Contact Line Research Articles

Optimal Allocation of Hybrid Energy Storage Capacity Based on ISSA-Optimized VMD Parameters

To address the issue where the grid integration of renewable energy field stations may exacerbate the power fluctuation in tie-line agreements and jeopardize safe grid operation, we propose a hybrid energy storage system (HESS) capacity allocation optimization method based on variational mode decomposition (VMD) and a multi-strategy improved salp swarm algorithm (ISSA). From typical wind load power and contact line agreement power, the HESS power is obtained. VMD decomposes this power into high- and low-frequency power, respectively, for the super capacitor and the Li-ion battery. Considering charging and discharging power and state of charge (SOC) constraints, an optimization model minimizing the system equivalent annual value cost is established. ISSA optimizes the best decomposition layer K and penalty coefficients α in VMD. The optimal cut-off point and corresponding energy storage allocation scheme are analyzed. A simulation and analysis on MATLAB show that the proposed ISSA-VMD HESS capacity allocation scheme saves 7.53% in costs compared to an empirical mode decomposition (EMD) scheme, proving the method’s effectiveness and superiority.

Effect of variable load on centralized dimple in opposite sliding condition

Abstract In ball bearings without a cage, adjacent balls exhibit a zero-entrainment velocity (ZEV) contact condition, which is worse than typical pure rolling or rolling-sliding contact, and the contact between adjacent balls under periodic loading is notably more complicated. In this work, thermal elastohydrodynamic lubrication (EHL) numerical calculation is carried out under the condition of periodic impact and opposite sliding line contact over a wide range of surface speeds. the pressure is solved by multigrid method, the elastic deformation is evaluated using multigrid integration method, the temperature field is calculated by column-by-column scanning technique. The results show that the loading-unloading process exerts significant influence on the variation of the centralized dimple, pressure, and temperature rises as well as the oil characteristics. With the increase of surface speed, the effect of load fluctuations diminishes, and the central dimple exhibits the following evolutionary trend under ZEV conditions: no dimple at very low velocity - small central dimple - large typical dimple - no dimple at high velocity. The result indicates that under the ZEV condition of EHL stage, elevated velocities decrease the coefficient of friction and augment the film thickness.

Motion behaviors of droplets containing Au nanoparticles on a superhydrophobic laser-induced graphene surface

The movement of nanoparticle-containing droplets on solid surfaces significantly affects the distribution of the nanoparticles and is of great interest in the fields of two-phase separation, biosensing detection, inkjet printing, and microarrays. There has been little research on the initiation and motion behaviors of colloidal droplets containing nanoparticles on superhydrophobic surfaces. Here, we prepare superhydrophobic laser-induced graphene (LIG) surfaces with excellent depinning effects using an extremely simple method and explore the formation mechanism of the depinning-LIG surfaces. The reduction of nano-graphene fibers and the increased hydroxyl group ratio after alcohol modification further enhance the hydrophobic properties of depinning-LIG, reducing its surface adhesion. The initial and continuous motion of droplets containing Au nanoparticles (AuNPs) on these superhydrophobic surfaces under airflow is studied using high-speed microscopy. The coupling effects of the droplet size, surface properties, airflow velocity, and nanoparticles on the droplet motion behaviors are analyzed. The dimensionless parameter G is incorporated to obtain the partition diagram of AuNP droplet motion behaviors on depinning-LIG surfaces, which delineate the critical conditions for droplet “oscillation,” “initiate sliding,” and “continuous rolling” as a function of system parameters. For AuNP droplets, the viscous force Fγ,p exerted by the nanoparticles on the contact line significantly affects the droplet movement behaviors. In addition, a mathematical model about the competition of dynamic forces and resistance is established to describe the motion of AuNP droplets, and the critical conditions for different motion behaviors of the droplet are clarified to guide practical applications.

Effect of the dynamic contact angle on electromagnetically driven flows in free liquid films

We study the effect of a dynamic contact angle on an electromagnetically driven flow in a horizontal free electrolyte film stretched between two coaxial cylindrical electrodes and placed in a uniform magnetic field. The flow dynamics and film deformation are described using the reduced hydrodynamic model derived in the lubrication approximation in [A. Pototsky and S. A. Suslov, J. Fluid Mech., 984, A75 (2024)]. The linearized molecular kinetic model is used to relate the dynamic and static contact angles to the wetting-line friction coefficient. Steady azimuthal flow is found for arbitrary static contact angles. Linear stability of the base azimuthal flow with respect to azimuthally invariant perturbations is studied using the numerical continuation method. We find that the flow stability is highly sensitive to variations of the wetting-line friction coefficient and the static contact angle. The least stable azimuthal flow is found for the frictionless contact line corresponding to a free film that remains perpendicular to the surface of the electrodes. The azimuthal flows are found to experience a supercritical Hopf bifurcation upon which they transition to a stable oscillatory dynamic regime characterized by alternating squeezing and swelling of the film near the inner and outer electrodes.

Formation dynamics of the satellite droplet in the breakup of a symmetrical liquid bridge

Inkjet printing technology has played an irreplaceable role in life science, precision manufacturing, and other frontier fields in recent years. However, the further development of this technology is limited by the fact that its printing resolution is difficult to raise to a higher level. The emerging satellite droplet printing technology offers a new approach for inkjet printing to break through the bottleneck of printing resolution limitations. In this paper, a symmetrical satellite droplet printing strategy is proposed. The effects of the geometric parameters of the satellite droplet generating device, the physical properties of the ink, and the operating parameters on the liquid bridge breakup process and the size of the satellite droplet are systematically studied. The phase field method and adaptive mesh refinement strategy are applied to solve the two-dimensional symmetrical model. The results indicate that the length of the liquid bridge, the radius of the bridge, the viscosity of the ink, and the drainage velocity are all positively correlated with the satellite droplet size, while the surface tension coefficient has a negative correlation with the satellite droplet size. Furthermore, the three-phase contact line at the orifice end will slip toward the center if the initial radius of the liquid bridge is quite large. Based on these investigations and discussions, a corresponding effective working space for satellite droplet printing is obtained, which lays the foundation for the popularization and further development of satellite droplet printing technology.

Enhanced interfacial capture with an elliptical cylinder

Interfacial capture of particles and droplets is important in practical applications. Interfacial capture owing to the surface tension force occurs only when the target (particle or droplet) is close to the collector, leading to low efficiency with collector or collector arrays. An elliptical cylinder instead of a common circular cylinder is a method to enhance capture efficiency. We theoretically investigate this situation by modelling the motion of floating particles around a surface-piercing elliptical cylindrical collector at Reynolds numbers of 1–10. Results indicate that, despite a smaller capture width, elliptical cross-sections, especially with smaller aspect ratios, are more efficient in capturing owing to a much smaller contact line perimeter compared with circular cross-sections. The aligned orientation (the major axis is parallel to the flow) is better than the orthogonal orientation (the major axis is perpendicular to the flow) owing to a larger capture width. A larger collector is beneficial to capillary capture but a very large size is adverse. Smaller but heavier floating particles for smaller capillary numbers can be easily captured at lower Reynolds numbers. The aligned orientation has a greater advantage over the circular cross-section and the orthogonal orientation in the capillary capture. This provides a good method for enhancing the capture efficiency of floating particles in applications.

Droplet boiling on two-tier hierarchical micro-pillar array surface – Nucleate boiling regime

Although hierarchical structured surfaces have shown great potential in improving heat transfer performance of boiling, the mechanisms associated with structure configuration and structure size remain elusive. In this work, the nucleate boiling regime of droplet on single-tier micro-pillar array (SM) surfaces and three types of two-tier hierarchical micro-pillar array (THM) surfaces is investigated comprehensively using the lattice Boltzmann model. Effects brought by the primary pillar size and the secondary pillar configuration on the development of vapor confined in pillar gaps are emphatically discussed from bubble nucleation through vapor coalescence to vapor expansion. Boiling dynamic characteristics concerning droplet morphological evolution, liquid-vapor interfacial deformation and triple-phase contact line (TPCL) motion are elucidated by the distributions of vapor pressure, fluid temperature and substrate heat flux. It is most efficient for the secondary pillar to enhance boiling heat transfer performance when configured on the side of primary pillar and least efficient when configured on the top of primary pillar.

Effects of dynamic wetting and liquid–solid slip on self-propelled nanodrops in tapered nanochannels

Drops inside tapered microchannels exhibit self-propelled behavior, driven by the capillary pressure gradient within the drops. This driven force may be balanced by the viscous drag and the contact line drag to determine the drop displacement, in analogy to the way to predict capillary imbibition. However, how the drops move exactly with time at the nanoscale is unclear. This study employs molecular dynamics simulations to explore the dynamics of nanodrops within tapered channels with hydrophobic and hydrophilic coatings. The simulations reveal that in a hydrophobic tapered channel, drops migrate toward the wider side of the channel but may halt midway as the driving pressure approaches zero during their movements. Conversely, in hydrophilic tapered channels, drops move unlimitedly toward the channel's tip. Incorporating considerations for dynamic contact angles based on the molecular kinetic theory and liquid–solid slip, a theoretical model is derived that accurately predicts the drop displacement observed in molecular simulations without free parameters. In our simulations of drop motion in hydrophilic tapered channels, the drop displacement x is found linear with time x ∼t, as the viscous drag is dominant and the slip length is small. However, the theory further predicts that drop displacement may behave as x2 ∼t when slip length is large. Conversely, under dominant contact line drag, the theory predicts x3 ∼t for drop motion in tapered nanoslits. These findings underscore the critical influence of dynamic wetting and liquid–solid slip in precisely predicting drop motions on solid surfaces at the nanoscale.

Spreading dynamics of a microgel particle-laden thermosensitive polymer drop along smooth and nanofiber surfaces

The research focuses on the influence of 300-μm microgel particles in an aqueous solution of a thermosensitive biopolymer on the spreading and deformation of 3.7-mm drops. The drops impact a smooth hydrophilic and a rough hydrophobic surface. A mass fraction of microgel particles varies in a range of 0–0.2. A universal physical model of the spreading of thermosensitive polymer drops laden with microgel particles along surfaces with significantly different roughness is proposed. It explains the strong inhomogeneity of the contact line stretching due to the deceleration of the continuous phase flow by microgel particles and the increased flow vorticity because of the addition of the surface roughness factor. The validity of the proposed physical model is proven by qualitative and quantitative assessments of the contact line deformation when spreading. An empirical expression for the maximum spreading factor is derived, taking into account the properties of liquids, wall roughness, and microgel particle concentration; it reliably predicts when Re≈110−3100, the surface roughness is 0.5–125 nm, Ca=4.5×10−7, and the number of microgel particles in drops is up to 100. The expression was successfully tested during the modeling of arbitrary surface roughness and the increased concentration of microgel particles relative to those considered in experiments during the formation of a biopolymer layer. When developing the method of additive manufacturing of a functional layer, a practical correlation was established between the volume content of microgel particles, acting as potential containers for living cells, in a drop and the area of the biopolymer layer.

Acoustic-streaming driven liquid filling patterns inside through-glass vias

Filling through-glass vias (TGVs) with liquid remains a significant challenge in IC packaging technology. This study presents an acoustic-streaming method to modulate the wetting behavior as well as the interfacial dynamics to fill the TGVs. We categorize the incomplete filling into three typical patterns: (a) neck wetting, (b) head and end wetting, and (c) bubble wrapping. Experimental results show that the ultrasonic driving at 522.5 kHz/160 V can effectively achieve ideal filling of these patterns in TGVs (aspect ratio of 1:2/1:3). The filling processes are elucidated from a new perspective: the liquid flow induced by acoustic streaming regulates the moving of contact line to complete wetting on sidewalls, while the acoustic wave impacts the gas–liquid interface to cause oscillations for pushing bubbles out. A Lattice Boltzmann model is constructed to reveal the mechanism. This method offers a viable and promising solution to promote liquid filling of TGVs.

Toward submicron inkjet-printed ZnO microdots with suppressed coffee-ring effect via controlled drying conditions for potential solar cell applications

The high-resolution, inkjet-printed zinc oxide (ZnO) microdot arrays with suppressed coffee-ring effect was demonstrated by investigating the correlation between drying and solidification processes. The internal microfluidic behavior of an ejected droplet and the associated drying process is geometry-dependent, which can be controlled by the temperature and surface energy of the substrate. During evaporation, droplets in contact with a wettable surface exhibit a dominant outward convective flow, resulting in a pronounced coffee-ring effect. In contrast, for droplets with minimal contact area on a substrate with low surface energy, the surface energy gradient along the relatively long thermal conducting path length reinforces the Marangoni flow, which retards the pinning of the contact line, resulting in tiny microdots with suppressed coffee-ring effect. The controlled ZnO microdots exhibit a diameter of approximately 3 μm with a thickness of 50 nm, which is one of the smallest microstructures produced by the inkjet printing method. Additionally, the integration of the ZnO microdot arrays into organic solar cells aimed to alter the light path length, leading to enhanced internal absorption. The P3HT:PCBM, PTB7-Th:PCBM, and PM6:Y6 devices with ZnO microdot arrays exhibit higher power conversion efficiencies of 3.54%, 9.04%, and 15.61% compared to reference devices of 3.38%, 8.85%, and 15.25% respectively.

О влиянии «гидрофобности» газовой фазы на образование флотокомплексов в процессах флотации

Introduction. A model of a three-phase system in which, as a result of hetero coagulation from a bulk liquid, its thin layer has formed, the surfaces of which separate the gas and condensed phases with different potentials, is a wetting film. The study of wetting films adds to the knowledge of the nature of the structure-induced surface forces acting in them, which serves to develop the theory of hetero coagulation and is of interest for solving various topical problems of the theory and practice of flotation. The purpose of the work is to study the influence of “hydrophobic” properties of the gas phase on the separation of minerals by flotation with a vapor-air mixture in flotation schemes with jet countercurrent flow of feed and rough concentrate. Materials and Methods. Methods and installations have been developed to investigate the temperature dependence of the equilibrium thickness of wetting films and wetting edge angles. Studies of wetting films are supplemented by measurements of induction time at adhesion of minerals to each other and to an air bubble on a specially designed installation. In-situ flotation experiments were performed on a sample of apatite-nepheline ores. Results. The temperature dependence of the equilibrium thickness of the wetting film has been revealed, which does not contradict the experimentally established decrease of the exponentially decreasing (non-oscillating) part of the cleavage pressure with increasing temperature. It is shown that the temperature dependence of the boundary angles formed by the wetting film on the hydrophobic and hydrophilic surface is multidirectional. The connection between the temperature dependence of the boundary angle and the temperature dependence of the spreading coefficient obtained from Young’s law and determined by multiplication of parameters characterizing the magnitude and long-range action of forces caused by the difference between the structure and properties of the liquid in the boundary layers and their values in the volume is shown. “Hydrophobicity” of the bubble is associated with a smaller range effect of structural repulsion forces compared to hydrophobic attraction forces. By measuring the induction time, it is shown that the “hydrophobicity” of air manifests itself in the difference in the stability of wetting (when hydrophobic and hydrophilic particles adhere to the air bubble) and symmetric (when particles of the same hydrophobicity/hydrophilicity adhere to each other) films as the temperature increases. Discussion. In the framework of the phonon mechanism of surface forces, the dynamic structure of the liquid in the boundary layers (the sign and magnitude of the phonon component of the bowing pressure) determines the selectivity of aggregation and completeness of particle extraction, as well as the stability of symmetric and wetting films from temperature. Conclusion. When discussing the stability of disperse systems, the concepts of additional (to dispersive (van der Waals) and ionic-electrostatic interactions) forces associated with the overlap of boundary layers of liquids with structure parameters changed compared to their bulk values are fruitfully used. Such differences are understood as static deviations of the structure and properties of the liquid induced by the surface. However, the main reason for changes in the stability of wetting films at increasing temperature may be the high sensitivity to temperature of the entire set of rotational and vibrational motions of atoms and molecules of the liquid, i. e., its dynamic structure and the associated phonon component of the wedging pressure. Resume. The results of the study can be used to improve the technological performance of ores enriched by flotation. Consideration of the influence of linear tension on the system with the line of threephase contact will be useful for revealing the peculiarities of flotation of micro-dispersions of minerals by the developed technology.

Incorporating specific sambo exercises into distance learning for high school students aged 15-16

Background and Study Aim. The military situation in Ukraine necessitates a revision of the school class organization system. Proximity to the military contact line forces schools to switch to online learning. Additionally, there is a decrease in physical activity among school students. In these conditions, it is important to explore the effectiveness of using specific sambo exercises to develop physical qualities in high school students during distance learning. The aim of the study is to determine the effectiveness of such application of sambo exercises for the development of physical qualities in high school students in a distance learning format. Materias and Methods. The study involved tenth-grade students (n=15), aged 15-16 years. Data collection was conducted through surveys using Google Forms and testing to determine physical quality indicators. The experiment lasted for 8 weeks (with sessions three times a week), during which specific sambo exercises were applied in a remote format during physical education lessons. Results. The study results showed that 80% of the students were interested in implementing a new module - sambo - in physical education lessons. Correlational links were established between the results of the exercises and indicators of strength, flexibility, and coordination. Moreover, there was a significant improvement in the test results for coordination, flexibility, and strength, averaging 20%. Conclusions. The study results indicate significant interest among high school students in implementing specific sambo exercises in a distance learning environment. This is confirmed by the high percentage of students who expressed a desire to practice sambo during physical education lessons.

Comprehensive study on collision patterns of viscous droplets impacting on a heated particle

The collision process involving droplets and heated particles has gained significant attention due to its wide industrial relevance. This study utilizes a high-speed photography to investigate the collision dynamics between viscous droplets and heated particles. The research identifies six distinct collision patterns. In the bubble-breakup mode, the particle experiences the greatest temperature drop, resulting in the most substantial heat transfer. The particle temperature plays a crucial role in determining collision behavior when the Reynolds number exceeds 100 and the Weber number exceeds 55. The maximum spreading area demonstrates a linear relationship with the Weber number, while it reaches a peak and stabilizes with Reynolds numbers in the deposition regime. Contact angle fluctuations are caused by the instability of the contact line. The liquid film thickness exhibits linear and power growth phases, followed by a rapid decrease in the bubble-breakup regime. While the branch-breakup pattern sees smaller fragmented droplet sizes, the atomization-breakup pattern sees flow velocity rise with both Reynolds and Weber numbers. The predicted wavelength of the disturbance in the atomization regime, based on Rayleigh-Taylor instability theory, aligns well with the experimental measurements. The residence time correlates positively with the Weber number.

Enhanced insights into paired droplet evaporation dynamics on heated substrates: Unveiling the role of convection and diffusion

This study aims to examine the evaporation characteristics of single and multiple droplets on a heated substrate. By utilizing a multi-syringe pump, deionized water droplets were precisely deposited on a copper substrate, ensuring uniformity and accuracy in the experimental setup. The shadowgraph technique was instrumental in determining the droplet contact angle and volume with exceptional clarity and precision. This work numerically predicted the vapor distribution and local evaporation flux across the liquid-air interface. A critical assessment of the role of natural convection at varying substrate temperatures was performed by contrasting diffusion-only cases with those incorporating both diffusion and convection. The findings reveal that the droplet pinning motion remains unchanged across different distances between droplets and various substrate temperatures, indicating that neither vapor accumulation nor substrate temperature significantly influences the behavior of the contact line. Notably, the study identifies a reduction in the evaporation rate of closely positioned paired droplets, related to a shielding effect. However, with increasing substrate temperature, the role of natural convection was found to become more pronounced, effectively reducing the overall evaporation time for both single and paired droplets, thus facilitating a quicker evaporation process.

Heat transfer analysis in open pan heat exchanger (OPHE) with different cross‐sections of conduits for jaggery processing

AbstractIndia leads the world in jaggery production, with the jaggery industry being a vital rural‐based sector. The jaggery plants in the country face challenges in effectively utilizing energy, resulting in varying efficiency levels ranging from 20% to 65% across different plants. To address this, a modified approach employing open pan heat exchangers (OPHEs) in jaggery plants is proposed to enhance overall performance. The effectiveness of the heat exchanger (HE) relies on factors such as heat transfer coefficient (HTC), surface contact area, and temperature differences between surfaces and the warm liquid. Circular conduits are predominantly favored in HE design, but this study delves into the impact of conduit shapes specifically circular, semi‐circular, and square on the achievement of the HE. The study reveals that semi‐circular conduits outperform circular conduits by 25%–28% in terms of HTC, while square conduits show a 21%–24% improvement. Moreover, comparing the efficiency of a conventional open pan jaggery plant with a circular conduit OPHE and a modified version featuring semi‐circular conduits OPHE, significant improvements are noted. A one hp pump is enough to overcome the issue related to pumping power due to a change in conduit shape. Heat transfer rate (HTR) is very poor for circular conduit due to line contact, whereas HTR for semi‐circular conduit is 38%–39% better than the square conduit. Efficiency increases from 24.36% for the conventional open pan to 62.5% for the circular conduit and further to 83.22% for the semi‐circular conduit. Processing time for jaggery making also varies significantly, with 165 min for the conventional open pan, which is reduced by 33.33% for the circular conduit OPHE and 45.45% for the semi‐circular conduit OPHE. As compared to circular conduit processing time of semicircular conduit OPHE is reduced by 18.18%.

The Paradoxical Behavior of Rough Colloids at Fluid Interfaces.

Colloidal particles adsorb and remain trapped at immiscible fluid interfaces due to strong interfacial adsorption energy with a contact angle defined by the chemistry of the particle and fluid phases. An undulated contact line may appear due to either particle surface roughness or shape anisotropy, which results in a quadrupolar interfacial deformation and strong long-range capillary interaction between neighboring particles. While each effect has been observed separately, here we report the paradoxical impact of surface roughness on spherical and anisotropic ellipsoidal polymer colloids. Using a seeded emulsion polymerization technique, we synthesize spherical and ellipsoidal particles with controlled roughness magnitudes and topography (convex/concave). Via in situ measurement of the interfacial deformation around colloids at an air-water interface, we find that while surface roughness strengthens the quadrupolar deformation in spheres as expected by theory, in stark contrast, it weakens the same in ellipsoids. As roughness increases, particles of both shapes become more hydrophilic, and their apparent contact angle decreases. Using numerical predictions, we show that this partially explains the decreased interfacial deformation and capillary interactions between the ellipsoids. Therefore, particle surface engineering has the potential to decrease the capillary deformation by asymmetric particles via changing their capillary pinning, as well as wetting behavior at fluid interfaces.

Distinction of Plasmonic Intrananoparticle and Internanoparticle Molecular Reaction Rates at the Three-Phase Contact Line of an Evaporating Sessile Droplet.

Molecular reactions on the surface of a plasmonic nanoparticle (intrananoparticle) and between nanoparticles (internanoparticle) may differ in kinetics, dynamics, and product selectivity. We report that the difficulty in distinguishing the kinetics in a dispersion medium could be overcome by probing the reactions at the three-phase contact line (TPCL) of an evaporating sessile droplet using surface-enhanced Raman spectroscopy (SERS). Thus, when an evaporating aqueous droplet on glass containing 4-aminothiophenol-stabilized Ag nanoparticles was monitored by SERS at the TPCL, dimerization into 4,4'-dimercaptoazobenzene followed two steps, each preceded by the loss of H-bonded water accordingly. On the basis of the results, we assigned the first step with a higher relative kinetic rate (∼3 times) to be an intrananoparticle reaction and the second one as an internanoparticle reaction. In D2O medium, the ratio of the rates was ∼1.8. The observed vibrational signatures of the losses of water molecules before reactions and product formations were accounted for by using density functional theoretical calculations.

A Review on Single Phase AC System of Railway Electrification

The widespread adoption of 25 kV, 50 Hz single-phase AC supply in long-distance electrified railway systems poses significant challenges to power quality in transmission networks. This paper presents an in-depth investigation into the influence of electric railway systems on a 110 kV transmission system, with a specific focus on locomotives equipped with diode rectifiers. Harmonic currents generated by these locomotives and unbalanced voltages introduced by single-phase traction loads are known to adversely affect power system components, leading to issues such as overheating, additional losses, and interference with communication systems. The focus of this paper is not only to understand the fundamental principles but to conduct a deep exploration of the functioning of various components such as locomotives, contact lines, and substations. High voltage This voltage is supplied from the substation or directly from the generating station. This high AC voltage (25KV) is first transformed into low AC voltage (415V). Three-phase induction motors are used because they provide high torque, are reliable, and are more efficient. The AC voltage in the second phase is rectified to DC and then converted into a phase AC using VFD. The VFD provides variable frequency and voltage to run the induction motor at different speeds.

Well-posedness of a bulk-surface convective Cahn–Hilliard system with dynamic boundary conditions

We consider a general class of bulk-surface convective Cahn–Hilliard systems with dynamic boundary conditions. In contrast to classical Neumann boundary conditions, the dynamic boundary conditions of Cahn–Hilliard type allow for dynamic changes of the contact angle between the diffuse interface and the boundary, a convection-induced motion of the contact line as well as absorption of material by the boundary. The coupling conditions for bulk and surface quantities involve parameters K,L∈[0,∞]\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$K,L\\in [0,\\infty ]$$\\end{document}, whose choice declares whether these conditions are of Dirichlet, Robin or Neumann type. We first prove the existence of a weak solution to our model in the case K,L∈(0,∞)\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$K,L\\in (0,\\infty )$$\\end{document} by means of a Faedo–Galerkin approach. For all other cases, the existence of a weak solution is then shown by means of the asymptotic limits, where K and L are sent to zero or to infinity, respectively. Eventually, we establish higher regularity for the phase-fields, and we prove the uniqueness of weak solutions given that the mobility functions are constant.