Peak Metamorphic Conditions Research Articles

Origin and metamorphism of ophiolitic serpentinites from the Yuli belt, eastern Taiwan: new findings and tectonic implications

ABSTRACT Serpentinites associated with metamafic and metaplagiogranitic rocks occur sporadically within metasedimentary schists in the Yuli belt. Such metaigneous rocks are considered to represent ophiolitic protoliths and some contain high-pressure (HP) metamorphic minerals or assemblages. However, the origin and metamorphism of these serpentinites have long been a mystery. This study systematically investigates the four major serpentinite-bearing exposures at the Fengtien, Wanjung, Tsunkuanshan, and Chinshuichi. The results reveal that the serpentinites are of two different protoliths on the basis of relict chromian spinel composition. Cr-spinel compositions of the Fengtien and Tsunkuanshan samples are characterised by moderate Cr# [Cr/(Cr + Al)] (0.45–0.57), relatively high Mg# [Mg/(Mg+Fe2+)] (0.59–0.79), but low Fe3+# [Fe3+/(Fe3++Cr+Al)] (0.02–0.06), reflecting an abyssal peridotite type protolith. By contrast, Cr-spinel compositions of the Wanjung and Chinshuichi samples show high Cr# (up to 0.74) and Fe3+# (0.03–0.08), but low Mg# (<0.6), indicating a forearc mantle peridotite origin. Peak metamorphic conditions of the serpentinites are represented by the assemblage of antigorite + magnetite + chlorite + olivine + diopside, which is estimated as up to 550°C but the pressure cannot be constrained quantitatively. Based on field relations, it is inferred that the serpentinites, associated HP metaigneous rocks, and garnet-bearing metasedimentary schists were metamorphosed isofacially. Despite two origins, the peridotitic protoliths were all subjected to hydration and subduction processes. We suggest that precursors of the serpentinites, metaigneous rocks, and metasedimentary schists were juxtaposed and metamorphosed at intermediate to great depths (~35–55 km) of a subduction zone. Therefore, the Yuli belt serpentinites and associated rocks likely represent exhumed materials from a palaeo-subduction interface.

Polymetamorphism and metastability in Paleozoic schists of the central Appalachian Baltimore Terrane, USA

Metapelitic assemblages are often considered highly reactive during prograde metamorphism, such that they effectively record a history of tectono-metamorphic processes. Across eastern North America, metamorphosed rift-to-drift stratigraphy has been central to disentangling the terminal history of Appalachian convergence. We report results from a single metapelitic outcrop in the Loch Raven Schist of Maryland's Baltimore Terrane, where regional metamorphism is historically interpreted to have derived only from the Ordovician Taconic orogeny. An aluminum-rich litho-horizon alludes to two phases of metamorphism: an early, low/medium-pressure (P) sillimanite-stabilizing phase largely overprinted by a subsequent medium/high-P kyanite-stabilizing event, terminating at c. 391–383 Ma. This provides evidence of substantial crustal disturbances in the central Appalachians during Avalonian collision of comparable timing to equivalent events in the north. In a subordinate and aluminum-poor litho-horizon, large (2–3.5 cm) garnet provides geochronological evidence only for a protracted phase of metamorphism at 440–424 Ma. We interpret this age as recording the early, low/medium-P phase of metamorphism that either: (a) extends the duration of the Taconic event; or (b) provides new evidence for metamorphism associated with Silurian tectonism and/or extension in the Central Appalachians. However, this assemblage appears to have been metamorphically unresponsive during Devonian overprinting, despite peak metamorphic conditions of ∼670 °C and ∼8 kbar. We suggest that a potential combination of the paucity of fluid, limited strain accumulation, and coarse refractive assemblages stabilized a kinetically sluggish and metastable composition.

Metamorphic history of amphibolite facies metapelites from the Southern margin of the Limpopo Belt: In situ U-Pb dating of Zircon, monazite and rutile

The Southern Marginal Zone (SMZ) comprises, in part, Archean granulite facies metapelitic rocks deposited at ∼ 2733 Ma and metamorphosed to granulite facies at ∼ 2713 Ma of the Limpopo Belt in direct contact with the Kaapvaal craton. The SMZ also contains amphibolite facies metapelites within a fragment that is in direct contact with the thrust-faulted tectonic boundary with the Kaapvaal craton. These metapelites are proposed to represent former granulites that were comprehensively rehydrated under amphibolite facies. However, no previous study has directly investigated the conditions of metamorphism or timing of the proposed higher-grade events in these retrograde rocks. Neither has the timing of retrogression in the retrogressed metapelites been well constrained. Here, detailed petrographic analysis, mineral composition and in situ U-Pb dating of zircon, monazite and rutile are presented for the amphibolite facies metapelites. These rocks are characterized by assemblages consisting of garnet, orthoamphibole, biotite, quartz, plagioclase, rutile, kyanite and graphite. Although there is pervasive retrogression to orthoamphiboles (anthophyllite to gedrite series), rare relics of orthopyroxene are preserved. The compositions of the first garnet (Grt 1) generation suggests granulite facies peak metamorphic conditions of 860 ± 10 °C and 11 ± 0.4 kbar. Metamorphic zircon grains and overgrowth rims and monazite, included in Grt 1, indicate that peak metamorphic conditions occurred between 2714 ± 7 and 2713 ± 4 Ma. Dating of rutile inclusions in Grt 1 from granulite yield a Concordia age of 2677 ± 6 Ma. This indicates post-granulite facies cooling and shows that later retrograde metamorphism did not reach temperatures high enough to reset rutile inclusions in Grt 1 garnet. Orthoamphibole and second garnet with kyanite inclusions (Grt 2) compositions suggest that retrogression occurred under amphibolite facies conditions of 600 ± 10 °C and 6.0 ± 0.5 kbar. Rutile included in Grt 2 and as discrete grains equilibrated with the retrograde textures record a range of Paleoproterozoic ages (2212 ± 19, 2148 ± 12 and 2012 ± 10 Ma). Thus, the metamorphic history of the amphibolite facies metapelites of the SMZ is hotter than thought and similar to their Archean granulite facies counterparts, except for younger Paleoproterozoic ages, likely indicating a pervasive retrogression to amphibolite facies conditions.

Extension during the Liebig Orogeny: Revised tectonic setting of Paleoproterozoic central Australia

Magnetotelluric imaging of a lithospheric-scale boundary in central Australia has been used to support a model of collision between the North Australian Craton and an exotic continental ribbon referred to as the Warumpi Province during the late Paleoproterozoic Liebig Orogeny (c. 1640 Ma). This idea of collision has become an important element to reconstructions of late Paleoproterozoic Australia. In this study, we present mineral equilibria forward models from c. 1640 Ma metamorphic rocks to delineate the thermal regime associated with the Liebig Orogeny. Liebig-aged cordierite–orthopyroxene–biotite–quartz–plagioclase–K-feldspar–ilmenite–magnetite assemblages constrain peak metamorphic conditions to 4–5 kbar and 770–800 °C. These conditions are indicative of a high geothermal gradient regime and the mineral assemblage evolution shows no evidence for significant pressure changes that would generally support a crustal thickening model. Detrital zircon age spectra for the metasediments in the assumed exotic crust are broadly similar to the age record in the Aileron Province in the southern part of the North Australian Craton. Furthermore, εNd and εHf isotopic data of Liebig-aged granitic rocks make it permissible that they are derived from melting of North Australian Craton crust. This suggests the Warumpi Province was not exotic to the North Australian Craton and was instead a part of it. On the basis of the shared history between the Warumpi and Aileron Provinces and the newly constrained thermal character of c. 1640 Ma metamorphism, we suggest the Liebig Orogeny was characterised by extensional deformation of the North Australian Craton in the upper plate above a southward retreating subduction system. Tectonically, the Liebig Orogeny is interpreted to record a back-arc regime characterised by sedimentation, mafic and felsic magmatism, and predominantly contact metamorphism, and represents the continuation of a long-lived (c. 200 Ma) upper plate system that dictated the evolution of the North Australian Craton during the late Paleoproterozoic.

Deformation and pressure-temperature-time history of the External Tuscan Units in the Northern Apennines (Italy): The case of the Punta Bianca Unit

In this study we investigated through a multidisciplinary approach the still poorly known tectono-metamorphic evolution of the Punta Bianca Unit in the Northern Apennines. The Punta Bianca Unit is part of the Tuscan Metamorphic Units, a group of units derived from the Adria passive margin, metamorphosed at different conditions, and forming the backbone of the Northern Apennine belt. We combined meso- and microstructural analyses, 40Ar/39Ar white-mica geochronology and multi-equilibrium geothermobarometry from high-resolution X-ray chemical maps, to unravel the deformation and metamorphic history of this part of the belt. Meso- and microstructural data indicate that the Punta Bianca Unit recorded two main phases of ductile deformation (here referred to Dp-1 and Dp) associated with syn-kinematic growth of K-white mica, chlorite, calcite, quartz on the related tectonic foliations (Sp-1 and Sp), followed by a later ductile deformation phase (Dp+1) lacking of metamorphic blastesis. P-T estimates complemented by microstructural data suggest that peak metamorphic conditions reached ∼0.8 GPa and ∼350°C and occurred synchronously with the first deformation phase (Dp-1). Temperature values were also confirmed by Raman spectroscopy of carbonaceous material on selected samples. This stage was followed by the exhumation of the Punta Bianca Unit, as testified by decreasing pressure and temperature down to ∼0.4 GPa and ∼300°C respectively, together with the development of the main foliation (Sp). At the regional scale, the Tuscan Metamorphic Units have been mostly affected by HP-LT metamorphic gradients equilibrated under blueschist-facies conditions (up to ∼1.4 GPa). Results from the present work on the contrary, suggest that the Punta Bianca Unit never reached such HP-LT conditions, testifying that it was deformed at relatively upper structural levels, thus highlighting an important variation in the tectono-metamorphic evolution of the Tuscan Metamorphic Units along strike in the Northern Apennines. 40Ar/39Ar laserprobe data (using both the in-situ and step-heating techniques) indicate a minimum age for the onset of continental subduction of ∼20 Ma (Dp-1), which was followed in close succession by exhumation at ∼16 Ma. This approach, if applied to different tectonic units building up the nappe pile of the Northern Apennines, could be successful in better unravelling the tectonic history.

Xenolith Petrochronology (San Luis Potosi, Mexico) Constrains Heat Sources for Cenozoic Ultrahigh‐Temperature Metamorphism in the Lower Crust

AbstractUltrahigh‐temperature (UHT; &gt;900°C) metamorphism drives crustal differentiation and is widely recognized in the rock record, but its geodynamic causes are debated. Previous work on granulite‐facies metapelite xenoliths from San Luis Potosí, Mexico suggests the lower crust experienced a protracted UHT metamorphic event that coincided with the onset of regional extension. To determine the duration, conditions, and heat sources of UHT metamorphism recorded by these xenoliths, this study characterizes the major‐element, trace‐element, and U‐Pb isotopic systematics of quartz, rutile, feldspar, garnet, and zircon by in situ electron microprobe (EPMA) and laser‐ablation inductively coupled‐plasma mass spectrometry (LA‐ICP‐MS), and augments these data with detailed petrography, thermobarometry, phase equilibria modeling, and diffusion modeling. Thermobarometry and phase equilibria modeling suggest peak metamorphic conditions exceeded 0.7 GPa and 900°C. Zircon petrochronology confirms &gt;15 Myr of UHT conditions since its onset at ∼30 Ma. A small population of zircon record elevated temperatures following transition from backarc compression to extension during the waning stages of orogenesis (60–37 Ma). Garnet preserves trace‐element zoning and mineral inclusions consistent with suprasolidus garnet growth and subsequent compositional modification by intracrystalline rare‐earth element diffusion during protracted heating, with diffusion chronometry timescales in agreement with zircon data, followed by fluid‐driven remobilization of trace elements along now‐healed fractures within ∼1 Myr of eruption. In sum, these data are most compatible with lithospheric mantle attenuation or removal as the dominant heat transport mechanism driving synextensional UHT metamorphism and crustal melting, which has bearing on models for crustal differentiation and formation of modern and ancient granulite terranes globally.

Timing of multiple fluid pulses recorded by garnet and accessory minerals in metarodingites

Metarodingites are commonly garnet-bearing metasomatized mafic dykes within serpentinized mantle rocks. Garnet in metarodingites has the potential to preserve compositional and chronological information about the entire metamorphic-metasomatic evolution, from ocean floor formation to deep subduction. In this study, we investigate the chemical and chronological record of garnet, titanite, and zircon from metarodingites and garnet veins in chloritized blackwall, from the Zermatt-Saas zone in the Western European Alps. Garnet in the chlorite-rich metasomatic rind (blackwall) displays re-crystallization and new growth textures and therefore represents a second generation of garnet (Grt2), after the one in the metarodingite core (Grt1). Major and trace element mapping shows that Grt2 is richer in andradite and Ti-andradite components compared to the more grossular-rich Grt1 in the metarodingite. Moreover, we found that in both Grt1 and Grt2, Ti and U content are positively correlated, with U abundances up to 1.5 μg⋅g−1. Grt2 does not show rare earth element (REE) zonation, suggesting that REE transport was facilitaed by the presence of a fluid phase. We propose that the metasomatizing fluids from which Grt2 precipitated, were serpentinite-derived high-temperature brines capable of transporting Fe3+, Ti and REE.LA-ICPMS U–Pb dating of metarodingite garnet Grt1 samples yielded overlapping ages between 43.6 ± 0.9 and 44.1 ± 1.3 Ma, which are consistent with previous estimates of peak metamorphic conditions. Our data indicate that the metarodingite Grt1 grew within <2 Myr, suggesting a rapid burial rate of the unit or fast and pulsed garnet growth aided by the presence of fluids in the intergranular medium. Titanite from the blackwall sample yields an age of 45.0 ± 1.7 Ma and zircon rim an age of 48.0 ± 1.1 Ma, indicating that fluid release and chloritization occurred at peak conditions. U–Pb ages of garnet in the blackwall samples (Grt2) are significantly younger, yielding ages of 40.1 ± 0.9 Ma and 38.4 ± 0.8 Ma, respectively. The presence of multiple generations of metasomatic garnet in the blackwall suggests that periods of increased rock permeability occurred repeatedly, plausibily aided by deformation, as supported by the consistency of our multi-mineral geochronology. We show how garnet from metarodingites and blackwalls records the metamorphic-metasomatic history and can be used to obtain information on (de)hydration reactions and fluid flow during subduction.

2.13 Ga Lawsonite/Barroisite-Bearing E-Morb Signature Metagabbro Associated with Spinel Metaperidotite from Itaguara (São Francisco Craton, Brazil): Oldest Blueschist-Facies Fragment of Oceanic Moho?

In close association with Paleoproterozoic retroeclogite and accretionary prism-related mica-quartz schist, a 2.13 Ga (metamorphic titanite U-Pb age) lawsonite/barroisite-bearing E-MORB signature metagabbro associated with spinel metaperidotite is found in the Itaguara Sequence from southern São Francisco craton, Brazil. Petrography and pressure-temperature equilibrium phase diagrams suggest that the metagabbro experienced blueschist-facies metamorphism, attaining peak metamorphic conditions at ~16 kbar and ~450 °C during subduction. The retrograde metamorphic path crossed epidote amphibolite-facies, in which the mineral assemblage found in metaperidotite (olivine, clinopyroxene, spinel, serpentine, chlorite, talc, and tremolite) was stable during a ca. 2.1 Ga continental collision-related exhumation that occurred between the Archean Campo Belo/Bonfim and Divinópolis complexes. This geological framework suggests that the metagabbro and adjacent spinel metaperidotite represent a subducted and exhumed blueschist-facies fragment of a Paleoproterozoic oceanic Mohorovičić (Moho) discontinuity, thus establishing the Itaguara metagabbro as the oldest-known occurrence of retrogressed blueschist and providing evidence for the activity of the modern-style plate tectonics more than 2 Gyr ago.

New metamorphic constraints on the Nova-Bollinger Ni–Cu deposit, Fraser Zone, Western Australia

Metamorphic investigations were conducted using mineral chemistry, phase equilibria modelling and conventional thermobarometry on four metamorphic country rock samples from the Nova-Bollinger Ni–Cu deposit, Western Australia. New P–T constraints obtained from phase equilibria modelling of garnet-bearing granulites and cordierite–sillimanite-bearing metasedimentary rocks indicate that the Nova-Bollinger deposit formed at mid-crustal depths (0.75–0.76 GPa and 880–920 °C), along high thermal gradients around 1200 °C/GPa. Peak metamorphic conditions are consistent with those obtained from the Nova-Bollinger intrusive rocks, and with metagabbros from the southern Fraser Zone, but are slightly elevated relative to metapelites examined in the southern Fraser Zone. The peak metamorphic conditions at Nova-Bollinger reflect the combined effects of regional-scale high-T conditions during orogenesis superimposed by contact metamorphism in a thermal aureole adjacent to the Nova-Bollinger mafic–ultramafic magmas. Thermal metamorphism may have been further enhanced by local heat transfer from intruding sulfide liquid, which pervasively infiltrated country rocks on scales of tens to hundreds of metres beneath the orebodies. This additional heat source may be locally significant, despite being volumetrically limited. Retrograde P–T conditions were determined by garnet–biotite conventional thermobarometry of garnet-core–matrix biotite pairs (0.29–0.45 GPa and 550–640 °C). These P–T conditions suggest that the Nova-Bollinger country rocks cooled along a near-isobaric cooling path and reflect the effects of thermal decay following emplacement of voluminous magmas into the Fraser Zone during Stage I Albany–Fraser Orogeny.

Two episodes of Early Palaeozoic high-pressure metamorphism in North Balkhash ophiolite zone (Central Kazakhstan, western Central Asian Orogenic Belt): Evidence for tectonic evolution of Junggar–Balkhash Ocean

The structure of serpentinite mélange of the North Balkhash ophiolite zone (Central Kazakhstan; west Central Asian Orogenic Belt) is ascertained to be high-grade formations assigned to epidote-glaucophane eclogites and garnet blueschists, and their varieties. The rocks follow a clockwise ‘subduction-type’ evolution with the estimated near–peak metamorphic conditions of 1.6–1.9 GPa and 500–560 °C. 40Ar39Ar phengite ages of ∼491 Ma and ∼ 465 Ma obtained for the eclogites and garnet blueschists, respectively, are interpreted to reflect the near-peak to shortly retrograde stages of rock evolution and to record the late Cambrian and Middle Ordovician episodes of high-pressure re-equilibration in the North Balkhash zone. Protoliths of the eclogites were N-MORB-like mafic rocks, which comprised structurally different (from the lower gabbroic to the upper dolerite/basalt) parts of pre-late Cambrian oceanic crust and were formed in the spreading centre setting at the expense of depleted mantle source. Protoliths of the garnet blueschists and associated rocks were represented by volcanogenic–sedimentary, predominantly mafic, complexes (tuffaceous sandstones, greywackes), an accumulation of which and subsequent involvement into subduction occurred at ∼478–465 Ma in the intra-oceanic (fore-arc) setting. Zircon core ages indicate formation of the source of the protoliths of the garnet blueschists occurred in the 509–478 Ma range. A comprehensive correlation of the metamorphic and igneous formations of the North Balkhash zone with those assigned to the adjacent complexes of the southern part of the West Junggar area (NW China) suggested their mutual Early Palaeozoic tectonic evolution within the Junggar–Balkhash Ocean.

Orogen‐scale uniformity of recorded granulite facies conditions due to thermal buffering and melt retention

AbstractGranulite facies metapelitic gneisses collected over a km exposed area of the Kakamas Domain of the Namaqua–Natal Metamorphic Province in southern Namibia all contain similar garnet–sillimanite–cordierite–biotite–quartz–K‐feldspar–ilmenite plagioclase magnetite mineral assemblages. These assemblages are interpreted to have equilibrated at suprasolidus retrograde conditions, and most samples contain distinct biotite‐ or sillimanite‐free peak assemblages. Pseudosection modelling constrains extremely uniform residuum solidus conditions of kbar and °C for the entire Kakamas Domain. Estimated peak metamorphic conditions overlap with these but are more smeared out at between 4 and 7 kbar at 760°C to potentially more than 900°C. The uniformity of residuum solidus conditions is not coincidental, but is a consequence of retrograde re‐equilibration due to minor melt retention after peak metamorphism. Re‐equilibration could only stop once all retained melt had crystallized, which required the concomitant growth of a hydrous mineral to account for its H2O component. Biotite is the most stable hydrous mineral in these rocks, such that the residuum – conditions in the Kakamas Domain reflect the upper‐ stability of biotite, and also corresponds to the intersection of the well‐known biotite–sillimanite melting reaction that consumed all biotite during prograde metamorphism. The calculated melt fertility of the sample suite indicates that the variable amounts of heat consumed to overcome the latent heat of fusion could have caused a 25°C spread in the peak temperature achieved by the most and least fertile samples. Peak temperature in the Kakamas Domain may have been as much as 100°C higher than residuum solidus conditions for specific samples but cannot be confidently constrained as it is obscured by the effects of both thermal buffering during prograde metamorphism and melt retention during retrograde metamorphism. Both processes are an inescapable part of the evolution of all granulite facies rocks, but their effects are most pronounced in fertile rocks like metapelites that are traditionally the preferred lithology for quantifying the – history of exhumed terranes.

The Grenville Province: revisiting the orogenic framework and integrating recent findings

The Grenville Province holds record of Mesoproterozoic orogenic processes at the Laurentian margin during the assembly of Rodinia. This contribution reviews key characteristics of the Province, integrates recently published data, and questions some earlier interpretations. Despite crustal reworking during the Grenvillian orogeny (1.09–0.98 Ga), contrasts between crustal-age domains across the Allochthon Boundary largely reflect differences between internal and external Laurentia, and allochthonous units were far-travelled in the west but not in the east. In addition, there is growing evidence towards a continuum between the Ottawan and Rigolet orogenic phases. Based on ages of metamorphism, the High-Pressure segments of the hinterland reflect localized thickening at the front of the Ottawan orogen and evidence for an orogenic plateau is limited to the western Grenville. Peak-metamorphic conditions in the Mid-P orogenic core, mostly within the confines of biotite dehydration melting (max ~900oC) for aluminous rocks, culminated in early Ottawan and were followed by protracted extension. In addition, high-temperature granitoid magmatism was active throughout the duration of the orogeny and localized in formerly pericratonic terranes accreted at ~1.4 Ga and 1.2–1.1 Ga, indicating an influence of inherited lithospheric structures on Grenvillian mantle dynamics. The overall orogenic pattern reveals considerable lateral variations in the hinterland potentially linked to the earlier configuration of external Lautentia and is consistent with weak lithosphere supporting a broad, hot, but not necessarily high-standing orogen for most of the Ottawan, in contrast to the Rigolet phase that marks the propagation of the orogen against Archean lithosphere of internal Laurentia.

Dating prograde metamorphism: U–Pb geochronology of allanite and REE-rich epidote in the Eastern Alps

We use U–Pb dating of allanite and REE-rich epidote in three polymetamorphosed units from the Eastern Alps to constrain the timing of prograde metamorphism. All three units (Ennstal, Wölz and Rappold Complex) record several metamorphic cycles (Variscan, Permian and Eoalpine) and presently define an Eoalpine (Cretaceous) metamorphic field gradient from lower greenschist to amphibolite facies. For U–Pb data, a method is introduced to test the magnitude of 230Th disequilibrium and potentially approximate the Th/U ratio of the reservoir out of which allanite and REE-rich epidote grew. We also show that the modelled stability of epidote-group minerals in the REE-free MnNCKFMASH and MnNCKFMASHTO systems and REE-bearing systems is nearly identical. By combining the stability fields of (clino-)zoisite and epidote modelled in REE-free systems with known geothermal gradients for the region, REE-rich epidote growth is constrained to 200–450 °C and 0.2–0.8 GPa during prograde metamorphism. In the Rappold Complex, allanite cores yield a Variscan age of ca. 327 Ma. In the Ennstal and Wölz Complex, allanite growth during the Permian event occurred at ca. 279–286 Ma. Importantly, recrystallized allanite laths and REE-rich epidote overgrowths in samples from all three units yield prograde Eoalpine ages of ca. 100 Ma, even though these units subsequently reached different peak conditions, most likely at different times. This suggests that all units were buried roughly at the same time during the onset of Eoalpine continental subduction. This interpretation leaves room for the model proposing that diachronous peak metamorphic conditions reported for the field gradient may be related to the inertia of thermal equilibration rather than tectonic processes.

Basal erosion during the initiation of continental deep subduction in the North Qaidam ultrahigh-pressure metamorphic belt (NW China): Constraints from geochemistry and geochronology on eclogites and gneisses in the Chachahe unit

Subduction erosion is thought to be a common process in active continental margins that removes upper-plate material and transfers it to the subduction channel. The North Qaidam ultrahigh-pressure metamorphic belt of NW China was formed by subduction of the Qaidam Block beneath the Quanji Block in the early Paleozoic. In this study, we found gneisses and eclogites in the Chachahe unit of the North Qaidam ultrahigh-pressure metamorphic belt that recorded 2.39−2.28 Ga magmatism and 1.93−1.87 Ga amphibolite-facies metamorphism prior to the early Paleozoic (452−439 Ma) eclogite-facies metamorphism. The Paleoproterozoic tectono-thermal history recorded by these gneisses and eclogites is distinct from that of the Qaidam Block but similar to that of the Quanji Block. The rock assemblages, field occurrences, geochemical characteristics, and zircon Lu-Hf isotopic compositions of these rocks closely resemble those of gneisses and enclosed mafic enclaves in the Delingha Complex in the basement of the Quanji Block and the mafic dikes intruded within it. This evidence clearly illustrates that the protoliths of gneisses and eclogites in the Chachahe unit were from the basement of the upper Quanji Block rather than the subducted Qaidam Block. Further considering the spatial location of the Chachahe unit, as well as similarities in early Paleozoic metamorphic ages, peak metamorphic conditions, and clockwise P-T paths between rocks in the Chachahe unit and those that originated from the Qaidam Block, we propose that the bottom basement of the Quanji Block was scraped off by basal erosion during the initiation of continental subduction, transported to mantle depth, and then exhumed with other slices from the subducted slab.

Hot Cordilleran hinterland promoted lower crust mobility and decoupling of Laramide deformation

The Late Cretaceous to Paleogene Laramide orogen in the North American Cordillera involved deformation >1,000 km from the plate margin that has been attributed to either plate-boundary end loading or basal traction exerted on the upper plate from the subducted Farallon flat slab. Prevailing tectonic models fail to explain the relative absence of Laramide-aged (ca. 90–60 Ma) contractional deformation within the Cordillera hinterland. Based on Raman spectroscopy of carbonaceous material thermometry and literature data from the restored upper 15–20 km of the Cordilleran crust we reconstruct the Late Cretaceous thermal architecture of the hinterland. Interpolation of compiled temperature data (n = 200) through a vertical crustal column reveals that the hinterland experienced a continuous but regionally elevated, upper-crustal geothermal gradient of >40 °C/km during Laramide orogenesis, consistent with peak metamorphic conditions and synchronous peraluminous granitic plutonism. The hot and partially melted hinterland promoted lower crust mobility and crust-mantle decoupling during flat-slab traction.

Magmatic, Metamorphic and Structural History of the Variscan Lizard Ophiolite and Metamorphic Sole, Cornwall, UK

AbstractThe Lizard ophiolite, Cornwall, South‐West England, is the largest and best‐preserved ophiolite within the Variscan orogenic belt. It forms part of the Rheic‐Rhenohercynian suture zone, and was obducted northwestward onto the passive continental margin of Avalonia (Laurussia) during the Middle Devonian. It comprises an almost complete thrust slice of oceanic crust with sheeted dykes, gabbros, Moho transition sequence, and upper‐mantle peridotites, underlain by a metamorphic sole. Despite the importance of the Lizard ophiolite in understanding Variscan tectonics, the origin and age of the Lizard ophiolite are debated. We present new field observations, structural maps and cross‐sections of the Lizard ophiolite from extensive re‐mapping, integrated with U–Pb geochronology, petrology, thermobarometry, and whole rock geochemistry. We report new U–Pb zircon (CA‐ID‐TIMS and LA‐ICPMS) ages of 386.80 ± 0.25/0.31/0.52 Ma (Givetian) from a plagiogranite dyke intruding the Crousa Gabbros at Porthoustock, and 395.08 ± 0.14/0.22/0.47 Ma (Emsian) from partial melts of the metamorphic sole Landewednack Amphibolites at Mullion Cove. These ages, respectively, precisely date the formation of the Lizard ophiolite oceanic crust, and the age of cooling post peak‐metamorphism of the sole. Petrological modeling on the Landewednack Amphibolites suggests peak metamorphic conditions of 10 ± 2 kbar and 600 ± 75°C. We demonstrate that the Lizard ophiolite formed as a supra‐subduction zone ophiolite overlying an inverted metamorphic sole, and we combine our observations and data into a new geodynamic model for the formation and obduction of the ophiolite. The current data supports an induced subduction initiation model.

Neoproterozoic low-T/P metamorphism in the Yangtze Block manifests a long-lived subduction girdle around Rodinia

Identifying long-lived subduction at the periphery of supercontinents provides insights into the processes of block assembly and dispersal within the supercontinent cycle. The Yangtze Block of South China stands as a key component during the transition from Rodinia to Gondwana, characterized by active tectono-magmatic processes throughout the early to middle Neoproterozoic. However, the lack of metamorphic records associated with accretionary orogenesis results in ambiguity about the tectonic regime and its evolution in Rodinia during this period. Here, we present evidence of low-temperature/pressure ratio (low-T/P) metamorphism in phengite-bearing orthogneisses from the western margin of the Yangtze Block (WYB). Through petrographic investigations and zircon U–Pb–Hf–O isotopic analysis in core and rim domains, we identify two distinct metamorphic rock types, with protolith ages of 1419 ± 19 Ma and 831 ± 9 Ma. Both rock types record metamorphism at ca. 830–820 Ma, accompanied by infiltration of externally-derived melts with high-δ18O and unradiogenic Hf isotopes. Our phase equilibria modeling, combined with mineral thermometry and Si-in-phengite content, shows peak metamorphic conditions of ∼550 °C and ∼8.2–8.6 kbar, corresponding to a cold geothermal gradient (19.0–20.5 °C/km). The low-T/P metamorphism is interpreted to occur either in a subduction zone accretionary wedge or in an overriding forearc continental crust, providing robust evidence for Neoproterozoic orogenesis of the WYB within a subduction framework. Based on petrological, isotopic, and paleomagnetic data, we conclude that the WYB represents part of a long-lived subduction girdle (at least ca. 970–750 Ma) at the periphery of Rodinia. Since the early stage of Rodinia breakup, this girdle was involved in alternating advance and retreat accretionary orogenesis as the Yangtze Block continuously drifted away from a mantle upwelling toward the degree-2 girdle of mantle downwelling. Our study provides a snapshot of the evolution of a complete long-lived circum-Rodinian subduction girdle during the transition from Rodinia to Gondwana.

Crystallisation of trapped carbonate–silicate melts terminating at the carbonated solidus ledge: a record of carbon immobilisation mechanism in the lithospheric mantle

Orogenic peridotites in the crystalline basement of the northwestern Bohemian Massif contain multiphase solid inclusions (MSI), which are interpreted to be crystallisation products of trapped former carbonate–silicate melts metasomatizing their host rocks. We applied conventional thermobarometry and forward thermodynamic modelling to constrain the P–T evolution ranging from the peak metamorphic conditions of the investigated harzburgite and lherzolite, through entrapment of the melts in the outer parts of garnets, to the (re)-equilibration of the MSI assemblages. The peak conditions of c. 1100 °C/4.5–5.5 GPa are recorded by garnet cores and large pyroxene porphyroclasts. The melt entrapment, during which garnet outer parts grew, was associated with influx of the metasomatizing liquids and probably took place during the early stage of the exhumation. Thermodynamic model of amphibole-free MSI assemblage comprising kinoshitalite/Ba-rich phlogopite (approximated by phlogopite in the model), dolomite, magnesite, clinopyroxene, orthopyroxene, garnet and chromite provided robust estimate of P and T of its (re)-equilibration, c. 900–1000 °C, 1.8–2.2 GPa. Furthermore, the lack of olivine reflects co-existence of COH fluid with high X(CO2) = CO2/(CO2 + H2O) ≥ 0.6. Models employing identical P–T–X(CO2) parameters successfully reproduced the other two amphibole-bearing assemblages observed. The modelled stability fields show perfect alignment with a characteristic isobaric segment of the solidus curve of carbonated peridotite. This co-incidence implies that the (re)-equilibration corresponds to the termination of the melt crystallisation once the near-isothermal exhumation path intersected the solidus. Decreased solubility of silicates at the carbonated peridotite “solidus ledge”, inferred from the published experimental data, as well as concentric textures of some MSI indicates sequential crystallisation from the early silicates to late dolomite. The carbonated “solidus ledge” is a relatively narrow boundary in the lithospheric mantle capable of an abrupt immobilisation of fluxing or transported carbonated melts. The investigated rocks are estimated to store approximately 0.02 kg C/m3 (or 6 ppm C) occurring as carbonates in the MSI.

Mechanisms and durations of metamorphic garnet crystallization in the lower nappes of the Caledonian Kalak Nappe Complex, Arctic Norway

AbstractThe 3D microstructure and compositional zoning of garnet populations in micaschists from the Kolvik and Bekkarfjord nappes indicate the quasi‐equilibration of their major components across the rock matrices during interface‐controlled, size‐independent garnet growth. There is microstructural evidence for foliation‐parallel, small‐scale resorption of garnet rims in the Kolvik Nappe, influencing the metamorphic peak conditions obtained from thermodynamic modelling. The local chemical compositions of rims less affected by resorption indicate a peak temperature of ~630°C, which is ~40°C higher than the temperature obtained from resorbed rims of the largest garnet crystal. Using a diffusion geospeedometry approach that considers the geometry of the compositional zoning of the garnet population, as well as the higher, more realistic peak temperature, a duration of 1 to 4.9 Myr is obtained for garnet growth in the Kolvik Nappe. This is approximately 1 order of magnitude faster than duration estimates obtained when using the apparent, lower temperature estimated from the resorbed garnet rims. Concomitantly to garnet growth in the Kolvik Nappe, garnet overgrowths formed in the Bekkarfjord Nappe for circa 2.5 Myr at metamorphic peak temperatures of ~560°C. The garnet growth durations obtained here are comparable with the uncertainty on the Lu–Hf garnet–whole rock isochron ages of 419.9 ± 2.4 Ma and 423.0 ± 1.9 Ma, previously obtained for these rocks. These results provide new insight into the timescales of repeated Barrovian‐type metamorphic events experienced by the lower nappes of the Kalak Nappe Complex during the Caledonian Orogeny in Arctic Norway. This study emphasizes the importance of microstructural and chemical characterization of garnet populations in assessing metamorphic crystallization mechanisms and the extent of equilibration of garnet‐forming components during prograde metamorphism. Moreover, our results provide means for reducing the uncertainty on metamorphic durations obtained via diffusion geospeedometry and, so, contributing to our understanding of geological timescales and processes.

A record of Late Cretaceous to early Paleogene Insular terrane accretion within the northern Cordillera: Insights from monazite petrochronology across the Kluane Schist, southwest Yukon, Canada

The Kluane Schist is a metamorphosed package of siliciclastic and lesser calcareous rocks that lies between the inboard pericratonic Intermontane terranes and outboard Insular terranes of the North American Cordillera within Yukon, Canada. The metamorphic sequence of the Kluane Schist preserves a record of the tectono-thermal evolution and timing of Insular terrane accretion. Here we document the timing of metamorphism and deformation across the Kluane Schist using in situ laser ablation−inductively coupled plasma−mass spectrometry U-Th-Pb monazite petrochronology. Monazite-bearing samples collected across an inverted metamorphic sequence preserved in the northern regions of the Kluane Schist yield dates ranging from ca. 70 Ma to 55 Ma. Complementary phase equilibria modeling and thin section analysis indicate monazite grew between ∼450 °C and 3.0−3.5 kbar to ∼700−715 °C and 4.0−4.5 kbar, coeval with the development of the Kluane Schist’s inverted metamorphic sequence. Dating the four chemical zones preserved by monazite demonstrates its protracted growth during three distinct periods of garnet crystallization and breakdown, as well as coeval with melt generation. Our data illustrate that peak metamorphic conditions were reached at progressively younger ages with decreasing structural level within the Kluane Schist. Our results are consistent with Buchan-style metamorphism associated with the terminal accretion of the outboard Insular terranes and southwest-directed overriding of the inboard Yukon-Tanana terrane from ca. 70 Ma to 55 Ma. These findings are further congruous with a Late Cretaceous timing for the terminal accretion of the Insular terranes within southwest Yukon, facilitated by east-dipping subduction beneath a westward migrating North American continent.