Composition Of Crust Research Articles

Aqueous Alteration as an Origin of Martian Magnetization

AbstractStrong magnetic fields have been measured from orbit around Mars over parts of the ancient southern highlands crust and on the surface at the InSight landing site. The geological processes that are responsible for generating strong magnetization within the crust remain poorly understood. One possibility is that intense aqueous alteration of crustal materials, through the process of serpentinization, could have produced magnetite that was magnetized in the presence of a global core‐generated magnetic field. Here, we test this idea with geophysical and geochemical models. We first determine the magnetizations required to account for the observed magnetic field strengths and then estimate the amount of magnetite necessary to account for these magnetizations. For the strongest orbital magnetic field strengths, about 7 wt% magnetite is required if the magnetic layer is 10 km thick. For the surface field strength observed at the InSight landing site, 0.4–1.1 wt% magnetite is required if the magnetic layer corresponds to one or more of the three crustal layers observed in the InSight seismic data (with thicknesses from 8 to 39 km). We then investigate the minerals that are produced by aqueous alteration for various possible crustal compositions and water‐to‐rock ratios using a thermodynamic model. Magnetite abundances up to 6 wt% can be generated for dunitic compositions that could account for the strongest magnetic anomalies. For more representative basaltic starting compositions, however, more than 0.4 wt% can only be generated when using high water‐to‐rock ratios, which could account for the weaker magnetizations beneath the InSight landing site.

The Addition of Felsic Sediments to the Lower Continental Crust During the Variscan Orogeny

AbstractLower crustal metasedimentary xenoliths (garnet‐sillimanite granulites) from the Bournac breccia pipe in the Massif Central, France, provide a robust example of sediments transported to depth and incorporated into stable lower continental crust during a collisional orogeny. Dates for detrital igneous zircon range from the Archean (up to 3,300 Ma) to the Devonian and record sedimentation prior to the onset of the collisional phase of the Variscan orogeny. Metamorphic zircon and monazite document the presence of the metasediments in the lower crust by ca. 330 Ma during the later phase of Variscan collision. Zircon and monazite crystallization continued within the lower crust until ca. 265 Ma, corresponding to a period of slow cooling following an episode of ultra‐high temperature (UHT) metamorphism that peaked at 313 Ma. Zr‐in‐rutile thermometry and GASP barometry applied to these samples record conditions of 0.63–0.77 GPa and 830–910°C, which correspond to Ti‐in‐zircon temperatures from the latter part of the Variscan orogeny and geotherms in excess of typical continent‐continent collisions. Rutile in these samples remained open to Pb loss until their eruption at ca. 11.6 Ma, providing an indirect date of the Bournac eruption. These rocks record the incorporation of felsic sedimentary material into the stable deep continental crust during a collisional orogen and their residence there for over 300 Ma. More broadly, the addition of sediments to stable lower crust contributes to changes in crustal composition and has significant implications for the heterogeneity of the deep continental crust, as well as overall crustal heat production and mantle heat flow.

Modelling of Moho depths and crustal composition in the Aravalli (Rajasthan) Craton, north-west India

Modelling of Moho depths and crustal composition in the Aravalli (Rajasthan) Craton, north-west India

Crustal properties beneath the northeastern United States shaped by past tectonic processes

Constraints on the thickness, transitional boundaries, and composition of Earth's crust are pivotal in studying its formation and evolution. We use data from 132 seismic installations throughout northeastern U.S. to explore how tectonic events, such as orogenesis and rifting, have altered the crust of the northeastern U.S. and southeastern Canada, and to distinguish differences between Laurentia and the Appalachian terranes. We include data from seismic installations from the NEST and SEISConn experiments, spanning the Laurentia-Appalachian boundary, and present estimates of crustal thickness, Vp/Vs, and thickness of the transition between crustal and mantle rocks using Ps receiver functions. We find some first-order differences between Laurentia and Appalachian terranes, with Laurentia exhibiting thicker crust (∼39 km vs. ∼33 km) and a broader crust-mantle transition thickness (∼3 km vs. <1.5 km). Average Vp/Vs values are similar between Laurentia (∼1.77) and Appalachian terranes (∼1.74); however, we identify anomalous Vp/Vs in a few regions, including high Vp/Vs around the Adirondack Mountains and low Vp/Vs in southern New England. The southern New England region is also anomalous in terms of its systematically thinner crust and sharper crust-mantle transition, which may be a consequence of the formation and collapse of the Acadian altiplano during the mid-to-late Paleozoic.

Quantifying Crustal Growth in Arc‐Backarc Systems: Gravity Inversion Modeling of the Lau Basin

AbstractThe formation and evolution of arc‐backarc systems govern crustal production in some of the most volcanically and hydrothermally active environments on Earth. This study presents the first complete three‐dimensional density model of the active arc‐backarc system in the southwest Pacific comprising the Lau Basin and Tofua arc. Seafloor density and crustal thickness maps reveal changes in crustal composition and growth rates throughout the basin and along the volcanic arc. Crustal thickness varies significantly between the different centers of accretion (i.e., assemblages), resulting from seafloor spreading and subsurface melt accumulation below volcanic fields. Volumetric growth rates were calculated for each assemblage, corresponding to their respective contribution to basin expansion. The highest crustal density and growth rates are thought to be related to a mantle‐derived melt source entering the basin from the north around the edge of the subducting Pacific Plate. This study shows that the inverse modeling approach can be applied to global gravity data sets to characterize and quantify the density and thickness of the crust anywhere in the oceans.

East–west-trending tearing of the Indian slab beneath the eastern Tibetan Plateau: Insights from Eocene–Oligocene potassic adakite-like granites in western Yunnan

Large-scale Eocene–Oligocene potassic adakite-like granites predominantly occur between 25° N and 27° N, north of the Ailaoshan suture in western Yunnan, eastern Tibetan Plateau. However, limited interpretations of their spatial characteristics hinder our understanding of the tectonic evolution in this region. Herein, we present new petrographic analyses, zircon UPb ages, whole-rock major and trace element compositions, SrNd isotopic data and zircon Hf isotopic mapping for these granites. Zircon UPb ages indicate that the adakite-like granites were emplaced at approximately 37.1–33.6 Ma. These granites exhibit high-K calc-alkaline compositions, enriched light rare earth elements and significant depletion in heavy rare earth elements, characterised by high Sr contents (667–1795 ppm), Sr/Y ratios (35–158) and La/Yb ratios (13–62), alongside low Y (8.2–23.3 ppm) and Yb (0.71–1.13 ppm) contents. The adakite-like granites possess high initial 87Sr/86Sr ratios (0.70596–0.70687) and low εNd(t) values (−5.73 to −0.65), with two-stage depleted mantle model ages (TDM2) ranging from 1.3 to 0.9 Ga. Their zircon εHf(t) values range from −5.1 to +0.7, with Neoproterozoic TDM2 ages of 1.4–1.1 Ga. Notably, these adakite-like rocks in western Yunnan exhibit an eastward decrease in zircon εHf(t) and whole-rock εNd(t) values. By integrating these findings with the Hf isotopic mapping results, we suggest spatial heterogeneity in lower crustal composition in western Yunnan. The lower crust in the western Yangtze block comprises Neoproterozoic arc roots, while the lower crust of the Simao block represents a superposition of Neoproterozoic and Permian–Triassic arc roots. Based on the abrupt changes in angle and depth of the eastward-subducting Indian slab, along with the spatial characteristics of the Eocene–Oligocene magmatism, we propose that east–west-trending tearing of the subducted Indian slab occurs along approximately 26° N beneath the eastern Tibetan Plateau.

Cooling of neutron stars in soft X-ray transients with realistic crust composition

Thermal radiation of neutron stars in soft X-ray transients (SXTs) in a quiescent state is believed to be powered by the heat deposited in the stellar crust due to nuclear reactions during accretion. Confronting observations of this radiation with simulations helps to verify theoretical models of the dense matter in neutron stars. We simulate the thermal evolution of the SXTs with theoretical models of the equation of state and composition of the accreted crust. The new family of such models were recently developed within a thermodynamically consistent approach by modeling the nuclear evolution of an accreted matter as it sinks toward the stellar center, starting from representative thermonuclear ash compositions. The crust cooling curves computed with the traditional and modern theory are compared with observations of SXTs MXB 1659−29 and IGR J17480−2446. We show that the new and traditional models of the accreted neutron star crusts are similar in their capability to explain the thermal evolution of neutron stars in SXTs. Both kinds of models require inclusion of additional ingredients not supplied by the current theory, such as the shallow heating and variation of thermal conductivity, to fit observations.

The Pb, Sr and Nd isotopic composition of the upper continental crust: An Australian perspective

A bulk composition for the upper continental crust (UCC) is often constructed using sediments and associated river waters, which are both assumed to efficiently average contributions from a multitude of bedrock components. Many potential biases, however, exist in sedimentary systems, rendering this approach less than optimal. In order to further investigate these phenomena, we estimate the bulk Pb, Sr, and Nd isotopic composition of the Australian UCC using archived National Geochemical Survey of Australia (NGSA) regolith samples, collected so as to represent 1186 catchments covering an area approaching 6.17 million km2. The size of the dataset and its systematic nature provide a high level of confidence that it is statistically representative, while the relative tectonic stability of the Australian continent, preserving a wide range of sample ages and lithologies, suggests that the data may form a reliable proxy for the global bulk UCC composition. Calculated median values for the Pb isotope system based on 1229 NGSA samples (some catchments were sampled in duplicate) representing an area of 5.65 million km2 (206Pb/204Pb = 18.838, 207Pb/204Pb = 15.686, 208Pb/204Pb = 38.989, 207Pb/206Pb = 0.83210, 208Pb/206Pb = 2.0669) are comparable to previous estimates of the global UCC, providing a strong validation of our methodology. We believe these new global bulk UCC values to be considerably more robust, however, given the much larger and more spatially representative dataset they derive from. In contrast, however, our Sr and Nd isotope results (median 87Sr/86Sr = 0.7377, 143Nd/144Nd = 0.511817), derived from significantly smaller subsets of the NGSA sample suite (576 and 93 samples, respectively, in turn representing areas of 2.6 million and 490 thousand km2), are considerably more radiogenic/evolved than previous UCC estimates. We discuss potential reasons for these discrepancies and conclude that the present data appear to confirm the possibility of multiple potential biases in current global assessments of bulk UCC isotopic values, related to methodological approach, over-sampling of younger, tectonically active regimes, and significant non-gaussian behaviour in sedimentary datasets.

Iron isotope fractionation during transcrustal magmatic differentiation: Implications for continental crustal formation in subduction zones

Earth’s continental crust is hypothesized to originate from mantle melting in subduction zones. However, mantle melts are typically Fe-rich, with light Fe isotopes (δ56Fe = 0.05‰), unlike the Fe-depleted and heavy Fe isotope (δ56Fe can be up to 0.2‰) compositions of continental crust. The mechanisms responsible for this paradox remain elusive. Here, we report Fe isotope data from a suite of co-magmatic Middle Triassic continental arc rocks in the Ailaoshan tectonic zone (Yunnan, SW China). Gabbroic diorites have light Fe isotopes (δ56Fe = 0.04‰−0.09‰), while granodiorites and normal-arc granites have slightly heavier values (δ56Fe = 0.07‰−0.14‰). Adakitic granites, with high Sr/Y (61−183) and La/Yb (47−90) ratios, exhibit the heaviest δ56Fe (0.16‰−0.19‰). Rayleigh fractionation modeling results suggest that fractionation of isotopically light Fe minerals (e.g., olivine, pyroxene, and amphibole) can reproduce the Fe isotopic variations in most samples, but fails to explain the high Sr/Y, La/Yb, and δ56Fe values of adakitic granites, which would require Fe-rich garnet fractionation. Notably, the different Fe isotopes of the adakitic granites and non-adakitic rocks reveal two distinct transcrustal magmatic differentiation pathways: lower crustal, high-pressure, garnet-dominated fractionation; and middle−upper crustal, amphibole-dominated fractionation. The heavy Fe isotopic and Fe-depleted characteristics of the Ailaoshan magmatic arc suites are more comparable to the calc-alkaline arc magmas from normal to thick crust arcs (e.g., the Andean arc), but remarkably different from the tholeiitic arc magmas from thin crust arcs (e.g., the Mariana arc). This study highlights the role of amphibole and garnet fractionation in magmatic calc-alkaline differentiation. We propose that a thickened crust would permit a longer magmatic differentiation column, thus facilitating felsic and Fe-depleted continental crustal formation. The fractionated Fe-rich, garnet-bearing arc cumulates with light Fe isotopes are density-unstable and may be recycled into the mantle by lower crustal foundering.

Subductability of continental lithosphere

Multiple lines of evidence from geological and geophysical observations indicate the deep subduction of continental lithosphere; however, the potential and driving forces of (self-sustained) continental subduction remain unclear. Here, systematic thermal-petrological models were conducted to quantitatively evaluate the subductability of continental lithosphere by analyzing its density structure and slab-pull evolution during subduction. The results indicate that the metamorphic densification of deeply subducted continental lithosphere (upper, middle, lower crust and lithospheric mantle) could provide considerable driving force for continental deep subduction. The numerical models further indicate that, if a Phanerozoic or Proterozoic continental lithosphere is dragged to a large depth of >300 km, then the continental slab pull overcomes the overall resistance force. Consequently, the continental subduction occurs self-consistently without any drag from the preceding oceanic slab. For Archean continental lithosphere, it is more difficult for self-sustained subduction to occur, due to the highly depleted mantle composition. In addition, we also systematically quantified the effects of multiple factors, including the scraping of continental crust, subduction velocity, subduction angle, and variable bulk-rock compositions of continental crust. Finally, a representative case study of the Himalayan orogen revealed that the slab pull of presently subducting Indian continental lithosphere ranges from 13 TN/m to 29 TN/m, providing a major contribution for the ongoing India-Asia collision.

Crustal silica content of East China: A seismological perspective and its significance

East China has experienced multiple periods of tectonic movements, which have contributed to the composition and rheological properties of its present crust. Estimating the composition of the crust is crucial for understanding the tectonic processes. Based on the teleseismic receiver functions with data from the National Seismic Network of China, we applied the H-κ-c method to obtain the crustal bulk VP/VS ratio and to constrain the SiO2 content in the crust. We estimated the SiO2 content to range from 50.89 wt% to 73.51 wt%, with an average value of 65.87 wt%, indicating a predominant felsic composition of the East China's crust. Our study suggests that the North-South Gravity Lineament (NSGL) is an approximate delimitator of the felsic and mafic crust in East China, hinting at a widespread deficiency of mafic lower crust in the east of the NSGL. The mafic crust is extensively distributed in the Taihang orogenic region (TSR) and WuLingshan gravity gradient belts (WLG), particularly in the Datong volcanic area, which manifests the mantle materials intraplating. The scatteredly distributed mafic crust at the east of the NSGL is mainly concentrated in the southeast coast of China and in the intersection region of the Tanlu Fault (TLF) and Sulu region. In Sulu region, the TLF may primarily provide a channel for the thermal intrusion from the underlying mantle lithosphere, which has increased the mafic content. The Pacific/Philippine Sea plate subduction has triggered a significant amount of crust-mantle material exchange below southeast China that resulted in a high degree of mafic crustal composition.

Generation of Neoproterozoic granites of the Huangling batholith in the northern Yangtze Block, South China: Implications for the evolution of the Precambrian continental crust

Granites may contain critical information about composition and reworking of continental crust and are widely used to investigate continental crust evolution. Extensive Neoproterozoic granites in the northern Yangtze Block are significant to the Neoproterozoic continental evolution of the Yangtze Block. We investigated the petrology, mineralogy, whole-rock geochemistry, and zircon U–Pb–Hf isotopes of the Neoproterozoic Wuduhe biotite granites and Xiabaoping K-feldspar granites of the Huangling batholith in the northern Yangtze Block to determine their source characteristics and geological implications for the northern Yangtze Block. The Wuduhe biotite granites yielded zircon U–Pb ages of ca. 818–815 Ma. They displayed high SiO2 contents (70.19–74.23 wt%) and Na2O/K2O ratios (1.38–3.35) but low MgO (0.37–0.90 wt%) and CaO (1.49–2.97 wt%) contents, representing calc-alkaline Na-rich I-type granites. They exhibited enriched whole-rock εNd(t) (−19.8 to − 18.8) and zircon εHf(t) values (−41.3 to − 24.2), and had low CaO/Na2O (0.34–0.63), Al2O3/TiO2 (46.6–89.7), Rb/Ba (0.02–0.08), and Rb/Sr (0.04–0.12) ratios, as well as low zircon saturation temperatures (739 − 770 °C), indicating derivation from Na-rich metabasalts of the Archean Kongling complex. The Xiabaoping K-feldspar granites had zircon U − Pb crystallization ages of ca. 816–812 Ma. They displayed high SiO2 (70.82–74.80 wt%), K2O (4.41–6.35 wt%), and Al2O3 (13.46–16.31 wt%) contents, suggesting A2-type affinities. They showed enriched zircon εHf(t) (−44.3 to − 18.4) and whole-rock εNd(t) values (−23.4 to − 18.4) and high zircon saturation temperatures (869–912 °C), indicating formation by anhydrous melting of K-rich felsic rocks from the Archean Kongling complex. The geochemical diversity of these granites from the Huangling batholith was primarily controlled by source heterogeneity of the Kongling complex and distinct melting temperatures. We infer that the northern Yangtze Block underwent significant remelting of ancient continental crust in a subduction background during the Neoproterozoic, induced by continuous upwelling of mantle-derived mafic magmas.

A New Crustal Thickness and VP/VS Model of the Indochina Peninsula

Abstract The Indochina peninsula is formed by the collision of continental terranes, magmatic arcs, and suture zones due to the closure of the Palaeo-Tethys oceans during the Mesozoic and has experienced complex tectonic activities during the Cenozoic. Crustal thickness and VP/VS of the peninsula can help better understand its tectonics and formation, so we generate a new high-precision crust model for this region via the receiver function H−κ stacking method. The Khorat plateau has thicker crust (∼36.3 km) than other regions (∼32.4 km), whereas the elevation is similar (<500 m) or even lower. The poor correlation between crustal thickness and elevation suggests that there are other factors controlling the Khorat plateau elevation, for example, negative buoyancy of the lithosphere mantle. High crustal VP/VS (1.79–1.83) observed in southern Khorat plateau and southeastern Indochina Terrane indicates a mafic crustal composition that is consistent with extensive Late Cenozoic basaltic volcanism. Furthermore, our new model reveals high crustal VP/VS (1.81–1.95) in the east of the Nan suture and north of Khorat plateau, which could be interpreted as mafic–ultramafic intrusions in the continental back-arc basin east of the Sukhothai arc in the Late Palaeozoic. Our model does not support the existence of the eastward branch of the midlower crustal flow of the Tibetan plateau because a crustal weak layer would be too thin or too dispersed to flow.

Constraining accreted neutron star crust shallow heating with the inferred depth of carbon ignition in X-ray superbursts

ABSTRACT Evidence has accumulated for an as-yet unaccounted for source of heat located at shallow depths within the accreted neutron star crust. However, the nature of this heat source is unknown. I demonstrate that the inferred depth of carbon ignition in X-ray superbursts can be used as an additional constraint for the magnitude and depth of shallow heating. The inferred shallow heating properties are relatively insensitive to the assumed crust composition and carbon fusion reaction rate. For low-accretion rates, the results are weakly dependent on the duration of the accretion outburst, so long as accretion has ensued for enough time to replace the ocean down to the superburst ignition depth. For accretion rates at the Eddington rate, results show a stronger dependence on the outburst duration. Consistent with earlier work, it is shown that urca cooling does not impact the calculated superburst ignition depth unless there is some proximity in depth between the heating and cooling sources.

Phanerozoic emergence of global continental collision and onset of massive crustal eclogitization

Abstract Post-Archean secular changes in continental crust composition, which provide key evidence for the evolution of plate tectonics, remain uncertain, particularly regarding the lower crust. Here, by digitizing 18,000 km of seismic profiles, we demonstrate a change in bulk crustal composition at the Proterozoic–Phanerozoic transition. We document that a mafic crustal layer is preserved in Proterozoic orogens but generally absent in Phanerozoic orogens. We explain this fundamental shift by a change in the global subduction style, where continental collision became important in the Phanerozoic. Densification of the lower crust by widespread eclogitization, triggered by continental collision and subduction, led to massive recycling of mafic lower crust into the mantle, leaving behind buoyant felsic crust and promoting the rise of continents, which led to the emergence of large continental areas above sea level and the related Neoproterozoic oxidation event, followed by the explosion of life in the Phanerozoic.

Zinc isotopic composition of oceanic crust: Insights from oceanic gabbro cumulates and MORBs

Subducting oceanic crust is a critical driver of chemical and lithological heterogeneity within the deep mantle. Zinc isotopes (δ66ZnJMC-Lyon) have been widely utilized to trace recycled oceanic crust and surficial materials. However, the lower oceanic crust rocks are not well studied given limited sampling, making it unclear if the δ66Zn estimated from mid-ocean ridge basalts (MORBs) is valid to represent that of the bulk oceanic crust. In this study, we report δ66Zn data for a series of gabbro cumulates (n = 37) from the ultraslow-spreading Southwest Indian Ridge, alongside MORBs (n = 12) from the fast-spreading East Pacific Rise and the slow-spreading South Mid-Atlantic Ridge. MORBs across various spreading rates exhibit homogeneous δ66Zn values (0.27 ± 0.05 ‰, 2sd), in agreement with previous studies. In contrast, the gabbros with several magma episodes exhibit a significant variation of δ66Zn from 0.11 ‰ to 0.34 ‰, with an average of 0.22 ± 0.11 ‰ (2sd). Magma differentiation to form oceanic crust can partly explain such variation (∼ 0.10 ‰), and post-cumulus modification further extends this range. Given the voluminous lower oceanic crust, the weighted δ66Zn estimated for the bulk oceanic crust (0.23 ± 0.03 ‰) is lower than the MORB-based value, which reconciles with the predictions from mantle partial melting. Therefore, recycled oceanic crust with significantly varied Zn isotopic compositions would lead to heterogeneous δ66Zn of the metasomatized mantle. The overall lower δ66Zn value underscores the importance of surficial materials other than oceanic crust, such as carbonates, to explain high δ66Zn of many mantle-derived magmas.

Multi‐Stage Magmatism During Slab Exhumation Drives the Geochemical Evolution of Continental Crust: Insights From Paleozoic Granitoids in South Altyn, Western China

AbstractThe present continental crust is characterized by a felsic upper crust and a mafic lower crust, resulting from significant geochemical differentiation over geological time. While various processes have been proposed to explain this differentiation, subduction zones remain pivotal regions for understanding the compositional evolution of continental crust. This study focuses on the South Altyn (SA) continental subduction‐collision belt in western China, a unique setting that experienced ultra‐deep (>300 km) continental subduction followed by multi‐stage exhumation. We present a comprehensive study of four granitoid suites from Tatelekebulake (TTLK) area in SA: biotite granite (BG), monzogranite (MG), K‐feldspar granite (KG), and leucogranite (LG). Comprehensive studies on petrology, geochemistry and zircon U‐Pb dating show that these granitoids formed at 494, 451, 414, and 418 Ma, respectively, and originated from protoliths with affinity to the subducted continental crust in SA. Phase equilibrium modeling suggests that BG formed at ∼800°C and 0.6 GPa, while the MG, KG, and LG formed by differentiation crystallization of the BG magma under progressively decreasing temperature and pressure conditions (750°C, 0.5 GPa; 740–700°C, 0.2 GPa; and 700–640°C, 0.1 GPa, respectively). These results, combined with previous studies, allow us to reconstruct the tectonic processes of continental exhumation and subsequent orogenic collapse in SA during the Early Paleozoic. Importantly, our findings reveal that magmatism derived from partial melting of subducted continental crust can promote the geochemical evolution of continental crust toward more felsic compositions, even in the absence of significant crustal growth or mantle‐derived magmatism. This study provides a valuable case for understanding the compositional evolution of continental crust in deep subduction zones and challenges conventional models that rely heavily on arc magmatism for crustal differentiation. Moreover, our results contribute to a broader understanding of crustal evolution processes in collisional orogens worldwide and highlight the importance of recycling and differentiation of subducted continental material in shaping crustal compositions.

What is “eczema”?

AbstractEczema is the most common category of inflammatory skin disorders as dermatologists see many patients with eczematous diseases in daily practice. It is characterized by the three major morphological features: multiple‐pinpoint condition, polymorphism, and itch. To describe polymorphism, “eczema triangle” has been used in German/Japanese dermatology. The multiple pinpoints correspond to numerous tiny foci from which individual papules/vesicles arise. The polymorphism betrays composition of erythema, papule, seropapule, vesicle, pustule, scale, and crust, which are seen in acute eczema. Meanwhile, chronic eczema is represented by lichenification and hyperpigmentation, and possibly by hypopigmentation. In acute eczema, spongiosis is associated with overproduction of hyaluronic acid, secretion of self‐protective galectin‐7, and decreased expression of E‐cadherin. In the upper dermis, Th1/Tc1 or Th2/Tc2, and additional Th17, Th22, and/or Tc22 infiltrate, depending on each eczematous disease. Innate lymphoid cells are also involved in the formation of eczema. In chronic eczema, periostin contributes to remodeling of inflammatory skin with dermal fibrosis, and epidermal melanogenesis and dermal pigment deposition result in hyperpigmentation. Finally, eczematous diseases are potentially associated with increased risk of comorbidities, including not only other allergic diseases but also coronary heart disease and mental problems such as depression. Although the original word for eczema is derived from old Greek “ekzein,” eczema remains a major target of modern science and novel therapies.

Petrography and geochemistry of aplites from the Seridó Pegmatite Province, NE Brazil: Petrogenetic Implications

In the Seridó Pegmatite Province (SPP) there are thousands of granitic pegmatite intrusions, including unzoned and barren, and zoned and mineralized ones. The whole rock chemical analysis of pegmatite is usually unfeasible because of its large grain size. However, fine-grained aplites syn crystallized with pegmatites should allow them to be used as proxies to assess pegmatite melt differentiation. We selected 15 representative aplite occurrences within unzoned pegmatite intrusions, including 7 intrusions with the grayish muscovite-aplite type and 8 with the reddish magnetite-aplite type. We also used for new trace element analysis samples of medium-to coarse-grained facies of host unzoned pegmatites. These pegmatites occur as NE-SW and N-S dykes and sills intruding mica schist and paragneiss from the Seridó Belt. Both aplite types contain along with quartz and feldspars accessory apatite, zircon, monazite, and xenotime. Tourmaline, muscovite, and garnet occur in the grayish aplites, whereas biotite and opaque minerals occur in the reddish aplites. The grayish aplites are slightly to strong peraluminous, while the reddish aplites are slightly metaluminous to slightly peraluminous. The reddish aplites and their host pegmatites are enriched in Ba, Sr, U and Th, while the grayish aplites and their host pegmatites are enriched in B, Li and Cs. The K/Rb ratios of the aplites varies from 11 to 44 with similar ranges in both reddish and grayish aplites. Normalized to the average upper continental crust composition, both aplite types present positive anomalies of Rb, Pb, U, and Hf, and negative anomalies of Ba, Sr and Ti. K, Nb and Ta show variable enrichment and depletion. They usually show HREE enrichment in relation to LREE and negative Eu anomaly, but positive Eu anomaly and tetrad patterns occur in few samples. In the normative QAP diagram the aplites show a wide range of compositions with a trend from quartz-plagioclase-rich tonalite to quartz-poor K-feldspars-rich alkali granite. Such trend is inverted in relation to the characteristic trends of melt differentiation by crystal fractionation. The albite/K-feldspar ratio of aplites shows a wide distribution range that would be related to the compositional variety of the partially melted protoliths and/or the variation in melting rate during prograde anatexis. The trace element compositions of the medium-to coarse-grained facies of the unzoned pegmatites are very similar to those of the coexisting aplites. The obtained data using aplites as a proxy for their host pegmatites precludes a unique line of melt descent at the origin of the SPP aplites and unzoned pegmatites and thus strongly support an anatectic origin from different sources.

Plate tectonics through Earth’s history: constraints from the thermal evolution of Earth’s upper mantle

ABSTRACT Temporal changes in Earth’s tectonic style play a crucial role in understanding the planet’s evolution. Modern-style tectonics is characterized by the formation of basaltic crust at divergent plate boundaries and its subsequent recycling at subduction zones, accompanied by wedge mantle formation and arc magmatism. It is commonly believed that the secular cooling of the mantle modified the tectonic style from stagnant lid or heat pipe on an early hotter Earth to horizontal tectonics during Meso-Neoarchean. However, various field, petrographic, and geochemical studies suggest that the onset of plate tectonics ranges from Hadean to Neoproterozoic. In this study, we re-evaluate the primary magma temperature (mantle potential temperature, Tp) of the upper ambient mantle, spanning from Eoarchean to Neoproterozoic. We used basalts from several Archean and Proterozoic greenstone belts worldwide, along with Proterozoic ophiolites, to (re)calculate the Tp using the FRACTIONATE-PT method. We observed a Tp range of 1444–1639°C during the Archean and 1414–1611°C during the Proterozoic. These findings indicate a strong correlation with previously estimated Tp values obtained from PRIMELT3 method. This further highlights strong internal consistency among different methods and supports models of a hot ambient mantle during the Archean and Proterozoic. We further reviewed numerical models regarding the effect of mantle temperature on the viability of early Earth plate tectonics. Such model results, composition of Archean continental crust, recent crustal growth models, and field evidence are consistent with the operation of plate tectonics on an early hotter Earth. The transition from a hotter mantle to a colder one from Eo-Neoarchean resulted in thinner oceanic lithosphere and a less depleted lithospheric mantle. Subduction of this thinner oceanic lithosphere led to modern-style tectonics. The intensity and style of plate tectonics on the early Earth differed from modern tectonics, which emerged during the Neoarchean.