Conceptual Structural Design Research Articles

Extending the π‐Conjugation of a Donor‐Acceptor Covalent Organic Framework for High‐Rate and High‐Capacity Lithium‐Ion Batteries

AbstractRealizing high‐rate and high‐capacity features of Lihium‐organic batteries is essential for their practical use but remains a big challenge, which is due to the instrinsic poor conductivity, limited redox kinetics and low utility of organic electrode mateials. This work presents a well‐designed donor‐acceptor Covalent Organic Framework (COFs) with extended conjugation, mesoscale porosity, and dual redox‐active centers to promote fast charge transfer and multi‐electron processes. As anticipated, the prepared cathode with benzo [1,2‐b:3,4‐b′:5,6‐b′′] trithiophene (BTT) as p‐type and pyrene‐4,5,9,10‐tetraone (PTO) as n‐type material (BTT‐PTO‐COF) delivers impressive specific capacity (218 mAh g−1 at 0.2 A g−1 in ether‐based electrolyte and 275 mAh g−1 at 0.2 A g−1 in carbonate‐based electrolyte) and outstanding rate capability (79 mAh g−1 at 50 A g−1 in ether‐based electrolyte and 124 mAh g−1 at 10 A g−1 in carbonate‐based electrolyte). In addition, the potential of BTT‐PTO‐COF electrode for prototype batteries has been demonstrated by full cells of dual‐ion (FDIBs), which attain comparable electrochemical performances to the half cells. Moreover, mechanism studies combining ex situ characterization and theoratical calculations reveal the efficient dual‐ion storage process and facile charge transfer of BTT‐PTO‐COF. This work not only expands the diversity of redox‐active COFs but also provide concept of structure design for high‐rate and high‐capacity organic electrodes.

Extending the π-Conjugation of a Donor-Acceptor Covalent Organic Framework for High-Rate and High-Capacity Lithium-Ion Batteries.

Realizing high-rate and high-capacity features of Lihium-organic batteries is essential for their practical use but remains a big challenge, which is due to the instrinsic poor conductivity, limited redox kinetics and low utility of organic electrode mateials. This work presents a well-designed donor-acceptor Covalent Organic Framework (COFs) with extended conjugation, mesoscale porosity, and dual redox-active centers to promote fast charge transfer and multi-electron processes. As anticipated, the prepared cathode with benzo [1,2-b:3,4-b':5,6-b''] trithiophene (BTT) as p-type and pyrene-4,5,9,10-tetraone (PTO) as n-type material (BTT-PTO-COF) delivers impressive specific capacity (218 mAh g-1 at 0.2 A g-1 in ether-based electrolyte and 275 mAh g-1 at 0.2 A g-1 in carbonate-based electrolyte) and outstanding rate capability (79 mAh g-1 at 50 A g-1 in ether-based electrolyte and 124 mAh g-1 at 10 A g-1 in carbonate-based electrolyte). In addition, the potential of BTT-PTO-COF electrode for prototype batteries has been demonstrated by full cells of dual-ion (FDIBs), which attain comparable electrochemical performances to the half cells. Moreover, mechanism studies combining ex situ characterization and theoratical calculations reveal the efficient dual-ion storage process and facile charge transfer of BTT-PTO-COF. This work not only expands the diversity of redox-active COFs but also provide concept of structure design for high-rate and high-capacity organic electrodes.

Reviving Multivalent‐Metal Anodes in Simple Salt Electrolytes via Component Modifier Design

AbstractUsing combinatory electrolyte blends represents an imperative avenue to achieve good magnesium (Mg)‐metal anode compatibility and commercial feasibility in fields of promising rechargeable Mg batteries. However, fundamental challenges of how to manipulate component modifier reactivity on molecule level still remain to be solved. Here, molecular structure design concepts towards seeking bromophenyl complex‐based component modifiers has been proposed according to implications of electron‐donating and/or electron‐withdrawing substituents on Br−C bond dissociation reactivity. Exceptional Mg electro‐plating/stripping properties (a stable cycle life of 250 days in Mg//Cu asymmetric cells) have been firstly achieved in a simple salt electrolyte with 1‐(3‐bromophenyl)‐N,N‐dimethylmethanamine (BPDMA) as optimal component modifier. Comprehensive analyses disclose the unique electrochemically‐active Br‐containing ion‐pairs formation, such as [(Mg2+)2(TFSI−)Br−]2+ and [(Mg2+)2(TFSI−)(Br−)(G2)2]2+, which results in the much thinner Br− containing and organic–inorganic mixed interphases on Mg‐metal anodes. Furthermore, conventional MgSO4‐based electrolytes and even calcium (Ca)‐ion electrolytes can also be revived by similar strategy, demonstrating its generality and superiority.

Optimization Design of Redundant Parallel Posture Adjustment Mechanism for Solar Wing Docking Based on Response Surface Methodology

The parallel mechanism exhibits high stiffness and excellent dynamic response, making it ideal for high-precision applications. In our early work, a novel 6-DOF redundant parallel posture mechanism with four limbs for solar wing docking has been proposed; each limb consists of three links and four joints. This paper primarily focuses on optimization design of the mechanism. The calculation of workspace volume reveals that factors influencing the range of posture adjustment include dynamic platform parameters, static platform parameters, the drive trajectory of each kinematic pair, and the angles between each kinematic pair. A sensitivity analysis was conducted to examine the impact of each parameter on the range of posture adjustment. To reduce computational complexity and improve analysis efficiency, a combined approach of single-factor analysis and response surface methodology (RSM) is used in the paper. Single-factor analysis is utilized to evaluate the effect of each parameter on the posture adjustment range. Based on these results, RSM is used to establish a regression model for parameters; thereby, the optimal parameter combination for the mechanism is determined. The regression coefficient R2 = 0.9374 attests to the validity of the proposed model. Finally, a comparison of the posture adjustment range before and after optimization is presented, providing a foundation for the practical application of the redundant parallel mechanism. This paper introduces a novel structural design concept aimed at resolving the conflict between heavy loads and compact sizes in redundant parallel mechanisms while providing valuable insights for miniaturized design.

Predicting maximum deflection of N-Edged thin-shelled hyperbolic-Paraboloid umbrella using machine learning techniques

Many thin-shelled hyperbolic paraboloid (hypar) umbrella forms have been built in the last 60 years as roof coverings. While the stresses in these forms remain relatively low, the deflections are a critical design parameter, and one that must be considered by architects and engineers in the conceptual design phase, meaning the design stage when the scale and form is given to the structure. To-date, there is no closed-form solution that can predict the maximum deflection of umbrellas due to their highly varying and complex geometry. The best option for predicting deflection is via finite element analysis, which is time-consuming for conceptual (preliminary) design purposes. In response, this paper uses machine learning via genetic programming (GP) and gene expression programming (GEP) to develop closed-form equations that predict the maximum corner deflection of N-edged hypar umbrellas – where N = 3, 4, 5, 6, 7, and 8. For a given a boundary condition and material, geometry is the most significant parameter influencing a shell's stiffness; thus, elastic finite element (FE) models use geometric properties as input variables (N, projected area, normalized rise, and shell thickness). The maximum corner deflection is recorded as an output and the FE analyses generate a large dataset of 53,754 results. It is observed that both GP and GEP can effectively parameterize the maximum deflection of N-edged hypar umbrellas, with GEP producing more concise, but relatively less accurate, equations than GP. While the formulations are trained using concrete material, a material factor multiplier transforms the results to other material properties within the assumption of elastic limits. The results of the study can be used to assist with conceptual design of hypar umbrellas and to validate complex FE models of hypar umbrellas. This research also illustrates the use of machine learning techniques as applied to the conceptual design of structures with highly varying geometries.

Reviving Multivalent-Metal Anodes in Simple Salt Electrolytes via Component Modifier Design.

Using combinatory electrolyte blends represents an imperative avenue to achieve good magnesium (Mg)-metal anode compatibility and commercial feasibility in fields of promising rechargeable Mg batteries. However, fundamental challenges of how to manipulate component modifier reactivity on molecule level still remain to be solved. Here, molecular structure design concepts towards seeking bromophenyl complex-based component modifiers has been proposed according to implications of electron-donating and/or electron-withdrawing substituents on Br-C bond dissociation reactivity. Exceptional Mg electro-plating/stripping properties (a stable cycle life of 250 days in Mg//Cu asymmetric cells) have been firstly achieved in a simple salt electrolyte with 1-(3-bromophenyl)-N,N-dimethylmethanamine (BPDMA) as optimal component modifier. Comprehensive analyses disclose the unique electrochemically-active Br-containing ion-pairs formation, such as [(Mg2+)2(TFSI-)Br-]2+ and [(Mg2+)2(TFSI-)(Br-)(G2)2]2+, which results in the much thinner Br- containing and organic-inorganic mixed interphases on Mg-metal anodes. Furthermore, conventional MgSO4-based electrolytes and even calcium (Ca)-ion electrolytes can also be revived by similar strategy, demonstrating its generality and superiority.

An extensive qualitative and quantitative multi criteria analysis for a hybrid renewable energy system applied to tribal zone - based primary health centres, and maximizing the societal parameters

Remote electrification enhances the quality of life quality of people in remote areas, with no access to electricity through distributed coverage of electricity. Due to the irregular and unbalanced fuel cost and impracticable expansion of the grid, hybrid integrated renewable energy sources become dependable substitute for remote electrification. The necessity of uninterrupted power dispatch is a prime factor for primary health centres, located in tribal and remote areas. This article proposes an integrated primary analysis like financial, production, quantity and environmental, applied to an optimum sizing of a hybrid standalone renewable energy source, which might be carried out in eight primary health centres, situated in the Gudalur Zone in Nilgiris District, Tamil Nadu, India. Four different criteria were inspected in this study, as standard loading, boost up loading, step down loading and complete renewable loading. In addition, every criterion was assessed with four kinds of PV tracking arrangements. The peak load requirement of power and energy, for eight primary health centres, was around 121.08 kW and 907.96 kWh/day respectively. HOMER Pro Micro-grid Analysis Tool was used, to analyze the different primary parameters of this study. The foremost financial parameters like COE (Cost of Energy) and NPC (Net Present Cost), could range from 0.102 to 0.118 $ per kWh and from 0.4047 to 0.5708 Million $ respectively. Annual energy production of solar PV could vary from 318.5 to 427.65 MWh. The main quantity parameter like percentage of excess electricity was obtained from 13.3 to 21.5% annually. The leading emission parameters like CO2 and CO were reported to range from 1700 to 4502 and from 7.98 to 28.1 kg per year respectively. Generator and fuel parameters, key properties of energy storage and converter, were also analyzed extensively. In addition, sensitivity analysis and social parameters were also discussed in this study. The result of this work gives a conceptual and flexible design of structure, to make possible the continuous power supply to the remote tribal area - based primary health centres, under in all situations.

Constructing unique dual-functional double-hollow architecture for enhanced high-voltage structural stability of layered oxide cathode

Elevating the working voltage has proven to be an effective strategy for enhancing the energy density of ternary layered cathode materials. However, the accelerated failure of secondary particle structure during high-voltage cycling hinders their practical application. Although some attempts have been exerted to address this issue by designing particle arrangement, these secondary structure modifications only provide the limited help to the structural failure problem. Herein, we focus on the cause and characteristic of secondary particle cracks, investigate their formation principle and development rule, and delicately propose a unique double-hollow secondary structure. The two hollow regions create an environment that facilitates the release of internal strain and reduces stress at grain boundaries, thus ensuring the homogeneous stress distribution within the secondary particles. Thereby, the formation of intergranular crack is effectively mitigated. Additionally, the hollow regions act as barrier layers to impede the crack propagation. The dual functions of this double-hollow structure efficiently maintain the tight connection among these primary particles, greatly boosting the high-voltage cycling stability. The designed material with double-hollow architecture exhibits an obvious capacity retention increase from 67.8 % (conventional structure) to 84.4 % at 1 C within 3.0-4.5 V after 300 cycles. This work demonstrates that the double-hollow structure can effectively address the key issues of crack occurrence and development, providing a novel structural design concept for the exploration of high-voltage cathode materials with superior stability.

Constructability-driven design of frame structures with state-space search methods

In the design of frames and trusses, the relationship between the structural form, the construction sequence, and the structural behavior during construction is rarely systematically considered. This paper proposes a method to systematically consider constructability in design, specifically focusing on minimizing the maximum displacement or stress during construction. The paper presents the formulation of the optimal assembly sequencing problem as a state-space search with a unique design of the search heuristic and constraint bounding schemes. It proposes three variants of heuristic search algorithms for finding a feasible sequence, a diverse set of feasible sequences, and an optimal sequence, respectively. These algorithms are tested on a case study structure to showcase their ability to navigate the combinatorial space of assembly sequences, and provide means for designers to incorporate sequence-related performance into conceptual structural design.

Techno-Economic Assessment of Coaxial HTS HVAC Transmission Cables with Critical Current Grading between Phases Using the OSCaR Tool

In recent years, the scientific and industrial interest regarding alternative technologies for transmission cables has increased. These conductors should efficiently transmit significant amounts of power between grid nodes, which are expected to be particularly congested due to the projected global increase in electricity production. Superconducting cables are considered a promising solution in this context, offering the potential to transmit large amounts of energy with minimal losses and compact dimensions, thereby potentially benefiting the environment. To evaluate the feasibility of integrating superconducting cables into existing grids, techno-economic approaches should be adopted. Such techniques enable the conceptual design of a specific cable structure, allowing users to explore a wide range of operating parameters to derive optimal designs. This paper reports a comprehensive techno-economic analysis of High Voltage Alternating Current (HVAC) cables realized with High-Temperature Superconducting (HTS) tapes, with the aim to transmit extremely high-power level. The optimal coaxial design is selected using Optimization Tool for Superconducting Cable Research (OSCaR) by implementing a graded approach to the critical current of the HTS tapes used for the different phases. This optimization aims to achieve the most effective balance between the cost of the coated conductors and their electrical properties. The whole set of model equations, the user-defined parameters, and the applied constraints are detailed. The OSCaR tool is then applied to assess the impact on the optimized design of the cable system and the corresponding cost indexes of several crucial parameters, such as the maximum transmitted power, the voltage level, and the line length.

Conceptual Design of Compliant Structures for Morphing Wingtips Using Single-Row Corrugated Panels

Morphing wingtips have the potential to improve aircraft performance. By connecting the wingtips and the wings with a compliant structure, a continuous aerodynamic surface can be achieved for a better aerodynamic performance. However, how to maintain the shape-changing capability while keeping a high stiffness to carry aerodynamic loads is a key problem. In this paper, based on asymmetric stiffness, a type of single-row corrugated panel is designed to satisfy the limited space around the wingtip. A finite element model of the single-row corrugated panels is established, and parameter analysis is performed to investigate the impact of the thickness characteristics of the corrugated panel on the folding angle. The corrugated panel is then optimised to find the maximum folding angle. Based on the optimisation results, corrugated panels with asymmetric and symmetric stiffness are fabricated and tested. The results demonstrate that the asymmetric stiffness corrugated panels have the capability to increase the wingtip folding angle.

Topology Optimization with Explicit Components Considering Stress Constraints

Topology optimization focuses on the conceptual design of structures, characterized by a large optimization space and a significant impact on structural performance, and has been widely applied in industrial fields such as aviation and aerospace. However, most topology optimization methods prioritize structural stiffness and often overlook stress levels, which are critical factors in engineering design. In recent years, explicit topology optimization methods have been extensively developed due to their ability to produce clear boundaries and their compatibility with CAD/CAE systems. Nevertheless, research on incorporating stress constraints within the explicit topology optimization framework remains scarce. This paper is dedicated to investigating stress constraints within the explicit topology optimization framework. Due to the clear boundaries and absence of intermediate density elements in the explicit topology optimization framework, this approach avoids the challenge of stress calculation for intermediate density elements encountered in the traditional density method. This provides a natural advantage in solving topology optimization problems considering stress constraints, resulting in more accurate stress calculations. Compared with existing approaches, this paper proposes a novel component topology description function that enhances the deformability of components, improving the representation of geometric boundaries. The lower-bound Kreisselmeier–Steinhauser aggregation function is employed to manage the stress constraint, reducing the solution scale and computational burden. The effectiveness of the proposed method is demonstrated through two classic examples of topology optimization.

Conceptual design and experimental investigation of regolith bag structures for lunar in situ construction

Lunar habitat construction is a critical engineering requirement in lunar exploration missions, characterized by unique structural and material challenges distinct from Earth. To meet the demands of in situ large-scale construction in extreme lunar environments, a general mode of “Prefabricated core module & Inflatable structure &In situ materials structure” is adopted. This work analyzed the structural internal forces and foundation bearing capacity for lunar habitats, highlighting the significance of structural tensile performance and the foundation's allowable bearing capacity. A construction scheme based on regolith bags is proposed, encompassing architectural and structural design, and long-term planning. Multiscale experimental investigations conducted on “material, component, structure, and construction” levels confirm the excellent properties of regolith bag. Aramid fabric and CUG lunar regolith simulant were chosen for material and component testing, focusing on evaluating the regolith bag's performance under tension and compression. Successful construction demonstrations of a regolith bag arch structure and a regolith bag – airbag structural unit validate the feasibility of this construction scheme. Conclusively, the proposed lunar habitat construction scheme based on regolith bag technology provides a viable and efficient method for in situ lunar construction.

In-situ synthesis of Fe3O4@Fe3C nanoparticles with heterostructures embedded in the N-doped porous carbon for high-performance lithium ion batteries

Metal oxides (Fe3O4) have attracted immense attention as high-capacity anode materials for high-performance electrochemical energy storage systems. However, the large structural change and sluggish reaction kinetics in the lithiation and delithiation reactions critically limit their practical development. Here, we design a novel composite consisting of Fe3O4@Fe3C nanoparticles embedded in N-doped porous carbon (Fe3O4@Fe3C-NPC) for lithium ion batteries. Benefiting from the synergistic effect of heterostructures, the Fe3O4@Fe3C-NPC delivers high reversible capacities (911.9 mAh g−1 at 0.2 A g−1, 319.6 mAh g−1 at 5.0 A g−1). The formed heterointerfaces can build an internal electric field, which help to improve reaction kinetics with fast ion diffusion kinetics and low charge transfer resistance. Furthermore, the Fe3O4@Fe3C-NPC//LiFePO4 full cell also displays great performance. The structural design concept and efficient synthesis method in the work can be extended to construct metal oxide/carbide heterostructures for anode materials.

FeP nanoparticle embedded in N,P-doped 3D porous wood-derived carbon aerogel for oxygen reduction reaction

Metal-air batteries require the exploration of affordable electrocatalysts with exceptional catalytic performance for oxygen reduction reactions (ORR). One of the powerful ways to develop highly active and robust oxygen electrocatalysts is to load transition metal compounds onto a highly porous carbon aerogel. Here, we report a cell wall nanoengineering strategy to transform natural balsa wood into a wood-derived carbon aerogel (WCA), following by loading FeP nanoparticles inside the hierarchical N, P-doped WCA for ORR electrocatalysts. Wood nanotechnology is applied to manipulate the microstructure of the porous carbon aerogel with low-tortuosity, multichannel, and aligned pore, which benefits to the electron transportation for boosting the ORR. Under 0.1 M KOH conditions, the initial potential, half wave potential and limit current of FeP@N,P-WCA are 0.95 V, 0.84 V, and 5.20 mA cm−2 respectively, which are much higher than that of untreated wood and comparable to commercial Pt/C. The aqueous Zn-air batteries assembled with this catalyst exhibit a remarkable specific capacity of 775.5 mA h g−1 and better charge-discharge cycling stability. The excellent electrocatalytic activity demonstrated by FeP@N,P-WCA for ORR is attributed to the inherent tri-pathway (lumen, pit, and ray cell) porous structure of wood, the high conductivity and specific surface area of WCA (584.2 m2 g−1), and the highly dispersed FeP nanoparticles. This work provides a structural design concept for achieving high electrocatalytic biobased WCA reactors by combining wood nanotechnology and electrocatalysts chemistry for energy storage and conversion.

Supertough MXene/Sodium Alginate Composite Fiber Felts Integrated with Outstanding Electromagnetic Interference Shielding and Heating Properties.

The development of multifunctional MXene-based fabrics for smart textiles and portable devices has garnered significant attention. However, very limited studies have focused on their structure design and associated mechanical properties. Here, the supertough MXene fiber felts composed of MXene/sodium alginate (SA) fibers were fabricated. The fracture strength and bending stiffness of felts can be up to 97.8 MPa and 1.04 N mm2, respectively. Besides, the fracture toughness of felts was evaluated using the classic Griffith theory, yielding to a critical stress intensity factor of 1.79 . In addition, this kind of felt presents outstanding electrothermal conversion performance (up to 119 °C at a voltage of 2.5 V), high cryogenic and high-temperature tolerance of photothermal conversion performance (-196 to 160 °C), and excellent electromagnetic interference (EMI) shielding effectiveness (54.4 dB in the X-band). This work provides new structural design concepts for high-performance MXene-based textiles, broadening their future applications.

Research Progress on Helmet Liner Materials and Structural Applications.

As an important part of head protection equipment, research on the material and structural application of helmet liners has always been one of the hotspots in the field of helmets. This paper first discusses common helmet liner materials, including traditional polystyrene, polyethylene, polypropylene, etc., as well as newly emerging anisotropic materials, polymer nanocomposites, etc. Secondly, the design concept of the helmet liner structure is discussed, including the use of a multi-layer structure, the addition of geometric irregular bubbles to enhance the energy absorption effect, and the introduction of new manufacturing processes, such as additive manufacturing technology, to realize the preparation of complex structures. Then, the application of biomimetic structures to helmet liner design is analyzed, such as the design of helmet liner structures with more energy absorption properties based on biological tissue structures. On this basis, we propose extending the concept of bionic structural design to the fusion of plant stalks and animal skeletal structures, and combining additive manufacturing technology to significantly reduce energy loss during elastic yield energy absorption, thus developing a reusable helmet that provides a research direction for future helmet liner materials and structural applications.

RuiXue Multi-Hall-Human machine collaboration in reciprocal structures

This article centers on the RuiXue Multi-Hall architectural design project in Chengdu, China, with a specific focus on a comprehensive workflow framework that integrates reciprocal geometric design and digital construction methods, primarily within the context of shell structures. The research expands on the concepts of structural design, adjustments of performance parameters, and the optimization of free-form shells. In addition, it outlines the spatial design approach for the shell structure. The study delves into reciprocal geometric design for the existing shell structure, establishing a library of reciprocal geometric shapes suitable for architectural design. The primary focus is on the application of these shapes to the shell structure, optimizing parameters for several grids within the library, and comparing various design schemes. Furthermore, the article discusses digital construction methods for the existing shell space and reciprocal structure, with a specific emphasis on the material performance of timber components. This discussion includes reciprocal timber structures and 3D-printed roofs for shell surfaces, all guided by a geometric control system to facilitate an interactive design and construction process. This research on reciprocal geometric design and digital construction methods for shell structures holds dual significance. It not only traces the historical development of reciprocal structures but also explores innovative construction methods using digital technology. The establishment of a comprehensive framework for reciprocal geometric design-construction is expected to catalyze innovative breakthroughs in future architectural design, spanning aspects such as space, form, materials, and structure.

Material Research for Hypersonic Travel

The goal of travelling faster than five times the speed ofsound, or hypersonic travel, has enormous potential to transform global transportation, defence capabilities, and space access. However, materials and structures face severe obstacles because to harsh aerothermal conditions inherent in high Mach number trajectories. This work focuses on new approaches to do research for ceramics, composites, and refractory alloys that are essential for building hypersonic vehicles. Essential design concepts for primary structures, heat shielding, and propulsion systems are covered, highlighting the critical role that theory and computation play in comprehending the links between structure, property, and processing. The remarkable high-temperature capabilities, stiffness, strength, and corrosion resistance of ceramic materials are highlighted in the study as reasons for theirincreasing importance in aircraft applications. Based on their distinct features, titanium alloys, nickel aluminides, metal- matrix composites, carbon-carbon, and ceramic-matrix composites stand out as top choices for a high temperature. In pursuit of lightweight, high- performance materials for hypersonic travel, this paper summarises ongoing researchefforts, evaluates the state of the art, offers insights into technological hurdles, and identifies areas that require future improvement. To explore the complex field of hypersonicmaterials design and selection in this research, this paper hope to shed light on the critical role that materials science plays in pushing the boundaries of aerospace technology by investigating the special difficulties presented by hypersonic flight as well as the characteristics and potential of various material classes.

Structural Design and Energy and Environmental Applications of Hydrogen-Bonded Organic Frameworks: A Systematic Review.

Hydrogen-bonded organic frameworks (HOFs) are emerging porous materials that show high structural flexibility, mild synthetic conditions, good solution processability, easy healing and regeneration, and good recyclability. Although these properties give them many potential multifunctional applications, their frameworks are unstable due to the presence of only weak and reversible hydrogen bonds. In this work, the development history and synthesis methods of HOFs are reviewed, and categorize their structural design concepts and strategies to improve their stability. More importantly, due to the significant potential of the latest HOF-related research for addressing energy and environmental issues, this work discusses the latest advances in the methods of energy storage and conversion, energy substance generation and isolation, environmental detection and isolation, degradation and transformation, and biological applications. Furthermore, a discussion of the coupling orientation of HOF in the cross-cutting fields of energy and environment is presented for the first time. Finally, current challenges, opportunities, and strategies for the development of HOFs to advance their energy and environmental applications are discussed.