We considered branched shock-wave structures (triple configurations of shock waves) which forms in supersonic flows of perfect gas, mainly at high flow Mach numbers and low values of the adiabatic index. Ambiguity of the solution for triple configurations of steady shock waves formed at Mach reflection, including for configurations with a negative slope angle of the reflected shock, was studied analytically and numerically. The conditions for the coexistence of triple configurations which correspond to Mach reflection with other shock-wave structures are derived and graphically demonstrated.