HF Concentration Research Articles

Effects of Hf additions on the microstructures and mechanical properties of Ni-rich Ni55Ti45 alloys

The microstructural characterization and mechanical properties of the oil quenched binary Ni55Ti45 alloy and Hf-modified Ni55Ti45-xHfx (x = 3, 5, 7 at.%) alloys were investigated. The results showed that the microstructure of binary alloy is composed of NiTi phase, nanoscale Ni4Ti3 precipitates, and a small amount of Ti4Ni2O and Ni3Ti2 phases. The Hf additions suppresses the formation of the Ti4Ni2O and Ni3Ti2 phases and promotes the HfO2 particles. When the Hf content is less than 5 at.%, the main precipitated phase is still Ni4Ti3, but which is gradually refined and spheroidized with the increase of Hf content. While the Ni4Ti3 phases disappeared and the fine H-phases precipitated massively in the Ni55Ti38Hf7 alloy. With the gaining content of Hf, the Vickers hardness increases, but the fracture toughness and tensile strength increase first and then decrease. When the addition of Hf is 3 at.%, the alloy possesses the best property with the fracture toughness of 21.02 MPa/m1/2 and the tensile strength of 2.25 GPa.

U - Pb geochronology and composition of zircon mineral from granodiorite in the G18 Gold mine, Quang Nam and its significance in regional tectonics

The Tam Ky - Phuoc Son suture zone (TPSZ) is located in central Indochina and is referred to as a amalgamation site between the Truong Son and Kon Tum terranes during the early Paleozoic. The amphibolite and ultramafic rocks within the region were considered as a part of the Tam Ky - Phuoc Son ophiolitic complex. In this study, the authors present results of the U - Pb dating and trace element composition of the zircon grains derived from a granodioritic sample collected in the G18 gold mine in Quang Nam province in order to clarify the timing of magma emplacement and tectonic setting. The U - Pb dating data indicates that the granodioritic rocks formed at 447,4±2,9 Ma while the U/Yb ratio is ̴1 (average: 1.32) and the Sc/Yb ratio is ̴ 1.04, high Hf content (Average Hf: 10937 ppm) and low Yb content (Average Yb: 308 ppm). These geochemical values are comparable with the zircon, which is formed in the continental magmatic arc. Combination with the pre - existing data allowed us to confirm the existence of two contrast magma members in the North Kontum massif: The Middle Cambrian island arc complex and the Middle Ordovician continental complex.

Generation of Cretaceous high-silica granite by complementary crystal accumulation and silicic melt extraction in the coastal region of southeastern China

Abstract It is generally hypothesized that high-silica (SiO2 > 75 wt%) granite (HSG) originates from crystal fractionation in the shallow crust. Yet, identifying the complementary cumulate residue of HSG within plutons remains difficult. In this work, we examine the genetic links between the porphyritic monzogranite and HSG (including porphyritic granite, monzogranite, and alkali feldspar granite) from the coastal area of southeastern China using detailed zircon U-Pb ages, trace elements, Hf-O isotopes, and whole-rock geochemistry and Nd-Hf isotopic compositions. Zircon U-Pb ages indicate that the porphyritic monzogranite and HSG are coeval (ca. 96–99 Ma). The HSG and porphyritic monzogranite have similar formation ages within analytic error, identical mineral assemblages, similar Nd-Hf isotopic compositions, and consistent variations in their zircon compositions (i.e., Eu/Eu*, Zr/Hf, and Sm/Yb), which suggests that their parental magma came from a common silicic magma reservoir and that the lithological differences are the result of melt extraction processes. The porphyritic monzogranite has relatively high SiO2 (70.0–73.4 wt%), Ba (718–1070 ppm), and Sr (493–657 ppm) contents, low K2O and Rb concentrations and low Rb/Sr ratios (0.1–0.2), and it displays weak Eu anomalies (Eu/Eu* = 0.57–0.90). Together with the petrographic features of the porphyritic monzogranite, these geochemical variations indicate that the porphyritic monzongranite is the residual silicic cumulate of the crystal mush column. The HSG (SiO2 = 75.0–78.4) has variable Rb/Sr ratios (2–490) and very low Sr (1–109 ppm) and Ba (9–323 ppm) contents. Zircon from the HSG and porphyritic monzogranite overlap in Eu/Eu*, Zr/Hf, and Sm/Yb ratios and Hf contents; however, some zircon from the HSG show very low Eu/Eu* (<0.1) and Zr/Hf ratios. These features suggest that the HSG represents the high-silica melt that was extracted from a crystal-rich mush. The injection of mantle-derived hotter mafic magma into the mush column and the exsolution of F/Cl−-enriched volatiles (or fluids) from the interstitial melt rejuvenated the pre-existing highly crystalline mush. Subsequent extraction and upward migration of silicic melt resulting from compaction of the mush column formed the HSG at shallow crustal levels, which left the complementary crystal residue solidified as porphyritic monzogranite at the bottom.

Thermal stability and pyrolysis products of HFO-1234yf as an environment-friendly working fluid for Organic Rankine Cycle

HFO-1234yf is considered as one of the most promising working fluids for Organic Rankine Cycle (ORC) owing to its good environmental performance and thermal performance. In this study, an experimental system was designed to determine the thermal stability of HFO-1234yf. The results showed that pyrolysis temperature ranges of HFO-1234yf were 170–190 °C. The pyrolysis products of HFO-1234yf were gas and liquid products. Six gases detected in vapor phase products were HF, CHF3, CH2F2, CF4, C2F6 and C3F8. The concentration of HF in vapor phase had an absolute advantage in the gas products. The thick yellow oily liquid product was observed and their chemical composition and the corresponding forming mechanism were studied. There mainly were 3 monomer units (A, B and C) in the liquid polymers. The optimal generation pathways of the liquid polymers were studied by density functional theory (DFT) method, and the theoretical calculation results were consistent with the experimental results. Finally, the effects of pressure on the thermal stability of HFO-1234yf were discussed.

Separation of hafnium from zirconium in HNO3 solution by solvent extraction with Cyanex572

Extraction and separation of hafnium (Hf) from zirconium (Zr) in HNO3 solution were carried out with Cyanex572 as extractant. Hf could be selectively extracted with an optimized extraction rate of 76.8%, and the separation factor between Hf and Zr could reach up to 15.7 when the concentration of Zr(IV), Hf(IV), H+, NO3− and (NH4)2SO4 in aqueous phase were fixed at 110 g/L, 3.0 g/L, 2.6 M, 1.8 M and 0.8 M, respectively. The stoichiometry and coordination structure of the extracted complex for Hf was investigated by slope analysis, Fourier transform infrared (FT-IR) spectrometry and nuclear magnetic resonance (NMR) spectrometry. It was found that HfO2+ in nitric acid medium could be extracted into the organic phase through two routes. The dominant route was via a cation-exchange mechanism, according to 2HfO2+aq + H2A2 org + 2NO3̄ aq↔ (HfO2+)2·(NO3̄)2·A2 org + 2H+aq. Meanwhile, the subordinate route was coordinate with PO in Cyanex572 extractant. Therefore, it is possible to developing an effective solvent extraction system to separate Hf from Zr by utilizing Cyanex572.

Geochemistry and Petrogenesis of Late Ediacaran Rare‐metal Albite Granites of the Arabian‐Nubian Shield

AbstractThe Abu Dabbab albite granite (ADAG), in the central Eastern Desert of Egypt, hosts the most significant rare metal ore deposit in the northern part of the Neoproterozoic Arabian‐Nubian Shield. Here, we report detailed field, petrographic, mineralogical and geochemical investigation of the ADAG, an isolated stock‐like granitic body with sharp intrusive contacts against metamorphic country rocks, probably emplaced at about 600 Ma. The fine‐grained porphyritic upper unit is a preserved remnant of the shallowly‐emplaced apex of the magma chamber, whereas the medium‐grained lower unit crystallized at deeper levels under subvolcanic conditions. The peraluminous leucocratic ADAG shares common geochemical characteristics with post‐collisional intraplate A‐type magmas. In addition to the conspicuous enrichment in Na2O, the ADAG is remarkable for its anomalous concentrations of Ta, Nb, Li, Hf, Ga, Sn, Zn and heavy rare‐earth elements. Nb‐Ta minerals in the ADAG are mixed with Fe‐Mn oxides, forming black patches that increase in abundance toward of the base of the intrusion. Columbite‐tantalite, cassiterite and wolframite are the most important ore minerals. Pronounced negative Eu anomalies (Eu/Eu∗ = 0.10–0.24) reflect extreme magmatic fractionation and perhaps the effects of late fluid‐rock interaction. The ADAG was most likely generated by partial melting of the juvenile middle crust of the ANS as the geotherm was elevated by erosional uplift following lithospheric delamination and it was emplaced at the intersection of lineations of structural weakness. Although formation of the ADAG and its primary enrichment in rare metals are essentially due to magmatic processes, late‐stage metasomatism caused limited redistribution of rare metals. Fluid‐driven subsolidus modification was limited to the apex of the magma chamber and drove development of greisen, amazonite, and quartz veins along fracture systems.

Effect of hafnium addition on structure, wear resistance and high temperature oxidation of MOSx thin films

Pure MoSx and MoSx + Hf thin films were deposited by magnetron sputtering and characterized by RBS, GAXRD, XPS, high temperature oxidation tests and tribological tests. Hf content was set at 12 at.% by RBS and GAXRD analyses revealed a complete amorphization caused by Hf incorporation. XPS analyses indicated that hafnium is inserted in MoSx in the form of HfSx, moreover, such compound was responsible for inhibiting the formation of MoS. These factors are closely correlated with improvements obtained in oxidation resistance, friction coefficient, wear rate and lifespan of MoSx thin films.

Microstructure, phase relationships and microhardness of Fe60Al40–n Hf n alloys (n = 1, 3, and 5 at.%)

Abstract The microstructural evolution, solidification behavior, phase relationships, microhardness and room temperature magnetic properties of the hypoeutectic Fe60Al40-n Hf n (n = 1, 3, and 5 at.%) compositions are investigated in detail. The micro-structure of the studied alloys is composed of Fe–Al based dendrites and eutectic mixture. The components of the eutectic are B2 Fe–Al based and HfFe6Al6 τ1 phases. With increasing Hf fraction, the amounts of eutectic and τ1 phases increase continuously which results in significant strengthening. Based on the differential scanning calorimetry results, the eutectic reaction temperature is measured as 1251 °C. Fe60Al40-n Hf n alloys show weak room temperature ferromagnetism and their magnetization values also increase with increasing Hf content.

Pinning Characteristics of Zr and Hf- Added REBCO Coated Conductors Made by Advanced MOCVD in Low-to-High Magnetic Fields

BaMO <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">3</sub> (M = Zr, Hf) pinning centers introduced in REBa <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">2</sub> Cu <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">3</sub> O <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">7-x</sub> (REBCO and RE = rare earth) coated conductors yield superior performance in high magnetic fields. We present the critical current density J <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">c</sub> over a temperature range of 4.2-77 K and magnetic fields of 0-14 T (B || c-axis), of 5-15 mol.% Zr- and Hf- added REBCO 4+ μm thick film tapes fabricated by advanced metal organic chemical vapor deposition (A-MOCVD). The morphology of self-assembled BMO nanorods aligned along c-axis is found to be dependent on the Zr/Hf content. We also observe a correlation between the density of RE <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">2</sub> O <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">3</sub> in-plane nanoprecipitates and the continuity and concentration of BMO nanorods in films of different Ba content. It is found that the (Ba + M)/Cu (M = Zr, Hf) content in REBa <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">2</sub> Cu <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">3</sub> O <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">7-x</sub> affects the shape of pinning force density curves over a wide magnetic field range and temperatures below 20 K. Another remarkable observation is the similarity in the critical current properties of Hf and Zr- added REBCO films as function of (Ba + M)/Cu content at intermediate to high range of (Ba + M)/Cu content. A quantitative analysis of pinning efficiency and correlation with the microstructure of Zr and Hf- added REBCO coated conductors is discussed.

Growth of High-Performance 4-5μm Thick Film REBCO Tapes Doped With Hafnium Using Advanced MOCVD

Advanced metal organic chemical vapor deposition technique (A-MOCVD) was used to grow 4-5 μm thick REBa <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">2</sub> Cu <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">3</sub> O <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">7-δ</sub> (REBCO, RE = rare earth) films, doped with 5% and 15% Hf. Thick REBCO films doped with 5% Hf exhibit self-field critical current density (J <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">c</sub> ) over 1.8 MA/cm <sup xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">2</sup> at 77 K and 3 MA/cm <sup xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">2</sup> at 65 K, 1.5 T. Increasing the Hf content to 15% resulted in J <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">c</sub> above 9 MA/cm <sup xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">2</sup> at 20 K, 9 T. The effect of (Ba+Hf)/Cu content in Hf-added (5 and 15 mol.%) REBCO films on the critical current density at 77 K, 0 T, c-axis lattice parameter and out-of- plane texture has been studied. In addition to growth of thick film REBCO tapes with superior performance, the A-MOCVD reactor has been used to quadruple the precursor-to-film conversion efficiency above 45%. This achievement has a first order impact in lowering the cost of REBCO tapes made by A-MOCVD.

Genesis of Dulong Sn-Zn-In Polymetallic Deposit in Yunnan Province, South China: Insights from Cassiterite U-Pb Ages and Trace Element Compositions

The Dulong Sn-Zn-In polymetallic deposit in the Yunnan province, SW China, hosts a reserve of 5.0 Mt Zn, 0.4 Mt Sn, and 7 Kt In. It is one of the most important polymetallic tin ore districts in China. Granites at Dulong mining area include mainly the Laojunshan granite (third phase), which occurs as quartz porphyry or granite porphyry dikes in the Southern edge of the Laojunshan intrusive complex. Granites of phases one and two are intersected at drill holes at depth. There are three types of cassiterite mineralization developed in the deposit: cassiterite-magnetite ± sulfide ore (Cst I), cassiterite-sulfide ore (Cst II) within the proximal skarn in contact with the concealed granite (granites of phases one to two and three), and cassiterite-quartz vein ore (Cst III) near porphyritic granite. Field geology and petrographic studies indicate that acid neutralising muscovitization and pyroxene reactions were part of mechanisms for Sn precipitation resulting from fluid-rock interaction. In situ U–Pb dating of cassiterite samples from the ore stages of cassiterite-sulfide (Cst II) and Cassiterite-quartz vein (Cst III) yielded Tera-Wasserburg U–Pb lower intercept ages of 88.5 ± 2.1 Ma and 82.1 ± 6.3 Ma, respectively. The two mineralization ages are consistent with the emplacement age of the Laojunshan granite (75.9–92.9 Ma) within error, suggesting a close temporal link between Sn-Zn(-In) mineralization and granitic magmatism. LA-ICPMS trace element study of cassiterite indicates that tetravalent elements (such as Zr, Hf, Ti, U, W) are incorporated in cassiterite by direct substitution, and the trivalent element (Fe) is replaced by coupled substitution. CL image shows that the fluorescence signal of Cst I–II is greater than that of Cst III, which is caused by differences in contents of activating luminescence elements (Al, Ti, W, etc.) and quenching luminescence element (Fe). Elevated W and Fe but lowered Zr, Hf, Nb, and Ta concentrations of the three type cassiterites from the Dulong Sn-Zn-In polymetallic deposit are distinctly different from those of cassiterites in VMS/SEDEX tin deposits, but similar to those from granite-related tin deposits. From cassiterite-magnetite ± sulfide (Cst I), cassiterite-sulfide ore (Cst II), to cassiterite-quartz vein ore-stage (Cst III), high field strength elements (HFSEs: Zr, Nb, Ta, Hf) decrease. This fact combined with cassiterite crystallization ages, indicates that Cst I–II mainly related to concealed granite (Laojunshan granites of phases one and two) while Cst III is mainly related to porphyritic granite (Laojunshan granites of phase three).

Protracted Storage for Calc-Alkaline Andesitic Magma in Magma Chambers: Perspective from the Nageng Andesite, East Kunlun Orogen, NW China

Calc-alkaline andesitic rocks are a major product of subduction-related magmatism at convergent margins. Where these melts are originated, how long they are stored in the magma chambers, and how they evolved is still a matter of debate. In this study, we present new data of whole-rock elemental and Sr-Nd-Pb isotope compositions, and zircon U-Pb-Th isotopes and trace element contents of Nageng (basaltic-)andesites in the East Kunlun Orogen (NW China). The similar age and whole-rock elemental and Sr-Nd-Pb isotope contents suggest that the Nageng andesite and basaltic andesite are co-magmatic. Their low initial 87Sr/86Sr (0.7084–0.7086) but negative εNd(t) values (−10.61 to −9.49) are consistent with a magma source from the juvenile mafic lower crust, possibly related to the mantle wedge with recycled sediment input. The U-Pb age gap between the zircon core (ca. 248 Ma) and rim (ca. 240 Ma) reveals a protracted magma storage (~8 Myr) prior to the volcanic eruption. When compared to the zircon rims, the zircon cores have higher Ti content and Zr/Hf and Nb/Ta ratios, but lower Hf content and light/heavy rare earth element ratios, which suggests that the parental magma was hotter and less evolved than the basaltic andesite. The plagioclase accumulation likely resulted in Al2O3-enrichment and Fe-depletion, forming the calc-alkaline signature of the Nageng (basaltic-)andesites. The magma temperature, as indicated by the zircon saturation and Ti-in-zircon thermometry, remained low (725–828 °C), and allowed for the magma chamber to survive over ~8 Myr. The decreasing εHf(t) values from zircon core (avg. 0.21, range: −1.28 to 1.32) to rim (avg. −3.68, range: −7.30 to −1.13), together with the presence of some very old xenocrystic zircons (268–856 Ma), suggest that the magma chamber had undergone extensive crustal contamination.

Tailoring the microstructure, martensitic transformation and strain recovery characteristics of Ti-Ta shape memory alloys by changing Hf content

In the present work, the microstructure features, martensitic transformation, mechanical properties and strain recovery characteristics of Ti-Ta based shape memory alloys were tailored by changing Hf contents. The single α´´ martensite phase was dominated in Ti-Ta alloy with 2 at.%H f. Upon Hf content exceeded 2 at.%, β phase started to appear. Moreover, the amount of β phase gradually increased with Hf content increasing. The martensitic transformation temperatures continuously decreased with the increased Hf content, which was attributed to the rising of valence electron concentration. Meanwhile, Hf addition improved the thermal cycling stability of Ti-Ta alloys due to the suppression of ω precipitation. The yield stress of Ti-Ta based alloys firstly decreased and then increased with Hf content increasing. In addition, the completely recoverable strain of 4 % can be obtained in Ti-Ta alloy with 6 at.% Hf as a consequence of the higher critical stress for dislocation slip. Besieds, the Ti-Ta based alloy containing 8 at.% Hf had the superior superelasticity behavior with the fully recoverable strain of 2 % at room temperature.

Formulation and Evaluation of Diluted Sulfuric-Peroxide-HF (DSP+) Mixtures for Cleaning High-Aspect Ratio Contacts in 3D NAND

In this study, organic strip, particle removal efficiency and wettability were investigated at different mixing concentrations of diluted Sulfuric-Peroxide-HF (DSP+) solutions with and without the addition of IPA. Organic strip evaluation was carried out with KrF photoresist (PR), and the strip rate was increased rapidly with the increase in H2SO4 concentration mixed with DI water (DIW). The effects of H2O2 and IPA addition on diluted H2SO4 were observed below 30 vol% of H2SO4. The thickness of PR was increased with the addition of H2O2 to the solutions and the strip rate was increased when IPA was added. Silica particles were used to evaluate particle removal efficiency. The concentration of HF was the predominant factor of increasing PRE, and the addition of H2SO4 and H2O2 assisted in obtaining high PRE, while IPA addition reduced PRE. Decreasing of contact angle was observed with an increase of IPA addition to DSP+ solutions, and improved wettability of DSP+ solutions was expected to effectively clean particles in high-aspect-ratio (HAR) contact holes.

Measurement of the melting temperature of ZrB2 as determined by laser heating and spectrometric analysis

AbstractThe melting temperatures of two different ZrB2 ceramics were studied using laser induced melting. ZrB2 having a low Hf content, produced by reaction hot pressing, had a melting temperature of 3546 K and a commercial grade ZrB2 had a melting temperature of 3553 K. Uncertainty of the temperature measurements was 1% of the absolute temperature, or ~35 K for both materials based upon 2‐sigma and a 95% confidence interval. While these values were consistent with the previously reported ZrB2 melting temperature of 3518 K, this study was able to measure Tm with less uncertainty than previous studies (±45 K). Furthermore, this study assessed the effect of Hf content on melting temperature, finding that melting temperature did not change significantly for hafnium contents of 1.75 to 0.01 at%. This study also measured a normal spectral emissivity of 0.34 for ZrB2 at 3000 K. The emissivity decreased to 0.28 at the melting temperature, then, stabilized at 0.30 in a liquid phase.

Episodic crustal growth and reworking at the southeastern margin of the North China Craton: evidence from zircon U–Pb and Lu–Hf isotopes of Archean tonalite–trondhjemite–granodiorite gneisses in the Bengbu-Wuhe area

The cratonization history of the North China Craton (NCC) and the nature of tectonothermal events are still highly controversial. Tonalite-trondhjemite-granodiorite (TTG) gneisses, as the dominant lithological assemblages in Archean metamorphic terranes, can provide significant clues to the magmatic and metamorphic evolution of Precambrian crust. This study presents zircon laser-ablation inductively-coupled-plasma mass spectrometry U–Pb ages, trace-element, and in-situ LA-MC-ICP-MS zircon Hf isotope data for the TTG gneisses from the Bengbu-Wuhe area on the southeastern margin of the NCC. Cathodoluminescence images and trace elements indicated that magmatic zircons display the characteristics of euhedral-subhedral crystals with oscillatory growth zoning structures, high ΣREE contents, marked Ce positive anomalies, and Pr–Eu negative anomalies. The metamorphic zircons display the spherical-oval crystals with distinct core-rim structures, high and homogeneous luminescent intensity, lower ΣREE, Nb, Ta, Hf contents, relative flat REE patterns, weak Ce positive anomalies, and Pr-Eu negative anomalies. The Ti–in–zircon geothermometer data indicate that the crystallization temperature of the TTG gneiss ranged from 754 to 868 °C. Zircon U–Pb ages indicate that the TTG gneisses formed at 2.79–2.77 Ga and 2.50 Ga and underwent metamorphism at 2.57–2.52 Ga. The Hf isotopic data indicate that the magmatic zircons exhibit high, positive eHf(t) values close to those of the coeval depleted mantle, whereas the metamorphic zircons exhibit negative or nil eHf(t) values. This implies that the TTG gneisses were derived from the partial melting of the ~ 2.9–2.6 Ga juvenile crustal sources mixed with ~ 3.0–2.8 Ga ancient crustal materials. Combined with the regional tectonic evolution, we propose that the metamorphic basement at the southeastern margin of the NCC underwent episodic crustal growth at ~ 2.7 and ~ 2.5 Ga and subsequently underwent crustal reworking or re-melting of the ancient crust during the Neoarchean. The Neoarchean TTG gneisses might have been derived from the partial melting of lower crustal materials related to plate subduction.

Evolution behavior of liquid film in the heat-affected zone of laser cladding non-weldable nickel-based superalloy

Laser cladding with a paraxial powder-feeding device was used to repair as-cast K447A nickel-based superalloy, a kind of non-weldable alloy with a high Hf content and working as gas-turbine hot-section components. In the present study, the metallurgical evolution behavior of liquid film and liquation cracking mechanisms are studied. The results showed that a kind of uncommon Ni21Hf8 phase was found in the incipient melting regions (IMR) of the intergranular region. In the thermal cycle, γ/Ni21Hf8 eutectic liquefaction, M5B3 dissolved, and γ/γ’ eutectic liquefaction successively occurred in the heating process in IMR, and liquid → γ + γ/γ’ + M5B3 + γ/Ni21Hf8 → γ + γ’(3) + γ/γ’ + γ/Ni21Hf8 + M5B3 occurred in the cooling process. The inhomogeneity of the intergranular structure leads to the liquid film with the characteristics of discontinuous distribution and uneven width. The cracking criterion of the liquid film was established based on pressure drop. When the closed liquid film meets the condition of 2γsl<1/K*(ρs/ρl−1*R*dt+∆hε), the liquid film with a thickness that is greater than critical thickness will be induced into a liquation cracking.

Differentiating Zr/HfIV Aqueous Polyoxocation Chemistry with Peroxide Ligation.

This work complements our recent discovery of new phases derived from zirconium perchlorate by addition of hydrogen peroxide. Here, we investigate analogous reactions with hafnium perchlorate, which is found to have modifications of the Clearfield-Vaughan tetramer (CVT). For hafnium perchlorate derivatives, we find distorted versions of CVT by X-ray diffraction and study the reaction solutions by SAXS, Raman spectroscopy, and ESI-MS. Furthermore, we investigate mixed Hf-Zr solution and solid phases and find the latter resemble the zirconium family at low Hf concentrations and the hafnium family at higher hafnium contents.

Dependence of characteristics of Hf(M)SiBCN (M = Y, Ho, Ta, Mo) thin films on the M choice: Ab-initio and experimental study

Amorphous HfMSiBCN materials (M = Y, Ho, Ta, Mo or an enhanced Hf content instead of any other M) are investigated by ab-initio calculations and magnetron sputtering. We focus on combining the high-temperature stability and oxidation resistance of these materials with optimised mechanical, optical and electrical properties. First, we predict the corresponding trends by calculating the effect of the M choice and fraction on formation energy (Eform) and mechanical properties of MN and HfxM1–xN crystals. We discuss the dependence of Eform(HfxM1–xN) on the crystal structure and the distribution of Hf and M in the metal sublattice. The mechanical properties calculated for MN correlate with those measured for HfMSiBCN. The driving force towards N incorporation, decreasing with the periodic-table group number of M according to the calculated Eform(MN), correlates with the measured increasing electrical conductivity and extinction coefficient of HfMSiBCN. Second, we model the amorphous HfMSiBCN materials themselves by ab-initio molecular dynamics. The calculated band gap, localisation of electronic states and bonding preferences of M also correspond to the increasing metallicity with respect to the periodic-table group number of M and confirm the possibility of predicting the trends in characteristics of HfMSiBCN using those of MN. Third, we study the measured HfMSiBCN properties as functions of each other and identify sputter target compositions leading to hard films with high electrical conductivity at a relatively low extinction coefficient. The results are important for the design of hard, conductive and/or transparent high-temperature coatings.

Successive magma mixing in deep-seated magma chambers recorded in zircon from mafic microgranular enclaves in the Triassic Mishuling granitic pluton, Western Qinling, Central China

Abstract Extensive Mesozoic magmatism in the Qinling orogenic belt, Central China, has produced voluminous granitic plutons. In Western Qinling, the Triassic Mishuling pluton contains abundant mafic microgranular enclaves (MMEs), recording magma mixing processes in the generation of the pluton. The Mishuling pluton is composed of quartz monzonite, whereas the MMEs are mainly diorite and monzonite. In this study, zircons from the MMEs are all dated by LA-ICP-MS at ca. 215 Ma, clearly consistent with the crystallization age of the host pluton. Quartz monzonites have low Mg# (43–48), Cr (30–64 ppm), and Ni (11–39 ppm) and high Th/U relative to the MMEs. Quartz monzonites are considered to have been produced by melting of Neoproterozoic mafic rocks in the northwestern part of the Yangtze Block, whereas the MMEs were likely the products of mixed mafic and felsic magmas. The mafic magmas may have been derived from partial melting of the enriched lithospheric mantle. Both the MMEs and host quartz monzonites have nearly identical Sr-Nd isotopic compositions, indicating that the hybrid melts and felsic magmas may have reached Sr-Nd isotopic equilibrium due to magma mixing. Zircon grains from the MMEs can be further divided into three types on the basis of internal texture and eHf(t). Overall, all these types of zircon grains have Th/U ranging from 0.18 to 1.63, typical of magmatic origin. Type-1 zircon grains show well-developed {1 0 0} and {1 1 0} prisms as well as {1 0 1} and {2 1 1} pyramids, whereas Type-2 zircon grains show well-developed {1 0 1} pyramids and {1 1 0} prisms. Types-1 and 2 zircon grains have slightly higher eHf(t) (–0.2 to –4.4) than those of the zircon grains from quartz monzonites (eHf(t) = –2.7 to –5.4), indicating crystallization from different hybrid magmas. Type-3 zircon grains have morphology and eHf(t) similar to and Hf concentrations lower than those of the zircon grains from quartz monzonites. We interpret that the Type-3 zircon grains were likely captured from less evolved granitic magmas and are thus xenocrysts in the MMEs. Therefore, the three types of zircon grains from the MMEs record successive magma mixing processes in deep-seated magma chambers. Such a scenario may have broad implications for magma mixing in the generation of granitic plutons.