Production Of Composite Materials Research Articles

Study on the impact of water absorption processes on the application of wood waste in composite material production

The issue of recycling and reusing waste from the wood processing industry has garnered significant attention from researchers, as effective solutions could yield economic benefits while mitigating environmental impacts. This article focuses on the development of artificial wood using unsaturated polyester resin combined with waste materials from carpentry workshops, specifically investigating its water absorption properties. Research findings indicate that the water absorption coefficient of the samples increased with longer immersion times, higher organic filler content, and larger particle diameters. The calculated density reveals a broad spectrum of solid industrial boards that can be produced from these compositions, suggesting that consistent forming conditions enhance economic viability. Notably, optimal results were achieved with samples made from mixed wood powder without prior sorting, which contributes to reduced production costs, aligning with the study's objectives. Furthermore, the investigation highlighted that the water absorption coefficient escalates with increased soaking time, organic filler content, and particle size, indicating that in humid environments, it is advisable to limit both filler content and particle size to maintain performance. Overall, the studies confirm the feasibility of utilizing wood powder as a filler, with varying particle diameters imparting distinct characteristics to the final product. These findings underscore the potential for innovative approaches to wood waste management in the industry.

Experimental Investigations of the Influence of Spent Coffee Grounds Content on PLA Based Composite for 3D Printing

Nowadays Fused Deposition Modeling, a widely utilized additive manufacturing technology, is significantly transforming as modern production processes. Beyond basic uses to it role in sustainability, Fused Deposition Modeling offers processing potential for implanting circular economy by reducing virgin materials consumption and enhance the integration of waste food for sustainable 3D printing. This research paper investigated the production of new composite materials based on spent coffee grounds. In addition, PLA and SCG at various contents (0, 3, 5, 10, and 15 wt%) were dried and premixed, then processed into PLA/SCG composite pellets using twin-screw extrusion. These pellets were successfully converted into filaments and subsequently used for 3D printing. The effect of spent coffee grounds in PLA composites was investigated via physical and mechanical analysis of 3D printed samples. Regarding density measurements, results revealed that adding up to 5 wt% of spent coffee grounds increased the density while further additions led to a decrease which due to the printing parameters such as extrusion temperature and nozzle diameter. Considering the mechanical properties, the Young’s modulus increased once the spent coffee grounds content reached 3 wt% and then decreased. In the other hand, there was no enhancement in tensile strength and elongation at break which corroborating with density measurements. This mainly contributed to the changes in mechanical properties caused by printing parameters. This study demonstrates that coffee waste can be used as a filler in environmentally friendly composites for 3D printing, with a maximum SCG content of 15 wt%. This approach not only promotes the reuse of coffee waste but also reduces the cost of traditional PLA filaments.

High‐Performance Supercapacitor Electrodes Based on Porosity‐Controllable Carbon Paper by Centrifugal Spinning

Carbon paper is widely utilized in supercapacitors primarily for its notable attributes, including high specific surface area, commendable electrical conductivity, and excellent chemical stability. Then investigate the effect of carbon paper with different porosities as supercapacitor substrates on the electrochemical performance of electrodes. Meanwhile, tungsten oxide is grown on the surface of carbon paper using the hydrothermal method to test the electrochemical performance of the composite electrode. The prepared carbon paper and oxygen‐deficient tungsten oxide (WOx) composite electrode (CP@WOx) exhibit an area‐specific capacitance of 915.8 mF/cm² at a current density of 5 mA/cm². In addition, the electrode exhibits good cycling stability. After 20,000 cycles, the capacitance remains 104.1% of the original capacity at 50 mA/cm² current density. Solid‐state symmetric supercapacitors assembled using CP@WOx electrode exhibit excellent performance in terms of surface energy density of 6.25 µWh/cm2(at a power density of 0.6 mW/cm2) and maintain 100.4% of their original capacity after 7000 charge/discharge cycles. Relying on the higher productivity advantage of centrifugal spinning technology over electrostatic spinning technology and other preparation processes, this study develops a new way of thinking for the large‐scale production of composite electrode materials, which has more considerable potential for large‐scale development.

Modification of polyurethane latexes of the Aquapol® brand with polymer-polymer complexes for the production of fibrous-porous polymer composite materials

Modification of polyurethane latexes of the Aquapol® brand with polymer-polymer complexes for the production of fibrous-porous polymer composite materials

Microstructure and Selected Properties of Al2O3 Matrix Composites Fabricated by Pulse Plasma Sintering of Al2O3 and Pre-composite Powder (NiAl–Al2O3)

Paper-related production of composite materials from Al2O3-pre-composite powder (NiAl–10 wt pct Al2O3). PPS allowed for forming ceramic–intermetallic composites. MA produced the pre-composite powder. Six series of composites were made, differing in temperature (1200 °C, 1300 °C, 1400 °C) and content of pre-composite powder (2.5 and 5 wt pct with respect to the amount of Al2O3). Highest hardness was obtained for composite series sintered at 1300 °C. Both series, with various pre-composite powder content, had a value of 20.8 to 20.9 GPa. Samples containing 2.5 wt pct pre-composite powder sintered at 1200 °C were highest KIC value of 4.72 ± 0.34 MPa·m0.5. Interestingly, the same value was obtained in composites containing 5 wt pct pre-composite powder sintered at 1300 °C. For both series with different pre-composite powder content, sintering at 1400 °C obtained the highest strength. For composites containing 2.5 wt pct pre-composite powder, splitting tensile strength value was 255.98 MPa, while for samples with 5 wt pct, pre-composite powder was 264.01 MPaGraphical

3D Printing of Wood Composites: State of the Art and Opportunities

With the production of wood waste constantly on the increase, questions relating to its recycling and reuse are becoming unavoidable. The reuse of wood and its derivatives can be achieved through the production of composite materials, using wood as a reinforcement or even as the main matrix of the material. Additive manufacturing (also known as 3D printing) is an emerging and very promising process, particularly with the use of bio-based and renewable materials such as wood or its industrial derivatives. The aim of this paper is to present an overview of additive manufacturing processes using wood as a raw material and including industrial solutions. After presenting wood and its waste products, all the additive manufacturing processes using wood or its industrial derivatives will be presented. Finally, for each 3D printing process, this review will consider the current state of research, the industrial solutions that may exist, as well as the main challenges and issues that still need to be overcome.

Analysis of technologies of disposal and use fibrous paper skopje

The article examines the current state and trends in the development of waste management technologies in the pulp and paper industry, with the aim of analyzing the reasons that hinder, and sometimes make impossible, the effective utilization of fibrous waste paper to obtain environmentally safe materials and raw products. The production of paper products is one of the most capital-intensive and energy-intensive industries, second only to the metallurgical and chemical industries, with a correspondingly large amount of waste and a negative impact on the environment. The technological processes of scum formation as a result of waste paper recycling and paper production wastewater treatment are considered and analyzed. Skopje is the final waste of the pulp and paper industry, which is formed at various stages of the paper and cardboard manufacturing process, therefore it is deposited in landfills. Multiton volumes of skopje require significant areas for its storage. Despite the low IV hazard class, this leads to serious environmental problems, as the leachate from the skopje landfill pollutes surface and ground water. Technologies of possible disposal and reuse of skopje, known in domestic and foreign literature, are described and analyzed. The technology of reusing scoop is determined by its relatively environmentally safe physicochemical composition. The indicated fibrous, mineral, extractive constituents and lignin determine the possibility of reusing skopje, mainly for the construction industry. The perspective of the complex use of multi-tonnage waste – slag, sludge, ash and slag of thermal power plants as plasticizers, fillers, binders and binding components in the production of building structural and heat-insulating materials is named. Technologies for using scapula as a filler in the production of building materials require a high content of inorganic compounds and a minimum amount of organic compounds. A high content of fibrous particles and a low content of mineral substances is necessary when using scapula in the production of composite wood composite materials. The specified technological limitations ensure only small amounts of skopje use in the production of building materials. The effectiveness of using skopje as an additive to the asphalt mixture for road construction and production of fuel materials is determined by the economic costs of transportation and dewatering. It is noted that the high humidity, ash content and low calorific value of scum are the main reason for the lack of effective technologies for its utilization. The solution to the problem is the use of low-energy technologies through the direct use of osprey as a component of the soil mixture for biological reclamation of man-made landscapes. The article substantiates an environmentally safe and socially favourable option for using a soil substrate based on osprey. It is emphasised that the humidity and organic viscosity of the plant origin of osprey form the agrotechnical properties of soil substrates of prolonged action, which ensure optimal technological efficiency of phytomelioration of degraded lands. The reclaimed areas will reduce greenhouse gas emissions from the soil, prevent wind and water erosion, and ensure the environmental safety of natural and man-made ecosystems.

Impregnation of Graphite with Aluminum under High Pressure

To impregnate graphite of the GMZ brand with liquid aluminum alloy D16, a high-pressure method and apparatus previously used for impregnating carbon frames with liquid coal pitch in the isostatic technology for the production of carbon-carbon composite materials were used. The graphite blank and the amount of aluminum alloy calculated from the initial porosity of graphite were placed in a thin-walled container, degassed in a vacuum furnace, after which the container with the contents was sealed. Thermobaric treatment was carried out at a temperature of 750°C and pressure of 100 and 200 MPa. After finishing the treatment, the density and porosity of the obtained metallographic composites, as well as their compressive strength, were determined. As a result of these thermobaric treatments, the density and compressive strength of the obtained composites increased significantly, and the porosity decreased markedly.

Ways to decarbonize the construction industry as a modern challenge for obtaining low-carbon building materials

The analysis of modern approaches and ideas for the production of new building composite materials with a low carbon footprint, including those obtained using recycled materials from man-made waste, is presented. It is concluded that the reduction of carbon dioxide emissions in the production of low-carbon concretes occurs as a result of replacing part of the cement with other types of binders or special fillers that ensure the preservation or improvement of the basic parameters of the structure of the building material, or due to technologies that reduce the clinker fraction of the binder while maintaining the specified properties of concrete. The leaders in the world practice in the field of low-carbon materials science are noted. The relevance of the development of the topic of environmental safety and sustainable development is indicated.

Study of technological aspects of manufacture of polymer composite material by centrifugal fiber forming method

The object of the study is the technological aspects of manufacturing the hesperidin polymer composite material by the method of centrifugal fiber formation. This method is considered the basis of a relatively new and cost-effective way of producing solid dispersion systems. Using the centrifugal molding method, it is possible to obtain highly soluble forms of active pharmaceutical ingredients in the form of fibers of various sizes using a wide range of polymeric materials with high speed and low cost due to simple equipment. Due to the innovative design of the centrifugal fiber formation method, it was chosen for the development of solid dispersion systems of the bioflavonoid hesperidin, which has a wide range of different pharmacological properties, but low bioavailability. Solid dispersed systems of hesperidin by the method of centrifugal fiber formation were produced on the basis of a pharmaceutically acceptable polymeric carrier of polyvinylpyrrolidone and mannitol. For the obtained solid dispersed systems, such basic pharmaco-technological characteristics as loss in mass during drying, bulk volume, bulk volume after shrinkage, bulk density, bulk density after shrinkage, compressibility index, Gaussner coefficient were determined. Comprehensive tests of the stability of the studied samples of the solid dispersion system of hesperidin were carried out under the conditions of accelerated tests for 6 months. According to the obtained results, it was established that the developed polymer composite material is stable in the studied conditions, and its conditional shelf life is 2 years. A technological scheme for the production of the hesperidin polymer composite material in the form of solid dispersed systems by the method of centrifugal fiber formation has been developed. In particular, the technological process is described step by step and the critical indicators of quality control of the obtained composite material are determined. The proposed technology can be implemented in modern chemical and pharmaceutical industries. This will contribute to the expansion of the market of highly effective socially oriented medicines.

INVESTIGATION OF THE MECHANICAL AND TRIBOLOGICAL BEHAVIOURS OF CUPOLA SLAG AND MWCNT-REINFORCED EPOXY HYBRID NANOCOMPOSITES: A SUSTAINABLE APPROACH FOR ENVIRONMENTAL PRESERVATION

This experimental investigation explores the mechanical and tribological characteristics of cupola slag (CS) and multiwall carbon nanotubes (MWCNTs) reinforced hybrid nanofiller epoxy composites. Cupola slag is an industrial by-product that is generated during the melting of cast iron. The disposal of slag residues in landfills results in environmental pollution. In the context of environmental preserving as well developing new engineering composites material from waste to resource. MWCNTs possess an excellent strength-to-weight ratio, high stiffness, and thermal properties. The mechanical and tribological characteristics of the hybrid nanocomposites comprising epoxy were examined by varying the weight fraction of fillers composed of CS and MWCNTs. The experimental results indicated that the ECSM3 hybrid nanocomposites have superior tensile strength and the flexural modulus improved by 92 % and 78 % respectively when compared with epoxy. Similarly, the tribology performance of the ECSM3 exhibited improved specific wear resistance of 97 %, 106 % and 88 % on the dry-sliding loads of 10 N, 20 N and 30N, respectively. A morphological analysis was carried out on fractured and worn surfaces of the specimen to understand the homogeneous dispersion and matrix-interlocking mechanism between the hybrid nanofillers and the epoxy matrix. The integration of CS alongside MWCNTs for the fabrication of epoxy hybrid nanocomposites represents a stride towards sustainable and eco-friendly technology in the production of multifunctional composite materials for diverse engineering applications.

Cotton-quality fibers from complexation between anionic and cationic cellulose nanoparticles

Natural polymers are attractive sustainable materials for production of fibers and composite materials. Cotton and flux are traditional plants used to produce textiles with comforting properties while technologies like Viscose, Lyocell and Ioncell-F allowed to extent fiber use into regenerated cellulose from wood. Neither natural nor man-made fibers completely satisfy the needs for cellulose based fabrics boosting development of new approaches to bring more sustainability into the fashion. Technologies like Spinnova are arising based on the spinning of mechanically pretreated cellulose materials with a lower environmental impact though challenged by the fiber quality and strength related to the inconsistency of the mechanical fibers. Nanoscaled cellulose is an excellent solution to improve the consistency of spin fibers, but charges introduced by traditional chemical treatments prevent rebuilding native hydrogen bonding and compromise the mechanical properties especially in wet conditions. We used nanocellulose with low surface charge isolated using reactive eutectic media to spin fibers able to restore the native hydrogen bonding and enable constitutional mechanical strength of cellulose. We performed un-optimized spinning to reveal the intrinsic properties of the fibers and confirmed the preserved strength of wet fibers compliant with the low surface charge enabling further engineering towards cotton-like fabric from wood.

Chemical Modification of Wood Waste for the Production of Composite Materials as a Prospective Solution to the Recycling Issue

The issue of increasing the physical and mechanical properties of composites by modifying the wood is considered. To improve the quality and increase the resistance of wood filler to various influences, the acetylation has been proposed, which is carried out aiming to introduce the acetyl groups into the composition of wood by replacing free hydroxyl radicals. The effectiveness of acetylation as a method of modifying wood filler in the production of composite materials in order to improve their physical and mechanical properties (dimensional stability, hydrophobicity and biostability) has been experimentally confirmed.

Assessing Intra-Bundle Impregnation in Partially Impregnated Glass Fiber-Reinforced Polypropylene Composites Using a 2D Extended-Field and Multimodal Imaging Approach.

This study evaluates multimodal imaging for characterizing microstructures in partially impregnated thermoplastic matrix composites made of woven glass fiber and polypropylene. The research quantifies the impregnation degree of fiber bundles within composite plates manufactured through a simplified compression resin transfer molding process. For comparison, a reference plate was produced using compression molding of film stacks. An original surface polishing procedure was introduced to minimize surface defects while polishing partially impregnated samples. Extended-field 2D imaging techniques, including polarized light, fluorescence, and scanning electron microscopies, were used to generate images of the same microstructure at fiber-scale resolutions throughout the plate. Post-processing workflows at the macro-scale involved stitching, rigid registration, and pixel classification of FM and SEM images. Meso-scale workflows focused on 0°-oriented fiber bundles extracted from extended-field images to conduct quantitative analyses of glass fiber and porosity area fractions. A one-way ANOVA analysis confirmed the reliability of the statistical data within the 95% confidence interval. Porosity quantification based on the conducted multimodal approach indicated the sensitivity of the impregnation degree according to the layer distance from the pool of melted polypropylene in the context of simplified-CRTM. The findings underscore the potential of multimodal imaging for quantitative analysis in composite material production.

Production of sustainable polyester composite building material using industrial waste plastic core, hemp fabric, and shrimp shell powder: Effect of quasi-isotropic fiber stacking and particle loading

Production of sustainable polyester composite building material using industrial waste plastic core, hemp fabric, and shrimp shell powder: Effect of quasi-isotropic fiber stacking and particle loading

Study the application of polydopamine preparation technology in the interface modification of phthalonitrile composite

Polydopamine (PDA), recognized for its exceptional adhesion and high-temperature resistance, serves as an effective sizing agent in demanding composite material production. This study explores the application of PDA as an interface adhesive for carbon fiber-reinforced high-temperature phthalonitrile (PN) composites (CFRPN), assessing the effects of two PDA synthesis methods—electrochemical and solution oxidation—on interfacial modification. The electrochemical method uniformly fills grooves on CF surfaces, creating an optimal interface layer, yet it encounters challenges in bulk, multi-layer fiber processing. Conversely, the solution oxidation method, despite less uniform PDA distribution, exhibits greater consistency in batch processing and significantly enhances the interlaminar shear strength of CFRPN, outperforming the electrochemical method in mechanical enhancements. Given its simplicity and reduced equipment requirements, the solution oxidation method offers considerable potential for broader engineering applications.

A fast and efficient pseudo-direct identification method for orthotropic elastic properties of multi-layered composite plates

New types of laminated composites are continuously being developed to meet various requirements involved in engineering applications. Before mass production of these new composite materials can take place, it is necessary to identify their elastic properties. Although current identification methods based on vibration tests and optimization algorithms are highly accurate, their high computation cost is a drawback. To address this issue, this paper proposes a new method to identify orthotropic elastic properties of multi-layered composite plates. The proposed method is based on the Modal Stability Procedure, using the experimental vibration frequencies and corresponding numerical mode shapes of structures. It converges after only two or three iterations without requiring an optimization algorithm. Therefore, the computational cost of the proposed method is significantly lower than that of optimization-based methods. The effectiveness and robustness of this method are demonstrated through three examples with different material, stacking sequences, and geometries including curved plate.

Chemical Modification of Nanocrystalline Cellulose for Manufacturing of Osteoconductive Composite Materials.

Cellulose is one of the main renewable polymers whose properties are very attractive in many fields, including biomedical applications. The modification of nanocrystalline cellulose (NCC) opens up the possibility of creating nanomaterials with properties of interest as well as combining them with other biomedical polymers. In this work, we proposed the covalent modification of NCC with amphiphilic polyanions such as modified heparin (Hep) and poly(αL-glutamic acid) (PGlu). The modification of NCC should overcome two drawbacks in the production of composite materials based on poly(ε-caprolactone) (PCL), namely, (1) to improve the distribution of modified NCC in the PCL matrix, and (2) to provide the composite material with osteoconductive properties. The obtained specimens of modified NCC were characterized by Fourier-transform infrared spectroscopy and solid-state 13C nuclear magnetic resonance spectroscopy, dynamic and electrophoretic light scattering, as well as thermogravimetric analysis. The morphology of PCL-based composites containing neat or modified NCC as filler was studied by optical and scanning electron microscopy. The mechanical properties of the obtained composites were examined in tensile tests. The homogeneity of filler distribution as well as the mechanical properties of the composites depended on the method of NCC modification and the amount of attached polyanion. In vitro biological evaluation showed improved adhesion of human fetal mesenchymal stem cells (FetMSCs) and human osteoblast-like cells (MG-63 osteosarcoma cell line) to PCL-based composites filled with NCC bearing Hep or PGlu derivatives compared to pure PCL. Furthermore, these composites demonstrated the osteoconductive properties in the experiment on the osteogenic differentiation of FetMSCs.

Шыны қалдықтарына негізделген тұтқыр материалдарды алу технологиясын зерттеу

The undeniable advantage of the technology of production of binders on the basis of vitrified glass is its low energy consumption. This is explained by the absence of technological processes, the realisation of which involves high temperature, pressure, etc. Often raw materials, which are production waste, do not require additional preparation, and are subjected only to cleaning and co-milling. However, despite the simplicity of the technology of production of binder on the basis of broken glass, there are a number of reasons preventing its implementation, primarily the lack of sufficient information on the technological features of glass-alkaline systems of glass hardening. The aim of this work: optimisation of the technology of production of composite materials based on glass-alkaline binders under conditions of normal temperature and humidity or at temperatures not exceeding 90°C. Scientific methods of research in the work-analysis, observation, experiment, mathematical modelling.

Production, Testing, Modeling, Characterization, and Application of Composite Material from Melting Unsorted Plastic Waste

Production, Testing, Modeling, Characterization, and Application of Composite Material from Melting Unsorted Plastic Waste