The advancement of next-generation aerospace vehicles has presented new requirements and challenges for ensuring the structural integrity of aircraft components in extreme environments. Consequently, the utilization of high temperature resistant polyamide composite materials has become pivotal in the manufacturing of aerospace vehicle parts that operate under high temperatures (250 °C). As a critical connection technology for these materials, the mechanical behavior of bolted connection structures under high temperatures requires further investigation. In this paper, a combination of experimental and numerical simulation is used to investigate the load carrying capacity and failure mechanism of T700/BMP316 composite bolted joints at room temperature and 250 °C. The experimental results show that the ultimate load carrying capacity of the structure at 250 °C is only 13.1 % lower than that of the room temperature environment, indicating that the temperature softening effect of such composites is not significant. Scanning electron microscope (SEM) and computed tomography (CT) results indicate that the structural damage modes were the crushing of the hole edge fibers and matrix due to the extrusion by the bolts, as well as the interlaminar delamination damage. Temperature effects were taken into account for the composite principal structure and finite element modeling was performed using a combination of Pinho criterion and Cohesive model. Numerical simulations allow accurate prediction of the load-displacement response and damage pattern throughout the damage evolution phase. The high temperature test results and the developed finite element model involved in this study can support the design of new-generation aerospace vehicles.