Deposition Conditions Research Articles

In search of lost time: Recovering missing stratigraphical data from fossil marine reptile specimens using micropalaeontological analyses

Many museum and university collections contain fossil marine reptile specimens that have no provenance data associated with them, particularly those collected in the 19th and early 20th centuries. This may be because the information was never known to the museum or because the data have since been lost. Moreover, data that are associated with a specimen may have been assumed historically rather than verified and it is known that collectors, donors or sellers of specimens have sometimes been deliberately secretive or even misleading about the actual provenance of the fossils. If invertebrate macrofossils can be identified in the host matrix of the marine reptile specimen these can sometimes offer clues as to the stratigraphical origin of the specimen, but these instances are rare. Micropalaeontological analyses, however, can be undertaken on relatively small amounts of matrix associated with a specimen to attempt the recovery of lost data or confirm or reject assumed provenance details. Permission has been obtained to take small samples (as little as five grams) of host matrix from the rear of several ichthyosaur specimens during recent conservation projects where the provenance of the specimen was either totally unknown or was in doubt. These samples were analysed for their calcareous microfossil content, including ostracods and foraminifera. It was found that well-cemented limestones contained little or no recoverable material but softer mudstones have sometimes yielded very useful assemblages allowing specific biozones to be attributed to the host specimens, successfully recovering lost data and making the specimens much more useful scientifically. Even when the assemblage of microfauna is found to be poor or absent, some information about the sedimentary conditions of the preservational environment can often be ascertained from the micropalaeontological residues.

Defect formation and growth in metal nanocomposites consisting of Cu nanoparticles embedded in Ni or Al coatings

Fully inorganic or metallic nanocomposite coatings are promising materials for various applications but face limitations in term of their synthesis. A complementary synthesis process, Physical Vapor Deposition combined with magnetron sputtering and plasma-assisted gas-phase aggregation produced Cu nanoparticles embedded in metallic matrix. In this study, the effect of embedded nanoparticles on the matrix structure was investigated. Al and Ni were selected as matrix materials due to their different sputter yields leading to different growth modes film morphologies and difference in surface energy. Depending on the nanocomposite and deposition conditions, defects such as nodular growth were occasionally observed. These growth anomalies originated from the presence of nanoparticles creating new nucleation points for the matrix to grow disturbing the grain growth around it. Key factors responsible for their formation include the surface energy difference between the NPs and the matrix and the geometrical disruption occurring for large NP. In extreme cases with a high concentration of nanoparticles, coatings entirely constituted of nodular defects were produced which can be advantageous for applications needing large specific surface area.

Sedimentation conditions and conservation properties of clay deposits of the Lower Cretaceous of the Northwestern Caucasus

Sedimentation conditions and conservation properties of clay deposits of the Lower Cretaceous of the Northwestern Caucasus

Forward numerical modelling of pleistocene marine strata, North-West of Morocco

Numerical stratigraphic forward modelling is useful to understand and reconstruct the relative sea-level and sediment supply history responsible for particular strata. This analysis uses BARSIM, a simple 2D forward stratigraphic process-response model that simulates wave and storm processes, applied with an inverse modelling optimisation method to better understand the history of Pleistocene strata in the Achakkar basin of the Tangier region, Morocco. Observations of grain size and bed thickness in four outcrop vertical sections are matched with BARSIM model output to estimate the lowest-error best-fit relative sea level and sediment supply histories that may have controlled deposition of the observed strata assuming deposition over a 10 ky period, consistent with available dating from outcrop sections. The best-fit relative sea level history drops from 4.88 to −2.82 m with two lower-amplitude highstands in between, most likely representing interglacial eustatic and tectonic event. The best-fit sediment supply is variable through time and different for each vertical section, with greatest variation from 11.7 to 2.11 m2y-1 over the 10 ky interval in the north-east vertical section. The spatial and temporal variation of sediment supply in the four vertical sections represents typically dynamic depositional conditions in shallow marine nearshore areas. On the other hand, it can indicate high stratigraphic incompleteness caused by periods of non-deposition or erosion with temporal variations in sediment supply. The optimum way for the simple model to reproduce short intervals of high sedimentation rate separated by longer periods of hiatus and deposition followed by erosion results in a discontinuous stratigraphic record.

Investigation of rainfall‐runoff and sediment yield dynamics under varying slope land use patterns in the Three Gorges Reservoir Area of China

AbstractField experiments were conducted on various runoff plots within the Zhangjiachong watershed, located in the Three Gorges Reservoir Area, to study rainfall‐runoff processes and sediment yields under different slope land use patterns. A hillslope run‐on model considering vegetation interception was used to simulate runoff generation and concentration. A slope erosion model including raindrop erosion, sheet erosion, and rill erosion was developed to estimate sediment yield and concentration. The parameters of both models were calibrated and validated using observed runoff and sediment yield data. The results show that the runoff simulations in the validation have relative errors below 20% for all runoff plots, except those planted with crops. The saturated hydraulic conductivity of soil was found to be ca. 10% higher on slope lands with hedgerows than those without. In addition, it was about 15% higher on slope lands with crops than on slope lands with tea plants and citrus. The sediment yield was shown to be influenced by both precipitation characteristics and antecedent sediment conditions. There was a significant relationship between sheet erosion, rill erosion, and vegetation coverage, while the amount of raindrop erosion was similar across different runoff plots. The proportions of sheet and rill erosion on slope land with crops were minimal whether hedgerows existed or not. The proportions of the three main forms of soil erosion on slope lands with tea plants and citrus were more or less the same under concentrated rainfall. For more evenly distributed rainfall, raindrop erosion was the primary form on slope lands with hedgerows‐tea plants and citrus. The proportions of sheet and rill erosion significantly increased on slope lands without hedgerows.

Numerical assessment of thermal insulation and stress responses in film-cooled turbine vane thermal barrier coatings under CMAS deposition conditions

Deposition of CaO-MgO-Al2O3-SiO2 (CMAS) significantly contributes to the spalling of thermal barrier coatings (TBCs) on turbine vanes. A thorough understanding of the thermodynamic properties during CMAS deposition is critical for advancing the lifetime design of TBCs. This study employs the CMAS gas thermal shock test to determine the deposition characteristics, which were then analyzed using the critical velocity model. The results of this analysis align closely with experimental outcomes. Based on the numerical simulation of the fluid-solid coupling method, we further explored the insulation efficiency and stress distribution in TBCs under CMAS deposition conditions. It was observed that CMAS predominantly accumulates on the pressure side and within the film pores of the vane TBCs, with minimal deposition on the suction side. Such deposition patterns result in an increased overall temperature of the vane, concurrently diminishing the TBCs' insulation efficiency. Specifically, CMAS deposition raised the maximum surface temperature of the vane by 100 K and decreased the peak insulation performance of the TBCs by 16 %. Additionally, the deposition induced higher stresses within both the TBCs and the underlying vane substrate, with a 7 % increase in the maximum principal stresses at the TBC surface and a 6 % increase in the substrate. Consequently, under CMAS deposition conditions, TBCs in regions of low insulation efficiency and high stress on turbine vanes are prone to cracking and subsequent spallation.

Electrochemical Comparison Between HEA Films in Different Deposition Conditions

Electrochemical Comparison Between HEA Films in Different Deposition Conditions

Amine plasma polymers deposited on porous hydroxyapatite artificial bone with bipolar pulsed discharges

A recent in vivo study [Kodama et al., Sci. Rep. 11, 1 (2021)] showed that porous artificial bones coated with amine-containing polymers deposited by plasma-enhanced chemical vapor deposition (PECVD) significantly enhanced bone regeneration. This article reports the chemical and physical properties of amine plasma polymers (PPs) formed under the same deposition conditions, including the film stability for up to two months, the effects of sterilization on the chemical compositions of the films, and the penetration of amine PPs into the inner surfaces of interconnected microscopic pores of the amine PP-coated porous artificial bone. It was found that, immediately after the plasma polymerization process, approximately 20% of nitrogen atoms on the surface of the deposited amine PP formed primary amines. However, the value decreased to approximately 5% over one month if the sample was exposed to ambient air. The relative concentration of primary amines also decreased to a similar value after the sample was sterilized by autoclaving or ethylene oxide gas. Molecular dynamics simulations were used to examine possible formation mechanisms of nitriles in deposit films under the PECVD conditions and found that ion impact can significantly reduce the nitrile content.

Contourite-like deposits suggest stronger-than-present circulation in the Plio-Pleistocene Red Sea

Red Sea Deep Water is presently slow-moving, but was this true of the earlier Plio-Pleistocene (PP)? In seismic reflection records, the PP deposits are distorted by halokinetic deformation of their underlying Miocene evaporites. However, if reflections are flattened to a prominent reflector representing the top of the Miocene, they reveal mounded deposits within the earlier PP along both sides of the sea. Off Egypt, a plastered drift occurs along a salt wall. In the central Red Sea, they are mounded drifts. Seismic reflections from these deposits change shape gradually upwards to the modern seabed, which is commonly flatter, suggesting a gradual change in depositional conditions. To explain their origins, we appeal to other evidence. DSDP cores from the Late Pleistocene contain the rigid aragonite cements formed by restricted conditions, but not the lower and middle PP. Furthermore, mid-PP sedimentary δ18O values are similar to global ocean δ18O for that time, not enhanced as expected from excess evaporation. These data suggest that there was a greater exchange of Red Sea waters with the Indian Ocean during the mid-PP. That exchange may have allowed waters densified by evaporation in shallow regions of the northern Red Sea to flow south vigorously (the mounds would then be contourites). Alternatively, as the Pliocene seabed was shallower, wind-driven eddies may have affected more of the water column. Overall, the results indicate for the first time that deep circulation was stronger in the earlier PP compared with the present day. That circulation needs to be considered when evaluating organism dispersions across the Red Sea, regional climate, and influence of Red Sea Outflow Water on Indian Ocean Intermediate Water. Plain language summaryDuring the Pliocene (about 3–5 million years ago), temperatures on Earth's surface were similar to those predicted in some models of Earth's future climate. This has led to researchers becoming interested in studying geological evidence of conditions during the Pliocene as a clue to Earth's future. In detail, however, the comparison may not be exact. In our article, we describe mounds of sediment that were originally formed on the bed of the Red Sea in the Pliocene. They appear similar to snow drifts, and like snow drifts, may have formed under steady currents. Sea water becomes dense with evaporation (making it more saline). At the present day, dense water created in the Gulf of Suez cascades down into the deep Red Sea as a slow current. Perhaps such movements were more vigorous in the Pliocene, helped by the water escaping through a deeper barrier in the south into the Indian Ocean? Alternatively, these mounds were formed by giant eddies, such as those on the surface of the modern Red Sea, which are moved by strong winds. In either case, the deep waters of the Pliocene Pliocene Red Sea were more vigorously moving compared to the quiescent deep waters of the modern-day.

Residual stresses prediction in transition metal nitrides sputtered coatings using artificial neural network and experimental evaluation of surface morphology

In the production of transition metal nitride hard coatings under specific deposition conditions, the resulting residual stresses play a critical role in determining the mechanical properties, adhesion, and overall performance of the coatings. In this work, an artificial neural network (ANN) that utilizes feed-forward architecture is used to predict the average residual stress in titanium nitride (TiN) coatings with different coating thickness. These coatings are manufactured under varying bias voltages and temperature on substrate. The impact of variations in coating thickness, bias voltage, and temperature on development of internal residual stresses and changes in microstructure within sputtered coatings have been gathered from existing literature. The data collected is within the context of fibrous (zone I) and mix columnar and fibrous structure (combined zone) as defined by an existing structure zone model. The model is trained with experimental data from literature. The model is trained with experimental data from literature. The validation of the ANN model is carried out by comparing the predictions with experimental results. X-ray diffraction is used to analyze the residual stresses, preferred orientation, and the structure (zone I and combined zone) of produced coatings under different sputtering parameters. The regression and performance curves are used to assess the efficacy of ANN model. The coefficient of determination of trained model and mean square error are 0.9918 and 0.35, respectively. The predicted results show good agreement with experimental and subsequently AFM grain morphology analysis captures the growth mechanisms involved in the residual stresses evolution.

Influence of environmental settings, including vegetation, on speciation of the redox-sensitive elements in the sediments of monomictic Lake Kinneret

AbstractThe redox conditions in the littoral limnic sediments may be affected by the penetration of plant roots which provide channels for oxygen transport into the sediment while decomposition of the dead roots results in consumption of oxygen. The goal of this work was to study the impact of environmental parameters including penetration of roots of Cyperus articulatus L. into the sediments on cycling of the redox-sensitive elements in Lake Kinneret. We measured roots content, porosity, and chemical parameters including pH, sulfur, iron and manganese speciation in the sediments from the shore, littoral and sublittoral zones with and without vegetation. Our results show that at ≥ 12 m water depth, the upper 10 cm of the sediments are affected by the active sulfur cycling with concentrations of hydrogen sulfide > 70 μM near the sediment–water interface. Speciation of sulfur, iron, and manganese in the upper 10 cm of littoral sediments, which are covered by < 20 cm of water, are affected by their permeability and, to a lesser extent, by roots penetration. In the case when sediments are not covered by water, oxygen penetration to the sediments by desiccation is an additional important control of the redox zonation in the surface sediments. In the shore sediments, despite relatively high concentrations of sulfate in the pore-waters, sulfur cycling may be described as “cryptic” as expressed by very low concentrations of hydrogen sulfide in the pore-waters. This is most likely a result of its fast reoxidation by the abundant highly reactive Fe(III) and Mn(IV) phases.

The resting cyst of dinoflagellate Scrippsiella acuminata host bacterial microbiomes with more diverse trophic strategies under conditions typically observed in marine sediments.

Variation in the condition of marine sediments provides selective preservation milieus, which act as a key determinant for the abundance and distribution of dinoflagellate resting cysts in natural sediments. Microbial degradation is an understudied biological factor of potential importance in the processes. However, gaps remain in our knowledge about the fundamental information of the bacterial consortia associated with dinoflagellate resting cysts both in laboratory cultures and in the field. Here we used Scrippsiella acuminata as a representative of cyst-producing dinoflagellates to delineate the diversity and composition of bacterial microbiomes co-existing with the laboratory-cultured resting cysts, and to explore possible impacts of low temperature, darkness, and anoxia (the mock conditions commonly observed in marine sediments) on the associated bacterial consortia. Bacterial microbiome with high diversity were revealed associated with S. acuminata at resting stage. The mock conditions could significantly shift bacterial community structure and exert notably inhibitory effects on growth-promoting bacteria. Resting cysts under conditions typically observed in marine sediments fostered bacterial microbiomes with more diverse trophic strategies, characteristic of prominently enriched anaerobic chemotrophic bacteria generating energy via respiration with several different terminal electron acceptors, which yielded more acidic milieu unfavorable for the preservation of calcareous resting cysts. Our findings suggest that there is complex and dynamic interaction between dinoflagellates resting cysts and the associated bacterial consortia in natural sediments. This intrinsic interaction may influence the maintenance and/or accumulation of dinoflagellate resting cysts with potential of germination and initiation blooms in the field.

Synthesis of low-k SiONC thin films by plasma-assisted molecular layer deposition with tetraisocyanatesilane and phloroglucinol

Low-k SiONC thin films with excellent thermal stabilities were deposited using plasma-assisted molecular layer deposition (PA-MLD) with a tetraisocyanatesilane (Si(NCO)4) precursor, N2 plasma, and phloroglucinol (C6H3(OH)3). By adjusting the order of the N2 plasma exposure steps within the PA-MLD process, we successfully developed a deposition technique that allows accurate control of thickness at the Ångström level via self-limiting reactions. The thicknesses of the thin films were measured through spectroscopic ellipsometry (SE). By tuning the N2 plasma power, we facilitated the formation of –NH2 sites for phloroglucinol adsorption, achieving a growth per cycle of 0.18 Å cycle−1 with 300 W of N2 plasma power. Consequently, the thickness of the films increased linearly with each additional cycle. Moreover, the organic linkers within the film formed stable bonds through surface reactions, resulting in a negligible decrease in thickness of approximately −11% even upon exposure to a high annealing temperature of 600 °C. This observation was confirmed by SE, distinguishing the as-prepared film from previously reported low-k films that fail to maintain their thickness under similar conditions. X-ray photoelectron spectroscopy (XPS) and current–voltage (I–V) and capacitance–voltage (C–V) measurement were conducted to evaluate the composition, insulating properties, and dielectric constant according to the deposition and annealing conditions. XPS results revealed that as the plasma power increased from 200 to 300 W, the C/Si ratio increased from 0.37 to 0.67, decreasing the dielectric constant from 3.46 to 3.12. Furthermore, there was no significant difference in the composition before and after annealing, and the hysteresis decreased from 0.58 to 0.19 V owing to defect healing, while maintaining the leakage current density, breakdown field, and dielectric constant. The low dielectric constant, accurate thickness control, and excellent thermal stability of this MLD SiONC thin film enable its application as an interlayer dielectric in back-end-of-line process.

Air-Stable Wafer-Scale Ferromagnetic Metallo-Carbon Nitride Monolayer.

The pursuit of robust, long-range magnetic ordering in two-dimensional (2D) materials holds immense promise for driving technological advances. However, achieving this goal remains a grand challenge due to enhanced quantum and thermal fluctuations as well as chemical instability in the 2D limit. While magnetic ordering has been realized in atomically thin flakes of transition metal chalcogenides and metal halides, these materials often suffer from air instability. In contrast, 2D carbon-based materials are stable enough, yet the challenge lies in creating a high density of local magnetic moments and controlling their long-range magnetic ordering. Here, we report a novel wafer-scale synthesis of an air-stable metallo-carbon nitride monolayer (MCN, denoted as MN4/CNx), featuring ultradense single magnetic atoms and exhibiting robust room-temperature ferromagnetism. Under low-pressure chemical vapor deposition conditions, thermal dehydrogenation and polymerization of metal phthalocyanine (MPc) on copper foil at elevated temperature generate a substantial number of nitrogen coordination sites for anchoring magnetic single atoms in monolayer MN4/CNx (where M = Fe, Co, and Ni). The incorporation of densely populating MN4 sites into monolayer MCN networks leads to robust ferromagnetism up to room temperature, enabling the observation of anomalous Hall effects with excellent chemical stability. Detailed electronic structure calculations indicate that the presence of high-density metal sites results in the emergence of spin-split d-bands near the Fermi level, causing a favorable long-range ferromagnetic exchange coupling through direct exchange interactions. Our work demonstrates a novel synthesis approach for wafer-scale MCN monolayers with robust room-temperature ferromagnetism and may shed light on practical electronic and spintronic applications.

Influence of H2 on the properties of NiOxHy thin films deposited by reactive direct current magnetron sputtering for electrochromic devices

This study aims to optimize the deposition condition of Nickel hydroxide (NiOxHy) films for electrochromic devices by adjusting the H2 gas concentration during the reactive direct current magnetron sputtering. The influence of H2 content on the crystallinity, chemical composition, optical properties, and electrochromic behavior of the NiOxHy films was thoroughly investigated. In the absence of H2 gas in the sputtering system, the Nickel oxide (NiOx) film was obtained as confirmed by the X-ray diffraction results. However, introducing the H2 gas resulted in the formation of NiOxHy film, accompanied by a decrease in the film crystallinity. Fourier transform Infrared spectra were employed to confirm the presence of hydroxyl groups in the as-deposited NiOxHy films. X-ray photoelectron spectroscopy was employed to examine the influence of H2 content on the optical properties of the NiOxHy film. Additionally, it offered valuable insights into the film's chemical composition during the transition from a dark to a transparent state. Our findings revealed that increasing the H2 gas content enhanced the transmittance of NiOxHy films. Here, the optimal H2 flow ratio of 50 % was found to yield a high transmittance of 77.43 % (T550) along with the highest charge density, an optical density changed value of 0.84, and a coloration efficiency value of 83.67 cm2/C. These findings clearly illustrate the substantial influence of H2 concentration on the properties of NiOxHy films, particularly in relation to their application in electrochromic devices.

Changes in the meander belt and channel pattern in the middle-low segment of the Cuarto river. Córdoba. Argentina

The Cuarto River is an important watercourse in the Córdoba Province, Argentina. Its middle-low segment crosses the eastern plains of this province, one of the most populated and (agricultural-livestock) productive regions of the country. In this segment, the channel and fluvial belt morphometric parameters exhibit notable changes downstream. Understanding the morphodynamics of the Cuarto River allows the characterization and definition of channel reach with tendencies towards migration, aggradation and overflow. In this way, it is possible to identify critical channel reaches, a fundamental aspect for effective planning. This work aims to characterize the downstream changes in the fluvial belt, meanders geometry, channel pattern and channel slope, along the middle-low segment of the Cuarto River and link these modifications with authigenic (sediment supply and transport regime) and allogenic controls. Five channel reaches (R1-R5) were selected according to geological-geomorphological criteria and different geometric parameters (channel width, channel slope, braided index, meander geometry, confinement degree) were determined for each of them. Empirical equations were used to establish relationships between these geometric parameters. Although most parameters showed a generally downward trend towards downstream reaches, marked changes were observed. Particularly, in the R1-R2 reaches, the fluvial belt widens and is unconfined, and the channel width and braided index also increases. The relationship between meander length/channel width (Lm/w) and radius of curvature/channel width (rc/w) obtained were within the ranges for free meanders (8–14) and high mobility (2–3), respectively. These parameter values are associated with alluvial channels and suggest limitations in transport and conditions for sedimentation. However, in R3, R4 and R5, the fluvial belt narrows and becomes confined, with high sinuosity, a reduction in the width of the channel and the braiding index. This pattern is expected for reaches characterized by predominance of transport and a tendency to a mixed or suspensive load. Moreover, both groups of reaches also exhibit an abrupt contrast in bedload size (from very coarse sand/gravel in R1 and R2 to fine/very fine sand in R3, R4, and R5). The similarity between the exponents of the predictive functions (Lm/w, rc/w, and Lm/rc) and those obtained for the Cuarto River, in addition to the satisfactory regression coefficients of the measured parameters suggest an acceptable balance between meander geometry and channel width regime of sediment transport. The middle-low reach of the Cuarto River shows notable changes, which can be linked to regional-scale allogenic factors such as morphostructures and lithology (R1-R2 with elevated morphostructure, R3-R4 are transitional reaches towards depressed plains, while R5 with subsidence environments). Nonetheless, the river demonstrates the capacity to regulate these factors at the reach level through authigenic processes. Thus the variability of channel width, channel slope, braiding index, meander geometry and degree of confinement are explained mainly by downstream changes in sediment supply and transport regime (authigenic controls) and secondarily by changes in regional slope and banks lithology (allogeneic controls).

Impact of H-Related Chemical Bonds on Physical Properties of SiNx:H Films Deposited via Plasma-Enhanced Chemical Vapor Deposition

SiNx:H film deposition via plasma-enhanced chemical vapor deposition has been widely used in semiconductor devices. However, the relationship between the chemical bonds and the physical and chemical properties has rarely been studied for films deposited using tools in terms of the actual volume production. In this study, we investigated the effects of the deposition conditions on the H-related chemical bonding, physical and chemical properties, yield, and quality of SiNx:H films used as passivation layers at the 28 nm technology node. The radiofrequency (RF) power, electrode plate spacing, temperature, chamber pressure, and SiH4:NH3 gas flow ratio were selected as the deposition parameters. The results show a clear relationship between the H-related chemical bonds and the examined film properties. The difference in the refractive index (RI) and breakdown field (EB) of the SiNx:H films is mainly attributed to the change in the Si–H:N–H ratio. As the Si–H:N–H ratio increased, the RI and EB showed linear growth and exponential downward trends, respectively. In addition, compared with the Si–H:N–H ratio, the total Si–H and N–H contents had a greater impact on the wet etching rates of the SiNx:H films, but the stress was not entirely dependent on the total Si–H and N–H contents. Notably, excessive electrode plate spacing can lead to a significant undesired increase in the non-uniformity and surface roughness of SiNx:H films. This study provides industry-level processing guidance for the development of advanced silicon nitride film deposition technology.

Reduced seagrass resilience due to environmental and anthropogenic effects may lead to future die-off events in Florida Bay

Coastal systems often depend on foundation species such as seagrasses that are supported by self-facilitation. Seagrass meadows, however, are threatened worldwide due to climate change and local human impact, disrupting self-facilitation leading to system instability. Florida Bay is a large seagrass dominated coastal ecosystem that suffered from multiple seagrass mortality events over the last half century driven by hypoxia, high water temperatures, hypersalinity, and high biological oxygen demand. These conditions reduce the amount of photosynthetically-derived oxygen in the plant causing sulphide intrusion into meristematic tissues. Using a bay-wide sampling design and long-term monitoring trends of seagrass condition, we investigated the current state of the meadows, sediment characteristics (e.g., organic matter, sulphide, nutrients) and discuss how climate stressors interact with plant and sediment oxygen dynamics. Our survey revealed that at sites where seagrass had been previously denuded by die-off, the dominant seagrass Thalassia testudinum had not recovered, while the pioneering seagrass Halodule wrightii recolonized the impacted areas. Organic matter and sulphide levels were higher at the impacted sites, apparently a persistent characteristic of the formerly dense T. testudinum meadows in central and western Florida Bay. These sediment conditions promote sulphide intrusion of T. testudinum belowground tissue under anoxic conditions. Plant oxidation initially buffers sulphide intrusion, but disruption of this oxidation mechanism due to changing environmental conditions results in widespread mortality and seagrass community collapse. Climate change cannot be fully mitigated by local management, however, attempts can be made to control critical salinity and oxygen levels by increasing freshwater input, reducing hypersalinity and aiming to keep the internal seagrass oxidation feedback intact. Our study shows that the Florida Bay seagrass ecosystem is still recovering four years post die-off and continues to be susceptible to future climate change and system degradation.

Soil‐vegetation interplay in a Holocene toposequence at Torres del Paine National Park, southern Andes, Chile

AbstractChile's Torres del Paine National Park (TPNP) is one of the most impressive landscapes in southern Patagonia, with unique natural elements on the edge of the southern ice field, where knowledge of soils and ecological relationships is nonexistent. Therefore, the objective of this study was to determine the chemical, physical, mineralogical, and micromorphological characteristics of Holocene soils along a local toposequence representing the main vegetation types of the TPNP. The morphological, chemical, physical, and mineralogical properties of 12 soil profiles were studied and classified according to Soil Taxonomy. Coevolution of vegetation and soil taxa is clearly evident since glaciation, with podsolization under austral Nothofagus pumilio forests leading to the development of spodosols, while paludization in local depressions with Nothofagus forests allowed the formation of histosols. Slopes covered with loess and tephra led to the formation of Andisols with shrub vegetation. Predominant parent materials include till from Late Quaternary advances of southern Andean ice, Pleistocene loess, and volcanic ash from surrounding Chilean volcanoes. The parent materials were strongly influenced by Late Quaternary climatic and landscape changes following the retreat of the Last Glacial Maximum in southern Patagonia, resulting in erosional and depositional conditions (windblown loess, fluvial glacial deposits, and moraines). Stable landforms show the influence of allochthonous volcanic ash shaping Andean features, combined with the accumulation of organic matter in hydromorphic soils. Three main groups of soils have been identified: loess‐rich soils, organic‐rich soils, and poorly developed soils. The latter show low fertility related to recent landforms on different substrates ranging from till, rocky slopes, talus, or glacial deposits. In high mountain regions under periglacial conditions, cryoturbation features indicate seasonal frost–thaw cycles without current permafrost. The diversity of soil orders in the mountains of southern Patagonia is comparable to similar environmental conditions and latitudes in the Northern Hemisphere. However, the andic properties due to volcanic ejecta inputs, as well as organic‐rich soils at low altitudes of bottom valleys, are typical features of the soils at TNTP.

Integrating rapid habitat mapping with community metrics and functional traits to assess estuarine ecological conditions: A New Zealand case study

Estuarine ecosystems are under pressure from anthropogenic stressors in many parts of the world. In a New Zealand estuary, we integrated rapid habitat mapping, univariate and multivariate benthic community metrics and functional traits-based metrics to provide a holistic assessment of its ecological condition. Our integrative approach identified 11 different habitat classes across the study estuary and revealed how univariate, multivariate, and functional traits-based metrics varied spatially. Variation was driven mainly by sedimentary conditions, particularly, the sediment's organic matter and silt-clay content. Degraded conditions were apparent in several parts of the estuary, which overlapped with areas showing high concentrations of decaying algae, anoxic conditions, and low values of univariate and functional metrics. Our holistic approach, integrating mapping and quantitative community assessments, provided a more complete picture of estuarine conditions and enabled us to identify locations across the estuary with the greatest potential for restoration success.