Groundwater Contaminant Plume Research Articles

Cost-effective mini drive-point piezometers and multilevel samplers for monitoring the hyporheic zone

The development of cost-effective approaches to monitor groundwater–surface-water exchange processes and contaminant fate within the hyporheic zone fundamentally underpins implementation of legislation such as the European Community Water Framework Directive, which requires integrated management of groundwater and surface water. Cost-effective mini drive-point piezometers (MDPs) and multilevel samplers (MLSs) are presented that use cheap construction materials, involve simple fabrication and installation procedures, and have a proven durability with low vulnerability to flood events and vandalism. They have been used across a range of hydro(geo)logical settings in the UK and proven to be effective in discerning flow exchange, geochemical trends, and contaminant transport and attenuation over monitored depths of 0.25 to 2 m at a resolution as low as 0.05 m. Example depth profiles, cross-river transects and river-reach longitudinal profiles from the River Tame catchment (West Midlands, UK) illustrate the value of MDP–MLS approaches in establishing surface-water–groundwater mixing zone depths, contaminant natural attenuation as a result of biotic activity within the hyporheic zone, and estimates of contaminant flux exchanges between groundwater and surface water. The MDP–MLS approaches allow discernment of contaminated groundwater plume discharges that may go undetected, or at best poorly resolved, if reliance was solely placed on conventional riverside monitoring wells and/or surface-water sampling. The MDP–MLS approaches described also have potential to be used in the investigation of shallow sediment aquifers, lake shorelines and wetland features.

Characterization of controlled-release KMnO 4 (CRP) barrier system for groundwater remediation: A pilot-scale flow-tank study

Release and spreading of permanganate ( MnO 4 - ) in the well-based controlled-release potassium permanganate (KMnO 4) barrier system (CRP system) was investigated by conducting column release tests, model simulations, soil oxidant demand (SOD) analyses, and pilot-scale flow-tank experiments. A large flow tank ( L × W × D = 8 m × 4 m × 3 m) was constructed. Pilot-scale CRP pellets (OD × L = 0.05 m × 1.5 m; n = 110) were manufactured by mixing ∼198 kg of KMnO 4 powders with paraffin wax and silica sands in cylindrical moulds. The CRP system ( L × W × D = 3 m × 4 m × 1.5 m) comprising 110 delivery wells in three discrete barriers was constructed in the flow tank. Natural sands (organic carbon content = 0.18%; SOD = 3.7–11 g MnO 4 - kg −1) were used as porous media. Column release tests and model simulations indicated that the CRP system could continuously release MnO 4 - over several years, with slowly decreasing release rates of 2.5 kg d −1 (day one), 109 g d −1 (day 100), 58 g d −1 (year one), 22 g d −1 (year five), and 12 g d −1 (year 10). Mean MnO 4 - concentrations within the CRP system ranged from 0.5 to 6 mg l −1 during the 42 days of testing period. The continuously releasing MnO 4 - was gradually removed by SOD limiting the length of MnO 4 - zone in the porous media. These data suggested that the CRP system could create persistent and confined oxidation zone in the subsurface. Through development of advanced tools for describing agent transport and facilitating lateral agent spreading, the CRP system could provide new approach for long-term in situ treatment of contaminant plumes in groundwater.

Effect of TCE Concentration and Dissolved Groundwater Solutes on NZVI-Promoted TCE Dechlorination and H2 Evolution

Nanoscale zero-valent iron (NZVI) is used to remediate contaminated groundwater plumes and contaminant source zones. The target contaminant concentration and groundwater solutes (NO3-, Cl-, HCO3-, SO4(2-), and HPO4(2-)) should affect the NZVI longevity and reactivity with target contaminants, but these effects are not well understood. This study evaluates the effect of trichloroethylene (TCE) concentration and common dissolved groundwater solutes on the rates of NZVI-promoted TCE dechlorination and H2 evolution in batch reactors. Both model systems and real groundwater are evaluated. The TCE reaction rate constant was unaffected by TCE concentration for [TCE] < or = 0.46 mM and decreased by less than a factor of 2 for further increases in TCE concentration up to water saturation (8.4 mM). For [TCE] > or = 0.46 mM, acetylene formation increased, and the total amount of H2 evolved at the end of the particle reactive lifetime decreased with increasing [TCE], indicating a higher Fe0 utilization efficiency for TCE dechlorination. Common groundwater anions (5mN) had a minor effect on H2 evolution but inhibited TCE reduction up to 7-fold in increasing order of Cl- < SO4(2-) < HCO3- < HPO4(2). This order is consistent with their affinity to form complexes with iron oxide. Nitrate, a NZVI-reducible groundwater solute, present at 0.2 and 1 mN did not affect the rate of TCE reduction but increased acetylene production and decreased H2 evolution. NO3- present at > 3 mM slowed TCE dechlorination due to surface passivation. NO3- present at 5 mM stopped TCE dechlorination and H2 evolution after 3 days. Dissolved solutes accounted for the observed decrease of NZVI reactivity for TCE dechlorination in natural groundwater when the total organic content was small (< 1 mg/L).

A deterministic approach to evaluate and implement monitored natural attenuation for chlorinated solvents

AbstractA US EPA directive and related technical protocol outline the information needed to determine if monitored natural attenuation (MNA) for chlorinated solvents is a suitable remedy for a site. For some sites, conditions such as complex hydrology or perturbation of the contaminant plume caused by an existing remediation technology (e.g., pump‐and‐treat) make evaluation of MNA using only field data difficult. In these cases, a deterministic approach using reactive transport modeling can provide a technical basis to estimate how the plume will change and whether it can be expected to stabilize in the future and meet remediation goals. This type of approach was applied at the Petro‐Processors Inc. Brooklawn site near Baton Rouge, Louisiana, to evaluate and implement MNA. This site consists of a multicomponent nonaqueous‐phase source area creating a dissolved groundwater contamination plume in alluvial material near the Mississippi River. The hydraulic gradient of the groundwater varies seasonally with changes in the river stage. Due to the transient nature of the hydraulic gradient and the impact of a hydraulic containment system operated at the site for six years, direct field measurements could not be used to estimate natural attenuation processes. Reactive transport of contaminants were modeled using the RT3D code to estimate whether MNA has the potential to meet the site‐specific remediation goals and the requirements of the US EPA Office of Solid Waste and Emergency Response Directive 9200.4‐17P. Modeling results were incorporated into the long‐term monitoring plan as a basis for evaluating the effectiveness of the MNA remedy. As part of the long‐term monitoring plan, monitoring data will be compared to predictive simulation results to evaluate whether the plume is changing over time as predicted and can be expected to stabilize and meet remediation goals. This deterministic approach was used to support acceptance of MNA as a remedy. © 2007 Wiley Periodicals, Inc.

A geostatistical framework for incorporating transport information in estimating the distribution of a groundwater contaminant plume

The goal of groundwater contaminant plume interpolation is to provide an accurate representation of the spatial distribution of the plume given the data limitations associated with sparse monitoring networks with irregular geometries. Currently available methods for plume estimation cannot fully take advantage of prior knowledge of flow and transport information or the location of a contaminant source. This paper presents two new geostatistical tools for incorporating transport information in estimating the spatial distribution of groundwater contaminant plumes. The methods account for the spatial/temporal covariance of the contaminant plume in defining a best estimate of the plume distribution and its associated uncertainty. Overall, the methods require that the estimated plume distribution be physically feasible given both the available concentration measurements and the flow and transport in the affected aquifer. Sample applications in homogeneous and heterogeneous formations are presented. Even with relatively few observations, the new methods yield results that are superior to those obtained by kriging, with a better reproduction of the true plume shape and lower uncertainty.

Simultaneous optimization of dense non-aqueous phase liquid (DNAPL) source and contaminant plume remediation

A framework is developed for simultaneous, optimal design of groundwater contaminant source removal and plume remediation strategies. The framework allows for varying degrees of effort and cost to be dedicated to source removal versus plume remediation. We have accounted for the presence of physical heterogeneity in the DNAPL source, since source heterogeneity controls mass release into the plume and the efficiency of source removal efforts. We considered high and low estimates of capital and operating costs for chemical flushing removal of the source, since these are expected to vary form site to site. Using the lower chemical flushing cost estimates, it is found that the optimal allocation of funds to source removal or plume remediation is sensitive to the degree of heterogeneity in the source. When the time elapsed between the source release and the implementation of remediation was varied, it was found that, except for the longest elapsed time (50,000 days), a combination of partial source removal and plume remediation was most efficient. When first-order, dissolved contaminant degradation was allowed, source removal was found to be unnecessary for the cases where the degradation rate exceeded intermediate values of the first-order rate constant. Finally, it was found that source removal became more necessary as the degree of aquifer heterogeneity increased.

Reproductive Deficits in Male Freshwater Turtle Chrysemys picta from Cape Cod, Massachusetts1

Contaminated groundwater plumes have formed on the Massachusetts Military Reservation (MMR), a Superfund site on Cape Cod, Massachusetts, as a result of chemical waste disposal. The plumes are of concern to the local people who rely on groundwater as a drinking water source. We used the freshwater turtle as a sentinel species to monitor the reproductive effects of exposure and, by inference, the potential for impact on human health. Our observations of male Chrysemys picta field-trapped from Moody Pond (an impacted site) and Washburn Pond (a reference site) on Cape Cod extended and supported prior observations of reproductive deficits. Morphometric comparison of precloacal length (PCL), which is a sexually dimorphic trait in the turtle, showed that Moody Pond males had a significantly longer PCL than Washburn Pond males. Moody Pond turtles showed reduced testicular weight, which was associated with significantly smaller seminiferous tubule diameter. Epididymal sperm counts were also markedly reduced in Moody Pond animals compared to Washburn Pond animals. Testicular histology and gonial proliferation, as determined by PCNA, were similar in both male populations, while the Moody Pond males had significantly higher germ cell apoptosis than the animals in Washburn Pond. These results suggest that a low-level mixture of xenobiotic contaminants impairs the reproductive functions of turtles exposed to the impacted site but not to the reference site environment.

Comment on “Analysis of groundwater contamination using concentration-time series recorded during an integral pumping test: Bias introduced by strong concentration gradients within the plume” by Allelign Zeru and Gerhard Schäfer

We consider the results of a recent paper in this journal [Zeru, A. and Schäfer, G., 2005. Analysis of groundwater contamination using concentration–time series recorded during an integral pumping test: Bias introduced by strong concentration gradients within the plume. Journal of Contaminant Hydrology 81 (2005) 106–124], which addresses the field-scale characterisation of contaminant plumes in groundwater. There, it is concluded that contaminant concentration gradients can bias Integral Pumping Test (IPT) interpretations considerably, in particular if IPTs are conducted in advective fronts of contaminant plumes. We discuss implications of this setting and also argue that the longitudinal and transverse dispersivities used in the examples of Zeru and Schäfer (2005) of up to 30 m and 3 m, respectively, are generally very high for the here relevant capture zone scale (< 20 m). However, regardless of both longitudinal and transverse concentration gradients, we further show through a counter-example that IPT results are unbiased as long as the concentration attenuation along the flow direction is linear over the capture zone extent.

Effects of acid-sulfate weathering and cyanide-containing gold tailings on the transport and fate of mercury and other metals in Gossan Creek: Murray Brook mine, New Brunswick, Canada

Gossan Creek, a headwater stream in the SE Upsalquitch River watershed in New Brunswick, Canada, contains elevated concentrations of total Hg (Hg T up to 60 μg/L). Aqueous geochemical investigations of the shallow groundwater at the headwaters of the creek confirm that the source of Hg is a contaminated groundwater plume (neutral pH with Hg and Cl concentrations up to 150 μg/L and 20 mg/L, respectively), originating from the Murray Brook mine tailings, that discharges at the headwaters of the creek. The discharge area of the contaminant plume was partially delineated based on elevated pH and Cl concentrations in the groundwater. The local groundwater outside of the plume contains much lower concentrations of Hg and Cl (<0.1 μg/L and 3.8 mg/L, respectively) and displays the chemical characteristics of an acid-sulfate weathering system, with low pH (4.1–5.5) and elevated concentrations of Cu, Zn, Pb and SO 4 (up to 5400 μg Cu/L, 8700 μg Zn/L, 70 μg Pb/L and 330 mg SO 4/L), derived from oxidation of sulfide minerals in the Murray Brook volcanogenic massive sulfide deposit and surrounding bedrock. The Hg T mass loads measured at various hydrologic control points along the stream system indicate that 95–99% of the dissolved Hg T is attenuated in the first 3–4 km from the source. Analyses of creek bed sediments for Au, Ag, Cu, Zn, Pb and Hg indicate that these metals have partitioned strongly to the sediments. Mineralogical investigations of the contaminated sediments using analytical scanning electron microscopy (SEM), transmission electron microscopy (TEM) and scanning transmission electron microscopy (STEM), reveal discrete particles (<1–2 μm) of metacinnabar (HgS), mixed Au–Ag–Hg amalgam, Cu sulfide and Ag sulfide.

Density-driven Transport of Volatile Organic Compounds and its Impact on Contaminated Groundwater Plume Evolution

Density-driven advection of gas phase due to vaporization of chlorinated volatile organic compounds (VOCs) has a significant effect on fate and transport of contaminants. In this study, we investigated the effects of density-driven advection, infiltration, and permeability on contaminant plume evolution and natural attenuation of VOCs in the subsurface system. To analyze these effects, multiphase flow and contaminant transport processes were simulated using a three-dimensional Galerkin-finite-element-based model. Trichloroethylene (TCE) is selected as a target contaminant. Density-driven advection of gas phase elevated the potential of groundwater pollution in the saturated zone by accelerating downward migration of vaporized contaminant in the unsaturated zone. The advection contributed to increased removal rates of non-aqueous phase liquid (NAPL) TCE source and reduced dissolved TCE plume development in the downstream area. Infiltration reduced the velocity of the density-driven advection and its influence zone, but raised TCE transfer from the unsaturated to the saturated zone. The variation in soil permeability showed greater impact on contaminant migration within water phase in the saturated zone than within gas phase in the unsaturated zone. Temporal variations of TCE mass within two-dimensional (2D) and three-dimensional (3D) domains under several modeling conditions were compared. These results are important in evaluation of natural attenuation processes, and should be considered to effectively design monitored natural attenuation as a remedial option.

Multiobjective Analysis of a Public Wellfield Using Artificial Neural Networks

As competition for increasingly scarce ground water resources grows, many decision makers may come to rely upon rigorous multiobjective techniques to help identify appropriate and defensible policies, particularly when disparate stakeholder groups are involved. In this study, decision analysis was conducted on a public water supply wellfield to balance water supply needs with well vulnerability to contamination from a nearby ground water contaminant plume. With few alternative water sources, decision makers must balance the conflicting objectives of maximizing water supply volume from noncontaminated wells while minimizing their vulnerability to contamination from the plume. Artificial neural networks (ANNs) were developed with simulation data from a numerical ground water flow model developed for the study area. The ANN-derived state transition equations were embedded into a multiobjective optimization model, from which the Pareto frontier or trade-off curve between water supply and wellfield vulnerability was identified. Relative preference values and power factors were assigned to the three stakeholders, namely the company whose waste contaminated the aquifer, the community supplied by the wells, and the water utility company that owns and operates the wells. A compromise pumping policy that effectively balances the two conflicting objectives in accordance with the preferences of the three stakeholder groups was then identified using various distance-based methods.

Gonadotropin and estrogen responses in freshwater turtle ( Chrysemys picta) from Cape Cod, Massachusetts

As a result of chemical waste disposal on the Massachusetts Military Reservation, a Superfund site on Cape Cod, MA, contaminated groundwater plumes have formed. These plumes are of concern due to the widespread use of groundwater wells as a drinking water source by the local population. Prior observations on a sentinel species Chrysemys picta field-trapped from ponds on Cape Cod suggested deficits in reproductive processes including lower levels of vitellogenin, estradiol-17β, oviduct weights, and oocyte numbers in females and lower testicular weight and sperm count in males. Possible loci in the hypothalamic–pituitary–gonadal–liver axis at which xenobiotics may act were determined in turtles trapped from Moody Pond (a test site) and Washburn Pond (a reference site). Specifically, gonadotropin and estrogen responses were assessed using plasma steroids and vitellogenin as markers. Basal vitellogenin levels were significantly lower in Moody Pond females; however, vitellogenin responses to estradiol-17β were the same in both groups, indicating a normal hepatic response to estrogen. In contrast, estradiol-17β secretion was not stimulated by gonadotropin in Moody Pond females, compared to Washburn animals. Basal plasma testosterone and the response to gonadotropin in males were similar, although steroid levels in Moody Pond animals were slower to return to baseline after gonadotropin injection. The results suggest that a low-level mixture of xenobiotic contaminants may interfere with the steroid metabolic pathways in turtles exposed to the test site, but not the reference site, environment.

Pollution in an Urban Bayou: Magnitude, Spatial Distribution and Origin

Bayou Texar in Pensacola, FL, receives pollutants from a variety of sources, presumably including two USEPA's Priorities List sites. To evaluate the potential negative impacts of pollution in this type of setting, we determined the level and distribution of some of the pollutants in the bayou and identified the most likely sources for them. Results show that fluoride, a tracer for a contaminated groundwater plume from one of the Priorities List sites, enters sediments in the northern part of the bayou and migrates into the water. Radium in the bayou most likely also emanates from the contaminated groundwater plume. However, 228Ra/226Ra isotope ratios indicate that the radium enters the plume from the aquifer matrix, and thus does not originate directly at the Priorities List site. PAHs of creosote origin are known to have been released by the second Priorities List site but apparently they do not affect the sediments of the bayou because ratios of individual PAHs show that they are derived from combustion. The concentrations of the PAHs are slightly higher in the northern part of the bayou. Unlike other pollutants, most metals exceed their probable effects level (PEL) in many places in the bayou. The highest concentrations are observed in the northern part of the bayou. Low metal concentrations in monitoring wells and in deep sediments in the bayou suggest that the metals do not come from the groundwater plume. Sediment transport analysis shows that sediments are trapped in the northern part of the bayou. Consequently, long term accumulation explains the observed high concentrations of heavy metals, and other sediment bound pollutants, in the northern part of Bayou Texar. Pollutant concentrations vary greatly spatially, demonstrating the importance of geographical analysis for this type of environmental research.

Groundwater contamination plume monitoring in sealed waste dumps

Sealing waste dumps does not mean that they are no longer an environmental hazard, since almost all of them were constructed many years ago, without taking into account environmental regulations. Therefore, after being closed, a monitoring plan should be implemented and, when necessary, characterization studies must be undertaken to avoid unforeseen problems. To design monitoring plans for these areas, it is essential to have knowledge of local geology and hydrogeology, since potential contamination of soils and groundwater depends essentially on the physical characteristics of the area (e.g. porosity and permeability) and local dynamic of fluids (e.g. groundwater level, flow direction). This paper presents a methodology for monitoring the surrounding area of sealed waste dumps and for determining the presence of contamination in groundwater, based on Portuguese experience.

Identification of a reactive degradation zone at a landfill leachate plume fringe using high resolution sampling and incubation techniques

Vertical small-scale variation in phenoxy acid herbicide degradation across a landfill leachate plume fringe was studied using laboratory degradation experiments. Sediment cores (subdivided into 5 cm segments) were collected in the aquifer and the sediment and porewater were used for microcosm experiments (50 experiments) and for determination of solid organic carbon, solid–water partitioning coefficients, specific phenoxy acid degraders and porewater chemistry. Results from a multi-level sampler installed next to the cores provided information on the plume position and oxygen concentration in the groundwater. Oxygen concentration was controlled individually in each microcosm to mimic the conditions at their corresponding depths. A highly increased degradation potential existed at the narrow plume fringe (37.7 to 38.6 masl), governed by the presence of phenoxy acids and oxygen. This resulted in the proliferation of a microbial population of specific phenoxy acid degraders, which further enhanced the degradation potential for phenoxy acids at the fringe. The results illustrate the importance of fringe degradation processes in contaminant plumes. Furthermore, they highlight the relevance of using high-resolution sampling techniques as well as controlled microcosm experiments in the assessment of the natural attenuation capacity of contaminant plumes in groundwater.

Long-Term Natural Attenuation of Carbon and Nitrogen within a Groundwater Plume after Removal of the Treated Wastewater Source

Disposal of treated wastewater for more than 60 years onto infiltration beds on Cape Cod, Massachusetts produced a groundwater contaminant plume greater than 6 km long in a surficial sand and gravel aquifer. In December 1995 the wastewater disposal ceased. A long-term, continuous study was conducted to characterize the post-cessation attenuation of the plume from the source to 0.6 km downgradient. Concentrations and total pools of mobile constituents, such as boron and nitrate, steadily decreased within 1-4 years along the transect. Dissolved organic carbon loads also decreased, but to a lesser extent, particularly downgradient of the infiltration beds. After 4 years, concentrations and pools of carbon and nitrogen in groundwater were relatively constant with time and distance, but substantially elevated above background. The contaminant plume core remained anoxic for the entire 10-year study period; temporal patterns of integrated oxygen deficit decreased slowly at all sites. In 2004, substantial amounts of total dissolved carbon (7 mol C m(-2)) and fixed (dissolved plus sorbed) inorganic nitrogen (0.5 mol N m(-2)) were still present in a 28-m vertical interval at the disposal site. Sorbed constituents have contributed substantially to the dissolved carbon and nitrogen pools and are responsible for the long-term persistence of the contaminant plume. Natural aquifer restoration at the discharge location will take at least several decades, even though groundwater flow rates and the potential for contaminant flushing are relatively high.

Geophysical investigation in contamination hazard studies

The influence of mine water reservoir on the groundwater quality was estimated. The geophysical methods as the electromagnetic and conventional resistivity method combined with elementary hydrogeological techniques were used to mapping and monitoring groundwater contaminant plumes. The investigation area is situated around the reservoir of mine salt water in Upper Silesia, Poland, where groundwater contamination either does occur or may soon occur. First the electromagnetic measurements were carried out to mapping anomaly areas. Then on the basis of geophysical measurements interpretation the proving bore holes were made to measure.groundwater level and conductivity. The conductivity of water from surface seepages, reservoir and neighbouring rivers were also measured. The electromagnetic and hydrogeology results shown the connection of geophysical anomalies with migrated mine water from reservoir. It can enable mapping of the contaminated areas and identify contamination hazards.

Monitoring groundwater contamination and delineating source zones at industrial sites: Uncertainty analyses using integral pumping tests

Field-scale characterisations of contaminant plumes in groundwater, as well as source zone delineations, are associated with uncertainties that can be considerable. A major source of uncertainty in environmental datasets is due to variability of sampling results, as a direct consequence of the heterogeneity of environmental matrices. We develop a methodology for quantifying uncertainties in field-scale mass flow and average concentration estimations, using integral pumping tests (IPTs), where the contaminant concentration is measured as a function of time in a pumping well. This procedure increases the sampling volume and reduces the effect of small-scale variability that may bias point-scale measurements. In particular, using IPTs, the interpolation uncertainty of conventional point-scale measurements is transformed to a quantifiable uncertainty related to the (unknown) plume position relative to the pumping well. We show that this plume position uncertainty generally influenced the predicted mass flows and average concentrations (of acenapthene, benzene and CHCs) to a greater extent than a boundary condition uncertainty related to the local water balance, considering 19 control planes at a highly heterogeneous industrial site in southwest Germany. Furthermore, large (order of magnitude) uncertainties only occurred if the conditions were strongly heterogeneous in the nearest vicinity of the well. We also develop a consistent methodology for an assessment of the combined effect of uncertainty in hydraulic conditions and uncertainty in reactive transport parameters for delimiting of both contaminant source zones and zones absent of source, based on (downgradient) IPTs.

Electrolytic transformation of ordinance related compounds (ORCs) in groundwater: Laboratory mass balance studies

Electrolytic reactive barriers (e − barriers) consist of closely spaced permeable electrodes installed across a groundwater contaminant plume in a permeable reactive barrier format. Application of sufficient potential to the electrodes results in sequential oxidation and reduction of the target contaminant. The objective of this study was to quantify the mass distribution of compounds produced during sequential electrolytic oxidation and reduction of ordinance related compounds (ORCs) in a laboratory analog to an e − barrier. In this study, a series of column tests were conducted using RDX (hexahydro-1,3,5-trinitro-1,3,5-triazine) and TNT (2,4,6-trinitrotoluene) as representative ORCs. The experimental setup consisted of a plexiglass column packed with quartz–feldspar sand to simulate aquifer conditions. A single set of porous electrodes consisting of expanded titanium-mixed metal oxide mesh was placed at the midpoint of the sand column as a one-dimensional analog to an e − barrier. Constant current of 20 mA (variable voltage) was applied to the electrode set. Initial studies involved quantification of reaction products using unlabeled RDX and TNT. Approximately 70% of the influent concentration was transformed, in one pass, through sequential oxidation–reduction for both contaminants. Following the unlabeled studies, 14C labeled RDX and TNT were introduced to determine the mass balance. An activity balance of up to 96% was achieved for both 14C-RDX and 14C-TNT. For both contaminants, approximately 21% of the influent activity was mineralized to 14CO 2. The proportion of the initial activity in the dissolved fraction was different for the two test contaminants. Approximately 30% of the initial 14C-RDX was recovered as unreacted in the dissolved phase. The balance of the 14C-RDX was recovered as non-volatile, non-nitroso transformation products. None of the 14C-RDX was sorbed to the column sand packing. For 14C-TNT approximately 51% of the initial activity was recovered in the dissolved phase, the majority was unreacted TNT. The balance of the 14C-TNT was either sorbed to the sand packing (approximately 24%) or dissolved/mineralized as unidentified ring cleavage products (∼4%).

GeoSiphon™ groundwater remediation system hydraulics

Two pilot-scale, GeoSiphon systems have been installed and tested for the treatment of contaminated groundwater at the Savannah River Site. These systems consisted of an in-situ treatment cell located in an area of higher hydraulic head and a siphon connecting the cell to a surface stream at a lower hydraulic head. The siphon induced contaminated groundwater flow through a permeable treatment media in the cells and transported the treated water to the discharge points in a surface stream. The hydraulic head available to drive the systems is divided between the head losses associated with the aquifer-treatment cell and siphon. Six different treatment cell configurations and seven different siphon configurations have been hydraulically evaluated in association with the two pilot-scale systems and are described herein. These pilot-scale systems demonstrated that GeoSiphon systems can treat any contaminant for which an appropriate permeable treatment media is available and can be applied to shallow groundwater contaminant plumes (no deeper than 7.6 m [25 ft]), where at least a few feet of head differential can be exploited. The systems could typically be applied in flood plains.