Concentrations Of Inorganic Contaminants Research Articles

Performance Assessment of Household Water Treatment and Safe Storage in Kathmandu Valley, Nepal

Although many households in the Kathmandu Valley rely on household water treatment and safe storage (HWTS) to obtain drinking water, the safety of treated water has not been evaluated in actual usage. Therefore, we assessed the performance and maintenance of five HWTS methods used in 101 households. The choice of HWTS methods by households was primarily influenced by the raw water source, that is, jarred water users opted for boiling and groundwater users selected reverse osmosis with ultraviolet irradiation (RO-UV). While boiling and electric dispensers (ED) did not remove inorganic contaminants (ammonia nitrogen, arsenic, and manganese), ceramic candle filters (CCF) and RO-UV reduced them moderately. The HWTS methods reduced E. coli and total coliforms (TC) by 95.8 and 84.1%, respectively, but 11.8 and 69.3% of treated water samples remained positive for these two bacteria. Combined methods (CM) and RO-UV showed an inferior TC reduction compared to the simpler HWTS methods, boiling, CCF, and ED, possibly due to difficulties with regular maintenance and storage contamination. Therefore, it is recommended to choose simpler HWTS methods that meet the requirements of the household’s water sources rather than more expensive and difficult-to-maintain methods, which should be chosen only if the raw water contains high concentrations of inorganic contaminants.

Impact of inorganic and organic pollutants from a Belgian wastewater treatment plant on adjacent surface and groundwaters

Under the pressure of global droughts and water shortage, it is essential to evolve toward a sustainable and robust water system. One possible avenue is the maximum reuse of treated wastewater, but the quality of which determines its reuse. Therefore, inorganic (Cd, Pb, Cr, Ni, Cu, and As) and organic (xenoestrogens and polycyclic aromatic contaminants, PACs) contaminants were monthly monitored in an effluent of the wastewater treatment plant (WWTP), the surrounding surface waters and the local groundwater in Belgium. Dissolved and particulate concentrations of inorganic contaminants in these water bodies were analyzed. In addition, Diffusive Gradients in Thin-films (DGT) was used in situ to obtain bioavailable metal fractions. In the WWTP effluent and surface waters, only Ni exceeds the Annual Average-Environmental Quality Standard (AA-EQS), while in the groundwater, dissolved As was the predominant element. Moreover, in the surface and effluent waters the highest lability degrees were observed for Cd and Ni. The concentrations of these metal species in the effluent water were lower than in the other water bodies. Micro-organic pollutants, xenoestrogens and PACs were analyzed by dual Estrogen and Aryl hydrocarbon Receptor - Chemical Activated LUciferase gene eXpression (ER & AhR-CALUX) assays. Since the annual averaged (AA) bioequivalent concentration of E2 (0.18 ng/L) is below the AA-EQS standard (0.4 ng/L), and the bioequivalent concentration of benzo[a]pyrene never exceeded the maximum admissible concentration (MAC), the reclamation and reuse of treated wastewater for groundwater replenishment and agricultural irrigation should pose no environmental problems, at least in a short-term.

Assessment of anthropogenic metals in shipyard sediment in the Amazon delta estuary in northern Brazil.

Shipyard activities have contributed to the release of anthropogenic metals in sediment in the Amazon delta estuary, but no studies of the issue have been carried out in northern Brazil. This study evaluated the sediment that is under the influence of shipyard activities in the Guajará Bay and in the channel of the Maguari River, in Belém, Pará (PA) state, northern Brazil. Sediment samples were collected in the vicinity of the shipyards, while samples of paint and metal fragments were collected from hulls of abandoned vessels. Metals under analysis were Cu, Zn, Pb, Ni, Cr, Ba, V, Li, Fe and Al. Mean Cu concentrations found in the sediment in two shipyards - 28.3mgkg-1 and 41.0mgkg-1 - were above the threshold effect level (TEL) for the amphipod Hyalella azteca. The highest concentrations of metals found in paint fragments from abandoned vessels were 29,588mgkg-1 Ba, 9,350mgkg-1 Zn, 1,097mgkg-1 Pb and 548mgkg-1 Cr. This fact suggests that vessel abandonment is a major source of contamination in shipyard areas. The principal component analysis (PCA) showed that most metals under study are closely related to sediment contamination in the shipyards. Geoaccumulation index and screening concentrations of inorganic contaminants for metals in freshwater ecosystems confirmed that a shipyard was contaminated by copper. Results may support further studies of contamination and application of waste management to shipyards and vessel graveyards around the world.

Substrate-Driven Phosphorus Bioavailability Dynamics of Novel Inorganic and Organic Fertilizing Products Recovered from Municipal Wastewater—Tests with Ryegrass

Municipal wastewater is a valuable source of phosphorus (P) for the production of fertilizing products, such as microalgae (MA), crab carapace material (CCM), P salt produced by chemical leaching of sludge (P salt CL), and sewage sludge ash produced by pyrolysis and the incineration of sludge (SSA PI). This study compares the P availability of these fertilizing products in three planting substrates (S1, S2, and S3) during a four-month growth period of perennial ryegrass. The unfertilized control in substrate S3 had a high and available P that masked the effect of the added fertilizing products. The P salt CL fertilizer exhibited the lowest shoot dry matter in the alkaline S2 substrate. Still, it can be used as a good source of P in both acidic and alkaline substrates, given that its shoot P content was among the highest in all substrates tested. The organic-rich fertilizing products, MA and CCM, are better suited for acidic substrates since a pronounced reduction in the shoot yield and P content was seen in the alkaline S2 substrate. In contrast, for the SSA PI fertilizer, the very small differences in shoot dry matter and P content in S1 compared to S2 indicated that it is suitable for both acidic and alkaline substrates. Four months were needed to observe the maximum shoot yields treated with these P fertilizing products. Considering that the substrate solution P (using Rhizons) for the P salt CL and MA fertilizers proved to be similar to shoot P uptake, Rhizon extraction could be used for assessing P bioavailability. The chemical composition of novel products indicated their potential to deliver not only P, but also other nutrients to plants. However, concentrations of inorganic contaminants in all products, except CCM, pointed out a possibility to pollute the environment by applying these fertilizers.

Landscape composition and inorganic contaminants in water and muscle tissue of Plagioscion squamosissimus in the Araguari River (Amazon, Brazil)

Amazonian aquatic environments are seriously impacted by dam-building and deforestation, among other threats. Therefore, the present study aimed to examine water quality in the middle and lower course of the Araguari River with respect to the composition of vegetative cover and the concentration of As, Cd and Hg in order to determine risks to the preservation of biota and risks to human health from consumption of P. squamosissimus contaminated with these inorganic elements. To accomplish this, water samples and fish specimens were collected in the middle and lower Araguari River in 2019. The concentration of inorganic contaminants was analyzed by atomic absorption spectrophotometry. These stretches of the Araguari River presented higher proportions of forest fragments and evident expansion of buffalo pastures. According to Brazilian legislation, the concentrations of Cd and Hg in the water samples represented risk quotient values > 1, indicating risk to the preservation of aquatic biota. In particular, the concentrations of Cd in the muscle tissue of P. squamosissimus in the lower Araguari River also indicated risks to human health. The bioaccumulation factor indicated that Hg is bioavailable in the water. It can be concluded that water imbalances in the middle and lower Araguari River compromise the health of both aquatic and human life.

Pilot-scale expanded assessment of inorganic and organic tapwater exposures and predicted effects in Puerto Rico, USA

A pilot-scale expanded target assessment of mixtures of inorganic and organic contaminants in point-of-consumption drinking water (tapwater, TW) was conducted in Puerto Rico (PR) to continue to inform TW exposures and corresponding estimations of cumulative human-health risks across the US. In August 2018, a spatial synoptic pilot assessment of than 524 organic and 37 inorganic chemicals was conducted in 14 locations (7 home; 7 commercial) across PR. A follow-up 3-day temporal assessment of TW variability was conducted in December 2018 at two of the synoptic locations (1 home, 1 commercial) and included daily pre- and post-flush samples. Concentrations of regulated and unregulated TW contaminants were used to calculate cumulative in vitro bioactivity ratios and Hazard Indices (HI) based on existing human-health benchmarks. Synoptic results confirmed that human exposures to inorganic and organic contaminant mixtures, which are rarely monitored together in drinking water at the point of consumption, occurred across PR and consisted of elevated concentrations of inorganic contaminants (e.g., lead, copper), disinfection byproducts (DBP), and to a lesser extent per/polyfluoroalkyl substances (PFAS) and phthalates. Exceedances of human-health benchmarks in every synoptic TW sample support further investigation of the potential cumulative risk to vulnerable populations in PR and emphasize the importance of continued broad characterization of drinking-water exposures at the tap with analytical capabilities that better represent the complexity of both inorganic and organic contaminant mixtures known to occur in ambient source waters. Such health-based monitoring data are essential to support public engagement in source water sustainability and treatment and to inform consumer point-of-use treatment decision making in PR and throughout the US.

Evaluation of water sorption isotherm, glass transistion temperature, vitamin C and color stability of mango peel powder during storage

The purpose of this work was to study the physical and chemical stability of the mango peel powder produced by hot-air drying. Sorption isotherms at 25 °C and glass transition temperatures (Tg) of the samples in equilibrium at different aw were determined. The degradation of vitamin C and color parameter b* was evaluated along storage under controlled conditions (relative humidity = 60%, temperature = 10, 25 and 35 °C) during 180 days. GAB model well-described water adsorption of the product, showing a monolayer moisture content (Xm) of 0.1260 g water/g dry solids and a critical aw of 0.56. The Gordon-Taylor model predicted the plasticizing effect of water on glass transition temperature, since Tg of the powders kept at different relative humidity conditions decreased as water activity increased. No visual signs of agglomeration and darkening were observed for samples stored at aw ≤ 0.529. The powders are a source of calcium and rich in potassium, copper, magnesium and manganese. The concentration of inorganic contaminants and pesticide residues were below the maximum allowed limits. The degradation of vitamin C and color parameter b* followed the first and zero-order kinetic models, respectively. The study indicated good stability for the powders along the storage at 10 and 25 °C, which can be incorporated into different food products, showing high retention of vitamin C, phenolic compounds, antioxidant activity and maintenance of color characteristics.

Analysis of inorganic contaminants in Hoplias aimara Valenciennes 1846 (Trairão) explored by the fishing activity in the high Rio Araguari, Amapá, Brazil

This study aims to evaluate the concentration of inorganic contaminants in Hoplias aimara Valenciennes 1846, coming from the upper Rio Araguari, State of Amapa.

Understanding marine food web dynamics using fatty acid signatures and stable isotope ratios: Improving contaminant impacts assessments across trophic levels

Scotland's marine food webs support a diversity of species and habitats. They contribute to maintaining the balance of the natural environment. Previous studies show that these ecosystems are contaminated by persistent organic pollutants and trace metals; with animals in higher trophic levels (e.g. cetaceans and pinnipeds) containing concentrations that are among the highest found in the ocean. Contaminants represent one of many pressures to which species and habitats are exposed. In assessing the contribution of contaminants to the overall pressure, measuring contaminants at a specific trophic level and then using trophic magnification factors (TMFs) to estimate concentrations at other trophic levels permits assessments across the food web, as well as allowing the adjustment of contaminant concentrations to a particular trophic level for comparison to assessment criteria. Fatty acid (FA) signatures and stable isotope (SI) ratios were used to develop a picture of Scottish marine food web ecology and reliably ascribe trophic levels to a wide range of species. Fatty acid trophic markers (FATMs) were used as trophic level indicators and with SI analysis, permitted identification of the mean trophic level of each species and determination of the feeding patterns and predator-prey relationships existing in the Scottish marine food web. Two hundred and eleven (211) samples comprising of seven fish species, one shark species, fourteen marine invertebrate species, three marine mammal species and two zooplankton species from different locations around Scotland were found to have mean trophic levels ranging from 1.47 ± 0.11 in zooplankton to 5.02 ± 0.35 in harbour seal. Fatty acid profile showed specific dietary information which differed between the eleven taxonomic classes and twenty-seven species. The organic and inorganic contaminant concentrations of the species for which trophic level has been determined, together with TMFs, will be reported in future papers.

Environmental behavior of waste rocks based concrete: Leaching performance assessment

The reuse of mine waste rocks as construction material is an innovative and sustainable management technique that can lower their surface disposal, mitigate their environmental impacts and provide opportunity to conceive economic benefits. However, the implementation of this approach is still limited due principally to insufficient knowledge on environmental behavior of mine wastes-based products. This paper aims in investigating these issues by assessing the leaching behavior of two low sulfide-mining waste rocks suitable for concrete production. Concentrations of inorganic contaminants released from single waste rocks were measured by means of weathering cell, CTEU-9, TCLP and SPLP tests. Compressive strength and immobilization performance of obtained concretes based on these waste rocks were assessed. The results of humidity cell tests indicated that waste rock with higher sulfur content (0.47 wt%) and lower carbon content (0.26 wt%) did not present an acid generating potential according the Quebec environmental regulation. Those of TCLP, SPLP and CTEU-9 batch tests showed a concentration of contaminants in leachate solutions from waste rocks below the standardized limits fixed by the Environmental Protection Agency. Concretes made using these waste rocks as aggregates exhibited a suitable compressive strength. Concentration of heavy metals and sulphates released from concretes using tank-leaching test were under the limit requirements fixed by the Soil Quality Decree.

Evidence of accumulation and elimination of inorganic contaminants from the lachrymal salt glands of leatherback sea turtles (Dermochelys coriacea)

Plasma osmolalities of marine vertebrates are generally lower than the surrounding medium; therefore, marine organisms must cope with the osmoregulatory challenges of life in a salty environment. The salt glands serve to maintain osmotic and ionic homeostasis in a number of lower marine vertebrates. One marine reptile, the leatherback sea turtle (Dermochelys coriacea), ingests excessive amounts of salts due to their diet of gelatinous zooplankton. Outside of the normal osmoregulatory function of the salt gland, little research has been conducted on contaminant accumulation and excretion in this organ. Here, we established arsenic, cadmium, lead, mercury, and selenium concentrations in red blood cells (RBCs) and salt gland secretions (SGSs) of nesting leatherbacks. We also collected salt glands from different life stage classes of dead stranded leatherbacks from the western Atlantic Ocean to determine if inorganic contaminants accumulate in this organ. Using non-metric multidimensional scaling and regression analyses, we determined that RBC and SGS inorganic contaminant concentrations were not correlated. Additionally, RBCs showed significantly higher concentrations of these contaminants in comparison to SGSs, likely due to the affinity of inorganic contaminants for the heme group of RBCs. Lastly, we found that salt gland cadmium and mercury concentrations tended to increase with increasing curved carapace length (CCL) in stranded leatherbacks. Our results indicate that different physiological mechanisms determine the distribution of inorganic contaminants in blood and SGSs. Increases in salt gland contaminant concentrations with increasing CCL suggest this organ as a potential target for accumulation.

Open-water and under-ice seasonal variations in trace element content and physicochemical associations in fluvial bed sediment.

Across the circumpolar world, intensive anthropogenic activities in the southern reaches of many large, northward-flowing rivers can cause sediment contamination in the downstream depositional environment. The influence of ice cover on concentrations of inorganic contaminants in bed sediment (i.e., sediment quality) is unknown in these rivers, where winter is the dominant season. A geomorphic response unit approach was used to select hydraulically diverse sampling sites across a northern test-case system, the Slave River and delta (Northwest Territories, Canada). Surface sediment samples (top 1 cm) were collected from 6 predefined geomorphic response units (12 sites) to assess the relationships between bed sediment physicochemistry (particle size distribution and total organic carbon content) and trace element content (mercury and 18 other trace elements) during open-water conditions. A subset of sites was resampled under-ice to assess the influence of season on these relationships and on total trace element content. Concentrations of the majority of trace elements were strongly correlated with percent fines and proxies for grain size (aluminum and iron), with similar trace element grain size/grain size proxy relationships between seasons. However, finer materials were deposited under ice with associated increases in sediment total organic carbon content and the concentrations of most trace elements investigated. The geomorphic response unit approach was effective at identifying diverse hydrological environments for sampling prior to field operations. Our data demonstrate the need for under-ice sampling to confirm year-round consistency in trace element-geochemical relationships in fluvial systems and to define the upper extremes of these relationships. Whether contaminated or not, under-ice bed sediment can represent a "worst-case" scenario in terms of trace element concentrations and exposure for sediment-associated organisms in northern fluvial systems. Environ Toxicol Chem 2017;36:2916-2924. © 2017 SETAC.

Inorganic and organic contaminants in Alaskan shorebird eggs.

Many shorebird populations throughout North America are thought to be declining, with potential causes attributed to habitat loss and fragmentation, reduced prey availability, increased predation, human disturbance, and increased exposure to environmental pollutants. Shorebirds may be particularly vulnerable to contaminant exposure throughout their life cycle, as they forage primarily on invertebrates in wetlands, where many contaminants accumulate disproportionately in the sediments. Therefore, it is important to document and monitor shorebird populations thought to be at risk and assess the role that environmental contaminants may have on population declines. To investigate potential threats and provide baseline data on shorebird contaminant levels in Alaskan shorebirds, contaminant concentrations were evaluated in shorebird eggs from 16 species residing in seven geographic distinct regions of Alaska. Similar to previous studies, low levels of most inorganic and organic contaminants were found, although concentrations of several inorganic and organic contaminants were higher than those of previous studies. For example, elevated strontium levels were observed in several species, especially black oystercatcher (Haematopus bachmani) sampled in Prince William Sound, Alaska. Additionally, contaminant concentrations varied among species, with significantly higher concentrations of inorganic contaminants found in eggs of pectoral sandpiper (Calidris melanotos), semipalmated sandpiper (Calidris pusilla), black oystercatcher, and bar-tailed godwit (Limosa lapponica). Similarly, significantly higher concentrations of some organic contaminants were found in the eggs of American golden plover (Pluvialis dominica), black-bellied plover (Pluvialis squatarola), pacific golden plover (Pluvialis fulva), bar-tailed godwit, and semipalmated sandpiper. Despite these elevated levels, current concentrations of contaminants in shorebird eggs suggest that breeding environments are relatively free of most contaminants and that contaminant concentrations are below levels (except potentially strontium) that would likely affect the survival of individuals and consequently regulate the species at the population level.

Risk assessment of hazardous impacts on urbanization and industrialization activities based upon toxic substances

A risk assessment study was conducted topredict the expected hazardous influence on the ecosystem resulted from urbanization and industrialization activities at Helwan area, Egypt. To achieve these goals, soils, plants and water samples were collected from Helwan area, and their total concentrations of inorganic contaminants (Cd, Cr, Co, Cu, Fe, Mn, Ni, Pb, and Zn) and organic pollutants; such as Phenol and hydrocarbons were measured. The obtained results showed that, the concentrations of organic contaminants in water streams and surrounding soils recorded high concentration values than the permissible limits, while inorganic elements were within the safe limits for irrigation. In addition, soils irrigated with the effluents of industrial units recorded high values of inorganic and organic contaminants . Consequently, the levels of these contaminants were high in plant tissues grown thereon; especially the edible parts. Risk assessment based on available predicted no effect concentration values for the aquatic and terrestrial environment was performed. Inorganic elements were expected to cause serious hazard problems for both aquatic organisms and soil microorganisms. The impact of these pollutants on human health was calculated using daily metals intake of inorganic metals via consumption of edible plants. Hazard index values proved that concentrations of Cr may cause serious hazard problems for humans in this area; especially, children.

Inorganic Contaminants, Nutrient Reserves and Molt Intensity in Autumn Migrant Red-Necked Grebes (Podiceps grisegena) at Georgian Bay.

Red-necked grebes (Podiceps grisegena) are piscivorous waterbirds that breed on freshwater lakes in northwestern Canada and stop-over at the Great Lakes during autumn migration to molt feathers and replenish lipid and protein reserves. The objectives of this study were to (1) describe concentrations of, and correlations among, inorganic contaminants in a sample of autumn migrant red-necked grebes from the Great Lakes, (2) compare concentrations of inorganic contaminants to those in autumn migrant common loons from Schummer et al. (Arch Environ Contam Toxicol 62:704, 2011a), (3) evaluate if the inorganic elements are negatively associated with lipid and protein reserves, and (4) determine if nutrient reserves and molt intensity were correlated. None of the 14 contaminants analyzed were above threshold levels known to cause acute health problems in piscivorous birds. Body masses of plucked birds were within the normal reported range. Lipid reserves varied positively with hepatic concentrations of arsenic, copper, iron, nickel, lead, and selenium and negatively with mercury and magnesium. Protein reserves variety negatively with hepatic concentrations of arsenic, calcium, nickel, lead, and zinc and positively with aluminum, cadmium, and iron. A negative correlation was observed between chest molt and lipid reserves but not between nutrient reserves and other feather tracts. The relationships between lipid reserves and both mercury and selenium were consistent with current research on other piscivorous waterbirds at the Great Lakes and justify continued work to determine interactions of these contaminants in waterbirds that breed, stage, and winter in the region.

Decreasing the contamination and toxicity of a heavily contaminated soil by in situ bioremediation

Experimental plot consisting of acidic leached cinnamonic forest soil heavily contaminated with radionuclides (mainly U and Ra) and non-ferrous metals (mainly Cu, Zn and Cd) was treated in situ under real field conditions using the activity of the indigenous soil microflora. This activity was enhanced by suitable changes of some essential environmental factors such as pH and water, oxygen and nutrient contents of the soil. The treatment was connected with solubilization and removal of contaminants from the top soil layers (horizon A) due to the joint action of the soil microorganisms and leach solutions used to irrigate the soils (mainly acidophilic chemolithotrophic bacteria and diluted sulphuric acid). The dissolved contaminants were transferred through the drainage soil effluents to the deeply located soil subhorizon B2 where they were precipitated as the relevant insoluble forms (uranium as uraninite, and the non-ferrous metals as the relevant sulphides) as a result of the activity of the sulphate-reducing bacteria inhabiting this soil subhorizon. The effluents from the subhorizon B2 containing much lower concentrations of inorganic contaminants but enriched in dissolved biodegradable organics were subjected to additional treatment in a constructed wetland for removing these residual contaminants. It was also demonstrated that an efficient treatment of the effluents from the subhorizon B2 could be achieved by a microbial fuel cell in which the cleanup was connected with electricity generation.

Hepatic Concentrations of Inorganic Contaminants and Their Relationships with Nutrient Reserves in Autumn-Migrant Common Loons at Lake Erie

Common loons (Gavia immer) are piscivorous, high-trophic level feeders that bioaccumulate inorganic contaminants at concentrations that can negatively impact their health and reproduction. Concentrations of inorganic contaminants, especially mercury (Hg), in blood, organs, and muscle have been quantified in common loons on breeding grounds, but these data are limited for migrating loons. We investigated sex- and age-related hepatic concentrations of inorganic contaminants in common loons (n=53) that died from botulism and were salvaged at a Great Lakes staging area (i.e., Long Point, Lake Erie) during November 2005. We also investigated if hepatic concentrations of inorganic contaminants influenced lipid, protein, and mineral in our sample of migrant common loons. Last, we determined if there was correlation between Hg and selenium (Se). Consistent with data from breeding grounds, mean concentrations of Hg in liver were approximately 2.5 times greater in adult ([Formula: see text]=14.64±16.69μgg(-1)) compared with juvenile birds ([Formula: see text]=3.99±2.27μgg(-1)). Elements detected in liver at potentially harmful levels were Hg and Se, of which lipid reserves varied negatively with Hg concentrations but positively with Se concentrations. In addition, Hg and Se were correlated (r=0.65) at greater then a demethylation threshold (total Hg≥8.5μgg(-1) dw) but not lower than that. Concentrations of inorganic contaminants did not influence protein and mineral levels in our sample of common loons. Our results suggest that Hg accumulation negatively affects lipid levels in migrant common loons. Results are also consistent with a nontoxic Hg-Se protein complex protecting loons migrating through areas that are relatively Se rich. Although the acquisition of Se during the nonbreeding season may decrease the toxicity of Hg, future research should consider the synergistic Hg-Se effect on reproduction in common loons that migrate through Se-rich locales, such as the Great Lakes.

Dissolved Inorganic Contaminants in a Floodplain Soil: Comparison of In Situ Soil Solutions and Laboratory Methods

The applicability of laboratory tests for the prediction of soil solution composition and concentrations of inorganic contaminants is still under debate. Therefore, we carried out two batch-leaching tests differing in their liquid/solid ratios and column experiments (saturated flow, two flow velocities, four flow interruptions ranging from 4 h to 21 days) with a contaminated humic horizon (total contents: As, 196 mg kg−1; Cd, 4 mg kg−1; Cr, 202 mg kg−1; Cu, 227 mg kg−1; Ni, 64 mg kg−1; Pb, 308 mg kg−1; Zn, 1,176 mg kg−1) from a Mollic Fluvisol near the rivers Elbe and Saale (Germany) and compared the aqueous contaminant concentrations with those of soil solutions obtained in situ with ceramic suction cups on a monthly basis between 2002 and 2006. Contaminant release in the field slightly depended on the water regime, pH, and redox potential and was characterized by partially high concentrations (e.g., As, 47 µg l−1; Cd, 136 µg l−1; Ni, 328 µg l−1; Zn, 8.68 mg l−1), which exceeded the German inspection values. Metal concentrations obtained in batch-leaching tests partially fitted to those determined in the soil solution and to those from the column experiments even irrespective of the varying liquid/solid ratios. The column experiments yielded realistic concentrations of Cr, Cu, Ni, and Pb and their ranges. Furthermore, they provided an insight into release kinetics and release processes as well as into potential contaminant release due to enforced reducing conditions. As column experiments allow a larger temporal sampling resolution and enable quickly to manipulate experimental conditions, they are a useful complement of soil solution monitoring.

Scale-Up Methodology for Municipal Water Nanofiltration Based on Permeate Water Quality

A semiempirical differential model based on homogenous solution and diffusion is developed to analyze contaminant removal during municipal water nanofiltration at high feed water recoveries. An intrinsic transport parameter derived using this model from bench-top experiments employing flat membrane sheets is used to predict contaminant rejection in large-scale experiments using single and multiple spiral-wound modules conducted under the Information Collection Rule. Because solute back-transport dominated permeate flux, concentration polarization was negligible during these nanofiltration experiments. Permeation coefficients were found to increase monotonically with increasing solute aqueous diffusivity. Pseudostochastic simulations were performed in a purely predictive manner using the Monte Carlo methodology to theoretically calculate permeate concentrations in large-scale facilities using probability density functions for permeation coefficients (obtained from bench-top experiments) and observed feed water concentrations. These numerical simulations revealed that removal of natural organic matter and precursors to trihalomethanes, haloacetic acids, and total organic halide could be successfully scaled up from bench-top tests with flat membrane sheets to large-scale facilities employing spiral-wound elements. Thus, factors that strongly influence natural organic matter removal (steric and polar interactions) appear to be scaled accurately. However, statistically significant discrepancies in inorganic contaminant concentrations between theoretical predictions and observations from pilot- and full-scale tests suggest that the proposed methodology does not accurately quantify electrostatic interactions, ion pairing, and complexation.

A logical starting point for developing priorities for lizard and snake ecotoxicology: A review of available data

Reptiles, specifically lizards and snakes, usually are excluded from environmental contamination studies and ecological risk assessments. This brief summary of available lizard and snake environmental contaminant data is presented to assist in the development of priorities for lizard and snake ecotoxicology. Most contaminant studies were not conducted recently, list animals found dead or dying after pesticide application, report residue concentrations after pesticide exposure, compare contaminant concentrations in animals from different areas, compare residue concentrations found in different tissues and organs, or compare changes in concentrations over time. The biological significance of the contaminant concentrations is rarely studied. A few recent studies, especially those conducted on modern pesticides, link the contaminant effects with exposure concentrations. Nondestructive sampling techniques for determining organic and inorganic contaminant concentrations in lizards and snakes recently have been developed. Studies that relate exposure, concentration, and effects of all types of environmental contaminants on lizards and snakes are needed. Because most lizards eat insects, studies on the exposure, effects, and accumulation of insecticides in lizards, and their predators, should be a top priority. Because all snakes are upper-trophic-level carnivores, studies on the accumulation and effects of contaminants that are known to bioaccumulate or biomagnify up the food chain should be the top priority.