Lava Compositions Research Articles

Heavy Mo isotope enrichment in the Pitcairn plume: Implications for the subduction cycle of anoxic sediments

Subduction redistributes elements between Earth's principal geochemical reservoirs, modifying the chemical composition of Earth's mantle, crust, atmosphere, and hydrosphere, and consequently having an impact on the evolution of life itself. Subduction of surface material that has been geochemically modified by low-temperature processes leads to mineralogical and chemical heterogeneities in mantle reservoirs over time and is recorded in modern ocean island basalts. One of the principal geochemical end members of the heterogeneous deep mantle, the enriched mantle 1 (EM-1) source of Pitcairn Island, has been attributed to the contribution of crustal material with vastly different chemical compositions and ages. The Mo isotope composition of lavas from Pitcairn Island constrains the nature of this recycled crustal component. Pitcairn lavas have elevated δ98/95Mo relative to the depleted mantle. The high δ98/95Mo is associated with high time-integrated 232Th/238U and 87Rb/86Sr, and low time-integrated 147Sm/144Nd and 238U/204Pb. These characteristics can be attributed to the recycling of nearly pristine pelagic sediments that were deposited in a Proterozoic anoxic deep-ocean into the sources of the Pitcairn Island lavas. The isotope composition of these lavas is similar to that of EM-1 hotspots from the South Atlantic, indicating the addition of reduced sediments in both of Earth's large low shear wave velocity provinces (LLSVPs). Consistent data from both locations imply that the subduction cycling of sedimentary redox-sensitive elements such as Mo, S, Se, and U into arc magmas was in these cases inefficient in the Precambrian and the chemical and isotopic signature of reduced sediments is preserved in the source of ocean island basalts bearing the EM-1 characteristics.

Origin of the Mussau Trench in the Western Pacific: Geochemical and mineralogical constraints from basalts and serpentinized peridotites

The Mussau Trench is apparently an incipient subduction zone. However, petrologic and geochemical evidence for the nature and origin of the Mussau Trench is lacking. We present the first mineralogical and geochemical analyses of basalts and serpentinized peridotites from the Mussau Trench. All sampled Mussau Trench basalts yield MORB-like trace-element patterns and lack the geochemical characteristics of typical arc lavas. The Dupal-type isotopic compositions of the MORB-like lavas confirm that the overriding plate shows more affiliation to the Caroline Plate than to the Pacific Plate. The Mussau Trench could have formed along a pre-existing transform fault in the Caroline Plate. Peridotites from the Mussau Trench are highly serpentinized and can be divided into two groups. Group I peridotites have low MgO/SiO2 ratios and contain talc and quartz, suggesting that they were metasomatized by SiO2-rich fluids. Group II peridotites have higher Al2O3/SiO2 ratios at a given MgO/SiO2 ratio and rarely contain talc or quartz. The peridotites in the Mussau Trench differ from typical fore-arc peridotites in the Mariana Trench; for example, the Mussau peridotites are less depleted in trace elements and have lower spinel Cr# (<0.6) than those from the Mariana Trench, suggesting that they originated in the lithosphere of the Caroline plate. The temperatures (<688 °C) and pressures (<7.3 kbar) estimated using amphibole compositions (dominantly edenite and pargasite) suggest that the peridotites were serpentinized by high-temperature slab-derived fluids. Although the limited plate convergence at the Mussau Trench was insufficient to cause arc magmatism, subducted slab-derived fluids caused serpentinization of the overriding lithospheric mantle in an infant subduction channel. Therefore, the serpentinized peridotites and basalts in the Mussau Trench provide important information on the marks and processes of intra-oceanic subduction initiation.

The origin of Na-alkaline lavas revisited: new constraints from experimental melting of amphibole-rich metasomes+lherzolite at uppermost mantle pressure

We present a new experimental dataset for reaction experiments between natural amphibole-clinopyroxene metasomes (hornblendite) and synthetic lherzolite that produced Na-rich alkaline melts. Experiments were conducted at 1, 3 and 4 GPa and 1000–1300 °C. The generated melts range from foidite over basanite to phonotephrite. At 1 GPa between 1000 and 1100 °C amphibole decompression-breakdown products generate a phonotephritic melt. Among the breakdown components rhönite was found to be stable up to 1100 °C and 1 GPa. At 3 and 4 GPa the melt compositions are affected by phlogopite melting and shift to more foiditic compositions. We find that the melting of hornblendites and the reaction of the melt with the lherzolite produce wehrlitic residues with different olivine/clinopyroxene ratios. Wehrlite formation does not always require separate metasomatic processes but can be a direct by-product of alkaline volcanism. We applied a metasome melting model to the magmas of the Kula volcanic province, Turkey, and show that at 1 GPa basanite melts and phonotephrite melts cover the whole range of known Kula lava compositions. The Kula lava compositional trend can be therefore generated by basanite-phonotephrite melt mixing. A comparison of high-pressure (3–4 GPa) melts with natural nephelinite data shows overlap with many major, minor, and trace elements but differences in SiO2, FeO, and TiO2 argue that the natural nephelinite data do not represent primary metasome melts.

An isotopically enriched mantle component in the source of Rodrigues, Réunion volcanic hotspot

The Mascarene Islands in the western Indian Ocean, encompassing La Réunion, Mauritius, and Rodrigues, are the recent (<10 Ma) surface expressions of the Réunion hotspot. Ocean island basalts (OIB) from these islands exhibit a remarkably homogeneous long-lived radiogenic isotopic composition, coinciding with the convergence field of many global OIB trends in the mantle array. Réunion plume-related OIB therefore provide one of Earth’s most pristine representations of this “focal zone” component, which may have a primordial heritage. Besides this signature, Mascarene lavas have been suggested to retain contributions from sources with distinct compositions, including: (1) Archaean-aged zircons assimilated from continental crust within the oceanic lithosphere by trachytic magmas from Mauritius; (2) more deeply recycled continental crust components preserved by elevated 87Sr/86Sr and 208Pb/206Pb in lavas from the Piton des Neiges volcano of Réunion; and (3) an isotopically depleted mantle component resulting from interaction with Central Indian Ridge material.In this study we use Sr-Nd-Pb isotope systematics, along with major and trace element compositions of basaltic lavas from all three Mascarene Islands to investigate the relationship of their sources to well-characterized mantle endmembers. Among the Mascarene Islands, Rodrigues lavas are the most enriched in highly incompatible elements, likely reflecting shallower and lower degrees of partial melting than Réunion or Mauritius. Combined Sr-Nd-Pb isotope compositions indicate that lavas from the Older Series of Mauritius resemble those from Réunion, whereas lavas from the Younger and Intermediate Series, together with Rodrigues, are consistent with contributions from an isotopically depleted component. In addition, the Pb isotopic compositions of Rodrigues samples require an additional contribution from a component with a long-term enrichment in its Th/U ratio. Based on isotope mixing models, direct assimilation of continental crust embedded within the oceanic lithosphere is unlikely to account for the Pb isotopic variation of Rodrigues. A metasomatized mantle component, previously envisaged as a “fossil” Réunion plume near the Central Indian Ridge, is partially able to reproduce the trace element signature, but not the observed Sr-Nd-Pb isotopic compositions of Rodrigues. Instead, small proportions (<5%) of an EM1-like component provide a preferred endmember. The composition and origin of this component, which is exclusively reflected within Rodrigues lavas, may constitute a new geochemical feature of the Mascarene Islands and is consistent with geodynamical predictions that small-scale enriched mantle domains may be widespread in the source regions of hotspot volcanoes.

Redox and mineral controls on Fe and Ti isotopic fractionations during calc-alkaline magmatic differentiation

Titanium and Fe isotopic compositions of lavas from a calc-alkaline differentiation suite and corresponding mineral separates from the Rindjani Volcano, Indonesia show that Fe and Ti isotopic fractionations between minerals and melts are lower than those recorded in other suites at all stages of differentiation. The limited isotopic fractionation for Ti is likely due to low-Ti magnetite and clinopyroxene being the dominant carriers of Ti in Rindjani lavas, as these minerals are thought to have limited equilibrium Ti isotopic fractionation relative to silicate magmas. Other magmatic differentiation suites controlled by removal of Ti-rich magnetite and characterized by a lesser role of clinopyroxene have larger Ti isotopic fractionations. This effect is an indirect consequence of the elevated Fe3+/Fe2+ ratio of calc-alkaline magmas such as Rindjani, which promotes Fe3+ incorporation into magnetite at the expense of Fe2+-Ti4+ pairs, such that increased oxygen fugacity will subdue Ti isotopic fractionation in global magmatic series. Similarly, we find negligible Fe isotopic fractionation in Rindjani bulk rocks and mineral separates, unlike previous studies. This is also likely due to the oxidized nature of the Rindjani differentiation suite, which leads to similar Fe3+/Fe2+ ratios in melt and minerals and decreases overall mineral-melt Fe fractionation factors. Paired Ti and Fe isotopic analyses may therefore represent a powerful tool to assess oxygen fugacity during differentiation, independent from Fe 3+ determinations of erupted samples.

Magmatism during the continent – ocean transition

As continents break apart, the dominant mechanism of extension transitions from faulting and lithospheric stretching to magma intrusion and oceanic crust formation in a new ocean basin. A common feature of this evolution preserved at magmatic rifted margins worldwide are voluminous lava flows that erupted close to sea level during the final stages of development of the continent-ocean transition (COT). The mechanisms responsible for the generation of the melts that contribute to these voluminous flows, the so-called seaward dipping reflectors (SDR), and their significance in the context of COT development, are relatively poorly understood; they lie deep below post-rift strata along submarine rifted margins where they cannot be studied directly. Extensive coring of the Afar Stratoid Series - an areally-extensive sequence of Pliocene-aged basalts and intercalated sediments that lie atop the developing COT in the sub-aerial Afar Depression, northern Ethiopia - offers fresh scope to address this issue. We present a numerical model simulating the formation of enriched metasomes within the continental lithospheric mantle by the passage of magmas resembling modern axial basalts. Thermal destabilization of the metasome, caused by plate stretching, initiates melt formation within the metasome. These melts, when mixed with a depleted lithospheric mantle component, closely match the range of compositions of the Afar Stratoid Series lavas in this study. Metasomatic re-enrichment and subsequent melting of the lithospheric mantle during the COT may contribute to further plate thinning. These results demonstrate a novel mechanism by which large-volume flows may be erupted during the COT.

Lessons learned from the 1980–1986 eruption of the Mount St. Helens composite lava dome

Lessons learned from the 1980–1986 eruption of the Mount St. Helens composite lava dome

Isotopic decoupling of K from Sr and Nd in the Saima alkaline complex, NE China: interactions of cratonic roots and asthenosphere

AbstractWe report high-precision K isotopes, apatite U–Pb ages, whole-rock elements and Sr–Nd isotopes for the Saima nephelite syenite in the North China Craton. Trace-element and Sr–Nd–Hf–O isotope data indicate the presence of subducting sediments in the source region, while K isotopic compositions show a narrow range between –0.54 ‰ and –0.28 ‰, with an average of –0.41 ± 0.06 ‰, identical to the value of the asthenosphere. The nearly identical K isotopic compositions are low probability events compared with the K isotopic compositions of island arc lavas reported previously (–1.55 ‰ to +0.2 ‰). Although crustal contamination is consistent with the Sr–Nd–K isotopic data, alternatively we propose that the isotopic data also reconcile with the interaction between cratonic roots and the underlying convective asthenosphere, if this interaction is over prolonged periods of time. Numerical simulations successfully reproduced the observed data, if the metasomatism of the lithospheric mantle root, the source of the Saima alkaline rocks, occurred 500 Ma ago. Our study reveals that the isotopic compositions of fast-diffusion components in a lithospheric mantle metasomatized by ancient subducting melts can be effectively homogenized by convective asthenosphere through diffusion over a long time interval.

Trace element partitioning in silica-undersaturated alkaline magmatic systems

Alkaline magmatism is an important chemical end-member of magmatic activity that typically occurs in response to small volume melting of asthenospheric- and/or lithospheric mantle material in intra-continental settings. Understanding trace element partitioning and phase equilibria during alkaline magmatism can therefore provide constraints on intra-continental geodynamic settings. However, the partitioning of trace elements between alkaline melts and their dominant equilibrium mineral phases remains poorly constrained. Feldspathoids in particular have received limited attention with regards to their trace element contents, hampering our ability to interpret geochemical trends in alkaline magmatic systems. In this study, we performed a series of 1 atmosphere experiments in a gas-mixing furnace using a variety of highly alkaline (Na2O + K2O = 4.15–14.97 wt%) and silica-undersaturated (SiO2 = 36.73–45.96 wt%) lava compositions from Nyiragongo, Democratic Republic of Congo, in order to investigate the partitioning behaviour of trace elements in minerals from alkaline magmas. Experimental runs were performed with oxygen fugacity buffered at both QFM (quartz-fayalite-magnetite equilibrium) and QFM + 1 and cover a range of geologically-relevant temperatures (1025–1200 °C). The quenched products of these experiments contained leucite, nepheline, melilite, clinopyroxene, olivine, and rhönite crystals, of which glass-crystal pairs were analysed for rare earth elements, large-ion lithophile elements, and high-field-strength elements. Leucite and nepheline host considerable quantities of large-ion lithophile elements but take up negligible amounts of more highly charged cations. Åkermanitic melilite readily incorporates mono- to trivalent cations with a preference for light over heavy rare earth elements, but incorporates only select divalent cations. Rhönite and clinopyroxene have analogous partitioning behaviours, with a strong preference for heavy over light rare earth elements. Fractionation modelling using the reported partitioning behaviours reproduces the 2021 eruption products of Nyiragongo, with 48% fractionation from an olivine-melilitic parental melt composition. Crystallization of trace-element poor feldspathoid amplifies pre-existing high LREE/MREE ratios of the parental magma and progressively increase trace element abundances for all but monovalent cations.

Geological evolution of the Proterozoic Betul belt (∼2.16–0.95 Ga) of the Central Indian tectonic Zone: Its linkage to the assembly and dispersal of Columbia and Rodinia supercontinents

The Proterozoic Betul Belt is an important supracrustal unit that records the protracted history of crustal accretion and growth in the Central Indian Tectonic Zone (CITZ). Here, we present results from systematic geological mapping, petrological, geochemical (including Sm-Nd isotope) studies, and U-Th-Pb geochronology on rocks from the Betul belt, with the objective of reconstructing its Proterozoic evolution and its link with past supercontinents. The Betul belt comprises ca. 2167 ± 11 Ma granite gneisses, ca. 2051 ± 80 Ma mafic volcanics (pillowed lava), 1715 ± 10 Ma rhyolite, and older granitoids (1671 ± 29 Ma) that have undergone multi-stage deformation and amphibolite-facies regional metamorphism. The bulk rock geochemistry of gneisses, pillow lava, and mafic intrusions are characterized by arc-like signatures, whereas the rhyolite and granites are anorogenic and back-arc related. The whole-rock geochemical and Sr-Nd isotopic compositions of pillow lavas and mafic intrusions suggest the involvement of recycled crustal material in their source, possibly in the form of associated sediments. The Betul granite gneisses were emplaced at 2167 Ma in a collisional setting by melting crustal protoliths having an affinity with the Bundelkhand craton and may constitute the basement for the supracrustal sequence. The supracrustal units, i.e., mafic volcanics and rhyolites, occur as a bimodal suite formed in the arc and back-arc environment with penecontemporaneous sedimentation. Bulk rock geochemistry and age data indicate two phases of A-type granite magmatism at 1674 Ma and 1079 Ma, with post-collisional geochemical traits forming within an anorogenic and back-arc setting, respectively. Younger post-orogenic granites (Navegaon) were emplaced in a back-arc setting at ca 1079–954 Ma, synchronous with a collisional event in the Sausar belt. Spot ages from monazite in Hbl gabbro yield a weighted mean of 1026 ± 97 Ma (MSWD = 0.15), reflecting Grenville-age regional metamorphism in the CITZ. The geological events recorded in the rocks of the Betul belt between ca 2167 Ga and 954 Ma correlate well with events that affected Laurentia, Baltica, Australia, and East Antarctica within the frameworks of the Columbia (ca. 2.1–1.7 Ga) and Rodinia (ca.1.2–0.9 Ga) supercontinents.

K-Ca dating and Ca isotope composition of the oldest Solar System lava, Erg Chech 002

K-Ca dating and Ca isotope composition of the oldest Solar System lava, Erg Chech 002

Magnesium isotopic composition of back-arc basin lavas and its implication for the recycling of serpentinite-derived fluids

Dehydrated fluids expelled from the serpentinised mantle in subducted slabs contribute significantly to arc magmatism and element cycling on Earth. However, the recycling mechanism of serpentinite-derived fluids at various subduction zone depths remains unclear, as does their contribution to the genesis of back-arc basin lavas. In this study, we investigated magnesium (Mg) isotopic compositions of lavas from the Okinawa Trough (OT) and the Lau Basin, because Mg isotopes have shown great potential in tracing the dehydration of slab serpentinites in recent years. After excluding dubious samples affected by alteration, lavas from the OT and the Lau Basin have heavier Mg isotopic compositions than mid-ocean ridge basalt (MORB) mantle, which could be attributed to the involvement of slab serpentinite-derived fluids rather than crustal assimilation or subducted sediment inputs, as indicated by the isotopic modelling results. The δ26Mg values of the southern OT (SOT) and the southern Lau Basin lavas are generally higher than those in the middle OT (MOT) and the northern Lau Basin, respectively, with an average of −0.09 ± 0.02‰ (2SD, n = 6) for the SOT, −0.18 ± 0.10 ‰ (2SD, n = 9) for the MOT, −0.13 ± 0.08 ‰ for the southern Lau Basin (2SD, n = 5), and − 0.19 ± 0.06 ‰ (2SD, n = 10) for the northern Lau Basin. The binary modelling results show that various quantities of serpentinite-derived fluids could explain the variations in Mg isotopic compositions observed in the OT and the Lau Basin. We suggest that the thermal structure of the inter-subduction zone controls the signal of Mg-rich serpentinite-derived fluids, based on both reported δ26Mg values in subduction zones and our findings. In contrast, the contributions of these fluids to different segments in a specific subduction zone may depend on the slab depth beneath sites of magmatic activity.

No measurable calcium isotopic variations of back-arc lavas across the Okinawa Trough

Calcium (Ca) is an essential element closely connecting to the recycling of marine carbonate at subduction zones. Here, we report Ca isotopic compositions (denote as δ44/40Ca with respect to NIST SRM915a) of back-arc lavas collected across the Okinawa Trough. The δ44/40Ca values showed a narrow range with an average of 0.81 ± 0.08‰ (2SD, n = 13), almost identical to reported values of arc magmas, mid-ocean ridge basalts (MORBs), and other mafic rocks. The MORB-like δ44/40Ca values were dominantly attributed to the mantle partial melting. The accumulation of clinopyroxene and plagioclase has played a negligible role on the Ca isotopes, despite the collected lavas exhibited distinctive rock types ranging from basalt to dacite. The metasomatism by subduction components (slab-derived fluids, sediment melts) and/or crustal assimilation have imprinted trace elemental and HfNd isotopic signals on the Okinawa Trough lavas, while the Ca isotopes have not been significantly modified. Our work suggests that thermal structures and tectonic stages are not pivotal factors constraining the Ca isotopic characteristics of arc and back-arc magmas at subduction zones. The opportunity and possibility to discriminate carbonate Ca isotopic signals in subduction zones are obscured by the highly variable Ca isotopes and carbonate contents of subducted sediments, the homogenization effect of the mantle wedge, variable degrees of sediment melting, and the survival of sediment melts during petrogenesis.

Fluid-rock interactions at shallow depths in subduction zone: Insights from trace elements and B isotopic composition of metabasites from the Mariana forearc

To reveal the spatial variations of slab-derived fluids and to trace the in-situ dehydration in the shallow subduction zone, we investigated the petrography, mineral chemistry, and whole-rock B isotopes of metabasites that were recovered from the Fantangisña and Asùt Tesoru serpentinite mud volcanoes and originated from the shallow subduction channel at the forearc of the Mariana subduction zone. The alteration mineral assemblages in the investigated metabasites suggest zeolite- to prehnite-pumpellyite-facies metamorphism and lawsonite-blueschist facies metamorphism beneath Fantangisña and Asùt Tesoru seamounts, respectively. The fluid mobile elements (e.g., B, As, Sb, Pb) are preserved in the low grade metamorphic phyllosilicate minerals (e.g., glauconite, pumpellyite, celadonite), thus fixing the B concentrations of the subducted oceanic crust during shallow subduction (<18 km). Both B concentrations (16.7 to 43.9 μg/g) and δ 11 B values (−5.0 to +3.2‰) of the investigated metabasites are significantly higher than fresh normal mid-ocean ridge basalts (N-MORB) and ocean island basalts (OIB), and are generally comparable to the uppermost altered oceanic slab. Notably, the recovered metabasites from the Mariana forearc exhibit a decreasing trend in δ 11 B values with increasing distance to the trench from Fantangisña (62 km) through Asùt Tesoru (72 km) to South Chamorro (78 km) Seamounts. This trend together with Rayleigh dehydration modeling indicate that the 11 B-enriched aqueous fluids were released from the subducting slab during prograde metamorphic dehydration. The estimated B isotopic compositions of the slab-derived fluids released at arc magma genesis depths are generally comparable to that of the Mariana arc lavas. However, the fluids released by dehydration of subducted sediments at shallow depths should be characterized by lower δ 11 B values than fluids released from the slab at depths of magma genesis beneath the island arc. Then, the recycling of the hydrated forearc mantle is necessary to explain the high δ 11 B values of the Mariana arc lavas. While, the variable B isotope compositions of Mariana arc lavas should be controlled by the different ratios of sediment/AOC ratios. • The investigated metabasites experienced low-grade metamorphism. • Both B concentrations and δ 11 B values are significantly higher than their protolith. • δ 11 B values exhibit a decreasing trend with increasing distance to the trench axis. • Subducted serpentine is necessary to explain the high δ 11 B values of the arc lavas.

Off-rift Axis Channelized Melt and Lithospheric Metasomatism along Mid-ocean Ridges—A Case Study from Iceland on the Limits of Melt Channelling

AbstractMagmatism in Iceland is classically explained by the interaction of the mid-Atlantic ridge with the Iceland plume. The growth of Iceland through time is the result of volcanic activity at the rift axis. However, Holocene volcanism (0–11.5 ka) is not restricted to the rift zone (RZ) but also occurs off-axis, specifically in the western Snæfellsnes Volcanic Belt (SVB) and in the Southern Flank Zone (SFZ). The rift and off-axis postglacial volcanic zones are separated by a gap of ~60–80 km. While the volcanic activity of the SFZ seems correlated with the actual location of the Iceland plume, the plume relation to the SVB is uncertain. To address the origin and relationships between rift and off-rift magmas, we present new data from two transects perpendicular to the Reykjanes rift. The lavas in the SVB are characterized by transitional to alkaline compositions, with elevated incompatible trace element content. In contrast, the RZ volcanic rocks have tholeiitic compositions with trace element signatures slightly more enriched than Mid-Ocean Ridge Basalt (MORB). Rift and off-rift Iceland lavas are all characterized by positive Ba and Nb anomalies, particularly in alkaline rocks. Tholeiitic and alkaline lavas show distinct differentiation sequences, with the main difference being the delayed crystallization of plagioclase in the fractionating assemblage of alkaline magmas. We apply these sequences to calculate primary magma compositions, which are then used to constrain melting conditions. Geochemical modelling indicates that Iceland rift and off-rift magmas can be produced from a peridotitic mantle source if lithospheric processes are involved. We demonstrate that recycled crust in the form of pyroxenite is not required to generate Snæfellsnes alkaline lavas. The low solidus temperature and high productivity of pyroxenite favour early and more extensive melting producing primary magmas that are not sufficiently enriched in incompatible trace elements to explain the compositional variation of Snæfellsnes magmas. An alternative mechanism to involve pyroxenite in the source of Snæfellsnes lavas relates to the hybridization of recycled oceanic crust with peridotite, but such reacted pyroxenite requires specific compositions to reproduce the Ba and Nb anomalies. As an alternative, we suggest that Snæfellsnes alkaline lavas are the result of channelized low-degree melts produced on the periphery of the melting column at distances exceeding 65 km from the ridge axis. These melts accumulate and percolate into the lithosphere producing amphibole ± phlogopite-bearing hydrous cumulates. Incongruent melting of these cumulates via renewed magmatic activity and melt-peridotite reaction can reproduce the alkaline compositions observed in the SVB, including the Ba and Nb anomalies. Numerical simulations of melt extraction below mid-ocean ridges suggest that low-degree melts produced as far as ~65 km from the central ridge axis rise vertically to the base of the lithosphere and are then focussed towards the ridge axis in decompaction channels. We propose that these melts interact with hydrous cumulates previously formed during the development of decompaction channels at the lithosphere–asthenosphere boundary and acquire specific Ba and Nb anomalies. The mixing of these distal enriched melts with more depleted melts extracted from the central part of the melting regime explains the composition of RZ lavas. Alkaline lavas observed in the SFZ show numerous analogies with the Snæfellsnes magmas, suggesting that similar lithospheric processes control their chemistry. The high thermal regime in Iceland and thick lithosphere explains the difference between Icelandic tholeiite and typical MORB. Our results highlight the importance of mantle dynamics below mid-ocean ridges and lithospheric interaction to produce off-axis magmatism with enriched alkaline signatures.

Extreme geochemical heterogeneity beneath the North Tonga Arc: Interaction of a subduction zone with intraplate seamount chains

We provide new geochemical and isotope data for lavas from six young submarine volcanoes from the northernmost oceanic Tonga island arc. These lavas have low concentrations of moderately incompatible trace elements, but are enriched in Nb and Ta compared to all other Tonga island arc lavas, and their Nd, Hf and Pb isotope compositions resemble those of rejuvenated lavas from the nearby Samoa hotspot. These unusual compositions indicate that the mantle source of North Tonga lavas was depleted by prior melting events, before re-enrichment by a partial melt enriched in highly incompatible elements with Nd, Hf and Pb isotope compositions similar to Samoan intraplate lavas. Samoa plume mantle is flowing southwards beneath the northern Tonga island arc and Lau Basin, in part guided by rifting of the Tonga plate lithosphere. A fluid component was later added from a mixture of subducted pelagic sediment and subducting Louisville Seamount Chain volcanic material. Our new data show that the Louisville component is only found in lavas from volcanoes occurring along ∼100 km of the arc front, indicating that the oceanic crust loses Pb by dehydration over a relatively small depth interval during subduction. The compositions of lavas from the northern Tonga island arc are therefore influenced by material from two hotspots; southwards inflow of mantle from the active Samoa plume beneath the arc within the past 6 Ma, and a subduction component from >80 Ma old subducted Louisville Seamount Chain basalts.

Development of Shalbatana Vallis (Mars) by dry volcanic processes

Shalbatana Vallis is a large Martian outflow system that extends into Chryse Planitia from areas of topographic disturbance located north of Ganges Chasma. Development of this system has previously been attributed to processes including: 1) the expulsion of groundwater generated by interactions between magmatic intrusions and ground ice; and 2) the northward conveyance of water along subsurface conduits connected to a deep lake impounded within Ganges Chasma. However, aqueous interpretations of Shalbatana Vallis suffer from weaknesses such as the implausible nature of hypothesized outburst processes, discrepancies between the magnitudes of subsidence that characterize parts of the system and realistic volumes of excess ice that might have once existed in the subsurface, and contradictions between the nature of hypothesized aqueous processes and the mineralogy of associated geological materials. The attributes of Shalbatana Vallis are instead consistent with dry development as a result of the rapid and voluminous effusion of low-viscosity lavas of mafic or ultramafic composition. Volcanic development of the main channel of Shalbatana Vallis is estimated to have required a minimum effusion of ∼360,000 ​km3 of lava, though a total of several times this volume is more likely to have been necessary since channel development cannot be assumed to have taken place with full efficiency. Involved lavas are hypothesized to have been fed by a deeply-rooted igneous plumbing system, and terrain collapse and disturbance located at the head of the system is expected to be partly related to the collapse of intrusions during the latter stages of igneous events. A volcanic origin for Shalbatana Vallis further highlights the critical role played by igneous processes in channel development on rocky bodies of the inner solar system.

Co-Occurrence of HIMU and EM1 Components in a Single Magellan Seamount: Implications for the Formation of West Pacific Seamount Province

ABSTRACT Our general understanding of mantle composition and dynamics mainly comes from the composition of lavas from oceanic intraplate volcanoes. They are generally accepted to originate from deep, relatively stationary mantle plumes. Many groups of seamounts comprising the West Pacific Seamount Province (WPSP), however, do not form long-lived, narrow and continuous chains of volcanoes with clear age progression; thus, their origin does not seem to fit this general model. Here we show a wide compositional spectrum of lavas from the Pako guyot within the Magellan seamount trail (MST), an age-progressive but short-lived volcanic chain in the WPSP. For the first time, both extreme high μ = 238U/204Pb mantle (HIMU)- and enriched mantle 1 (EM1)-like mantle plume components occur in a single seamount in the Pacific Ocean. Based on alteration resistant trace element and Sr–Nd–Pb–Hf isotopic compositions, the Pako lavas fall into three distinct groups. Group 1 has a distinctive HIMU composition with high (206Pb/204Pb)i ratios (20.41–20.94) similar to the Arago (also known as ‘Young Rurutu’ or ‘Atiu’) hotspot composition, suggesting derivation from a HIMU mantle source. Groups 2 and 3 EM1-like lavas comprise the dominant rock type and display the largest Sr–Nd–Pb–Hf isotopic variations that can be best explained by mixing between melts of focal zone (FOZO) and EM1-like mantle components. Additionally, olivine phenocrysts from Group 3 EM1-like lavas have high Ni contents, Fe/Mn and Mn/Zn ratios and low Zn/Fe*10 000 ratios, which can be explained through fractional crystallization of high-pressure partial melts from fertile peridotite. The EM1-like Groups 2 and 3 lavas are compositionally similar to the Rarotonga hotspot composition, suggesting that the MST is possibly an old trace of the Rarotonga hotspot, which is most likely a long-lived hotspot generated above a deep mantle plume. Combined with existing geochemical and tectonic data, we propose that the Magellan seamounts were likely derived from partial melting of a heterogeneous mantle plume containing HIMU, FOZO and EM1-like components. Alternatively, they could have been derived from the Arago and Rarotonga mantle plumes, each having its distinct compositional signature. The occurrence of HIMU- and EM1-like mantle plume components in a single volcano suggests that the superposition of compositionally different hotspot volcanic trails in the South Pacific could have played an important role in the generation of the WPSP.

Geochronological, geochemical and isotopic characterisation of the basement of the Chocó-Panamá Block in Colombia

The Chocó-Panamá block is the land bridge that connects Central and South America and forms the trailing edge of the Caribbean Large Igneous Province (CLIP). New field observations are combined with new geochemical, isotopic and 40Ar/39Ar analyses of the mafic basement of the Chocó block within Colombia. These are integrated with new U/Pb ages of detrital zircons extracted from siliciclastic and carbonate rocks that unconformably overlie the mafic basement. The data are used to constrain the age, tectonic origin and evolution of the Chocó Block, which are used to improve tectonic models of the Caribbean Plate. The whole-rock chemical and isotopic compositions of the mafic lavas suggests they formed within an oceanic plateau, and are extremely similar to plateau units in Colombia, Ecuador, Panamá and Costa Rica. 40Ar/39Ar (groundmass) dates of the mafic basement are affected by early calcic and late potassic alteration, and none are accurate measurements of the time of crystallisation. A comparison of 40Ar(radiogenic), 39Ar(K) and 37Ar(Ca) reveals at least three argon reservoirs within the mafic groundmass, where at least two are a consequence of alteration. Our most accurate albeit imprecise estimate of the crystallisation age of the mafic basement is ≥86.0 ± 6.3 Ma, which is a plateau 40Ar/39Ar date from a groundmass aliquot which contains the lowest proportion of secondary Ar reservoirs. This age estimate is consistent with the few reliable crystallisation ages obtained for oceanic plateau rocks of the CLIP. U/Pb concordia dates of detrital zircons constrain the maximum depositional age of the overlying sedimentary rocks to ~28 Ma, supporting previous conclusions that the Chocó-Panamá block collided with South America during the Oligocene to Early Miocene. Detrital Precambrian – Triassic zircons in the older cover sequences are not present in younger sedimentary rocks due to surface uplift of the Serranía del Baudó, presumably due to collisional tectonics.

Magmatism of the Beka Volcanic Massifs (Cameroon Volcanic Line, West-Central Africa): New Petrographical and Mineralogical Data

The Beka volcanic massifs are located northeast of Ngaoundere region, within the Adamawa plateau. It consists mainly of basanites, trachytes and phonolites. The petrographic study shows that all the basanite lavas have porphyritic microlitic textures with a more pronounced magmatic fluidity than the felsic lavas displaying trachytic textures. The lavas are composed of phenocrysts, microlites and microphenocrysts of olivine, clinopyroxene, plagioclase and iron-titanium oxides for the basanites and of greenish clinopyroxene, alkali feldspar, and titanomagnetite for the felsic lavas. Chemical microprobe analysis indicates that the olivine crystals are magnesian (Fo73-78). Clinopyroxene crystals have a composition of diopside (Wo47-) in the basaltic lavas and diopside near the hedenbergite pole in the trachytes phonoliths and titanomagnetite (TiO2: 21.13% - 22.36% and FeO: 68% - 68%). Chemical analyses on whole rocks show that all the lavas belong to the same series and the felsic lavas come from the differentiation of basanite lavas by fractional crystallization of the minerals therein. The basanites originate from a low rate of partial melting of an OIB-type mantle. Contamination and mixing processes are suspected. Lavas of similar composition are found in other volcanic centres of the Adamawa plateau and the continental and oceanic sectors of the Cameroon Volcanic Line, in particular the Kapsiki plateau, Mounts Cameroon and Bamenda.