Composite System Research Articles

Ultrafast bounce of particle-laden droplets.

The rebound of liquid droplets on solid surfaces exhibits behavior reminiscent of elastic spheres, albeit with distinct contact dynamics. While the rapid detachment of droplets from surfaces holds significant relevance for various applications, previous endeavors relying on engineered surfaces can only reduce the contact time to several milliseconds, primarily due to capillary effects dominating droplet bounce. Here, we present ultrafast rebound by designing heterogeneous core-shell droplets encapsulating a particle (DEP), which achieves an unprecedentedly short contact time of 0.3 ms and 0.05 ms with polydimethylsiloxane and glass particles, respectively. This remarkable contact-time reduction is universally applicable to diverse systems, including both water and oil droplets, elastic and rigid particles, super-repellent and superlyophilic surfaces, and is effective across a wide range of impact velocities. Beyond exhibiting liquid-like dynamics, DEP manifests solid-like behavior owing to asynchronized motions between the particle and the droplet, which effectively breaks down the dominance of capillarity. With systematic experimental and analytical studies, we delineate contact times in three bouncing regimes and identify critical conditions governing regime transitions. DEP amalgamates the bouncing dynamics of both solids and liquids, offering a robust and versatile strategy for tailoring contact time to suit diverse applications involving solid-liquid composite systems.

Egg White-Based Gels with Candelilla Wax: A Study of Rheological, Mechanical, Calorimetric and Microstructural Properties

Bigels (BGs) are innovative composite systems that integrate oleogel and hydrogel structures, and are gaining increasing attention for their unique textural and functional properties in food applications. This study evaluated the rheological and mechanical properties of egg white-based bigels incorporating candelilla wax (CW) as an oleogelator. The results indicate that different egg white protein (EWP) (5–10%) concentrations and hydrogel-to-oleogel ratios (20:80 to 80:20) significantly influenced the structural and functional properties of the bigels. Compression testing revealed no significant differences in strength across the tested range; however, higher EWP concentrations enhanced the stability of the BGs. Furthermore, increased candelilla wax oleogel (CWO) content (60%) markedly improved emulsion stability, resulting in superior strength, as confirmed by dynamic light scattering. Rheological studies demonstrated shear-thinning behavior, particularly at higher hydrogel content related to the oleogel (W/O), which exhibited the highest yield stress. Microstructural investigations confirmed the presence of a continuous oleogel phase within the bigels (W/O) and revealed the formation of a complex structure. These findings suggest that a reduced hydrogel-to-oleogel ratio can be utilized across various food systems, opening new possibilities for creating customized food structures with desirable textural and functional attributes.

Enhanced tribological properties of sliding contacts through the synergistic effect of PTFE film and PSAIL 2280

Purpose The purpose of this study is to investigate the effectiveness of a composite lubrication system combining polytetrafluoroethylene (PTFE) film and oil lubrication in steel–steel friction pairs. Design/methodology/approach A PTFE layer was sintered on the surface of a steel disk, and a lubricant with additives was applied to the surface of the steel disk. A friction and wear tester was used to evaluate the tribological properties and insulation capacity. Fourier transform infrared spectrometer was used to analyze the changes in the composition of the lubricant, and X-ray photoelectron spectroscopy was used to analyze the chemical composition of the worn surface. Findings It was found that incorporating the PTFE film with PSAIL 2280 significantly enhanced both the friction reduction and insulation capabilities at the electrical contact interface during sliding. The system consistently achieved ultra-low friction coefficients (COF < 0.01) under loads of 2–4 N and elucidated the underlying lubrication mechanisms. Originality/value This work not only confirm the potential of PTFE films in insulating electrical contact lubrication but also offer a viable approach for maintaining efficient and stable low-friction wear conditions. Peer review The peer review history for this article is available at: https://publons.com/publon/10.1108/ILT-06-2024-0222/

Molecular dynamics study on the enhancement of high‐temperature friction and mechanical properties of perfluoroelastomers by carbon nanomaterials

AbstractThe mechanical and frictional properties of pure perfluoroelastomer, graphene (GN)/perfluoroelastomer, and carbon nanotube (CNT)/perfluoroelastomer composite systems were investigated using molecular dynamics simulations. The influence of carbon nanomaterials on the glass transition temperature, mechanical properties, and frictional behavior of perfluoroelastomers at various temperatures was evaluated. The simulation results demonstrated that the addition of GN and CNTs increased the glass transition temperature of perfluoroelastomers to varying extents. CNTs enhanced the mechanical properties of perfluoroelastomers more effectively than GN, whereas GN provided superior improvement in frictional properties compared to CNTs. Analysis of stress–strain distribution, atomic motion trajectory, interaction energy, mass density, and temperature distribution, bond orientation parameters, radial distribution function (RDF), mean square displacement (MSD), and diffusion coefficients revealed the mechanisms and differences by which GN and CNTs enhance the mechanical and frictional properties of perfluoroelastomers.Highlights Carbon nanomaterials enhance perfluoroelastomer's high‐temperature performance. CNTs provide higher mechanical strength but lower wear resistance. GN nanosheets outperform CNTs in reducing friction and wear. Molecular dynamics simulations reveal distinct enhancement mechanisms.

MARTINI Coarse-Grained Force Field for Thermoplastic Starch Nanocomposites.

Thermoplastic starch (TPS) is an excellent film-forming material, and the addition of fillers, such as tetramethylammonium-montmorillonite (TMA-MMT) clay, has significantly expanded its use in packaging applications. We first used an all-atom (AA) simulation to predict several macroscopic (Young's modulus, glass transition temperature, density) and microscopic (conformation along 1-4 and 1-6 glycosidic linkages, composite morphology) properties of TPS melt and TPS-TMA-MMT composite. The interplay of polymer-surface (weakly repulsive), plasticizer-surface (attractive), and polymer-plasticizer (weakly attractive) interactions leads to conformational and dynamics properties distinct from those in systems with either attractive or repulsive polymer-surface interactions. A subset of AA properties was used to parametrize the MARTINI-2 coarse-grained (CG) force field (FF) for the melt and composite systems. The missing bonded parameters of amylose and amylopectin and the bead types for 1-4 and 1-6 linked α-D glucose were determined using two-body excess entropy, density, and bond and angle distributions in the AA TPS melt. This new MARTINI-2 CG model was also compared with the MARTINI-3 model for the TPS melt. However, the requirement of a polarizable water model necessitates the use of MARTINI-2 FF for the composite system. This liquid-liquid partitioning-based FF shows freezing and compaction of polymer chains near the clay surface, further accentuated by lowering of dispersive interactions between pairs of high-covalent-coordination ring units of TPS polymers and the montmorillonite sheet. A rescaling of the effective dispersive component of TPS-MMT cross interactions was used to optimize the MARTINI-2 FF for the composite system with structural (chain size distribution), thermodynamic (chain conformational entropy and density), and dynamic (self-diffusion coefficient) properties obtained from long AA simulations forming the constraints for optimization. The obtained CG FF parameters provided excellent estimates for several other properties of the melt and composite systems not used in parameter estimation, thus establishing the robustness of the developed model.

A Fast-Calibrated Computational Fluid Dynamic Model for Timber–Concrete Composite Ventilated Façades

Timber–concrete composite (TCC) systems join the positive aspects of engineered wood products (good seismftaic behaviour, low thermal conductivity, environmental sustainability, good behaviour under fire if appropriately designed) with those of concrete (high thermal inertia, durability, excellent fire resistance). TCC facades are typically composed of an internal insulated timber-frame wall and an external concrete slab, separated by a ventilated air cavity. However, there is very limited knowledge concerning the performance of TCC facades, especially concerning their thermal behaviour. The present paper deals with the development and optimization of a 2D Computational Fluid Dynamic (CFD) model for the analysis of TCC ventilated façades’ thermal behaviour. The model is calibrated and validated against experimental data collected during the annual monitoring of a real TCC ventilated envelope in the north of Italy. Also, a new solver algorithm is developed to significantly speed up the simulation (i.e., 45 times faster simulation at an error below 3.5 °C compared to a typical CFD solver). The final model can be used for the time-efficient analysis (simulation time of approximately 23 min for a full day in real-time) and the optimization of the thermal performance of TCC ventilated facades, as well as other ventilated facades with external massive cladding. Our simulation strategy partially avoids the expensive and time-consuming construction of mock-ups, or the use of comparably slow (conventional) CFD solvers that are less suitable for optimization studies.

Research on Crack Sealing Performance of Polymer Microsphere/Hydrogel Composite System

Owing to their excellent water-absorption and swelling properties, polymer microspheres have been extensively applied as deep profile control agents in oilfields. These microspheres effectively seal large pore-throat channels in reservoirs, optimizing the water-absorption profile. In this study, a composite system was developed, comprising polymer microspheres and polyacrylamide polymers, with the inclusion of a cross-linking agent. The system leverages the synergistic effects of polymer microspheres and other plugging techniques to efficiently seal fractured reservoirs. Results indicate that the composite system exhibits strong blocking and scour resistance due to enhanced network integrity, higher viscosity, and improved elastic strength. Additionally, the composite system demonstrates a notable self-repairing capability, maintaining a high sealing efficiency even after a waterflood breakthrough.

Research on the early age mechanical properties of concrete based on hydration kinetics

Abstract. In the era of advanced construction techniques, the enhancement and regulation of the functionality of concrete, a widely utilized construction material, has gained significant prominence. The study delves into the exploration of the properties and heat reaction behavior during hydration of various composite cementitious materials with the incorporation of three distinct mineral additives: microspheres, cellulose, and early strength shrinkage reducing agent for early strength enhancement. Analyzing the impact of cement hydration reactions on the early-age performance of concrete, the Krstulovic-Dabic hydration kinetics model was utilized to simulate and study the hydration process of the composite cementitious system in concrete. The findings reveal that the introduction of microspheres and cellulose hinders the advancement of early-age strength in concrete, whereas the utilization of an early strength shrinkage reducing agent proves to be beneficial in enhancing early-age strength. Enhancing the hydration reaction rate is observed with the addition of early strength shrinkage reducing agent, whereas the presence of microspheres and cellulose slows down this process. The rate of hydration reaction accelerates, resulting in a greater early-age strength of the concrete.

Activated Charcoal-Alginate Platform for Simultaneous Local Delivery of Bioactive Agents: At the Nexus of Antimicrobial and Cytotoxic Activity of Zn2+ Ions

Antimicrobial resistance (AMR) is a global public health threat that affects cancer patients more than the general population. In this work, a composite system based on Zn-alginate hydrogel and activated charcoal (AC) particles that, upon contact with physiological fluids, simultaneously releases bioactive agents (Zn2+ and AC particles impregnated with povidone–iodine) was designed to locally address specific problems characteristic for malignant wounds (MWs). This composite was comprehensively investigated in vitro regarding its morphology (field-emission scanning electron microscopy), Zn2+ release (flame atomic absorption spectrometry), iodine adsorption and desorption from AC particles (energy dispersive X-ray analysis and UV–visible spectroscopy) as well as its antimicrobial and antitumor activity. With respect to the ongoing AMR crises, antimicrobial activity was tested against a wide range of wild multi-drug resistant bacterial and yeast strains, all isolated from patient wounds. Since Zn2+ ions proved to be selectors of resistant strains of bacteria, the synergistic activity of AC particles and adsorbed iodine was shown to be crucial for excellent antibacterial activity. On the other hand, the synergy of AC particles and Zn2+ ions showed an equally strong antifungal effect. In addition, antimicrobial concentrations of Zn2+ ions showed cytotoxic activity against two cancer cell lines derived from cancers affecting skin either as metastatic cancer (breast cancer MDA-MB-453 cell line) or primary cancer of the skin (malignant melanoma Fem-X cell line), which enables Zn2+ ions to be further investigated as potent local agents targeting malignant cells.

Design and application of a novel Improved Fire Hawk Optimization technique-tuned ANFIS for optimal regulation of energy of a composite microgrid system

Design and application of a novel Improved Fire Hawk Optimization technique-tuned ANFIS for optimal regulation of energy of a composite microgrid system

Improved design of optical-microforce sensor with high thermal-mechanical stability for insulation charge ellipsometer testing application

Optical-microforce sensor is the core of the sensing module for the insulation charge ellipsometer testing, whose thermal-mechanical stability directly affects the charge measurement reliability. In this paper, based on molecular simulation, the improved design for SU-8 photoresist-based optical-microforce sensor is proposed. It is found that carboxyl-functionalized carbon nanotube/SU-8 photoresist composite system with 75 % cross-linking index possesses the comparatively better thermal-mechanical stability. Then, based on the photolithography process, modified and unmodified optical-microforce sensors are prepared. Meanwhile, the thermal-mechanical stability is evaluated from the experimental perspective. The experiment is consistent with the molecular simulation, showing that compared with the unmodified optical-microforce sensor with measurement fluctuation of 17.6 %, the modified sensor exhibits better thermal-mechanical stability, whose measurement fluctuation is only 5.3 % during the temperature range of 25–100 °C. Further, the optical-microforce sensor measurement performance evaluation platform is built. It is shown that the modified sensor could achieve the response to different frequency, different magnitude elastic wave and picosecond pulse width elastic wave, which could be applied in the insulation charge ellipsometer testing application.

Control of the Motion of an Inverted Spherical Pendulum on a Moving Base. Hybrid Impact Approach

A new hybrid method for the construction of control actions of a linear control system with constant coefficients is considered in this paper. It is assumed in this paper that a part of the discussed system meets some conditions. Some states of the main system are considered to be control actions for a subsystem for which and LQR stabilizer is acquired. Then, those control actions of the subsystem are used to construct the control actions for the main system. In the problem of controlling the motion of a complex linear system of an inverted spherical pendulum on a moving base, a new approach to the construction of control actions (hybrid action method) was used. It is assumed that a component of the complex system under discussion satisfies certain conditions. The inertial forces at the center of mass of the base of the composite system are considered to be the controlling influences on the inversion of the pendulum, for which the LQR stabilizer was purchased. The determined internal control actions on the inverted pendulum are then used to construct external control actions on the base of the composite system. In the end, a numerical analysis was carried out.

Composite hydrogel contact lens systems for naringenin: A comparison of drug loading and release behaviour in drug carrier systems

Composite hydrogel contact lens systems for naringenin: A comparison of drug loading and release behaviour in drug carrier systems

Advanced Machine Learning and Experimental Studies of Polypropylene Based Polyesters Tribological Composite Systems for Sustainable Recycling Automation and Digitalization

Digitalization and automation are emerging solutions to the complex problems of recycling. In this research work, the experimental and Python based Archard deep learning wear rate models are introduced regarding recycling automation and composite tribological systems optimization. The optimum polyester fibers (PESF) of length of 3-3.5 mm were used for fabrication of polypropylene (PP)-PESF composite systems. The deformation, high texture, asperities, and micro-cracks were observed during scanning electron microscope and machine-learning studies. The lowest experimental value of abrasive wear of 3.0 × 10-6 mm3/Nm was observed for PP. Comparatively, higher experimental values of abrasive wear of the PP-PESF composites are found in the range of 4.35 × 10-6 to 4.7 × 10-6 mm3/Nm due to presence micro-defects on the surface of composites. The experimental values of Coefficient of friction (COF) of PP and PP-PESF are found in the range of 0.70 - 0.8 and 1.1 - 1.3, respectively. The experimental values of abrasive wear and COF are found compatible with literature. Similarly, the simulated values of abrasive wear of PP and PP-PESF composites are predicted in the range of 4.8×10-7 to 3.75×10-7 mm3/Nm, respectively. The predicted values of PP and PP-PESF composite show better resistance towards abrasive wear. The proposed experimental and simulated (in terms of Python coding, machine learning, image processing, artificial intelligence, and deep learning studies) research work can be introduced industrially for automation as well as digitalization of grinding of PES waste, processing, tribological testing, and SEM characterization evaluations.

Performance evaluation of innovative composite wall system under extreme loads

ABSTRACT Current reports on accidents in urban areas reveal the devastation of boundary walls and the consequent risks to human lives and property damage. The present study proposes to mitigate such risks through the development and application of a robust and shock-absorbent composite wall system to replace the normal concrete wall system. The paper adopted a comprehensive Finite Element (FE) study using ABAQUS and used the three-dimensional validated model to initially evaluate the selected four different innovative wall systems (Polypropylene fibre-reinforced composite, ECC-Concrete, ECC-Rubberised concrete, and Rubberised concrete-Concrete composite walls) to evaluate their structural performances under lateral impact and blast loads. The most suitable composition of the wall system is identified after comparing the impact resistance, blast resistance, and the energy absorption capacity of all the selected wall structures. Then, an optimisation study on the best-performed composite is conducted to propose the most appropriate geometric parameters for the composite wall. ECC-Rubberised concrete composite wall shows the least deflection at the selected magnitudes of impact loads and blast loads compared to the other walls. The energy absorption capacity of the ECC-Rubberised concrete composite wall is the highest among all the walls including the normal concrete wall.

Outside-in enhancement of phosphate solubilizing bacteria by sludge biochar for phenol remediation in soil: Pollution stress reduction, electron transfer gain and secretion regulation

The high toxicity of phenol poses a significant barrier to bacterial bio-removal capacity. This study innovatively proposes the utilization of sludge biochar (SB) to embed phosphate-solubilizing bacteria (CZB1), creating a composite system (SB-CZB1) that enhances the bio-removal efficiency of phenol. The research findings indicate that after being embedded with biochar, Phosphorus solubilizing bacteria (PSB) achieved a significant enhancement (49.7 %-67.0 %) in phenol removal efficiency across different concentration gradients (1500, 2000, 2500 mg/L). SB component in the SB-CZB1 composite system provides a stable and favorable growth environment for CZB1, significantly enhancing microbial metabolic activity. Notably, it stimulates CZB1 to secrete succinic acid and malic acid (with increases of 3.8 % and 23.9 %, respectively), effectively mitigating the detrimental effects of phenol toxicity on microorganisms. Three-dimensional fluorescence and electrochemical analysis demonstrate that SB not only exhibits exceptional electrochemical performance but also stimulates CZB1 to generate redox-active substances (quinone components in humic acid). The electron transfer rates between microorganisms and phenol in the SB-CZB1 system are 9.75–21.71 times and 23.94–63.95 times higher than those in SB and CZB1 alone, respectively. Meanwhile, the abundant oxygen-containing functional groups (COH/COC, COOH, CO) on the surface of SB-CZB1 play a pivotal role in the adsorption and removal of phenol. Furthermore, pot experiments further reveal that the SB-CZB1 composite system significantly enhances the removal efficiency of phenol in soil (98.1 %). Additionally, the application of SB-CZB1 effectively modulated soil properties, notably increasing available potassium and available phosphorus content by 40.86 % and 136.69 %. This application not only enriched soil microbial diversity but also promoted the proliferation of native organic pollutant remediation bacteria in the soil. Notably, the proliferation of Bacillus species affiliated with CZB1 was the most significant, increasing by 82.1 %. This result confirms that biochar embedding technology effectively enhanced the colonization of CZB1 in the soil, thereby significantly accelerating the bio-removal process of phenol.

A review on green materials: Exploring the potential of poly(vinyl alcohol) (PVA) and nanocellulose composites.

Polyvinyl alcohol (PVA) and nanocellulose (NC) composite systems are promising candidates with exciting implications for sustainability, adaptability, and future uses. This research investigates the synergistic features of PVA and nanocellulose, focusing on their renewable and biodegradable nature as important contributors to sustainable material development. An overview of various processing techniques of PVA/NC composites, and their morphological, thermo-mechanical, barrier and biodegradable properties is examined, revealing its enhanced performance attributes compared to conventional materials. This review also discusses the numerous applications of PVA and nanocellulose composites in packaging, biomedical engineering, and environmental remediation. Furthermore, the discussion expands on the potential future applications of these composites, emphasizing their importance in tackling critical global concerns such as pollution reduction, resource conservation, and healthcare breakthroughs. With ongoing research focusing on functionalisation strategies and scalable production methods, PVA and nanocellulose composites are poised to revolutionize multiple sectors, offering sustainable solutions that align with the principles of circular economy and environmental stewardship. Finally, this review emphasises the enormous contributions of PVA and nanocellulose composites to sustainable material innovation, their broad applicability across industries, and their promise to shape a more resilient and environmentally friendly future.

Polymeric ionic liquids and piperidinium synergistically improve proton conductivity and acid retention of polybenzimidazole-based proton exchange membranes

Amino-type polybenzimidazole is prepared, then ionic liquid with three nitrogen positive sites ([CTDTr]Br3) is polymerized into polymeric ionic liquids (PILs) by in-situ radical polymerization, and AmPBI-CTDTr-Px membranes were prepared by piperidinium (PPd) and [CTDTr]Br3 combination to cross-linked with AmPBI. Following treatment with KOH and phosphoric acid (PA), the ion pairs (N+ - H2PO4-) generated in the composite membrane system can enhance proton conductivity and facilitate proton transport. The AmPBI-CTDTr-Px membranes shown exceptional PA retention as a result of the alkaline properties of both [CTDTr]Br3 and PPd, which can engage in acid-base interactions with phosphoric acid. Specifically, the proton conductivity of AmPBI-CTDTr-P5 at 180 °C is 129.7 mS cm-1, which is 2.52 times that of pure membranes. Acid retention of AmPBI-CTDTr-P5 at 80 °C/40% RH and 160 °C are 64.4% and 84%.

Hypoglycemic activity of enzymatically extracted Eucommia ulmoides polysaccharide (EUL-w1) on IR-HepG2 cell via the AMPK/PI3K/Akt signaling pathway

This study devised optimal conditions to extract Eucommia ulmoides leaf (EUL) polysaccharides using a cellulase and pectinase composite enzyme system based on one-way experiments and response surface methodology. Crude EUL polysaccharides (EULPs) were extracted and purified using a DEAE chromatography column. The polysaccharides EUL-w, EUL1, EUL2, and EUL3 were obtained by elution with water, 0.1 mol/L NaCl, 0.2 mol/L NaCl, and 0.3 mol/L NaCl, respectively. The EUL-w fraction had the highest hypoglycemic activity based on its α-amylase and α-glucosidase activities. The preliminary structure of purified EUL-w1 was elucidated. In vitro hypoglycemic activity studies and metabolomics analyses suggested that EUL-w1 modulated glucose metabolism by mediating the AMPK/PI3K/Akt signaling pathway. Our findings provide novel insights and data support for the utilization of EULPs as an emerging food resource in functional foods.

Quantum nonlocality of density operators and their corresponding density matrices

Quantum nonlocality represents correlations between subsystems of a composite quantum system, usually including Bell nonlocality, steerability, and entanglement. According to the hypothesis of quantum mechanics, states of a quantum system Q described by a d-dimensional Hilbert space are denoted by density operators acting on . Under a basis e for the Hilbert space , every abstract density operator ρ of the system AB corresponds to a density matrix ρ e , which is a state of the complex Hilbert space . In this work, we discuss the consistency of quantum nonlocality of density operators ρ and their corresponding density matrices ρ e under the chosen basis e. It is proved that only when a basis e is a product one, a density operator ρ is entangled (respectively, Bell nonlocal, steerable) if and only if its density matrix ρ e is entangled (respectively, Bell nonlocal, steerable).