Chloride Concentration Research Articles

Chloride Resistance of Assembled Bridge Piers Reinforced with Epoxy-Coated Steel Bars

To reveal the influence of joint type and epoxy-coated steel bar surface damage on the durability of assembled bridge piers, this study simulated the potential damage to epoxy-coated steel bars at various stages of an actual construction process by bending, scratching, and knocking. The pier inter-segmental joint and the pier-bearing platform joint were designed to highlight the critical zones affecting the durability of sea-crossing bridge substructures. The migration of chloride ions into the concrete was accelerated by applying a constant voltage DC electric field. The electrochemical indexes of epoxy-coated steel bars and chloride ion content in concrete were measured regularly. Results show that the corrosion risk and corrosion rate of steel bars increase significantly when the damaged area ratio of epoxy coating is higher than 5%. The chloride ion transport rate at the interface of the pier-bearing platform joint is about 5 times that of the pier inter-segmental joint. The service life of the pier-bearing platform joint is only 1/2 that of the pier inter-segmental joint when epoxy-coated steel bars with the same treatment are used.

Investigating the Synergistic Corrosion Protection Effect of an Alloy Element and Corrosion Inhibitor on Steel Reinforcement Using Machine Learning and Electrochemical Impedance Spectroscopy

Steel reinforcement in marine concrete structures is vulnerable to chloride-induced corrosion, which compromises its structural integrity and durability. This study explores the combined effect of the alloying element Cr and the smart corrosion inhibitor LDH-NO2 on enhancing the corrosion resistance of steel reinforcement. Employing a machine learning approach with a support vector machine (SVM) algorithm, a predictive model was developed to estimate the polarization resistance of steel, considering Cr content, LDH-NO2 dosage, environmental pH, and chloride concentration. The model was rigorously trained and validated, demonstrating high accuracy, with a correlation coefficient exceeding 0.85. The findings reveal that the addition of Cr and application of LDH-NO2 synergistically improve corrosion resistance, with the model providing actionable insights for selecting effective corrosion protection methods in diverse concrete environments.

Determination of bioactive substances in 27 edible flowers based on LC-MS/MS

Edible flowers, as a food ingredient, are rich in bioactive substance and have received a lot of attention. In this study, we have established a pseudo-targeting method based on Multi Reaction Monitoring (MRM) - Enhanced Product Ions (EPI) in the Information Dependent Acquisition (IDA) mode. The results showed that a total of 43 metabolites, including flavonoids, phenolic acids, and terpenes were detected in 27 edible flowers using integrated liquid chromatography-tandem mass spectrometry (LC-MS/MS) strategy. Rutin was measured in all edible flowers, but the levels varied significantly among the different varieties of flowers, with the highest being about 3500 times the lowest. Albiflorin and paeoniflorin are polyphenolic substance unique to Paeonia suffruticosa. The cyanidin 3-O-glucoside chloride content in reddish-purple flowers is higher than that of other colors. Dicoumarin and 4-hydroxycoumarin were discovered in edible flowers for the first time. This study established a pseudo-targeted detection method to reveal the distribution of polyphenolic metabolites and enriched the research on polyphenolic metabolites in edible flowers. It can also serve as a general strategy to detect metabolites in other agricultural products, providing valuable information about potential metabolites for consumers.

The role of nanoparticle–surfactant interactions in air-stabilized foams used for improving oil recovery

Foam flooding, an emerging tertiary oil recovery technique, demonstrates efficacy as a conformance control method in enhanced oil recovery. Conformance control mitigates injected displacement fluid channeling and bypassing, improving macroscopic sweep efficiency. Generated foamed films preferentially enter high permeability zones, diverting subsequent injection into unswept lower permeability regions. Nanoparticle-reinforced foams exhibit consistent bulk stability and effective residual oil mobilization. This work utilizes dynamic foam analysis to probe the synergistic effects of zinc oxide nanoparticles and anionic surfactant on foam generation and persistence. Bulk and local scale foam stability is evaluated under various potassium chloride concentrations. Optimal foam stability occurs near the critical micelle concentration of the surfactant at 2,500 ppm. Increasing electrolyte concentration within a fixed surfactant formulation decreases foam stability due to salt-induced micellar swelling. An optimized electrolyte and nanoparticles with a surfactant combination produce high-quality foam with increased bubble density per unit area. Micellar swelling by nanoparticle adsorption inhibits lamellae thinning and liquid drainage. Enhanced foam properties improve microscopic displacement efficiency and mobility control in foam-assisted oil recovery. Oil recovery is increased by approximately 22% compared to conventional waterflooding.

Research on spatial corrosion behavior and durability protection technology of concrete box girder bridge in cold regions

In order to study the corrosion behavior of concrete box girder in deicing salt environment, a series scaled model of concrete box girders were made to study the deterioration mode of concrete box girder under load, chloride corrosion, freeze-thaw cycle and their combined action. Combined with silane impregnation, the durability protection technology of concrete box girder bridges in cold regions was proposed. The experimental results show that under freezing-thawing action, the top plate of the box girder has the most serious deterioration, and the performance of the web is better. The surface erosion of the top plate is 65.38 % and 80.77 % different from that of the bottom plate and web plate, respectively. The freezing-thawing erosion of the concrete box girder has a significant spatial multi-dimension. The chloride ion erosion law of the top plate and bottom plate of concrete box girder is similar to the distribution law of shear lag effect under load. The inhibition effect of compressive stress on chloride ion is 9.67 %, and the overall inhibition effect is not large. The maximum difference of chloride ion concentration at each measuring point on the bottom plate is 30.14 %. Silane can be used as a protective coating for concrete bridges in cold areas, and the coating thickness of 2 mm can meet the requirements of anti-freezing. With the increase of freeze-thaw time, the silane protection ability began to decline. The maximum silane protection effect of 0–1 cm from the surface at 90d and 180d decreased by 40.8 % and 71.7 %, respectively. After the silane coating was applied, the chloride ion erosion rate of the bottom plate still showed a faster trend. When the freeze-thaw cycle exceeded 30 times, the silane protection ability decreased almost at a linear rate with the freeze-thaw time. Regardless of whether the silane coating protection technology is adopted, the chloride ion concentration of the bottom plate of concrete box girders is at least 10 % more than that of the top plate for freeze-thawing 90d and 180d, and the maximum can reach 32.1 %. The deterioration behavior of concrete box girders in cold regions has significant spatial multi-dimension. The existing single-parameter durability design methods, which mainly focus on solid section, are no longer suitable for box girder structures.

Adaptive machine learning surrogate based multiobjective optimization for scavenging residual saltwater behind subsurface dams

High-fidelity physically based groundwater flow and solute transport models have been limited for seawater intrusion remediation design because of computationally intensive evolutionary algorithms. Data-driven machine learning approaches are promising to substitute expensive-cost groundwater numerical models within optimization due to computing efficiency. However, machine learning surrogates may accumulate error of forecasting and thereby result in infeasible optimal solutions. To achieve desired fidelity level, this study proposes a novel adaptive machine learning surrogate based multiobjective optimization method for coastal aquifer desalination. An adaptive modeling algorithm is newly introduced to iteratively retrain poorly-performed machine learning models and enhance predicting accuracy. The method is demonstrated to seek optimal extraction and injection strategies for scavenging residual saltwater trapped in an upstream aquifer behind a subsurface dam. Two conflicting objectives of minimizing the total extraction-injection rate and maximizing saltwater removal effectiveness are considered. Three machine learning models including artificial neural network (ANN), Gaussian process (GP) and response surface regression model (RSR) are developed to replace a high-fidelity seawater intrusion model for predicting chloride concentration and salinity mass. Non-dominated Sorting Genetic Algorithm II (NSGA-II) is employed to derive Pareto fronts. Pareto optimal solutions obtained from machine learning models are compared against those from the seawater intrusion model. Results indicate that the developed machine learning models do not only have strong predicting capability, but also maintain good quality of Pareto optimal solutions, while achieving substantial computational saving up to 95%. Especially, the adaptively retrained RSR model inhibits error accumulation of forecasting and accelerates correct convergence to the true Pareto front. The proposed method is found superior performance in accurate convergence, widely-spread diversity as well as high computing efficiency than conventional methods.

Effects of temperature, chloride and perchlorate salt concentration on the metabolic activity of Deinococcus radiodurans

The extremophile bacterium Deinococcus radiodurans is characterized by its ability to survive and sustain its activity at high levels of radiation and is considered an organism that might survive in extraterrestrial environments. In the present work, we studied the combined effects of temperature and chlorine-containing salts, with focus on perchlorate salts which have been detected at high concentrations in Martian regolith, on D. radiodurans activity (CO2 production rates) and viability after incubation in liquid cultures for up to 30 days. Reduced CO2 production capacity and viability was observed at high perchlorate concentrations (up to 10% w/v) during incubation at 0 or 25 °C. Both the metabolic activity and viability were reduced as the perchlorate and chloride salt concentration increased and temperature decreased, and an interactive effect of temperature and salt concentration on the metabolic activity was found. These results indicate the ability of D. radiodurans to remain metabolically active and survive in low temperature environments rich in perchlorate.

Comparison between the sodium chloride content and labeled salt value of industrially prepared Japanese single dishes.

Salt intake reduction is a global concern. In particular, Japanese consume higher amounts of salt than those of other ethnicities. The sodium content is mentioned on the label of industrially prepared dishes with an intention of reducing salt intake. This study aimed to evaluate the difference between the actual sodium content and labeled salt value of industrially prepared Japanese single dishes. Samples labeled "estimated" were collected and classified as Japanese, Western, and Chinese cuisines. The sodium content ranged from 180 to 1011mg/100g. The sodium content was higher than their reported values in other countries. Specifically, Chinese dishes contained high amounts of sodium, although the chloride content was similar across cuisine styles. Further, the molar ratio (i.e., sodium/chloride) had no significant effect on the difference between the actual content and labeled value. The measured salt contents were 20% higher than the labeled values. The results of decision tree analysis indicated that if the labeled salt value of stir-fried foods is determined by calculation, the actual sodium content is much higher than the labeled salt value. These findings are crucial for customers, dietitian, and researchers as they refer to the labeled salt value to determine the sodium content of industrially prepared foods.

Research on pollution identification and safety thresholds based on the olfactory effect on a halogenated hydrocarbon contaminated site

To effectively address odor control issues at sites contaminated with halogenated hydrocarbons, it is essential to establish an odor risk prediction system for evaluating potential risks that may impact future planning. This research focuses on a representative halogenated hydrocarbon-contaminated site, examining the spatial and temporal distribution characteristics of key pollutants in soil gas. By analyzing odor contribution rates, the study identifies significant odorants in soil gas, which enables the derivation of both probabilistic and deterministic safety thresholds for soil and groundwater based on olfactory effects. The findings indicate that 1,1-dichloroethylene, vinyl chloride, chloroform, and 1,1-dichloroethane are prevalent throughout the contaminated site, displaying elevated concentration levels and substantially influencing the overall contamination extent. These substances are highlighted as critical pollutants requiring attention. Correlation analysis (P < 0.05) reveals a strong relationship between the concentrations of vinyl chloride, 1,1-dichloroethane, and chloroform with groundwater depth and air temperature. Additionally, the analysis of odor activity values (OAV) identified 1,1-dichloroethene, 1,4-dichlorobenzene, chlorobenzene, chloroform, and vinyl chloride as key olfactory factors at the site. The corresponding probabilistic safety thresholds are 0.68, 1.65, 0.50, 7.87, and 3.72 mg kg−1 for soil, and 9.29, 3.46, and 1.09, 69.55, and 47.01 mg L−1 for groundwater, respectively. Among them, the odor risks of chlorobenzene and 1,1-dichloroethylene warrant more attention than soil contamination risks; regarding 1,4-dichlorobenzene, it is recommended to concurrently consider odor risks during human health risk assessment; as for vinyl chloride and chloroform, their odor risks can be largely eliminated based on human health-oriented pollution management.

The influence of passivation temperature on the corrosion resistance of passivation film for Q235 steel in simulated pore solution of concrete with chloride or/and sulfate ions

The effect of temperature on the corrosion resistance performance of the passivation film (PF) formed at 20 °C to 60 °C was investigated systematically in Cl− ion or/and SO4 2− ion solution. It is found that the temperature accelerates the growth rate of PF and increases the thickness of PF. In addition, the critical chloride ion concentration of PF at 20 °C to 40 °C, and that of PF at 50 °C and 60 °C, which is increased by 15.8%. In the single SO4 2−, all the PF were not depassivated with the increased concentration of SO4 2−. However, at the presence of Cl−, the PF were depassivated once the concentration of SO4 2− reaches 0.18 mol/L. These results show that in a single ion environment, the corrosion resistance of PF increased with the passivation temperature, while the impact of temperature on the corrosion resistance of PF is negligible in the combine solution of 3.5 wt% Cl− and SO4 2− ions.

An investigation into the aging mechanism of disposable face masks and the interaction between different influencing factors

In the natural environment, a symphony of environmental factors including sunlight exposure, current fluctuations, sodium chloride concentrations, and sediment dynamics intertwine, potentially magnifying the impacts on the aging process of disposable face masks (DFMs), thus escalating environmental risks. Employing Regular Two-Level Factorial Design, the study scrutinized interactive impacts of ultraviolet radiation, sand abrasion, acetic acid exposure, sodium chloride levels, and mechanical agitation on mask aging. Aging mechanisms and environmental risks linked with DFMs were elucidated through two-dimensional correlation analyses and risk index method. Following a simulated aging duration of three months, a single mask exhibited the propensity to release a substantial quantity of microplastics, ranging from 38,800 ± 360 to 938,400 ± 529 particles, and heavy metals, with concentrations from 0.06 ± 0.02μg/g (Pb) to 29.01 ± 1.83μg/g (Zn). Besides, specific contaminants such as zinc ions (24.24μg/g), chromium (VI) (4.20μg/g), thallium (I) (0.92μg/g), tetracycline (0.51μg/g), and acenaphthene (1.73μg/g) can be adsorbed significantly by aged masks. The study elucidates pivotal role of interactions between ultraviolet radiation and acetic acid exposure in exacerbating the environmental risks associated with masks, while emphasizing the pronounced influence of many other interactions. The research provides a comprehensive understanding of the intricate aging processes and ensuing environmental risks posed by DFMs, offering valuable insights essential for developing sustainable management strategies in aquatic ecosystems.

Analysis of service life and reliability of C50CASC structures in the splash zone of the South China Sea

This paper presents the results of a reliability analysis of the service life of hydraulic structures made of C50 coral aggregate seawater concrete (CASC) in the splash zone of the South China Sea. The analysis was conducted using the ChaDuraLife V1.0 software, which is based on reliability theory and modified chloride diffusion theory. Several parameters such as the surface free chloride concentration (Cs), chloride binding capacity (R), free chloride diffusion coefficient (Df), apparent chloride diffusion coefficient (Da), and time-dependent index (m) were considered in this analysis. The (1-m) boundary condition is adopted in this study. The effect of concrete cover thickness on the service life of CASC structures was discussed. The influence of rebar types and external protective measures on the service life was also investigated. Durability recommendations for C50CASC hydraulic structures in the splash zone were proposed. The minimum concrete cover thickness needed to achieve the service life of 30a to 100a was determined to provide theoretical support for the application of CASC in island and reef engineering. The results found that the best technical measures for extending the service life were the application of 2205 duplex stainless steel bars and silane protective coating on the surface of concrete structures. A concrete cover thickness of 6–7 cm could achieve the service life of 50a, while a thickness of 8.5–10 cm, could achieve the service life of 100a.

Three-Dimensional Spatial Distribution of the Sedimentation Rate of Chloride Ions on a Tropical Island

Chlorine ions in the air are a key factor in the corrosion of offshore buildings. Mastering the distribution law of the chloride ion settlement rate (RCl−) in three-dimensional (3D) spatiality is helpful in protecting offshore buildings. The self-designed “kite-hanging wet candle method” was used to collect chloride ions in the air, using ion chromatography to analyze the chloride ion concentration of the sample solution, and obtained the annual RCl− in the offshore atmosphere at different vertical heights, using the Pearson correlation coefficient method to analyze the influence of environmental factors on the RCl−. The results show that the RCl− has a significant linear relationship with temperature, relative humidity and wind speed. Among them, the RCl− is positively correlated with temperature and negatively correlated with wind speed and relative humidity. In the vertical height range of 10–100 m, the RCl− presents a “⊂”-shaped distribution. In the range of 10–30 m, the RCl− is mainly controlled by the impact of ocean spray; in the range of 30–80 m, the RCl− is mainly controlled by marine aerosols; and in the range of 80 m–100 m, the RCl− is mainly controlled by marine aerosols and wind speed. Under the influence of wind direction and wind speed, the RCl− of the windward side is higher than that of the leeward side at different monitoring points, which are close to the coastline and at a low vertical height. Studying the distribution of the RCl− in 3D spatiality can effectively prevent and reduce its impact on offshore buildings.

Pneumatic extrusion bioprinting-based high throughput fabrication of a melanoma 3D cell culture model for anti-cancer drug screening.

The high incidence of malignant melanoma highlights the need for in vitro models that accurately represent the tumour microenvironment, enabling developments in melanoma therapy and drug screening. Despite several advancements in 3D cell culture models, appropriate melanoma models for evaluating drug efficacy are still in high demand. The 3D pneumatic extrusion-based bioprinting technology offers numerous benefits, including the ability to achieve high-throughput capabilities. However, there is a lack of research that combines pneumatic extrusion-based bioprinting with analytical assays to enable efficient drug screening in 3D melanoma models. To address this gap, this study developed a simple and highly reproducible approach to fabricate a 3D A375 melanoma cell culture model using the pneumatic extrusion-based bioprinting technology. To optimise this method, the bioprinting parameters for producing 3D cell cultures in a 96-well plate were adjusted to improve reproducibility while maintaining the desired droplet size and a cell viability of 92.13± 6.02%. The cross-linking method was optimised by evaluating cell viability and proliferation of the 3D bioprinted cells in three different concentrations of calcium chloride. The lower concentration of 50 mM resulted in higher cell viability and increased cell proliferation after 9 days of incubation. The A375 cells exhibited a steadier proliferation rate in the 3D bioprinted cell cultures, and tended to aggregate into spheroids, whereas the 2D cell cultures generally formed monolayered cell sheets. In addition, we evaluated the drug responses of four different anti-cancer drugs on the A375 cells in both the 2D and 3D cell cultures. The 3D cell cultures exhibited higher levels of drug resistance in all four tested anti-cancer drugs. This method presents a simple and cost-effective method of producing and analysing 3D cell culture models that do not add additional complexity to current assays and shows considerable potential for advancing 3D cell culture models' drug efficacy evaluations.

Experimental exploration of potassium compounds in the vicinity of a burning biomass pellet: From near-surface to downstream

The concentrations of gas-phase potassium hydroxide (KOH), potassium chloride (KCl) and atomic potassium (K(g)) were quantitatively measured from the near-surface to downstream area of burning pinewood pellets by a newly developed photofragmentation tunable diode laser absorption spectroscopy (PF-TDLAS) technique to reveal the original form of the released potassium. The novel arrangement of the PF-TDLAS system enabled a spatial resolution of ∼1 mm3, which made it possible to obtain temporal release profiles of K(g)/KOH/KCl at different heights above the burning pellet surface. Surface temperature and mass loss of the wood pellet as well as the gas temperature at measurement points were measured simultaneously. During the devolatilization stage, the release of all three potassium species was observed, with each of them accounting for ∼1/3; while in char oxidation stage, the release of KOH was dominant, but the release intensity was strongly influenced by the local oxygen content. The results from different measurement heights showed there was a notable difference in potassium release profiles of different potassium species over the near-surface area, where the detected potassium forms were the best representative of the originally released forms of potassium. For a period of time during the devolatilization stage, only K(g) was detected in the near-surface area, and the concentration was significantly lower than the downstream area where KOH and KCl coexisted. This suggested that a large amount of potassium might leave the pellet as organic-K, which cannot be detected by the PF-TDLAS method. During char oxidation stage, the total potassium concentration at the near-surface area was also lower than the downstream area, but it was due to the lack of oxygen at the measurement position. A potassium release mechanism during the devolatilization stage of biomass combustion was proposed based on the experimental measurements, and the results also indicated the importance of spatially resolved measurement.

Metallurgical failure investigation of small bore piping (SBP) in a diesel hydrotreating unit (DHT) of an oil refinery

Abstract Hydrocarbon leaks were repeatedly found in the client’s refinery. Because of the recurring nature of this failure, the operator approached the authors’ laboratory to get a second opinion on the metallurgical root cause of the failure. It was known from the customer that corrosive species, such as ammonium chloride salt precipitates, are present in the subject diesel hydrotreating unit (DHT). From the findings obtained in the investigation that is the subject of this contribution, the conclusion of the original metallurgical root cause analysis (RCA), namely that the subject piping failed by transgranular chloride-induced stress corrosion cracking (Cl-SCC), could be verified and is indeed correct. The metallurgical root cause of the small bore piping (SBP) failure is chloride-induced SCC. The morphology of the cracking is very distinct and is clearly consistent with transgranular Cl-SCC. A material change to the nickel-base material Alloy 625, already considered by the client, since this alloy is believed to be immune to chloride-induced SCC, would be a good, even though expensive solution. It should be emphasized that there are no metallic materials completely resistant to SCC. If the environment is harsh enough, except for some titanium alloys, i. e., if the source of the chloride ions cannot be eliminated, which is likely the case here, a regular inspection and replacement of these SBP systems might have to be considered. It should further be emphasized that a chloride concentration below 50 ppm is by no means any guarantee for the avoidance of SCC, since chlorides can concentrate in crevices, corrosion pits and such, i. e., the local concentration is what matters, not the local.

Assessment of surface Water Quality for Drinking and Irrigation Purposes for Two Dams in the Semi-Arid Region of Northeast Algeria

&lt;p&gt;The surface water quality of Timgad and Yabous dams in the semi-arid region of northeast Algeria was evaluated using physicochemical data collected monthly from May 2023 to April 2024. Parameters including temperature (T), pH, electrical conductivity (EC), total dissolved solids (TDS), chloride (Cl⁻), sulfate (SO₄²⁻), bicarbonate (HCO₃⁻), nitrate (NO₃⁻), sodium (Na⁺), potassium (K⁺), calcium (Ca²⁺), and magnesium (Mg²⁺) were analyzed to assess suitability for drinking and irrigation purposes. For drinking purposes, the Water Quality Index (WQI) and CCME-WQI were employed. Results showed permissible WQI values for Timgad Dam throughout the year, with Yabous Dam exhibiting good quality consistently. However, CCME-WQI classified Timgad Dam as marginal and Yabous Dam as fair annually, indicating a need for caution, particularly for Timgad Dam. For irrigation purposes, various indices including Sodium Adsorption Ratio (SAR), Sodium Percentage (NA%), Residual Sodium Carbonate (RSC), Permeability Index (PI), Potential Salinity (PS), Kelly’s Ratio (KR), Residual Sodium Bicarbonate (RSBC), and Magnesium Hazard (MH) were utilized. While both dams generally demonstrated suitable classes for irrigation, Timgad Dam exhibited unsuitability due to elevated Potential Salinity values, attributed to high chloride and sulfate concentrations that probably come from anthropogenic activities and natural processes, and MH values were unsuitable for both dams throughout the year.&lt;/p&gt;

Overcoming passivation through improved mass transport in dense ionic fluids.

Deep Eutectic Solvents (DESs) have recently been shown to be part of a dense ionic fluid continuum between ionic liquids and concentrated aqueous brines. Charge transport was shown to be governed by fluidity, with no discontinuity between molar conductivity and fluidity irrespective of cation, charge density or ionic radius. By adjusting the activity of water and chloride ions, mass transport, speciation and reactivity can be altered. It has been shown that while brines provide a high chloride content at a lower viscosity than DESs, unlike DESs, brines are unable to prevent metal passivation due to their high water content. This results in the possibility to impart a level of selectivity towards metal dissolution (or passivation) when processing mixed metal materials. Forced convection can be used to avoid the issue of slow mass transport in viscous media, and the use of jets or targeted ultrasound are effective methods for overcoming this issue. High-powered ultrasound was applied to copper, cobalt, and aluminium electrodes undergoing anodic dissolution, and linear sweep voltammetry showed a linear current-voltage response at potentials anodic of the oxidation potential under sonication, with total charge passed being 5 to 134 times greater than under silent conditions. Application of ultrasound to silver and nickel electrodes displayed an initial linear current-voltage response, but the increased water content of the brines resulted in passivation. Mass transport throughout the bulk solution is governed by the forced convection imparted by the ultrasound and ionic species must only migrate across the electrical double layer. It is shown that the anodic dissolution of a range of metals classically expected to passivate, e.g. aluminium, can be significantly accelerated under insonation conditions.

An alternative approach to protect micro-cracked reinforced concrete under a marine environment

This research aimed to establish prevention guidelines and mitigate the effects of chloride penetration in micro-cracked concrete by enhancing the quality of additive materials or fly ash and employing galvanic cathodic protection to guard against steel corrosion. The effects of micro-crack deterioration in reinforced concrete beams on the corrosion of reinforcing steel bars were investigated. Fly ash (FA) was replaced ordinary Portland cement (OPC) at rates of 0 %, 15 %, 30 %, and 45 % by weight of binder, with a water-to-binder (W/B) ratio of 0.45. Prevention measures included removing large particle sizes of the fly ash, and grinding to achieve high fineness, ensuring that particles retained on a sieve No.325 were less than 5 %. The test results showed that increasing the replacement of OPC with FA improved the chloride penetration resistance of the concrete, with lower detected chloride content compared to OPC concrete, and reduced the weight loss of the reinforcing steel bars. Additionally, the improvement of fly ash (IPF concrete) reduced the electric current to less than 20 mA, whereas the control concrete (PC) exhibited electric currents of about 80–100 mA. Another effective method for protecting against steel corrosion is the use of galvanic cathodic protection (GCP) in concrete, which can help reduce the electric current to 10 mA. Guidelines and preventive measures are suggested to ensure that structures can withstand environmental over time, maintaining their reliability and safety throughout their service life.

Rectal organoid morphology analysis (ROMA) as a novel physiological assay for diagnostic classification in cystic fibrosis

BackgroundDiagnosing cystic fibrosis (CF) is not always straightforward, in particular when sweat chloride concentration (SCC) is intermediate and <2 CF-causing CFTR variants are identified. The physiological CFTR assays proposed in...