Sediment Concentration Research Articles

Spatiotemporal variations of domoic acid: New findings in the sedimentary environment of a typical nearshore mariculture bay, China

Domoic acid (DA) is a neurotoxin produced by marine microalgae. It tends to accumulate in marine shellfish and fish, posing a threat to aquaculture and seafood consumers’ health. In this study, DA in the surface and bottom seawater, sediment, and porewater of the Jiaozhou Bay, a typical mariculture bay in China, was systematically investigated for the first time over different seasons. Surprisingly, a high concentration of DA was discovered in the marine sediment porewater (maximum detected concentration: 289.49 ng/L) for the first time. DA was found to be extensively distributed in the water body and sedimentary environment of the Jiaozhou Bay. DA in the surface and bottom seawater of Jiaozhou Bay in spring was uniformly distributed, whereas DA showed obvious spatial variations in summer and winter. The high concentration areas of DA are located in the north of Jiaozhou Bay and decreased to the south areas. DA was also distributed in the sediment (spring mean: 316.57 ng/kg; summer mean: 10.22 ng/kg; winter mean: 237.08 ng/kg) and porewater (spring mean: 129.70 ng/L; summer mean: 53.54 ng/L; winter mean: 19.90 ng/L) of Jiaozhou Bay. The DA concentrations in the surface sediment and porewater were higher in the spring than in the winter and summer, contrary to the seasonal variation pattern observed in the surface and bottom seawater. The DA concentration in porewater was significantly higher than in the surface and bottom seawater, indicating that the risk of pollution contamination from DA to benthic fishery organisms may be underestimated. Overall, DA is widely distributed in the seawater and also in the benthic environment of Jiaozhou Bay and exhibited potential harm to fishery organisms varied greatly with seasons. It is an important discovery for marine algae toxins and has important guiding significance and important indicative role for the routine monitoring and management of DA pollution in water and benthic environment.

Decadal-scale decay of landslide-derived fluvial suspended sediment after Typhoon Morakot

Abstract. Landslides influence fluvial suspended sediment transport by changing sediment supply and grain size, which alter suspended sediment concentrations and fluxes for a period of time after landsliding. To investigate the duration and scale of altered suspended sediment transport due to landsliding, we analyzed suspended sediment concentration and water discharge measurements at 87 gauging stations across Taiwan over an 11-year period after Typhoon Morakot, which generated nearly 20 000 landslides in 2009. At each gauging station, we computed annual rating curves to quantify changes over time in the sensitivity of suspended sediment concentrations to water discharge. Among the 40 stations in basins that were impacted by landsliding, the discharge-normalized rating curve coefficient ã was higher than that before Morakot by a factor of 5.1±1.1 (mean ± standard error) in 2010, the first year after Morakot. The rating curve exponent b did not decrease at most stations until a year later (2011), when the average b value was lower than that before Morakot by 0.25±0.05. Across the compilation of gauging stations, post-Morakot changes in discharge-normalized sediment concentration (ã) were positively correlated with landslide intensity for 7 years after Morakot, while post-Morakot changes in the exponent of the discharge–concentration relationship (b) were negatively correlated with landslide intensity from 2011 to 2014. This reflects a tendency for larger changes in ã and b to occur in basins with more intense landsliding. At 26 of these 40 stations, elevated values of ã declined after the initial post-Morakot peak, consistent with a gradual return to pre-Morakot suspended sediment transport conditions. Exponential regressions to these ã values reveal a median characteristic decay time of 8.8 years (interquartile range: 5.7–14.8 years). Values of ã increased more and declined faster in basins with more intense landsliding, with a mean characteristic decay time of 6 years in the basins hit hardest by landsliding. Furthermore, changes in ã and b tended to be larger in basins with more intense landsliding. At stations that were not impacted or only minimally impacted by landsliding, neither ã nor b exhibited systematic responses to Morakot. To quantify the effect of landsliding on sediment discharge, we compared the measured sediment discharges after Morakot to the hypothetical sediment discharges that would have occurred if Morakot had induced no landslides, calculated by applying each station's pre-Morakot rating curve to its post-Morakot water discharge history. This analysis suggests that Morakot-induced landsliding increased sediment discharge by as much as > 10-fold in some basins in the 1–2 years after Morakot. Together, these results indicate that the influence of Morakot-induced landsliding on rating curves was large shortly after Morakot but diminished in less than a decade in most of the study rivers and will be imperceptible in another few decades in all of the study rivers. To the extent that these results are applicable to other landscapes, this suggests that periods of elevated sediment transport efficiency after landsliding should persist for years to decades, even if the landslide deposits persist for centuries to millennia.

Modelling of Granular Sediment Transport in Steady Flow over a Mobile Sloped Bed

This paper introduces a three-layer system, proposing a comprehensive model of granular mixture transport over a mobile sloped bed in a steady flow. This system, consisting of the bottom, contact, and upper zones, provides complete, continuous sediment velocity and concentration vertical profiles. The aim of this study is to develop and experimentally verify this model for sediment transport over a bottom locally sloping in line with or opposite the direction of sediment flow. The model considers gravity’s effect on sediment transport in the bottom (dense) layer when the component of gravity parallel to the bottom acts together with shear stresses associated with water flow. This is a crucial factor often overlooked in previous studies. This effect causes an increase in velocity in the mobile sublayer of the dense layer and significantly affects the vertical distributions of velocity and concentration above this layer. The proposed shear variation due to the interaction between fractions and an intensive sediment mixing and sorting process over a mobile sloped bed adds to the novelty of our approach. The data sets used for the model’s validation cover various conditions, including slopes, grain diameters, densities, and grain mobility conditions, from incipient motion to a fully mobilized bed. This extensive validation process instils confidence in the theoretical description and its applicability to real-world scenarios in the design of hydraulic infrastructure, such as dams, barrages, bridges, and irrigation, and flood control systems.

Study on Key Properties and Model Establishment of Innovative Recycled Aggregate Pervious Concrete.

In order to meet the needs of low-impact development and sustainable development, there is an urgent desire to develop an innovative recycled aggregate pervious concrete (I-RAPC) that is of high strength and permeability. In this study, I-RAPC was prepared based on response surface methodology (RSM) using recycled aggregate, river sand, and different types of pipes as the materials, and the effects of different pipe parameters (number, diameter, material, and distribution form) on the performance of I-RAPC were investigated. In addition, the calculation model of the compressive strength and the permeability coefficient of I-RAPC were proposed. The results showed that the frontal- and lateral-compressive strengths of I-RAPC were 39.8 MPa and 42.5 MPa, respectively, when the pipe material was acrylic, the position was 1EM, and the diameter was 10 mm-at which time the permeability coefficient was 3.02 mm/s, which was the highest in this study. The maximum relative errors of the compressive strength calculation model and the permeability coefficient calculation model were only 7.52% and 4.42%, respectively, as shown by the post hoc test. Therefore, I-RAPC has the advantages of high strength and permeability and is expected to be applied in low-impact development in cities with heavy surface sediment content and rainfall.

The dynamics of heavy metals and metalloids accumulation in oxbow bottom sediments of the Sok River

The article analyzes the dynamics of heavy metals (V, Cr, Mn, Co, Ni, Cu, Zn, Rb, Sr, Cd, Pb) and metalloids (As, Se) accumulation in the bottom sediments of the low-flow oxbow of the Sok River. This oxbow was formed as a result of the Saratov reservoir creation and located within the Krasnoglinsky District of the Samara city. The study was conducted in 2021 and 2022. Four trial plots were established in the oxbow of the river; the control plot was a sample area allocated in the Saratov reservoir, in the immediate vicinity of the oxbow. The quantitative determination of heavy metals and metalloids content in bottom sediments was carried out using inductively coupled plasma spectrometry. The results obtained showed that specific conditions arise in each research period that affect the studied elements accumulation in the oxbow bottom sediments. These processes are influenced by the location of the sample plot in the oxbow, the flow degree, the spring flood nature, the anthropogenic transformation and the overgrowth of Typha angustifolia L. For all sample plots located in the oxbow, higher concentrations of most of nalyzed elements were detected in 2022. Heavy metals and metalloids accumulated especially actively in the bottom sediments of sample plot 4, located in the oxbow behind an artificial dam and characterized by the weakest flow. The soil cover of Samara city posesses weak and moderate effect on the quantitative characteristics of metal accumulation in the oxbow bottom sediments. Compared to the control, the studied elements accumulated more actively in the bottom sediments of all oxbow sample areas, which confirms the accumulative nature of river oxbow of varying degrees of isolation.

Development of a Spectrum-Based Scheme for Simulating Fine-Grained Sediment Transport in Estuaries

Fine-grained cohesive sediments in estuaries play a critical role in sediment transport and biogeochemical cycles in estuaries. Due to the convergence of marine saltwater and freshwater runoff, combined with periodic tidal cycles, fine-grained sediments exhibit intricate flocculation processes that are challenging to simulate. A size-resolved flocculation module using a bin-based scheme aids in modeling these processes but is hindered by high computational costs. In this study, we develop a new spectrum-based scheme based on the spectral shape of floc size distribution from the original bin-based scheme to expedite modeling execution. This new scheme is implemented in the Stony Brook Parallel Ocean Model (sbPOM) and applied to simulate fine-grained sediment transport in the Hudson River estuary. The effectiveness of this spectrum-based scheme is assessed by comparing its simulations with observations and results from the original bin-based scheme. The findings indicate that the new scheme can simulate the evolution of suspended sediment concentration well at a specific point by comparisons with in-situ observations. Specifically, the results of the 50 paired experiments show an average percentage difference of 1.86% and an average speedup ratio of 4.51 times compared to the original bin-based scheme. In summary, the new spectrum-based scheme offers significant acceleration benefits for the size-resolved flocculation module and has the potential for widespread application in simulating fine-grained sediments in estuaries.

Comprehensive risk assessment of microplastics in tidal channel sediments in amazonian mangroves (northern Brazil)

Pollution by microplastics (MPs) in mangroves is a growing concern, given its potential ecological and human health impacts. The characteristics of microplastic pollution and a risk assessment of MPs in the Amazon region's coastal sediments are still insufficient, and information about MP pollution in the benthic component of the mangrove ecosystem is lacking. We analyzed MP concentrations in the surface sediment of 9 stations in three tidal channels along the Ajuruteua Peninsula connected to the Caeté River estuary, aiming to assess the hazard level on the environment based on the Pollution Load Index (PLI). Raman and Fourier transform infrared spectroscopy determined the MP's chemical composition. The results showed that the abundance of sediment MPs ranged from 100 to 1200 items kg−1, with an average of 433 ± 261.6 items kg−1. The MPs were mainly composed of transparent and blue fragments and fibers, ranging in size from 100 to 5000 μm. Six types of polymers were identified, including alkyd varnish (AV), resin dispersion (RD), chlorinated polyethylene (CPE), polyethylene-polypropylene (PE-PP), low-density polyethylene (LDPE), and hostaperm blue (HB). Hydrodynamic processes within estuaries and tidal channels play a crucial role in explaining the concentrations found, as circulation determines the pattern of sediment deposition and the particles adhered to it. PLI risk assessment showed that all sampling sites were at hazard level I: a low level of contamination in the mangrove sediments. However, a more comprehensive and systematic monitoring campaign is needed to expand our knowledge about pollution and contamination by MPs in Amazon mangrove areas.

Distribution and accumulation of UV filters (UVFs) and conservation status of Posidonia oceanica seagrass meadows in a prominent Mediterranean coastal tourist hub

This study investigates the presence and impact of UV filters in Posidonia oceanica meadows in Formentera, a Mediterranean tourist hotspot. It highlights the distribution of inorganic (TiO2 and ZnO) and organic UV filters (UVFs) in different environmental matrices, their accumulation in seagrass tissues and their impact on the seagrass health.In the overlying and canopy waters of P. oceanica, Zn concentrations surpassed Ti, with three organic UVFs (benzophenone-3 [BP-3], avobenzone and homosalate [HMS]) consistently detected. Ti concentrations were generally higher than Zn in rhizosphere sediments, along with recurrent presence of octocrylene, HMS, 2-ethylhexyl methoxycinnamate (EHMC), and 4-methylbenzylidene camphor (4-MBC). Maximum Zn concentrations were found in canopy waters (3052.9 ng L−1). Both Ti and Zn were found in all P. oceanica tissues and leaf epiphytes across all study sites. Additional UVFs like octocrylene, avobenzone, and BP-8 were also detected in P. oceanica tissues and epiphytes. Elevated levels of octocrylene in leaf epiphytes (2112.1 ng g−1 dw) and avobenzone in leaves (364.2 ng g−1 dw) and leaf epiphytes (199.6 ng g−1 dw) were observed in the Port of La Savina, the island's main entry port. Octocrylene concentrations (up to 2575 ng g−1 dw) in rhizosphere sediments near sewage discharge points exceeded reported maxima, highlighting wastewater treatment plants as significant sources of organic UVFs. Correlational analyses suggested that the accumulation of octocrylene, avobenzone, and BP-3 negatively impacted P. oceanica's conservation status, affecting global density, density at 100 % cover, and leaf morphometry. Positive correlations were observed between leaf polyphenols (antioxidants) and concentrations of avobenzone, benzophenone-8 (BP-8), and BP-3, indicating potential oxidative stress induced by UVFs in P. oceanica.Our study underscores the pervasive presence of UV filters in P. oceanica habitats, with implications for seagrass health and conservation, especially in areas of high tourism and sewage discharge.

Sources of nutrients fuelling post-flood phytoplankton biomass in a subtropical bay

Extreme rainfall from an ex-tropical cyclone caused a major flood event in the Logan River system in southeast Queensland, Australia. This resulted in a significant flood plume, containing nutrients and sediment, being discharged into the adjacent estuary/Bay system. The spatial extent of higher phytoplankton biomass (Chl a) matched the distribution of higher nutrient and sediment concentrations post-flood, suggesting nutrients fuelled phytoplankton production. Particulate nitrogen (PN) constituted over 50 % of total nitrogen in floodwaters, with lower proportions of dissolved inorganic nitrogen (DIN) and phosphate (PO4-P). Phytoplankton utilised DIN rapidly but may have maintained growth due to the release of ammonia from suspended sediments and microbial mineralisation of particulate organic nitrogen. Ammonia release from intertidal sediments contributed minimally (0.85 %) to daily phytoplankton nitrogen demands. Our study highlights the need to understand the fate of particulate nitrogen in coastal systems and its role in stimulating phytoplankton growth.

Contamination status, source analysis and exposure assessments of quinolone antibiotics in the south of Yancheng Coastal Wetland, China.

Yancheng coastal wetland, the largest coastal wetland in the west coast of the Pacific Ocean and the margin of the Asian continent, has significant environmental, economic and social effects on local human beings. The extensive contamination and potential risk of quinolone antibiotics (QNs) on local aquaculture and human health are still not clear until now. In this study, 52 surface sediment samples were collected to investigate the contamination status and polluted sources, and evaluate ecological risks of QNs in the south of Yancheng coastal wetland. The total contents of QNs ranged from 0.33 to 21.60ng/g dw (mean value of 4.51ng/g dw), following the detection frequencies of QNs ranging from 19.23 to 94.23%. The highest content of QNs occurred around an aquaculture pond dominated by flumequine. The total organic carbon contents of sediment were positively correlated with sarafloxacin and lomefloxacin (p < 0.05), indicating the enhanced absorption of these QNs onto sediments. Partial QNs, such as lomefloxacin, enrofloxacin, sarafloxacin and flumequine, presented the homology features originating from the emission of medical treatment and aquaculture. There was no potential risk of QNs to human beings but a potential risk to aquatic organisms (algae > plant > invertebrate). Totally, the management and protection of Yancheng coastal wetland should be of concern with aquaculture as the important industry.

Analyzing the adjustment mechanism of daily sediment content under large reservoir operations

Adjustment of daily discharge and sediment content in the Lower Jinsha River Basin has changed dramatically. However, the adjustment mechanism of daily sediment content under reservoir operation remains unclear. The Double Mass Curve (DMS) method was used to divide different periods of daily discharge-sediment content relationship change, and the Flow Duration Curve (FDC) was used to calculate the energy dissipation of streamflow by reservoirs. With the operation of large reservoirs, the average flood discharge and its proportion significantly decreased. With the variation in flow regime, the quantile relationship and Lower boundary relationship of daily discharge and sediment content both showed a downward trend, from 1999 to 2019. Under different periods, adjustment of the cross-flow profile was decreased with larger daily discharge, which was characterized by the ratio of sediment content to the lower boundary. An improved flow duration curve method was proposed to calculate the energy dissipation of streamflow. We discovered a novel model between the relative reduction of sediment content and relative energy dissipation of the daily discharge regime, with a good fitness of 0.97. In this study, the effect of the flow regime constructed on sediment content change was emphasized. It is helpful to evaluate the sediment reduction of the total basin caused by reservoirs.

Enrichment pattern of tungsten in sediments under methane seepage environments: Applicability as a proxy for tracing and reconstructing (paleo-)methane seepage

The release of hydrogen sulfide by sulfate-driven anaerobic oxidation of methane (SD-AOM) during methane seepage activities has a strong impact on the evolution of marine redox conditions and the cycles of redox-sensitive elements (e.g. Mo and U). Consequently, the sedimentary enrichment or depletion of these elements is often used to trace and reconstruct (paleo-)methane seepage activity. In recent years, tungsten (W) has shown promise as an indicator of marine redox changes, but its applicability to trace methane seepage activity is unknown. This study identified significant differences in the W content of sediments in methane seepage environments compared to suboxic environments not influenced by methane seepage and oxic environments in the South China Sea. The sediments subjected to methane seepage were characterized by low W contents, similar to those of euxinic Black Sea sapropels. It is believed that the sulfidic environment resulting from SD-AOM is the primary cause of W depletion in sediments subjected to methane seepage. By examining W's interaction with its twin element, Mo, we present WMo enrichment patterns in various environments. In methane seepage environment (sulfidic environments), sediments had high MoEF (> 10) and low WEF (< 2) with a high Mo/W molar ratio (> 10); in suboxic environments not influenced by methane seepage, sediments exhibited a WMo enrichment pattern similar to the UCC (the MoEF and WEF values are predominantly below 1 and 2, respectively, with a low Mo/W molar ratio, <1.5); in oxic environments (enrichment of FeMn (oxy)hydroxides), sediments exhibited high MoEF (2 < MoEF < 10) and high WEF (> 2), with a medium Mo/W molar ratio (1.5–10). This further indicates that the Mo/W molar ratio has great potential in tracing and reconstructing (paleo-)methane seepage activities.

Evaluating the quality of sediments in streams draining contrasting land-use areas in Osogbo metropolis, southwestern Nigeria.

The attendant effects of urbanization on the environment and human health are evaluable by measuring the potentially harmful element (PHE) concentrations in environmental media such as stream sediments. To evaluate the effect of urbanization in Osogbo Metropolis, the quality of stream sediments from a densely-populated area with commercial/industrial activities was contrasted with sediments from a sparsely-populated area with minimal anthropogenic input.Forty samples were obtained: 29 from Okoko stream draining a Residential/Commercial Area (RCA, n = 14) and an Industrial Area (IA, n = 15), and 11 from Omu stream draining a sparsely-populated area (SPA). The samples were air-dried, sieved to < 75 micron fraction, and analysed for PHEs using inductively-coupled plasma atomic emission spectrometry (ICP-AES). Index of geoaccumulation (Igeo), pollution index (PI), ecological risk factor (Er) and index (ERI) were used for assessment. Inter-elemental relationships and source identification were done using Pearson's correlation matrix and principal component analysis (PCA).PHE concentrations in the stream sediments were RCA: Zn > Pb > Cu > Cr > Sr > Ni > Co, IA: Zn > Cr > Ni > Co > Pb > Cu > Sr and SPA: Zn > Co > Cr > Cu > Sr > Ni > Pb. Igeo calculations revealed moderate-heavy contamination of Cu, Pb and Zn in parts of RCA, moderate-heavy contamination of Zn in IA while SPA had moderate contamination of Co and Zn. PI values revealed that stream sediments of RCA are extremely polluted, while those of IA and SPA are moderately and slightly polluted, respectively.The pollution of the stream sediments in RCA and IA is adduced to anthropogenic activities like vehicular traffic, automobile repairs/painting, blacksmithing/welding and metal scraping. In SPA however, the contamination resulted from the application of herbicides/fertilizers for agricultural purposes.

Vegetation‐Generated Turbulence Does Not Impact the Erosion of Natural Cohesive Sediment

AbstractPrevious studies have demonstrated that vegetation‐generated turbulence can enhance erosion rate and reduce the velocity threshold for erosion of non‐cohesive sediment. This study considered whether vegetation‐generated turbulence had a similar influence on natural cohesive sediment. Cores were collected from a black mangrove forest with aboveground biomass and exposed to stepwise increases in velocity. Erosion was recorded through suspended sediment concentration. For the same velocity, cores with pneumatophores had elevated turbulent kinetic energy compared to bare cores without pneumatophores. However, the vegetation‐generated turbulence did not increase bed stress or the rate of resuspension, relative to bare cores. It was hypothesized that the short time‐scale fluctuations associated with vegetation‐generated turbulence were not of sufficient duration to break cohesion between grains, explaining why elevated levels of turbulence associated with the pneumatophores had no impact on the erosion threshold or rate.

Effect of typhoon on suspended sediment concentration, bed erosion and sediment transport in the Yangtze Estuary

Annually 5–6 typhoons strike the Yangtze Estuary (YE) as extreme events. However, their high energy and importance for sediment transportation and geomorphic changes are still not fully understood. In this study, high-resolution observations of wind, wave, flow velocity, and suspended sediment concentration (SSC) at two in-situ stations were carried out during the 2022 Hinnamnor typhoon. Additionally, we simulated the change in SSC, estuarine bed erosion/deposition, and flow and sediment transport with and without a typhoon in the YE using MIKE3 numerical model. The findings revealed that the Hinnamnor typhoon-induced waves increased the SSC of the turbidity maximum zone (TMZ) by a factor of 5.6 times (maximum is 2.8 kg/m3). The TMZ area also extended by 2.68 times (maximum is 7880km2, 70.4% of YE) in the YE. Moreover, the typhoon caused a dramatic change in sediment transport and bed erosion/deposition in the YE. First, in the delta front area where the mean water depth is >5 m, the typhoon significantly increased the southward flux of residual flow and sediment, causing sediment transport into Hangzhou Bay to abruptly increase 26.3 times (increase of 52 million tons, accounting for 1/3 of the present annual flux of the Yangtze River (150 million tons)) during a single spring-neap period. The net erosional area and volume extended to 6770km2 (60.4% of YE) and 91.18 × 106 m3. Second, in the delta shoals (where the mean water depth is <5 m, including east Chongming Shoal, Hengsha Shoal, Jiuduansha Shoal, and east-south Nanhui Shoal), residual flow and sediment flux decreased northward from the typhoon and resulted in the erosion of the shoal. Third, in channels with trumpet-shaped mouths (North Branch (NB), North Channel (NC) and South Passage (SP), except for North Passage (NP)), the upward flux of residual flow and sediment increased due to the typhoon, resulting in bed deposition in these channels (NB, NC and SP). This study highlights the important influence of typhoons on flow and sediment transport and bed erosion in estuarine areas.

Soil hydro-physical variables and crop residues determinate runoff, soil loss, and glyphosate and AMPA concentration in the aqueous phase under simulated rainfall events.

Soil structural degradation and water erosion processes were observed even in no-tillage schemes in the Pampas region. Within these conservation systems, agrochemical application per hectare is one of the highest globally. Thus, this entails a serious risk of water contamination. The objectives of this study were to (1) test the hypothesis that the hydrological dynamics and sediment concentration related to surface runoff were conditioned by soil structure regardless of the presence of maize (Zea mays L.) crop residue and (2) assess the incidence of maize crop residue on glyphosate and aminomethylphosphonic acid (AMPA) concentration in runoff. The soil under study corresponded to Arroyo Dulce Series (Typic Argiudoll silty loam soil). Rain simulations were performed in the laboratory on undisturbed soil samples. Total runoff and infiltration rate were similar between treatments with C(+) and without C(-) maize crop residues (C(+) 1381.40mL and 14.27mm h-1, C(-): 1529.70mL and 21.67mm h-1). The C(-) treatments showed a higher sediment concentration than C(+) (1.58 and 0.42g 100mL-1, respectively). Glyphosate and AMPA average values in runoff were 15.9 and 33.9µg L-1. High variability of the hydro-physical properties and occurrence of soil structure, particularly platy ones, were detected. The hydrological variables were conditioned mainly by the occurrence of platy structures regardless of crop residue presence. Glyphosate concentration was increased in the first runoff event by the presence of corn residues, while AMPA concentrations were higher in the second runoff event in both residue treatments. In this study, maize residue on the soil surface protected the soil from sediment detachment but did not change runoff or infiltration. Thus, the implementation of agricultural management practices that promote vegetative residue cover has shown positive results to erosion.

Spatial heterogeneity, sediment-water exchange, and diffusion mechanisms of organophosphate esters from river to coastal aquatic system in a typical economic circle of northern China

Organophosphate esters (OPEs) have proven to be pervasive in aquatic environments globally. However, understanding their partitioning behavior and mechanisms at the sediment-water interface remains limited. This study elucidated the spatial heterogeneity, interfacial exchange, and diffusion mechanisms of 14 OPEs (∑14OPEs) from river to coastal aquatic system. The transport tendencies of OPEs at the sediment-water interface were quantitatively assessed using fugacity methods. The total ∑14OPEs concentrations in water and sediments ranged from 154 ng/L to 528 ng/L and 2.41 ng/g dry weight (dw) to 230 ng/g dw, respectively. This result indicated a descending spatial tendency with moderate variability. OPE distribution was primarily influenced by temperature, pH, and dissolved oxygen levels. As the carbon atom number increased, alkyl and chlorinated OPEs transitioned from diffusion towards the aqueous phase to equilibrium. In contrast, aryl OPEs and triphenylphosphine oxide, which had equivalent carbon atom counts, maintained equilibrium throughout. Diffusion trends of individual OPE congener at the sediment-water interface varied at the same total organic carbon contents (foc). As the foc increased, the fugacity fraction values for all OPE homologs showed a declining trend. The distinct molecular structure of each OPE monomer might lead to unique diffusive behaviors at the sediment-water interface. Higher soot carbon content had a more pronounced effect on the distribution patterns of OPEs. The sediment-water distribution of OPEs was primarily influenced by total organic carbon, sediment particle size, dry density, and moisture content. OPEs displayed the highest sensitivity to fluctuations in ammonium and dissolved organic carbon. This study holds significant scientific and theoretical implications for elucidating the interfacial transport and driving forces of OPEs and comprehending their fate and endogenous release in aquatic ecosystems.

Distribution Characteristics and Risk Assessment of Organophosphates in Water and Sediment in Dongting Lake

Organophosphates （OPEs） are widely used as flame retardants and additives and thus are commonly detected in the environment. In order to explore their environmental behavior, the concentrations of 13 OPEs in the surface water and sediment of Dongting Lake were analyzed using UPLC-MS/MS. The results showed that 11 OPEs were detected, with detection frequencies of 5.26%-100% and 58.3%-100%, and the concentrations of OPEs were 2.06-2 028 ng·L-1 and 19.6-2 232 ng·g-1 in water and sediment, respectively. Overall, contamination concentrations were ranked in descending order as follows： inflowing rivers, lake area, and outlet, whereas the spatial distribution of concentrations in sediment was inversely proportional to hydrodynamics. The concentration of OPEs in Dongting Lake was at a high level compared with that of domestic and foreign lakes. Among the detected 11 OPEs, tri-iso-butyl phosphate （TnBP） and （TiBP） were dominant in water, accounting for 52.3% and 22.4% of ∑OPEs, respectively. TPhP was the dominant OPEs in sediment, accounting for 31.2% of ∑OPEs. The correlation and principal component analysis indicated that OPEs pollution in Dongting Lake was mainly affected by industrial production emissions, fishery aquaculture, and atmospheric deposition. The assessment results of the risk entropy showed that most of the detected OPEs in water had relatively low ecological risks, whereas the ecological risk of 2-ethylhexyl diphenyl phosphate （EHDPP） at some sampling points requires further attention.

Spatiotemporal variation of sterols in sediment as markers of primary production and ocean sewage dumping in the southwestern East Sea (Japan Sea)

The sedimentation of organic carbon in the Ulleung Basin, in the southwestern East Sea (Japan Sea) was investigated using radiocarbon and sterols. The accumulation rates of organic carbon and the contents of brassicasterol and dinosterol were higher on the slope than in the central basin, reflecting the surface water productivity, whereas cholesterol showed similar or higher contents in the central basin. The coprostanol concentration in surface sediments reflected the dispersion of sewage dumped in this region. The vertical distribution showed that the coprostanol concentration was the highest in the top 5-cm layer near the Korea Strait, close to one of the two dumping sites. A high coprostanol concentration was also found near the coast further north, where the content peaked at ∼10 cm depth. The vertical distribution of coprostanol helped to estimate the sediment accumulation rate at sites where radiocarbon gradient was too small or the values were too variable.

Arsenic distribution characteristics and release mechanisms in aquaculture lake sediments

It is well known that aquaculture can alter the microenvironments of lakes at sediment-water interface (SWI). However, the main mechanisms underlying the effects of aquaculture activities on arsenic (As) transformations are still unclear. In this context, the present study aims to investigate the variations in the sediment As contents in Yangcheng Lake, as well as to assess its chemical transformations, release fluxes, and release mechanisms. The results showed substantial spatial differences in the dissolved As concentrations in the sediment pore water. The As release fluxes at the SWI ranged from 1.32 to 112.09 μg/L, with an average value of 33.68 μg/L. In addition, the highest As fluxes were observed in the aquaculture areas. The transformation of crystalline hydrous Fe oxide-bound As to adsorbed-As in the aquaculture lake sediments increased the ability of As release. The Partial least squares path modeling results demonstrated the great contributions of organic matter (OM) to the As transformations by influencing the sediment microbial communities and Fe/Mn minerals. The changes in the As fractionation and competing adsorption increased the dissolved As concentrations in the 0–10 mm surface sediment. Non-specifically and specifically adsorbed As were the major sources of dissolved As in the sediments. Specifically, microbial reduction of As[V] and dissolution of Fe oxides increased the dissolved As concentrations at the SWI (20 to −20 mm). The results of the current study highlight the positive enhancement effects of aquaculture on As release from sediments.