Composite Sorbent Research Articles

Predictive thermal performance analysis of T-wall based adsorption thermal battery for solar building heating

Moisture-based adsorption thermal battery (ATB) holds great potential for addressing energy storage and utilization challenges. In this work, a proof-of-concept solar harvesting building envelope using the Trombe-wall (T-wall) based ATB design is proposed and investigated, featuring a developed composite sorbent as the porous wall for effective heat storage and utilization. To demonstrate the feasibility of employing the ATB-based building envelope for day-and-night space heating, a 3-dimensional simulation model of the ATB wall is meticulously designed and comprehensively studied. Parametric analyses of various working conditions, including examining the effects of solar radiation intensity, air temperature, air humidity, and airflow velocity on the heat charging and discharging performances of the ATB wall, are conducted using the numerical model. Simulation results indicate that, under a solar irradiance level of 700 W m−2 during the daytime, an average output air temperature of 42.4 °C and an average heating power density of 2.5 kW m−3 are achieved. Extending the heat charging time to 8 h and 12 h significantly improves the desorption efficiency, which is able to reach 47.2% and 75.0%, respectively. In terms of heat discharging performances, various working conditions investigated in the ATB wall model will lead to different thermal output performances.

Preparation and thermal properties of zeolite/MgSO4 composite sorption material for heat storage

Thermochemical sorption heat storage based on salt hydrates offers the potential advantages such as high energy density, negligible heat loss, small volume change and flexible working modes. Magnesium sulphate (MgSO4) is a high energy density hydrated salt available for the thermochemical sorption heat storage. In this work, different types of zeolites (including 3A, 5A and 13X zeolites) have been selected as mass-transfer-enhancing and structural stabilizing materials, and a series of zeolite/MgSO4 composites have been fabricated. To investigate the thermal energy storage performance of zeolite/MgSO4 composites, the properties of the composites, such as micro-morphology, pore structure, chemical composition and sorption-desorption behavior, have been characterized and analyzed. Results indicated that the mass transfer performance of the composite materials is significantly better than that of the pure zeolites. As the mass fraction of MgSO4 in the composite sorbents increases, the specific surface area and porosity of the composite sorbent decreases, and the sorption performance has been enhanced. Compared with 3A zeolite-based and 5A zeolite-based composites, 13X zeolite/MgSO4 composite materials show the best heat storage performance. At the condition of 25 °C and 60% RH, the 13XM20 has the highest sorption capacity of 0.21 g/g, which is 24% higher than that of pure zeolite 13X. Accordingly, the maximum heat storage density is 438.4 kJ/kg, which exhibits the superior heat storage performance among of the hydrated salt sorbents. The potential of 13X zeolite/MgSO4 as sorption heat storage material in efficient utilization of solar heat and low-grade industrial waste heat has been revealed.

Composite magnetic sorbents based on magnetic Fe3O4 coated by Zn and Al layered double hydroxide for U(VI) removal from aqueous media

Composite magnetic sorbents based on magnetic Fe3O4 coated by Zn and Al layered double hydroxide for U(VI) removal from aqueous media

Synthesis of Novel Composite Sorbents Based on Titanium, Calcium, and Magnesium Phosphates

Synthesis of Novel Composite Sorbents Based on Titanium, Calcium, and Magnesium Phosphates

Novel Fe3O4–ZnO Carbonized Rice Husk Modified Nano Composite Sorbent for Removal of Humic Acid from Aqueous Media

Novel Fe3O4–ZnO Carbonized Rice Husk Modified Nano Composite Sorbent for Removal of Humic Acid from Aqueous Media

The role of natural sorbents and piping production waste in the treatment of acid iron-containing waste water

In this article, we consider the sorption purification of production wastewater from pipe industry enterprises. We have presented and studied the potential sorbents from among natural materials and from piping production waste. The authors of this paper have studied the sorption capacity of the materials under consideration with regard to heavy metals from highly acidic iron-containing wastewater both in static and dynamic modes. The static-mode research has been conducted for various temperatures: 10°С, 20°С and 30°С. In the dynamic conditions, the filtrate flow rate equaled 0.3, 0.6 and 1.2 l/h. The authors have proven that a number of the examined materials can be used as sorbents or constituting elements of composite sorbents for the technology of wastewater treatment at pipe industry enterprises.

Dual synergistic effect of the amine-functionalized MIL-101@cellulose sorbents for enhanced CO2 capture at ambient temperature

The development of high carbon dioxide (CO2) sorption capacity materials is necessary for the deployment of the CO2 capture and storage strategy. Metal-organic frameworks (MOFs) have emerged as promising substitutes for traditional liquid and solid CO2 capture sorbents due to their high surface area, tunable pore size, diverse composition, and various physical and chemical properties. However, MOFs feature the intrinsic limitations of powder agglomeration, weak binding affinity, and sluggish diffusion kinetics, thus hindering their industrial application in CO2 capture. Herein, we design an amine-functionalized MIL-101@cellulose (NH2-MIL-101@BM) composite sorbent by anchoring NH2-MIL-101 nanoparticles onto the BM matrix through hydrogen bonding interaction. The dual synergistic effect, origin from the physical sorption synergistic effect and chemisorption synergistic effect proposed between NH2-MIL-101 and BM, not only facilitates the mass transfer of CO2 by reducing the diffusion resistance through hierarchical-pore structure but also offers stronger sorption sites with CO2 by increasing the adsorption energy of metal-CO2 or amine-CO2, which are confirmed by series of characterizations and theory functional calculations. Benefiting from the above merits, the NH2-MIL-101@20 %BM sorbent delivers a superior initial CO2 sorption capacity of 13.4 mmol/g when the BM doping amount is 20 wt% at 25 °C, and also shows good recycle stability even after 15 runs with maintainable structure. This work displays the in-depth mechanism understanding for enhanced CO2 capture, providing value inspiration for future MOF-based composite sorbent construction for CO2 capture at ambient temperatures.

Excitation generated preferential binding sites for ethane on porous carbon-copper porphyrin sorbents: ethane/ethylene adsorptive separation improved by light.

Energy-efficient separation of C2H6/C2H4 is a great challenge, for which adsorptive separation is very promising. C2H6-selective adsorption has big implications, while the design of C2H6-sorbents with ideal adsorption capability, particularly with the C2H6/C2H4-selectivity exceeded 2.0, is still challenging. Instead of the current strategies such as chemical modification or pore space modulation, we propose a new methodology for the design of C2H6-sorbents. With a Cu-TCPP [TCPP = 5,10,15,20-tetrakis(4-carboxyphenyl)porphyrin] framework dispersed onto a microporous carbon and a hierarchical-pore carbon, two composite sorbents are fabricated. The composite sorbents exhibit enhanced C2H6-selective adsorption capabilities with visible light, particularly the composite sorbent based on the hierarchical-pore carbon, whose C2H6 and C2H4 adsorption capacities (0 °C, 1 bar) are targetedly increased by 27% and only 1.8% with visible light, and therefore, an C2H6-selectivity (C2H6/C2H4 = 10/90, v/v) of 4.8 can be realized. With visible light, the adsorption force of the C2H6 molecule can be asymmetrically enhanced by the excitation enriched electron density over the adsorption sites formed via the close interaction between the Cu-TCPP and the carbon layer, whereas that of the C2H4 molecule is symmetrically altered and the forces cancelled each other out. This strategy may open up a new route for energy-efficient adsorptive separation of C2H6/C2H4 with light.

Восстановление нарушенных земель в горных экосистемах

Introduction. The growing volumes of extraction, processing and transportation of minerals in Russia and the world contribute to an increase in disturbed lands, which actualizes the development of new approaches and methods for reclamation work. However, a clear structure of methods for restoring disturbed lands has not yet been developed. Hence the purpose of the work: to explore the world experience in the implementation of traditional and innovative approaches to the reclamation of disturbed lands in order to identify the most promising trends for further research. Materials and methods. The theoretical and methodological basis of the study are the scientific works of Russian and foreign scientists in the field of earth sciences, geo-ecology, physical chemistry, geo-botany and microbiology. Methods of the work are general scientific methods, such as dialectical, historical, analysis, synthesis, comparison, grouping, as well as systematic and empirical approaches. Results and discussion. The study substantiates the identification of two approaches: traditional and innovative; the author’s structure of methods for biological stage of reclamation work has been developed. The traditional approach is characterized by standard, but less effective, labor-intensive, and therefore expensive, methods of reclamation by using a fertile soil layer and potentially fertile rocks with the sowing of perennial grasses, trees and shrubs. An innovative approach is on agenda today. It can significantly reduce the cost of reclamation procedures due to the use of modern technologies and materials for restoring soil fertility and decontaminating pollutants. The innovative approach includes basic methods: 1. Algae; 2. Washing; 3. Bioremediation; 4. Sorbent-oriented. The study offers to improve the term «disturbed lands» in the regulatory field of the Russian Federation in order to take into account, along with the anthropogenic and natural factors. The structure of the disturbed lands of Russia is revealed in the context of the extraction of various types of minerals. Conclusions and offers. The article presents the results of the analysis of the world methodological experience in biological stage of reclamation work. It has been established that both in Russia and abroad, work is underway to improve the biological stage of reclamation. Attention is focused on the method of bioremediation and its sub-method of phytoremediation with the sorbent-oriented method, the combination of which, according to the authors, is of the greatest practical interest. It is revealed that the tasks of using local types of raw materials for the creation of composite sorbents are topical. The authors consider the creation of composite sorbents based on peat, as the most common raw material in Russia, to be a promising direction.

Removal of Diclofenac and Heavy Metal Ions from Aqueous Media Using Composite Sorbents in Dynamic Conditions.

Pharmaceuticals and heavy metals pose significant risks to human health and aquatic ecosystems, necessitating their removal from water and wastewater. A promising alternative for this purpose involves their removal by adsorption on composite sorbents prepared using a conventional layer-by-layer (LbL) method or an innovative coacervate direct deposition approach. In this study, four novel composite materials based on a silica core (IS) and a polyelectrolyte coacervate shell were used for the investigation of dynamic adsorption of three heavy metals (lead, nickel and cadmium) and an organic drug model (diclofenac sodium salt, DCF-Na). The four types of composite sorbents were tested for the first time in dynamic conditions (columns with continuous flow), and the column conditions were similar to those used in wastewater treatment plants. The influence of the polyanion nature (poly(acrylic acid) (PAA) vs. poly(sodium methacrylate) (PMAA)), maintaining a constant poly(ethyleneimine) (PEI), and the cross-linking degree (r = 0.1 and r = 1.0) of PEI chains on the immobilization of these pollutants (inorganic vs. organic) on the same type of composite was also studied. The experiments involved both single- and multi-component aqueous solutions. The kinetics of the dynamic adsorption process were examined using two non-linear models: the Thomas and Yoon-Nelson models. The tested sorbents demonstrated good adsorption capacities with affinities for the metal ions in the following order: Pb2+ > Cd2+ > Ni2+. An increase in the initial diclofenac sodium concentration led to an enhanced adsorption capacity of the IS/(PEI-PAA)c-r1 sorbent. The calculated sorption capacities were in good agreement with the adsorption capacity predicted by the Thomas and Yoon-Nelson models. The substantial affinity observed between DCF-Na and a column containing composite microparticles saturated with heavy metal ions was explained.

Optimization of two-phase synthesis of Fe-hydrochar for arsenic removal from drinking water: Effect of temperature and Fe concentration

Arsenic-contaminated water is a global concern that demands the development of cost-effective treatments to ensure a safe drinking water supply for people worldwide. In this paper, we report the optimization of a two-phase synthesis for producing a hydrochar core from olive pomace to serve as support for the deposition of Fe-hydroxide, which is the active component in As(V) removal. The operating conditions considered were the initial concentration of Fe in solution in the hydrothermal treatment (phase I) and the temperature of Fe precipitation (phase II). The obtained samples were characterized for their elemental composition, solid yield, mineral content (Fe and K), phenol release, As(V) sorption capacity, and sorbent stability.Correlation analysis revealed that higher Fe concentrations (26.8 g/L) ensured better carbonization during hydrothermal treatment, increased arsenic removal, reduced concentrations of phenols in the final liquid, and improved stability of the sorbent composite. On the other hand, the temperature during Fe precipitation (phase II) can be maintained at lower levels (25–80 °C) since higher temperatures yielded lower adsorption capacity. Regression analysis demonstrated the significance of the main effects of the parameters on sorption capacity and provided a model for selecting operating conditions (Fe concentration and phase II temperature) to obtain composite sorbents with tailored sorption properties.

Synthesis of a Magnetic Nanostructured Composite Sorbent Only from Waste Materials.

Water pollution is a big problem for the environment, and thus depollution, especially by adsorption processes, has garnered a lot of interest in research over the last decades. Since sorbents would be used in large quantities, ideally, they should be cheaply prepared in scalable reactions from waste materials or renewable sources and be reusable. Herein, we describe a novel preparation of a range of magnetic sorbents only from waste materials (sawdust and iron mud) and their performance in the adsorption of several dyes (methylene blue, crystal violet, fast green FCF, and congo red). The preparation is performed in a hydrothermal process and is thus easily scalable and requires little sophisticated equipment. The magnetic nanostructured materials were analyzed using FTIR, VSM, SEM/EDX, XRD, and XPS. For crystal violet as a pollutant, more in-depth adsorption studies were performed. It was found that the best-performing magnetic sorbent had a maximum sorption capacity of 97.9 mg/g for crystal violet (methylene blue: 149.8 mg/g, fast green FCF: 52.2 mg/g, congo red: 10.5 mg/g), could be reused several times without drastic changes in sorption behavior, and was easily separable from the solution by simply applying a magnet. It is thus envisioned to be used for depollution in industrial/environmental applications, especially for cationic dyes.

Assessment of performance and environmental friendliness of a sorbent-based remediation method for heavy metal and metalloid contaminated soils

The contamination of natural ecosystems with heavy metals and metalloids (HMMs) primarily results from anthropogenic activities. Consequently, ongoing efforts are dedicated to the development of technologies aimed at restraining the mobility of HMMs and expediting chemical reactions that convert pollutants from mobile to immobile states. Addressing the reclamation issue always necessitates the selection of the most promising and effective type of reclamation work, as well as justification of land prioritization for reclamation purposes. In terms of performance and future potential, the sorbent-oriented approach, grounded in the concept of “green” utilization of man-made waste as a raw material for creating novel composite sorbents, is gaining traction for land reclamation in disturbed areas. In international practice, diverse environmental risk assessment methods are employed to substantiate the necessity for and prioritize reclamation efforts.The aim of the present study is to evaluate established conventional methods for assessing the risks associated with environmental harm. Additionally, this research aims to assess the efficacy and ecological compatibility of the composite sorbents developed by the author. This evaluation will be conducted by assessing and comparing the levels of potential environmental risks or risks of environmental damage subsequent to the application of these sorbents.The objectives of this study are as follows: 1) to explore the theoretical aspects of HMMs: including the formulation of a definition, investigation onto the origins of HMMs, examination of HMMs’ toxicity, and identification of prevalent methods for evaluating the environmental risks associated with HMMs; 2) to evaluate the effectiveness of established methods for assessing the environmental risks posed by HMMs; 3) to assess the efficacy and environmental sustainability of the composite sorbents developed by the author. This evaluation will involve an examination and comparison of the levels of potential environmental risks and the risks of environmental damage subsequent to the a pplication of these sorbents.The research subject: the mining allotment within the Levikhinskoye mine (classified as an environmental disaster site) is investigated as a disturbed land ecosystem, encompassing industrial waste dumps containing HMMs.The research hypothesis aims to establish the viability of “green” waste utilization from industrial sources as a raw material for composite sorbents used in land reclamation, without escalating the environmental damage. The conducted experiments revealed that sorbents composed of peat/water treatment sludge (at a ratio of 20/80 wt. % with natural moisture content) and peat/diatomite/water treatment sludge (at a ratio of 5/15/80 wt. % with natural moisture content) exhibited the highest level of performance, surpassing an overall efficiency of 89%. A sorbent composed of peat/diatomite (at a ratio of 25/75 wt. % with natural moisture content) demonstrated an overall efficiency of 67.7%. The estimated environmental risks (ER and ED) after the application of the proprietary composite sorbents, which include water treatment sludge, exhibited an average reduction of 89.5% and 88%, respectively.

Using red mud as a sorbent for heavy metal cations

Red mud is the main by-product of the production of alumina according to the Bayer process. It is a highly alkaline, brick-red suspension. It is characterized by a diversity of chemical and mineralogical composition. The main elements in red mud are Fe, Al, Si, Ti, Na, Ca, and they account for about 90% of the mass of the mud. In addition to these, a large number of other components can be found in minor quantities. Most elements are present in the form of oxides and hydroxides in various minerals. The demand for aluminum is constantly growing, the amount of discharged red mud is continually increasing. The annual amount of red mud produced globally, is already estimated at 200 million tons, and further growth is expected. High production rates and only minimal and sporadic utilization of red mud have resulted in the accumulation of large quantities of disposed red mud, so that the global red mud stockpile is estimated at more than 5 billion tons. In addition to financial costs, the disposal of red mud also poses certain risks to the environment. For this reason, the safe disposal of red mud is one of the main concerns of all alumina producers. Reducing the amount of red mud that is disposed of, and consequently reducing the risks and costs, requires constant efforts to find procedures for its valorization. The possibilities of valorization of red mud are diverse. It has been shown that red mud can be successfully used in many areas, such as construction, metallurgy, chemical industry, environmental protection, agriculture, etc. Analyzing the patents related to the use of red mud, it can be observed that 12% of the patents refer to the wastewater and waste treatment. The heterogeneous composition of red mud indicates the possibility of its application as a composite sorbent. The application of red mud as a low-cost sorbent has been extensively investigated, and favorable results have been obtained in the sorption of metals and metalloids, radionuclides, phosphates, nitrates, fluorides, dyes and phenols, etc. In order to increase the sorption capacity of red mud and obtain a more environmentally friendly sorbent, various treatment techniques are applied. These treatment techniques can modify the physical and chemical properties, which can lead to a change in alkalinity, specific surface area and porosity, a change in the number of active sorption sites, and its surface charge can also be changed. Modifications of red mud to remove various types of pollutants have shown promising results. Many studies have shown that red mud can be used as an efficient and low-cost sorbent for removing heavy metal cations from solutions, such as Pb2+, Cu2+, Zn2+ , Cd2+, Ni2+, Co2+, Sr2+, Cs2+, as well as for the treatment of waste water and leachate from landfills and mines. During the removal of heavy metals from solutions using red mud, various mass transfer phenomena occur: physical and chemical adsorption, surface precipitation, co-precipitation, ion exchange, precipitation, complexation, hydration, dissolution, etc. Despite the numerous possibilities of application and the benefits that arise from it, we still do not have a significant utilization of red mud.

Low-Temperature Composite CO2 Sorbents Based on Amine-Containing Compounds

The use of technologies based on combustion of carbon-containing fossil fuel leads to emission of large amounts of CO2, one of the main greenhouse gases, into the atmosphere. To reduce the CO2 level in the atmosphere, systems for CO2 sorption from various gas sources are being developed. The systems allowing the CO2 sorption and desorption at low temperatures (25–200°С) are of most interest. Most frequently, such systems are composite materials consisting of a porous support and a CO2 chemisorbent dispersed on it. Low-volatile amine-containing compounds are the most promising among organic chemisorbents. Classification of the amine-containing sorbents with respect to the preparation procedure is discussed. The procedures include impregnation, covalent grafting, and in situ polymerization on the support surface. The impregnation procedure is simple and cheap in implementation. The sorption characteristics of materials prepared by impregnation depend on the efficiency of the dispersion of the active component, which is determined by the characteristics of the support pore structure, in particular, by the ability of the pore surface for chemical or electrostatic interaction with the supported amine-containing compound. The covalent grafting is based on immobilization of alkoxyaminosilanes on the surface of porous silica materials. The supports for implementing this approach should contain a large amount of silanol groups on the surface and should have the pore size sufficient for the efficient transport of CO2 molecules to amino groups. The main drawback of the grafting method is low thickness of the amine-containing component layers obtained. In situ polymerization is used for preparing materials with high content of grafted functional groups. Provided that the blocking of support pores is excluded in the course of in situ polymerization, materials of this type exhibit the highest sorption capacity for CO2.

Retrieval of zirconium ions from laboratory solutions upon insitu-gel-precipitated aluminium based composite sorbents

Synthesis of innovative substances that serve as potential adsorbents used to reduce pollution impacts or even capture valuable elements is still a target. The strategic point of this work is the preparation of aluminum silicate vanadate nano particles (AlSiV-NPs) and aluminum silicate vanadate tungstate nano particles (AlSiVW-NPs) via the insitu technique. The prepared adsorbents were characterized using FTIR, TGA, TEM, XRD, and SEM-EDX analyses. Studies were conducted on the effects of pH variation, feeding solution concentrations, equilibrium times, and adsorbent weight on the Zr4+ adsorption process on the synthesized adsorbents. With the experimental maximum adsorption capacities of 89 and 95 mg/g for AlSiV-NPs and AlSiVW-NPs, respectively, the equilibrium adsorption results for Zr4+ were in good agreement with the Langmuir isotherm and the qe values were more fitting. The pseudo-second-model kinetically matches both adsorbents suggesting that chemisorption was the approach of adsorption. Thermodynamic results for composites AlSiV-NPs and AlSiVW-NPs show similar values for enthalpy change (−31.5 and −21.08 kJ/mol), entropy change (−47.8 and −7.8 J/mol.. K), and negative free energy change. In summary, Zr4+ adsorption over AlSiV-NPs and AlSiVW-NPs is exothermic, spontaneous, and has a lower degree of disorder. These findings proved the promising future of these composites to recover Zr4+ from aqueous media.

Processes of Ion Exchange Sorption and Desorption of Cu2+ and Zn2+ Ions on a Composite Sorbent

Processes of Ion Exchange Sorption and Desorption of Cu2+ and Zn2+ Ions on a Composite Sorbent

Fabrication of superhydrophobic melamine sponge composite sorbent in supercritical carbon dioxide atmosphere for selective and effective oil removal from water

In this study, both the modification of activated halloysite nanotube (HNT) with methyltriethoxysilane (METES) and the fabrication of durable, superhydrophobic (water contact angle: 153.0°) and superoleophilic (oil contact angle: 0 °) melamine sponge (MS)-HNT-METES sorbent material (MS-METES) were achieved in supercritical carbon dioxide (scCO2) atmosphere. For the coating of MS with clay mineral and METES through sol-gel reaction in scCO2, optimal process conditions were determined to be pressure difference of 60 bars at 35 °C, solvent/METES mass ratio of 7.5, METES/MS mass ratio of 10, and degas time of 400 s. Successful preparation of MS-METES was proven by XPS, FTIR, 29Si-MAS NMR, SEM, and contact angle measurements. MS-METES displayed excellent sorption capacity for various petroleum products, oils, and organic solvents (49.6–122.4 g/g), remarkable oil-water separation efficiency (99.1%, for continuous separation technique), high selectivity for oil/organic solvent in acidic, salty, and alkaline solution conditions, good reusability, chemical stability and robustness, and outstanding flexibility and mechanical stability. We believe that the innovative process used in this study will have great potential to be used by researchers in the direct fabrication of new superhydrophobic and superoleophilic sorbent materials for the selective removal of oil and organic solvent spills from water.

Experimental and theoretical investigations on Hg(II) removal by recyclable composite sorbents comprised of polymers bearing thiourea or amidoxime functional groups and mesoporous silica

It is extremely desirable but still challenging to skilfully manufacture highly efficient sorbents to remmediate, in a reversible manner, the water pollution with mercury. Herein, new sorbents for Hg(II) ions have been designed by the initial synthesis of polyacrylonitrile networks inside mesoporous SiO2 microparticles, followed by the chemical modification of acrylonitrile groups with thiourea or amidoxime moieties. The Hg(II) ions sorption properties of the new composites were compared with respect of initial solution pH, contact time, equilibrium concentration and impact of interfering metal ions. It was demonstrated that the sorbents containing thiourea groups exhibited superior sorption capacities (1.76 mmol Hg(II) g−1) compared to the ones containing amidoxime groups (1.68 mmol Hg(II) g−1), and also higher selectivity for Hg(II) ions separation from binary mixtures with Cu(II), Cd(II) or Pb(II) ions. Kinetic study and DFT results supported a combined sorption mechanism, both physical sorption and chem-isorption being possible. Following the elution of Hg(II) ions with 1 M HNO3 and the regeneration with 0.1 M NaOH, all sorbents exhibited around 90 % sorption capacity recovery after 4 reuse cycles.

Adsorption behavior of trace elements of 90Sr on MnO2–ZrO2 loaded with polyacrylonitrile polymer from aqueous solutions

A MnO2–ZrO2-polyacrylonitrile (MnO2–ZrO2-PAN) composite ion exchanger was produced and its properties were examined by Fourier-transformed infrared spectroscopy, scanning electron microscopy, The BET (Brunauer, Emmett and Teller) surface area, X-Ray diffraction analysis and thermogravimetric analysis. The adsorption of Strontium (Sr) from solutions by MnO2–ZrO2-PAN composite was studied thru batch experiments. The distribution Coefficient of Sr (II) on the composite sorbent was investigated against pH, interaction time, and primary concentration ion. To study the kinetics of adsorption, Pseudo-first-order and Pseudo second-order adsorption kinetics were studied and the results revealed that adsorption kinetics better fit to the pseudo-second-order model. Three iso-temperature models, Langmuir, Freundlich, and Temkin were applied to fit the experimental results. Among those models, Langmuir revealed the most suitable one with minimum deviation. The created composite exhibited strong compatibility to the elimination of Y (III), Ni (II), Pb (II), and Co (II) from radioactive waste streams. On the other, it is evident from the data that the quantifiable extraction of Sr (II) ions from Zr (IV), Mo (VI), and La (III) is feasible. MnO2–ZrO2 Loaded with (PAN) Polymer was figured out to have high ion exchange capacity and thermal stability and selectivity for strontium.