AbstractIn‐situ bioremediation is a process by which contaminants in subsurface environments are biologically eliminated or mineralized; however, it is often difficult to implement. Microbes sparsely distributed in deep soils are incapable of degrading a chemical rapidly; furthermore, fine‐pore structures of soils tend to retard the penetration and propagation of these microbes and hinder oxygen transfer. The latter is particularly detrimental to the aerobic growth of microbes, which is often essential for bioremediation. Measures intended to promote bioremediation, such as the addition of surfactants for enhancing dissolution and the application of genetically engineered microbes for accelerating the biodegradation of contaminants, are almost impossible to adopt. This is attributable to the fact that various facets of the bioremediation process (e.g., the distribution of dissolved contaminants, nutrients, and oxygen, and the concentration of microbes) cannot be readily manipulated.This article proposes a novel technology, namely, bio‐wall. This technology resorts to an in‐situ constructed medium with porosity and organic content greater than those of the original soil for promoting the adsorption and retention of microbes and the biodegradation of contaminants. Moreover, oxygen and nutrients are supplied to the bio‐wall to facilitate microbialgrowth. The results of conceptual design study and simulation have revealed that the technology is indeed feasible and, under certain environmental conditions, cost‐effective. Particularly noteworthy is the fact that bio‐wall can prevent contaminant migration through the enhancement of the biodegradation rate and reduction of the plume‐distance, both by several orders of magnitude.