Concentrations Of Ozone-depleting Substances Research Articles

Signs of Slowing Recovery of Antarctic Ozone Hole in Recent Late Winter–Early Spring Seasons (2020–2023)

Every year since the early 1980s, the ozone hole has appeared in late winter/spring over Antarctica. The ozone hole is expected to disappear due to the observed decrease in the concentration of ozone-depleting substances in the stratosphere, which is enforced by the 1987 Montreal Protocol and its subsequent amendments. However, large ozone holes have appeared four years in a row (2020–2023), which may be a signal that Antarctic ozone repair has stopped. Statistical analyses of ozone hole metrics (hole area, minimum total column ozone, ozone mass deficit, and ozone mass deficit per unit area of the hole) are presented to determine how adding the data from these years changes the ozone recovery pattern. Statistically significant trends in the hole metrics were revealed for the short period (2000–2019) but not for the longer period (2000–2023). The modeled time series of metrics from multiple regressions with standard chemical and dynamic explanatory variables indicate that the recovery has slowed since around 2010. Moreover, a sequence of extreme events (wildfires in Australia in the summer of 2019/2020 and the eruption of the Hunga Tonga volcano in January 2022) may have caused additional ozone losses in Antarctica that masked the repair of polar ozone for a while.

Formulation of the cosmic ray–driven electron-induced reaction mechanism for quantitative understanding of global ozone depletion

This paper formulates the cosmic ray-driven electron-induced reaction as a universal mechanism to provide a quantitative understanding of global ozone depletion. Based on a proposed electrostatic bonding mechanism for charge-induced adsorption of molecules on surfaces and on the measured dissociative electron transfer (DET) cross sections of ozone-depleting substances (ODSs) adsorbed on ice, an analytical equation is derived to give atmospheric chlorine atom concentration: [Formula: see text] where Φe is the prehydrated electron (epre-) flux produced by cosmic ray ionization on atmospheric particle surfaces, [Formula: see text] is the surface coverage of an ODS, and ki is the ODS's effective DET coefficient that is the product of the DET cross section, the lifetimes of surface-trapped epre- and Cl-, and the particle surface area density. With concentrations of ODSs as the sole variable, our calculated results of time-series ozone depletion rates in global regions in the 1960s, 1980s, and 2000s show generally good agreement with observations, particularly with ground-based ozonesonde data and satellite-measured data over Antarctica and with satellite data in a narrow altitude band at 13 to 20 km of the tropics. Good agreements with satellite data in the Arctic and midlatitudes are also found. A previously unreported effect of denitrification on ozone loss is found and expressed quantitatively. But this equation overestimates tropospheric ozone loss at northern midlatitudes and the Arctic, likely due to increased ozone production by the halogen chemistry in polluted regions. The results render confidence in applying the equation to achieve a quantitative understanding of global ozone depletion.

A commentary of “Antarctic ozone layer is gradually recovering” in 10 remarkable discoveries from 2020 in Nature

In the mid-1980s, scientists discovered a spring atmospheric ozone hole over Antarctica, revealing the threat of human-made ozone-depleting substances to the atmosphere. The Antarctic ozone hole located 10 to 20 km above sea level, also affects the circulation of the atmosphere in the southern hemisphere, which in turn affects the global climate. One of its most noticeable effects is that the westerly jet in summer begins to move to the poles. The westerly jet is a planetary-scale atmospheric circulation phenomenon; there are several jet zones on the Earth. The 1987 Montreal Protocol and its subsequent amendments banned the production and use of ozone-depleting substances. Therefore, the concentration of ozone-depleting substances in the atmosphere is declining, and the ozone layer has shown preliminary signs of recovery. The study by Banerjee et al. pointed out that ozone hole-related effects on circulation and climate have ceased since the ozone layer began to recover [1]. While others had noticed this trend of cessation of ozone hole effects before, Banerjee and others officially attributed it to the impact of the Montreal Protocol for the first time.①①Original source in Chinese: Wenshou Tian, Antarctic ozone layer is gradually recovering, Bulletin of National Natural Science Foundation of China. 35 (2) (2021) 237-238

Квазидвухлетние осцилляции зонального ветра в экваториальной стратосфере и их влияние на межгодовые изменения мощности озоновой дыры в Антарктике

The Antarctic ozone hole is observed annually in spring due to the complex influence of photochemical and dynamical processes. The increased concentration of ozone-depleting substances in the atmosphere causes a long-term negative trend in total ozone (TO). Intense interannual fluctuations in TO against a background of the long-term trend associated with dynamic atmospheric processes do not allow assessing definitely the direction of the trend (growth/decline) in the recent years. Studying the dependence of interannual fluctuations in the ozone hole intensity on the equatorial quasi-biennial oscillation (QBO) allows identifying natural causes of variations and assessing the trend due to anthropogenic factors. The long-term QBO forecast allows predicting different phenomena that depend on the QBO.

Variability of the Antarctic Ozone Anomaly in 2011–2018

The variability of parameters of the Antarctic ozone anomaly is studied using data of the TOMS/OMI satellite monitoring of the ozone layer, MERRA-2 reanalysis, and balloon sounding of the vertical distribution of ozone and temperature at the South Pole. The dynamic processes in the Antarctic stratosphere which define conditions for the significant ozone layer destruction are analyzed. Despite the decrease in the concentration of ozone-depleting substances, the significant ozone loss in the recent 8 years was observed in the Antarctic in 2011 and 2015.

Antarctic ozone depletion between 1960 and 1980 in observations and chemistry–climate model simulations

Abstract. The year 1980 has often been used as a benchmark for the return of Antarctic ozone to conditions assumed to be unaffected by emissions of ozone-depleting substances (ODSs), implying that anthropogenic ozone depletion in Antarctica started around 1980. Here, the extent of anthropogenically driven Antarctic ozone depletion prior to 1980 is examined using output from transient chemistry–climate model (CCM) simulations from 1960 to 2000 with prescribed changes of ozone-depleting substance concentrations in conjunction with observations. A regression model is used to attribute CCM modelled and observed changes in Antarctic total column ozone to halogen-driven chemistry prior to 1980. Wintertime Antarctic ozone is strongly affected by dynamical processes that vary in amplitude from year to year and from model to model. However, when the dynamical and chemical impacts on ozone are separated, all models consistently show a long-term, halogen-induced negative trend in Antarctic ozone from 1960 to 1980. The anthropogenically driven ozone loss from 1960 to 1980 ranges between 26.4 ± 3.4 and 49.8 ± 6.2 % of the total anthropogenic ozone depletion from 1960 to 2000. An even stronger ozone decline of 56.4 ± 6.8 % was estimated from ozone observations. This analysis of the observations and simulations from 17 CCMs clarifies that while the return of Antarctic ozone to 1980 values remains a valid milestone, achieving that milestone is not indicative of full recovery of the Antarctic ozone layer from the effects of ODSs.

Distinguishing the impacts of ozone-depleting substances and well-mixed greenhouse gases on Arctic stratospheric ozone and temperature trends

Whether stratospheric cooling due to increases in well-mixed greenhouse gases (WMGHG) could increase the depletion of Arctic stratospheric ozone has been the subject of scientific and public attention for decades. Here we provide evidence that changes in the concentrations of ozone-depleting substances (ODS), not WMGHG, have been the primary driver of observed Arctic lower stratospheric trends in both ozone and temperature. We do so by analyzing polar cap ozone and temperature trends in reanalysis data: these clearly suggest that both trends are mainly driven by ODS in the lower stratosphere. This observation-based finding is supported by results from a stratosphere-resolving chemistry-climate model driven with time-varying ODS and WMGHG, specified in isolation and in combination. Taken together, these results provide strong evidence that ODS are the main driver of changes in the Arctic lower stratospheric temperatures and ozone, whereas WMGHG are the primary driver of changes in the upper stratosphere.

Response of the Antarctic stratosphere to warm pool El Niño Events in the GEOS CCM

Abstract. The Goddard Earth Observing System Chemistry-Climate Model, Version 2 (GEOS V2 CCM) is used to investigate the response of the Antarctic stratosphere to (1) warm pool El Niño (WPEN) events and (2) the sensitivity of this response to the phase of the QBO. A new formulation of the GEOS V2 CCM includes an improved general circulation model and an internally generated quasi-biennial oscillation (QBO). Two 50-yr time-slice simulations are forced by repeating annual cycles of sea surface temperatures and sea ice concentrations composited from observed WPEN and neutral ENSO (ENSON) events. In these simulations, greenhouse gas and ozone-depleting substance concentrations represent the present-day climate. The modelled responses to WPEN, and to the phase of the QBO during WPEN, are compared with NASA's Modern Era Retrospective-Analysis for Research and Applications (MERRA) reanalysis. WPEN events enhance poleward tropospheric planetary wave activity in the central South Pacific region during austral spring, leading to relative warming of the Antarctic lower stratosphere in November/December. During the easterly phase of the QBO (QBO-E), the GEOS V2 CCM reproduces the observed 4–5 K warming of the polar region at 50 hPa, in the WPEN simulation relative to ENSON. In the recent past, the response to WPEN events was sensitive to the phase of the QBO: the enhancement in planetary wave driving and the lower stratospheric warming signal were mainly associated with WPEN events coincident with QBO-E. In the GEOS V2 CCM, however, the Antarctic response to WPEN events is insensitive to the phase of the QBO: the modelled response is always easterly QBO-like. The QBO signal does not extend far enough into the lower stratosphere and upper troposphere to modulate convection and thus planetary wave activity in the south central Pacific.