed differed by vegetative parts where higher average accumulation occurred in leaves for Zn (0.363) and Cd (0.633), in barks for Pb (0.070) and Cr (0.396), while in roots for Cu (2.242). Translocation factor (TF) of Cr in barks was the most concentrated vegetative parts per elements measured in roots at ratio of 1.814 while the lowest was Pb in leaves at 0.515. Sonneratia caseolaris is a good vegetation for uptake the heavy metal from mangrove and can be recommended as a phytoremediation potential of heavy contamination of mangrove sediment.

Long-term mercury loading and trapping dynamics in a Western North America reservoir

Study RegionThe Carson River including Lahontan Reservoir in Northwestern Nevada, USA Study FocusThe discovery, mining, and processing of silver and gold from the Comstock Lode in northwestern Nevada heavily contaminated the Carson River system with mercury (Hg). The river now contains some of the highest recorded water column and bed sediment Hg concentrations reported in peer-reviewed literature. Acute Hg contamination in river and reservoir bed sediment has led to elevated methylmercury (MeHg) concentrations across all trophic levels of Lahontan Reservoir, culminating in significant health risks to humans. Lahontan Reservoir, located downstream from the mills that processed Comstock ore, has served as a Hg trap since the completion of the dam in 1915. Starting in 1997 and extending through 2021, the U.S. Geological Survey has collected and analyzed hundreds of discrete water samples entering and exiting Lahontan Reservoir for unfiltered total Hg (uf.THg), thereby providing a first-of-its-kind opportunity for studying long-term Hg trapping efficiencies within a western North American reservoir. Continuous time series of uf.THg concentration and flux above and below the reservoir were estimated using the weighted regressions on time, discharge, and season with the Kalman filtering (WRTDS-K) method employed with newly developed methods to account for non-natural (i.e., managed) hydrographs below a reservoir. New hydrological insights for the regionAn estimated 31,650 kg (34.89 US tons) of uf.THg entered Lahontan Reservoir during the 25 year period of analysis, accounting for approximately 0.5% of the total uf.THg estimated to have been released to the Carson River system [6.8 million kg (7500 US tons)] over a multi-decade mining boom. Moreover, approximately 92% of the estimated uf.THg entering Lahontan Reservoir was trapped. On an annual basis, however, trapping efficiencies range between 34% and 98%, and are closely related to the total annual discharge. Results also indicate that flow-normalized uf.THg concentrations and loads above and below the reservoir are trending down.

Heavy Metal Contamination Assessment in Sediments, Soils and Surface Waters in Agriculture-Based Rural Chhattisgarh, India, and Evaluation of Irrigation Water Quality

Regional geochemical mapping was carried out in Bilaspur and Korba Districts of Chhattisgarh, and stream sediments/slope wash, soil, and water samples were analyzed for concentration of heavy metals. The study contributes to understanding heavy metals contamination of sediments, soils, and water due to anthropogenic activity, mainly in agriculture-based rural areas. The study reveals that high geochemical anomalies observed for heavy metals like Ni, Cr, As, and Zn in sediments and soil samples are due to the extensive uses of phosphatic fertilizer and soil amendments in the form of poultry and swine manure. Water quality assessment of major streams in the study areas shows that the water is suitable for domestic and agricultural uses. Correlation analysis reveals that the chemical weathering of rock-forming minerals doesn’t control the surface water chemistry of the study area and is also an anthropogenic source of sodium in water. This study also shows the importance of the country’s geochemical mapping database, which will have much broader applications than conventional mineral exploration and geological mapping.

Crustal properties investigation in the Meratus Complex Zone, Southeast Borneo, using H-κ stacking of receiver function analysis

We study crustal properties using teleseismic receiver functions extracted from two broadband seismic stations around the Meratus Complex region, Southeast Borneo. The two seismic stations, BBKI and KBKI, are distributed in the Meratus Mountains and Pulau Laut. We then employ the H-κ stacking technique to measure the crustal thickness (H) and the crustal average Vp/Vs ratio (κ). The method works quite well for receiver functions recorded on seismic station KBKI. The thickness of the crust and Vp/Vs ratio underneath this station are around 38 km and 1.64, respectively. On the contrary, the standard H-κ method fails in estimating the crustal properties beneath station BBKI due to significant sedimentary contamination on the receiver functions. Thus, we apply the sequential H-κ stacking analysis by removing the sedimentary effect and increasing the Moho Ps amplitude. The result shows the thickness of the crust is around 29 km, although the Vp/Vs is not well determined. The research findings from both stations are comparable to those derived from the previous receiver function study using inversion modelling. The crustal properties around this area may reflect the continental material part of the Sunda continental block.

Speciation characteristics, ecological risk assessment, and source apportionment of heavy metals in the surface sediments of the Gomishan wetland

Metal contamination is one of the worldwide environmental issues. The main aim of this study was to evaluate the concentration, probable environmental risk, and source of investigated elements (Al, As, Co, Cr, Cu, Fe, Mn, Ni, and Zn) in sediments and water of the Gomishan wetland. Sediment contamination indices revealed sediments were solely polluted by As. The potential ecological risk index (RI), toxic risk index (TRI), and chemical speciation assessments indicated no major ecological hazards for investigated metals. Correlation analysis and principal component analysis (PCA) indicated that all studied metals in the Gomishan wetland sediments derived from natural sources. HPI, and HEI indices showed that the water quality in terms of hazardous components was inappropriate for aquatic life.

Assessing the Environmental Impact of Heavy Metal Contamination in Water, Sediments, and Aquatic Vegetation of River Yamuna in Delhi

Assessing the Environmental Impact of Heavy Metal Contamination in Water, Sediments, and Aquatic Vegetation of River Yamuna in Delhi

Cyclic and linear siloxane contamination in sediment and invertebrates around a thermal power plant in Korea: Source impact, distribution, seasonal variation, and potential for bioaccumulation

Siloxanes have been commonly used as additives in a variety of industrial and consumer products. Media and government investigations have revealed that defoamers containing siloxanes are used in the effluent of thermal power plants in Korea. However, investigations of the source impact of siloxane contamination from the discharge of thermal power plants into coastal environments are scarce. In this study, sediment and invertebrates were collected around a thermal power plant to assess source impact, seasonal variation, and a potential for bioaccumulation. Although siloxanes were detectable in sediment and invertebrates, the spatial distribution and composition (which differed between the siloxanes found in sediment and invertebrates and those in defoamer used in the plant) suggest they were likely transported by long-distance migration as well as the discharge of thermal power plant. Seasonal differences might affect sedimentary contamination and the bioaccumulation potential of siloxanes. Specifically, octamethylcyclotetrasiloxane (D4) may have limited adsorption capacity and potential for long-distance migration, as its contribution in sediment far from the coastline was greater than that of decamethylcyclopentasiloxane (D5) and dodecamethylcyclohexasiloxane (D6). However, higher D5 accumulation in invertebrates, and D5 has a potential bioaccumulation. A molecular docking analysis showed that the binding affinity between D5 and the cytochrome enzyme in invertebrates was weaker than that with other siloxanes, which could lead to higher D5 accumulation in invertebrates.

Evidence of transboundary movement of chemicals from Mexico to the U.S. in Tijuana River Estuary sediments

The Tijuana River Estuary (TRE) has been a public health hazard and point of contention between the United States and Mexico for decades, with sources of pollution on both sides of the border. The goal of our study is to determine the presence and dynamics of chemical contamination in the TRE. We sampled sediment from four TRE locations in the U.S. during stable dry conditions and immediately after a wet weather period. Organic chemicals were initially screened with non-targeted analysis using gas chromatography high-resolution mass spectrometry (GC/HRMS) that tentatively identified 6978 chemicals in the NIST 20 database. These tentative identifications were filtered using the USEPA CompTox database to guide quantitative targeted analysis at detection limits below 1 ng/g dry weight sediment. Quantitative targeted analysis of 152 organic pollutants and 18 inorganic elements via GC/HRMS revealed generally higher concentrations of contaminants in dry weather sediments compared to wet weather sediments. The highest concentrations of all chemical classes were detected at the site closest to the U.S.-Mexico border, followed by an urban area near Imperial Beach, California, U.S. All sites exhibited a mixture of petrogenic and pyrogenic polycyclic aromatic hydrocarbons (PAHs). Current-use pesticides were dominated by pyrethroid insecticides and the thiocarbamate herbicide s-Ethyl dipropylthiocarbamate (EPTC), while the U.S.-banned organochlorine pesticides were dominated by chlordanes, dieldrin, and dichlorodiphenyltrichloroethane (DDT) and its degradation byproducts. Polychlorinated biphenyl (PCB) concentrations were greatest at the site closest to the U.S.-Mexico border but in the low nanogram-per-gram range. Phthalates were only found at the same site, with relatively high concentrations of bis(2-ethylhexyl) phthalate. This study provides positive identification and quantitative concentrations for organic pollutants in TRE sediments. Our data suggest that there are multiple sources of chemical contamination in the estuary, including possible transboundary movement of pollutants from Mexico.

Assessment of heavy metal contamination of sediments in popular tourist beaches of the Kerala State, southern India: Implications on textural and mineralogical affinities and mitigation

Beaches form one of the most contaminated sedimentary environments by a myriad variety of anthropogenic activities, including tourism and recreational activities. The concentrations of metals and their pollution levels were studied for four tropical tourist beaches in Kerala state, Southern India. Bulk geochemical and mineralogical analyses of 16 sediment samples were performed to determine the environmental status and the environmental risk level using various geochemical indices. Based on the enrichment of TiO2 and SiO2 concentrations, the samples were grouped into ilmenite-rich samples (IRS) and quartz-rich samples (QRS) respectively and the geochemical signatures are significantly different. Mineralogically, the IRS group is dominated by ilmenite, quartz, sillimanite, zircon and rutile while the QRS group consists of quartz, spinel and calcite and garnets are common in both groups of sediments. Despite the variation in the trends of pollution indices, it has been found that Kovalam beach sediments are enriched with W, Th and U where, IRS with enrichment of W, U and Th while QRS only enriched with W and Th and not U. The mineralogical affinity of W with secondary tungsten-bearing minerals has been documented by the XRD analysis and these metals are mainly controlled by the geogenic sourced minerals. However, in terms of ecological risk, Pb, As and Cu have a considerable to moderate risk in both groups of sediments. Overall, both group of sediments shows a moderate risk. Based on the biological effect assessment the elements of concern are Pb and Zn in IRS and possible effect by the Cr, Cu and As in IRS and only by Cu in QRS. Though the prevalence of geogenic and anthropogenic processes and influences of metal enrichments are documented by the study, their relative influences, mobility and bioavailability need to be systematically studied.

Assessing the ecological risk of heavy metal sediment contamination from Port Everglades Florida USA.

Port sediments are often contaminated with metals and organic compounds from anthropogenic sources. Remobilization of sediment during a planned expansion of Port Everglades near Fort Lauderdale, Florida (USA) has the potential to harm adjacent benthic communities, including coral reefs. Twelve sediment cores were collected from four Port Everglades sites and a control site; surface sediment was collected at two nearby coral reef sites. Sediment cores, sampled every 5 cm, were analyzed for 14 heavy metals using inductively coupled plasma-mass spectrometry. Results for all three locations yielded concentration ranges (µg/g): As (0.607-223), Cd (n/d-0.916), Cr (0.155-56.8), Co (0.0238-7.40), Cu (0.004-215), Pb (0.0169-73.8), Mn (1.61-204), Hg (n/d-0.736), Mn (1.61-204), Ni (0.232-29.3), Se (n/d-4.79), Sn (n/d-140), V (0.160-176), and Zn (0.112-603), where n/d = non-detected. The geo-accumulation index shows moderate-to-strong contamination of As and Mo in port sediments, and potential ecological risk indicates moderate-to-significantly high overall metal contamination. All four port sites have sediment core subsamples with As concentrations above both threshold effect level (TEL, 7.24 µg/g) and probable effect level (PEL, 41.6 µg/g), while Mo geometric mean concentrations exceed the background continental crust level (1.5 µg/g) threshold. Control site sediments exceed TEL for As, while the reef sites has low to no overall heavy metal contamination. Results of this study indicate there is a moderate to high overall ecological risk from remobilized sediment due to metal contamination. Due to an imminent dredging at Port Everglades, this could have the potential to harm the threatened adjacent coral communities and surrounding protected habitats.

Joint research in the Baltic Sea by the Atlantic Branch of the VNIRO and the Atlantic Branch of the Shirshov Institute of Oceanology of the RAS

The aim: complex study of the Baltic Sea ecosystem, including the habitat conditions of aquatic biological resources based on the results of joint research by AtlantNIRO and the P.P. Shirshov Institute of Oceanology RAS (Atlantic Branch). Methods used: analysis of long-term data of joint expeditionary research in the open part and coastal zone of the Baltic Sea.Results: owing to the interaction of AtlantNIRO with AB IO RAS in 2018–2022, the continuity of long-term observations has been preserved and the volume of scientific information necessary for assessing the state of the habitat of aquatic biological resources in the Russian sectors of the Baltic Sea has been increased. Modern data on eutrophication and pollution, on distribution of phytoplankton, zooplankton, benthos, as well as the early ontogenetic stages of the main commercial fish have been obtained. The spatial distribution of plankton and benthic communities, including areas favorable for spawning and feeding of fish, has been detailed. A rather high contamination of bottom sediments with radionuclides in certain areas of the Baltic Sea, primarily in the Gulf of Finland, has been found.Practical significance: the implementation of the areas provided by the Agreement between Rosrybolovstvo and RAS, and above all, the participation of AtlantNIRO scientific groups in expeditions in the Baltic Sea in 2018–2022, was a significant addition to the annual research and state monitoring of aquatic biological resources and their habitats conducted by VNIRO in the Baltic Sea.

Growth of Pacific staghorn sculpin (Leptocottus armatus) is reduced at contaminated sites in the Lower Duwamish River, Washington

The Lower Duwamish River is a highly industrialized waterway flowing into the densely urbanized Puget Sound waterfront of Seattle, Washington, USA. The river has been profoundly altered from its natural state following more than a century of channelization, recurrent dredging, shoreline armoring, and pollution discharges. As part of a Natural Resource Damage Assessment addressing historical pollution at three designated Superfund sites (i.e., the assessment area), juvenile Pacific staghorn sculpin (Leptocottus armatus) were sampled throughout the lower river in order to evaluate injury from exposure to polycyclic aromatic hydrocarbons (PAHs), polychlorinated biphenyls (PCBs), dichlorodiphenyltrichloroethane (DDTs), and butyltins (BTs). Sculpin live in close association with the river sediments within and upriver of the assessment area. Fish were collected for analysis of contaminant concentrations in composited whole bodies and stomach contents, as well as individual fish health metrics including daily somatic growth rates measured from otoliths. Sediment contaminant concentrations were also measured at sites near to fishing locations. Fish growth rates varied from 0.65 to 1.05 mm/day, and were significantly lower at unremediated downriver sites compared to upriver and remediated locations. Sculpin growth rates were negatively correlated with concentrations of PCBs in fish bodies, PAHs in stomach contents, as well as PCBs, DDTs and PAHs in sediment. Mixed effects models for whole-body and stomach content contaminants showed positive correlations between growth rate and water temperature. Temperature was not a significant confounding variable for the relationship between growth rate and sediment contaminants. Overall, these results show that juvenile sculpin are harmed by contaminant exposure in the Lower Duwamish River. Furthermore, this study demonstrates the utility of using paired biological and chemical indicators of pollutant-induced injury in a resident fish to inform a complex Natural Resource Damage Assessment and associated restoration efforts.

Selective pressure of arsenic and antimony co-contamination on microbial community in alkaline sediments

Although response of microbial community to arsenic (As) and antimony (Sb) co-contamination has been investigated in neutral and acidic environments, little is known in alkaline environment. Herein, the microbial response and survival strategies under the stress of As and Sb co-contamination were determined in the alkaline sediments. Elevated concentrations of As (13700 ± 5012 mg/kg) and Sb (10222 ± 1619 mg/kg) were introduced into the alkaline sediments by the mine drainage, which was partially adopted in the aquatic environment and resulted in a relatively lower contamination (As, 6633 ± 1707 mg/kg; Sb, 6108 ± 1095 mg/kg) in the downstream sediments. The microbial richness was significantly damaged and the microbial compositions were dramatically shifted by the As and Sb co-contamination. Metagenomic analysis shed light on the survival strategies of the microbes under the pressure of As and Sb co-contamination including metal oxidation coupled with denitrification, metal reduction, and metal resistance. The representative microbes were revealed in the sediments with higher (Halomonas) and lower (Thiobacillus, Hydrogenophaga and Flavihumibacter) As and Sb concentration, respectively. In addition, antibiotic resistance genes were found to co-occur with metal resistance genes in the assembled bins. These findings might provide theoretical guidance for bioremediation of As and Sb co-contamination in alkaline environment.

Microplastic contamination in water and sediments of Mahanadi River, India: An assessment of ecological risk along rural-urban area

Worldwide, environmental concerns about MPs pollution have increased. Microplastic contamination that pollutes the ocean is mostly caused by terrestrial transfer from close proximity locations. A study of MPs pollution near coastal locations becomes necessary to address the MPs transit, fate, and mitigation. In the current study MPs pollution in the surface water and sediment of the Mahanadi River estuary was assessed during Pre-MS and MS. The size, shape, and colour of the MPs were determined using a stereomicroscope, and the MPs polymer composition was identified by Attenuated Total Reflection-Fourier Transform Infrared (ATR-FTIR) spectroscopy. The mean concentration of MPs that were potentially discovered in water was 16.6 ± 5.2 and sediments 197.3 ± 5.4 during Pre-MS. In the MS observed mean abundance of MPs was 15.1 ± 5.4 in water and 164.6 ± 76.9 in sediments. The highest abundant size was smaller than 1 mm; the most prevalent shape were fibers followed by film and fragments; black and white was a prominent colour in water and sediments respectively. Polyesters (PEs), polyethylene (PE), polyvinyl chloride (PVC), polypropylene (PP), polyamide (PA), Polystyrene (PS), and Polycarbonates (PC) were found in the analysis of the chemical composition of MPs in water and sediments samples. The calculated PLI value shows pollution load at category I, with polymer hazard levels at categories III, IV, and V, indicating very high risk. The current research results show that river inflows and fishing-related actions are probably the main causes of MPs pollution.

Correction: Yozukmaz, A.; Yabanlı, M. Heavy Metal Contamination and Potential Ecological Risk Assessment in Sediments of Lake Bafa (Turkey). Sustainability 2023, 15, 9969

The authors would like to make the following corrections to the published paper in [...]

Environmental Risk Assessment for Heavy Metals Contamination in Seawater and Sediments from the Western Coast of Suez Gulf, Egypt

Environmental Risk Assessment for Heavy Metals Contamination in Seawater and Sediments from the Western Coast of Suez Gulf, Egypt

Biogeochemical Assessment of Toxicity and Radioecological Danger of the Transboundary Kara-Balta River

The paper presents the results of researches of the concentration of chemical elements and natural radionuclide in the environmental objects of the Kara-Balta transboundary river basin (adjacent territories of Kyrgyzstan and Kazakhstan). The level of contamination of floodplain soils and bottom sediments of the Kara-Balta River with such chemical elements as U, Sb, As, Th, Pb, Sc, Co, Cu, Mo, Zn, V, Sr, Ba, Cs was established. Based on the calculated indicators of the contamination factor (CF), enrichment factor (EF), and index of geoaccumulation (Igeo), it was found that Sb, As and Br make the largest contribution to soil and bottom sediment pollution in the Kara-Balta water basin. At three checkpoints, an increased concentrations of U, B, Li, Sr, Mo were found in the water samples of the region’s reservoirs, which is related to the influence of the tailings of the Kara-Balta mining plant. The elevated concentrations of As, B, Ba, Co, Mn, Sb, V, and Zn were also established around the mouth of the Kara-Balta River, which flows into the Tasotkel reservoir (Kazakhstan). The results of the research can be explained by the fact that a significant part of the Kara-Balta transboundary river basin is located in the zone of a uranium natural–technogenic province.

Geochemical contamination of heavy metals and health risk assessment of coastal sediments along the North Chennai to Pondicherry, India using total reflection X-ray fluorescence spectroscopy (TXRF)

The present work aimed to assess the contamination and human health risk assessment of heavy metals (HMs) in 21 sediment samples collected from the North Chennai to Pondicherry coastal area of Tamil Nadu using total reflection X-ray fluorescence spectroscopy (TXRF). Enrichment factor (EF), contamination factor (CF), and geo-accumulation index (Igeo) were calculated to estimate sediment contamination. The average concentrations of HMs (mg kg−1 dry weight) were: Al (4305.12), V (25.77), Cr (15.08), Mn (83.39), Fe (4539.77), Ni (2.89), Cu (2.67), Zn (9.46), As (2.81), Hg (0.05), and Pb (0.92). Results of EF indicated no enrichment with Al, Ni, and Pb, moderate enrichment with V, and severe enrichment with As and Hg. Based on Igeo, all sediment samples showed unpolluted with HMs (except As and Hg). Based on total lifetime cancer risk (LCR), there are no significant health risks for people in the study area from carcinogenic Cr, As, and Pb.

Development of a Marine Radioactivity Expert System based on the Extended Marine Food Web: Experiments with Initial Bottom Contamination

An extended version of an expert system was developed as an effort to provide technical support to decision makers for the initial prompt assessment of environmental impacts of marine radioactivity, considering both pelagic and benthic marine food webs. The preliminary version of this system was firstly developed to determine the transfer of radionuclides through a pelagic marine food web (Kim et al, 2020). This system's approach was similar to the Cornell Mixing Zone Expert System (CORMIX) developed by Jirka (1995), as it used idealized settings for the physical/hydrodynamic coastal conditions. Existing or extended systems were executed by taking into account different kinds of radioactivity sources. The initial contamination of bottom sediment is considered in the present study, while the direct discharge to the coastal ocean from the nuclear power plant was considered in the early study. Assuming initial contamination, sensitivity experiments of temporal <sup>137</sup>Cs variations without/with horizontal advection and diffusion (EXP-WOHAD and EXP-WHAD, respectively) were conducted. In EXP-WOHAD, a total of six test cases were constructed, considering a range of vertical diffusion coefficients and sediment fluxes at the water-sea bed interface. The EXP-WHAD experiments were classified into two categories with six cases each, considering the horizontal diffusion and advection processes. The EXP-WOHAD results show that the vertical diffusion processes in the bottom sediment result in the exponential decay of the <sup>137</sup>Cs concentrations in the top sediment layer through upward and downward diffusive fluxes, producing pulse-like time variations in <sup>137</sup>Cs in the water column and the middle sediment layer. These sediment fluxes affect the peak height and its occurrence time in the water column and the middle sediment layer. From EXP-WHAD, it has been confirmed that part of <sup>137</sup>Cs diffused into the water column experiences horizontal dispersion and thereafter deposition to the bottom sediment. It is noted that due to the limited diffusion to the water column, the <sup>137</sup>Cs concentrations in benthic organisms are larger than those in pelagic organisms.

Advancing environmental monitoring: A comparative analysis of sequential radiochemical methods for precise alpha-particle spectrometry analysis of 241Am in soil and marine sediment samples

Environmental monitoring of alpha-emitting radionuclides is crucial for assessing the long-term impacts of nuclear activities and understanding ecosystem dynamics. Thus, long-term marine environmental monitoring needs a precise analytical method for determining isotopes in sediment and soil samples. Because 241Am is the first decay product of 241Pu, its activity in the environment will grow during the next 50 years. This study aims to compare and evaluate different sequential radiochemical methods for 241Am analysis, focusing on their precision and accuracy, to establish a more rapid, refined and reliable approach for environmental monitoring. Four radiochemical methods for 241Am determination in soil and marine sediment samples were compared using alpha-particle spectrometry. This sensitive technique plays a key role in quantifying low-level radioactive contaminants in sediment and soil samples. The procedure was optimised using reference materials prepared by IAEA: sediment (IAEA-300, IAEA-384 and IAEA-385) and soil (IAEA-327 and IAEA-375), and digestion, radiochemical separation, and purification on anion exchange resin (AG 1X8) and chromatographic resins (UTEVA, TRU) were used. The effectiveness of the Ca-oxalate precipitation method for iron removal was also evaluated. We used microcoprecipitation on neodymium fluoride (NdF3) to prepare measurement sources. As a significant outcome, we suggested the potential exclusion of co-precipitation (method D) in the determination of the 241Am isotope in sediment and soil samples. This recommendation aligns with our goal of developing a precise sequential radiochemical method for alpha-particle spectrometry. Our approach offers a valuable and optimised tool for monitoring the environmental impact of nuclear activities and accidents, particularly in marine ecosystems.