Ice-covered Conditions Research Articles

Last deglaciation and Holocene environmental change at high altitude in the Pyrenees: the geochemical and paleomagnetic record from Marboré Lake (N Spain)

Sedimentological, geochemical and magnetic data in a ~ 7-m sequence from Marbore Lake (2612 m asl, central Pyrenees) provide information about environmental variability since the last glacier retreat (14.6 cal ka BP) in high-altitude Pyrenean environments. The sediment sequence is composed of millimeter- to centimeter-thick rhythmites made of finer greyish laminae and coarser-grain, carbonate-bearing laminae arranged in varied patterns throughout the sequence. Finer laminae are interpreted as deposition during periods of predominantly ice-covered conditions, whereas coarser, carbonate-bearing sediments reflect periods of higher runoff. The age model, based on 13 14C dates and a reservoir effect assessed with 210Pb and 137Cs, is coherent with known synchronous vegetation changes across the Pyrenees. Warmer intervals such as GI-1 (14.6–12.8 cal ka BP, Bolling/Allerod period), 10.4–8.2 cal ka BP in the Early Holocene, 7.5–5.2 cal ka BP in the Mid Holocene and the Medieval Climate Anomaly (AD 900–1300), are characterized by peaks in productivity and higher carbonate preservation. Deposition during colder periods such as GS-1 (12.8–11.7 cal ka BP), the Neoglacial (ca. 5.2–3.5 cal ka BP) and the Little Ice Age (last 400 years) show an increase in finer laminae. The presence of magnetite throughout the whole section suggests that Marbore Lake maintained predominantly oxic conditions since its formation. Changes in magnetic properties and the increase in magnetite from 3.5 cal ka BP to present, however, indicate a more oxic environment at the lake bottom during the last few millennia. The occurrence of Pb concentration peaks in sediments of Roman and modern age demonstrates the global distribution of heavy metal deposition, even into high-mountain lakes.

Interrelationship between nutrients and chlorophyll-a in an urban stormwater lake during the ice-covered period

Urban stormwater lakes in cold regions are ice-covered for substantial parts of the winter. It has long been considered that the ice-covered period is the “dormant season,” during which ecological processes are inactive. However, little is known about this period due to the historical focus on the open-water season. Recent pioneering research on ice-covered natural lakes has suggested that some critical ecological processes play out on the ice. The objective of this study was to investigate the active processes in ice-covered stormwater lakes. Data collected during a two-year field measurement program at a stormwater lake located in Edmonton, Alberta, Canada were analyzed. The lake was covered by ice from November to mid-April of the following year. The mean value of chlorophyll-a during the ice-covered period was 22.09% of the mean value for the open-water season, suggesting that primary productivity under the ice can be important. Nitrogen and phosphorus were remarkably higher during the ice-covered period, while dissolved organic carbon showed little seasonal variation. Under ice-covered conditions, the total phosphorus was the major nutrient controlling the ratio of total nitrogen to total phosphorus, and a significant positive correlation existed between total phosphorus and chlorophyll-a when the ratio was smaller than 10. The results provide preliminary evidence of the critical nutrient processes in Stormwater Lake during the ice-covered period.

Hypoxic conditions in stormwater retention ponds: potential for hydrogen sulfide emission

ABSTRACTImproper design and maintenance of stormwater ponds (SWPs) may lead to hypoxic conditions, poor water quality and the production of hydrogen sulfide (H2S). The objective of this study is to develop a comprehensive understanding of hypoxic conditions of SWPs, with a focus on the potential for H2S production and emission. This study was conducted at two retention SWPs in Ottawa, Canada; a problematic pond with the propensity for H2S emission and a reference pond that did not demonstrate H2S emission. The investigation illustrated a significant impact of low dissolved oxygen (DO) concentrations, hypoxic conditions, on the concentration of total sulfides in the water column. Both ponds were shown to periodically experience hypoxic conditions at depth, especially during summer periods with less precipitation and across longer periods of winter, ice-covered conditions. The problem pond, however, was shown to experience lower DO and longer hypoxic conditions than the reference pond in both non-ice-covered and ice-covered conditions due to greater depth and a longer hydraulic retention time. Hypoxic conditions were initiated at the deepest locations in the problem pond and subsequently were spread across the entirety of the pond under winter, ice-covered conditions. Algal biomass (Chlorophyll-a) and soluble biochemical oxygen demand concentrations were shown to not likely be significant factors in the development of hypoxia in the H2S-generating pond. Algal blooms of colonial Chrysophyceae, Synura, a known mixotroph, were observed during ice-covered conditions in the problem pond possibly due to stress-coping mechanisms of algae.

The role of earthquakes and climate in the formation of diamictic sediments in a New Zealand mountain lake

We used Itrax XRF, magnetic susceptibility, grain size, and micro-CT scanning to provide a facies classification for a Late Holocene sediment sequence from Lake Chappa'ai in the Southern Alps, New Zealand. The record contained multiple diamictic layers and our objective was to determine the environmental significance of these deposits. Clast fabric analysis indicated that the diamicts comprise dropstones transported to the centre of the lake by ice rafting. Diamicts belonging to Facies 1 represent rock falls onto lake ice triggered by earthquakes that produced MMI (Modified Mercalli Intensity) > 8 shaking in the catchment. MMI >8 earthquakes may need to occur when the lake has ice cover to produce Facies 1 diamicts. MMI >8 earthquakes in the ice free season or MMI 7–8 earthquakes may also result in an increased flux of large (>1 mm) clasts to the centre of the lake, but may not produce a Facies 1 diamict. More work is required to establish the role of climate related processes on the formation of non-Facies 1 diamicts in Lake Chappa'ai. Climate change may directly lead to diamict formation by changing lake ice cover and facilitating transport of large clasts by anchor ice, or increasing the likelihood of rain on snow events in the spring. Changing ice cover conditions will also affect how mountain lakes record past earthquake events. Lakes that are ice free will not produce earthquake diamicts and lakes that have perennial ice cover may produce a single diamict representing multiple earthquakes if the lake becomes ice free. A reduction in the duration of winter ice cover will also decrease the probability of capturing primary rockfall deposits from earthquakes. Additional data, such as a diatom or chironomid record from Lake Chappa'ai may help to resolve the contribution of climate processes to diamict formation. We should consider the Lake Chappa'ai record as an indicator of minimum earthquake activity until we can disentangle the effects of climate change on non-Facies 1 diamict formation. This study highlights the multiple mechanisms that can lead to diamict formation in mountain lake sediments. These processes should always be considered before attributing the presence of diamict deposits to ice-rafted debris in a pro-glacial lake. This is particularly true in seismically active settings where earthquake triggered rockfalls may lead to diamict formation.

Response of phytoplankton community to different water types in the western Arctic Ocean surface water based on pigment analysis in summer 2008

Nutrients and photosynthesis pigments were investigated in the western Arctic Ocean during the 3rd Chinese Arctic Research Expedition Cruise in summer 2008. The study area was divided into five provinces using the Kmeans clustering method based on the physical and chemical characteristics of the sea water, and to discuss the distribution of the phytoplankton community structure in these provinces. CHEMTAX software was performed using HPLC pigments to estimate the contributions of eight algal classes to the total chlorophyll a (TChl a). The results showed that on the Chukchi Shelf, the Pacific Ocean inflow mainly controlled the Chl a biomass and phytoplankton communities by nutrient concentrations. The high nutrient Anadyr Water and Bering Shelf Water (AnW and BSW) controlled region have high Chl a levels and the diatom dominated community structure. In contrast, in the region occupied by low-nutrient like Alaska Coastal Water (ACW), the Chl a biomass was low, with pico- and nano-phytoplankton as dominated species, such as prasinophytes, chrysophytes and cryptophytes. However, over the off-shelf, the ice cover condition which would affect the physical and nutrient concentrations of the water masses, in consequence had a greater impact on the phytoplankton community structure. Diatom dominated in ice cover region and its contribution to Chl a biomass was up to 75%. In the region close to the Mendeleev Abyssal Plain (MAP), controlled by sea-ice melt water with relatively high salinity (MW-HS), higher nutrient and Chl a concentrations were found and the phytoplankton was dominated by pico- and nano-algae, while the diatom abundance reduced to 33%. In the southern Canada Basin, an ice-free basin (IfB) with the lowest nutrient concentrations and most freshened surface water, low Chl a biomass was a consequence of low nutrients. The ice retreating and a prolonged period of open ocean may not be beneficial to the carbon export efficiency due to reducing the Chl a biomass or intriguing smaller size algae growth.

Exceptional summer warming leads to contrasting outcomes for methane cycling in small Arctic lakes of Greenland

Abstract. In thermally stratified lakes, the greatest annual methane emissions typically occur during thermal overturn events. In July of 2012, Greenland experienced significant warming that resulted in substantial melting of the Greenland Ice Sheet and enhanced runoff events. This unusual climate phenomenon provided an opportunity to examine the effects of short-term natural heating on lake thermal structure and methane dynamics and compare these observations with those from the following year, when temperatures were normal. Here, we focus on methane concentrations within the water column of five adjacent small lakes on the ice-free margin of southwestern Greenland under open-water and ice-covered conditions from 2012–2014. Enhanced warming of the epilimnion in the lakes under open-water conditions in 2012 led to strong thermal stability and the development of anoxic hypolimnia in each of the lakes. As a result, during open-water conditions, mean dissolved methane concentrations in the water column were significantly (p < 0.0001) greater in 2012 than in 2013. In all of the lakes, mean methane concentrations under ice-covered conditions were significantly (p < 0.0001) greater than under open-water conditions, suggesting spring overturn is currently the largest annual methane flux to the atmosphere. As the climate continues to warm, shorter ice cover durations are expected, which may reduce the winter inventory of methane and lead to a decrease in total methane flux during ice melt. Under open-water conditions, greater heat income and warming of lake surface waters will lead to increased thermal stratification and hypolimnetic anoxia, which will consequently result in increased water column inventories of methane. This stored methane will be susceptible to emissions during fall overturn, which may result in a shift in greatest annual efflux of methane from spring melt to fall overturn. The results of this study suggest that interannual variation in ground-level air temperatures may be the primary driver of changes in methane dynamics because it controls both the duration of ice cover and the strength of thermal stratification.

Nonsmooth frameworks for an extended Budyko model

In latitude-dependent energy balance models, ice-free and ice-covered conditions form physical boundaries of the system. With carbon dioxide treated as a bifurcation parameter, the resulting bifurcation diagram is nonsmooth with curves of equilibria and boundaries forming corners at points of intersection. Over long time scales, atmospheric carbon dioxide varies dynamically and the nonsmooth diagram becomes a set of quasi-equilibria. However, when introducing carbon dynamics, care must be taken with the physical boundaries and appropriate boundary motion specified. In this article, we extend an energy balance model to include slowly varying carbon dioxide and develop nonsmooth frameworks based on physically relevant boundary dynamics. Within these frameworks, we prove existence and uniqueness of solutions, as well as invariance of the region of phase space bounded by ice-free and ice-covered states.

Aerial application of herding agents to advance in-situ burning for oil spill response in the Arctic: A pilot study

In-situ burning (ISB) aided by herding agents is a promising tool for oil spill response in Arctic waters. An advantageous aspect of the herder mediated ISB approach is that the application of herders as well as the subsequent ignition of the slick could potentially be carried out from aerial platforms. This could obviate the need for personnel to conduct operations on the surface near the burn, as well as reduce the response time required to mobilize the spill response equipment, especially in difficult Arctic conditions. In the last decade, several laboratory and field-scale tests have been conducted to prove the efficacy of herding agent mediated ISB operations, sometimes achieving burn efficiencies >90%. However, there have been no reports of aerial herder application followed by ignition. The objectives of this work were to evaluate a proof-of-concept level application of aerial herders and igniters for ISB operations in the Arctic, and to investigate the associated operational and technical challenges. This paper presents results from a series of field experiments performed in a custom-built test basin 50km northeast of Fairbanks, Alaska, in April 2015. A helicopter was employed to first apply herding agents (Siltech OP-40 or ThickSlick 6535) to Alaska North Slope crude oil slicks in simulated drift ice conditions, and then ignite the herded slicks using a heli-torch. Burn efficiency (BE) for the confined field scale in-situ burn tests ranged from 59% to 94% using the gravimetric approach and 73% to 84% using the conservative aerial imagery approaches to evaluate the herder action. The moderately high BE values observed in the field-scale light ice-cover (~10%) conditions, establish the effectiveness and promise of aerial application of herders to assist ISB in the Arctic. This is a first account of successful aerial application of herders for ISB in the Arctic or elsewhere, and furthers the development of better tools for oil spill response in Arctic waters and beyond.

Parameter Sensitivity of a Surface Water Quality Model of the Lower South Saskatchewan River—Comparison Between Ice-On and Ice-Off Periods

Little is known about seasonal differences (ice-on vs. ice-off periods) and the sensitivity of in-stream processes to surface water quality constituents in rivers that have a persistent ice cover in winter. The goal of this study is to investigate the sensitivity of nutrient transformation processes on surface water quality, especially rivers in cold regions where ice-covered conditions persist for a substantial part of the year. We established a sensitivity analysis framework for water quality modelling and monitoring of rivers in cold regions using the Water Quality Analysis Program WASP7. The lower South Saskatchewan River in the interior of western Canada, from the Gardiner Dam at Lake Diefenbaker to the confluence of the North and South Saskatchewan rivers, is used as a test case for this purpose. The study reveals that parameter sensitivities differ between ice-covered and ice-free periods and biological model parameters related to nutrient-phytoplankton dynamics can still be sensitive during the ice-covered season. For example, sediment oxygen demand is an important parameter during the ice-on period, whereas parameters related to nitrification are more sensitive in the ice-off period. These results provide insight into important water quality monitoring aspects in cold regions during different seasons.

Atmospheric Conditions during the Arctic Clouds in Summer Experiment (ACSE): Contrasting Open Water and Sea Ice Surfaces during Melt and Freeze-Up Seasons

Abstract The Arctic Clouds in Summer Experiment (ACSE) was conducted during summer and early autumn 2014, providing a detailed view of the seasonal transition from ice melt into freeze-up. Measurements were taken over both ice-free and ice-covered surfaces near the ice edge, offering insight into the role of the surface state in shaping the atmospheric conditions. The initiation of the autumn freeze-up was related to a change in air mass, rather than to changes in solar radiation alone; the lower atmosphere cooled abruptly, leading to a surface heat loss. During melt season, strong surface inversions persisted over the ice, while elevated inversions were more frequent over open water. These differences disappeared during autumn freeze-up, when elevated inversions persisted over both ice-free and ice-covered conditions. These results are in contrast to previous studies that found a well-mixed boundary layer persisting in summer and an increased frequency of surface-based inversions in autumn, suggesting that knowledge derived from measurements taken within the pan-Arctic area and on the central ice pack does not necessarily apply closer to the ice edge. This study offers an insight into the atmospheric processes that occur during a crucial period of the year; understanding and accurately modeling these processes is essential for the improvement of ice-extent predictions and future Arctic climate projections.

A numerical framework for modelling sediment and chemical constituents transport in the Lower Athabasca River

The transport of fine sediments and associated chemical constituents originating from potential anthropogenic and natural sources is becoming an issue of increasing importance in the Lower Athabasca River (LAR) ecosystem in northern Alberta, Canada. This study aims to (1) establish an integrated numerical modelling framework to investigate the transport of fine cohesive sediments and associated chemical constituents during both ice-covered and open-water periods and (2) apply the modelling framework to investigate the state and temporal/spatial variation in sediment and selected chemical constituents within the LAR. One-dimensional hydrodynamic and transport models, combined with a river ice model, are used to predict the flow characteristics, transport of sediments and a selection of three metals and three polycyclic aromatic hydrocarbons (PAHs) within a ∼200 km reach of the LAR, both in open-water and ice-covered conditions. The models are validated using available field measurements and are applied to investigate the state and variation of sediment and chemicals for a baseline period as well as to assess the effect of various hypothetical pollution scenarios. The model simulations successfully reproduce the hydrodynamics and sediment transport patterns as well as the state and variation of selected metal and PAH constituents. The results generally show that the concentration of chemical constituents in the bed sediment is the major factor in determining the state and variation of their concentration in the water column, and the high-flow season is the critical period for the transport of sediment and chemicals in the system. The scenario simulation results indicate that increases in the concentrations of chemical constituents in tributary streams have to be orders of magnitude higher to have a noticeable effect on their corresponding water column concentration in the LAR. Those effects are also found to be higher only within the immediate vicinity of the tributary confluences and gradually diminish with distance downstream of the confluences. The numerical modelling framework developed in this study provides a tool for investigation and understanding of the state and temporal/spatial variation of sediment and associated chemical constituents within cold region rivers such as the LAR. By conducting additional scenario-based studies (such as future climate and chemicals loading), the models can be used to identify possible future states of sediment and water quality constituents in the LAR ecosystem.

Investigation into freezing point depression in stormwater ponds caused by road salt

Variable and unpredictable ice cover conditions present a serious safety concern for winter recreational activities on urban stormwater ponds. Ice cover formation and decay are largely controlled by thermal and hydrodynamic factors; however, stormwater ponds receiving salt-laden runoff can have altered chemical properties, which may also affect ice processes. To identify the causal factors of variable ice cover conditions, water sampling and continuous water quality monitoring were conducted over two winters on four stormwater ponds located in Edmonton, Alberta, Canada. Laboratory experiments were conducted to determine the freezing point temperatures of the water samples. It was found that the freezing point temperature correlates strongly with specific conductivity and closely to the chloride concentration in the ponds. The magnitude of freezing point depression varied from pond to pond with a maximum magnitude of 0.353°C. The freezing point depression was also determined for the pond ice by measuring the specific conductivity of thawed ice cores, and was found to be significantly smaller than that of the pond water. A calculation of the heat transfer in a layer of ice showed that the ice growth and melting processes were not significantly affected by freezing point depression of this magnitude. Therefore, it was concluded that salt-laden runoff from nearby roads does not have a significant influence on ice formation or thawing in stormwater ponds.

Upwelling of Atlantic Water along the Canadian Beaufort Sea Continental Slope: Favorable Atmospheric Conditions and Seasonal and Interannual Variations

Abstract The role of wind forcing on the vertical displacement of the −1°C isotherm and 33.8 isohaline depths was examined based on snapshots of historical (1950–2013) temperature and salinity profiles along the Mackenzie continental slope (Beaufort Sea). It is found that upwelling is correlated with along-slope northeast (T59°) winds during both ice-free and ice-covered conditions, although the wind impact is more efficient during the ice-free season. One of the most important factors responsible for vertical displacements of isopycnals is sustained wind forcing that can last for several weeks and even longer. It accounts for 14%–55% of total variance in isotherm/isohaline depths, although these numbers might be underestimated. The upwelling and downwelling events are discussed in the context of the interplay between two regional centers of action—the Beaufort high and Aleutian low—that control the wind pattern over the southern Beaufort Sea. The probability of upwelling-favorable wind occurrence is closely related to the sea level pressure difference between these two centers, as well as their geographical positions. The combined effect of both centers expressed as the SLP differences is highly correlated (0.68/0.66 for summer/winter) with occurrences of extreme upwelling-favorable northeast (NE) winds over the Mackenzie slope, although the Beaufort high plays a more important role. The authors also diagnosed the predominant upwelling-favorable conditions over the Mackenzie slope in the recent decade associated with the summertime amplification of the Beaufort high. The upwelling-favorable NE wind occurrences also demonstrate the significant but low (−0.30) correlation with Arctic Oscillation (AO) during both summer and winter seasons, whereas the high correlation with North Pacific index (NPI; −0.52) is obtained only for the ice-covered period.

Large fractionations of C and H isotopes related to methane oxidation in Arctic lakes

Microbial oxidation of methane (CH4) plays a central role in carbon cycling in Arctic lakes, reducing potential CH4 emissions associated with warming. Isotopic signatures of CH4 (δ13C and δ2H) are indicators of microbial oxidation, wherein the process strongly enriches 13C and 2H in residual CH4. We present δ13C and δ2H measurements obtained from sampling the water column and sediment for dissolved CH4 from three, small Arctic lakes in western Greenland under both open-water and ice-covered conditions from 2013 to 2014. Despite substantial variations in aquatic chemistry among the lakes, δ13C and δ2H of CH4 suggested that CH4 was produced predominantly by acetoclastic methanogenesis in the littoral sediments and hydrogenotrophic methanogenesis in the profundal sediments in all of the lakes. Surprisingly large variations for both δ13C and δ2H of CH4 were observed, with δ13C extending from −72‰ to +7.4‰ and δ2H from −390‰ to +250‰. The CH4 isotopic values reported here were significantly more enriched (p<0.0001) in both 13C and 2H than values reported from other Arctic freshwater environments. As is characteristic of methanotrophy, the enrichment in 13C and 2H was associated with low CH4 concentrations. We suggest that the CH4 most enriched in 13C and 2H may reflect unusually efficient methanotrophic communities in Arctic ice-margin lakes. This study provides the first measurement of δ2H for CH4 in an Arctic freshwater environment at concentrations <10μM. The extreme enrichment of 13C and 2H of CH4 from Arctic methanotrophy has significant implications for interpreting sources and sinks of CH4. Without knowledge of local geology, stable isotope values of CH4 higher than −30‰ for δ13C and −150‰ for δ2H could be misinterpreted as thermogenic, geothermal, or abiogenic origins. Given crystalline bedrock and the strong positive correlation between δ13C and δ2H throughout the water columns in three Arctic lakes confirms that CH4 heavily enriched in 13C and 2H is the result of methanotrophy.

Methods of deep dives in whole ice cover conditions

The essence of methodological and engineering questions solved during the preparation and implementation of historic dives of the manned submersibles Mir-1 and Mir-2, allowing humans to see the bottom of the North Pole at a depth of 4300 m, are described together with innovative developments in underwater navigation, as well as the Mir’s propulsion, ballast, and other systems that ensured the safety of the dives. These innovative methods have opened up the Arctic’s underice space for scientific research and practical exploration for minerals with the direct participation of scientists and specialists.

Gas exchange of CO2 and O2 in partially ice-covered regions of the Arctic Ocean investigated using in situ sensors

Sea surface CO2 dynamics are not well characterized in the Arctic Ocean (AO). Most data are from ship-based studies during the low-ice period (May-September) and obtained from near shore areas because of accessibility. More CO2 data are needed to improve models for predicting the future of the carbon cycle in the region and its relationship to ocean acidification. Air-sea gas exchange rates are complicated by the presence of ice. Consequently gas exchange rates have a larger uncertainty in the AO compared to other ocean regions. To provide more information about CO2 dynamics and gas exchange in the AO, in situ time-series data have been collected from the Canada Basin during late summer to autumn of 2012. Partial pressure of CO2 (pCO2), dissolved O2 (DO) concentration, temperature, and salinity were measured at ∼6-m depth under little ice and multi-year ice on two ice-tethered profilers (ITPs) for 40-50 days. The pCO2 levels were always below atmospheric saturation whereas DO was almost always slightly above saturation. Although the two ITPs were on an average only 222 km apart, one was further south and had 14 ± 12% ice cover; whereas the more northern ITP had 63 ± 16% ice cover. Consequently the two data sets differed significantly in external forcings. Modeled variability of CO2 and DO estimate that gas exchange would significantly alter sea surface pCO2 in the low ice cover record but minimally in the more extensively ice-covered region. If these conditions extended over the entire AO, the total uptake of atmospheric CO2 would be 28.6 Tg C yr-1 and 15.4 Tg C yr-1 under low and high ice-covered conditions, respectively.

Quantifying Spatial Changes in the Structure of Water Quality Constituents in a Large Prairie River within Two Frameworks of a Water Quality Model

A global sensitivity analysis was carried out on a water quality model to quantify the spatial changes in parameter sensitivity of a model of a large prairie river, the South Saskatchewan River (SSR). The method is used to assess the relative impacts of major nutrient loading sources and a reservoir on the river’s water quality. The river completely freezes over during winter; hence, the sensitivity analysis was carried out seasonally, for winter and summer, to account for the influence of ice-covered conditions on nutrient transformations. Furthermore, the integrity of the river’s aquatic ecosystem was examined through the inter-relationship between variables and comparing hierarchy index values and water quality indices at four locations along the river. Sensitivities of model parameters varied slightly at different locations along the river, with the phytoplankton growth rate being the most influential parameter. Nitrogen and phosphorus transformation processes were more sensitive in winter, while chlorophyll-a and dissolved oxygen parameters showed higher sensitivity in summer. A more complicated correlation between variables was observed downstream of the junction of the Red Deer River. Our results reveal that the lower correlation between variables may suggest a more balanced and healthier system, although further analysis is needed to support this statement.

Features of winter sedimentation processes in Curonian Bay of the Baltic Sea

The concentration distribution was studied for dissolved oxygen, phosphorus forms, and particulate matter in Curonian Bay of the Baltic Sea in poorly known consolidated ice cover conditions during the winter seasons of 2010, 2011, and 2013. The surface and near-bottom waters were sampled at 51 stations. The ice cover exerts no significant effect on the typical seasonal variation of all considered parameters in the basin. The concentrations of mineral and organic phosphorus in the bay appeared to be lower by factors of 2–4 compared to summer values. A two- to threefold decrease in the concentrations of organic phosphorus since 2010 to 2011 and then to 2013 was recorded in the bay, which resulted from a decrease in phosphorus production by phytoplankton. Despite water being isolated from air by ice, the absence of wave mixing, and the decrease in oxygen production owing to the seasonal winter decrease in the intensity photosynthetic processes, no oxygen deficiency was found in the basin. This is because oxygen supplied to the bay by river runoff and production by photosynthesis in the bay exceed the utilization for oxidation of organic matter resulting from low bioproductivity of the waters during winter. The winter decrease in the fraction of biogenic particulate matter is seen as a four- to sevenfold drop in its total concentration in the waters compared to summer seasons. The absence of wave roiling of bottom sediments also caused a decrease in the secondary supply of biogenic particulate matter from sediments into near-bottom waters. No negative trends of geoecological conditions in the bay were revealed by the studied parameters under consolidated ice cover conditions.

Nautical electronic maps of S-411 standard and their suitability in navigation for assessment of ice cover condition of the Arctic Ocean

Abstract The research on the ice cover of waterways, rivers, lakes, seas and oceans by satellite remote sensing methods began at the end of the twentieth century. There was a lot of data sources in diverse file formats. It has not yet carried out a comparative assessment of their usefulness. A synthetic indicator of the quality of data sources binding maps resolution, file publication, time delay and the functionality for the user was developed in the research process. It reflects well a usefulness of maps and allows to compare them. Qualitative differences of map content have relatively little impact on the overall assessment of the data sources. Resolution of map is generally acceptable. Actuality has the greatest impact on the map content quality for the current vessel’s voyage planning in ice. The highest quality of all studied sources have the regional maps in GIF format issued by the NWS / NOAA, general maps of the Arctic Ocean in NetCDF format issued by the OSI SAF and the general maps of the Arctic Ocean in GRIB-2 format issued by the NCEP / NOAA. Among them are maps containing information on the quality of presented parameter. The leader among the map containing all three of the basic characteristics of ice cover (ice concentration, ice thickness and ice floe size) are vector maps in GML format. They are the new standard of electronic vector maps for the navigation of ships in ice. Publishing of ice cover maps in the standard electronic map format S-411 for navigation of vessels in ice adopted by the International Hydrographic Organization is advisable in case is planned to launch commercial navigation on the lagoons, rivers and canals. The wide availability of and exchange of information on the state of ice cover on rivers, lakes, estuaries and bays, which are used exclusively for water sports, ice sports and ice fishing is possible using handheld mobile phones, smartphones and tablets.

Seasonal and Regional Controls of Phytoplankton Production along a Climate Gradient in South-West Greenland During Ice-Cover and Ice-Free Conditions

ABSTRACTAcross a small geographic area (<180 km), the region of South-West Greenland covers a natural climate gradient. Variation in temperature and precipitation result in marked differences in limnology at three discrete locations: ice sheet margin, inland, and the coast. Replicate lakes from each location were sampled for physical (temperature, light), chemical (dissolved oxygen, pH, conductivity, nutrients), and biological (chlorophyll a [Chl a], photosynthetic pigments) variables on three occasions within a 12-month period: July–August 2010, April–May 2011, and June–July 2011 spanning ice cover. Variation in ice phenology was linked to the climate gradient; however, phytoplankton production and community composition did not differ regionally. Large-scale seasonal fluctuations in temperature and nutrient availability were the strongest predictors of phytoplankton production, with a shift from nitrate to phosphorus controlled production between ice-cover and ice-free conditions. Underlying seasonal drivers, variables predicting production were unique to each location—ice sheet margin (soluble reactive phosphorus), inland (temperature), and coast (silicate)—and reflect local differences in nutrient availability. Results from the current study have important consequences when controls over phytoplankton production in Arctic lakes are inferred from a limited number of sites, but up-scaled to represent pan-Arctic trends.