The electrical properties of carbon fibers serve as the foundation for the multifunctional applications of carbon fiber-reinforced composite structures. In scenarios that exploit the electrical characteristics of materials, accurate estimation of electrical resistivity stands as a critical factor. This study endeavors to elucidate the electrical conduction behaviors in unidirectional composites with different fiber orientation angles (0°, 15°, 30°, 45°, 60°, 75°, and 90°) and aspect ratios, thereby deriving the volume resistivity within an arbitrary Cartesian coordinate system. Employing thermal infrared imaging technology and finite element analysis, we identified distinctive electrical conduction behaviors associated with aspect ratios in carbon fiber composite plates. Notably, a critical aspect ratio exists wherein the diagonal yarn is the only conductive path between two electrodes. Below this critical threshold, no direct conductive path exists, and current flows through the shortest distance between parallel yarns. Conversely, beyond the critical aspect ratio value, multiple yarns form conductive paths between the two electrodes. Based on the electrical conduction behavior of unidirectional composites under different angles and aspect ratios, the volume resistivity with finite boundaries was derived and examined under an arbitrary Cartesian coordinate basis.