Rock Components Research Articles

Classification and Controlling Factors of Different Types of Pore Throat in Tight Sandstone Reservoirs Based on Fractal Features—A Case Study of Xujiahe Formation in Western Sichuan Depression

The effects of high debris content on pore structure in tight sandstone reservoirs tight sandstone reservoirs are multifaceted. Pore structure is an important factor controlling reservoir quality. Clarifying the effects of different types of rock debris on reservoirs is necessary to study the pore structure and their control factors of tight sandstones. The Western Sichuan Depression with complex rock components, containing multiple types of rock debris, leads to strong heterogeneity of pore throats, so it is necessary to study the factors controlling the development of different types of pore throats in tight reservoirs. In this paper, the Fourth member of Xujiahe Formation (T3x4) is taken as the research object. Based on high-pressure mercury intrusion experiments and the fractal theory, the types of pore throats and their heterogeneity in tight reservoirs were studied, the relationship of fractal dimensions with reservoir physical properties, pore structure, and rock compositions were investigated, and then the controlling factors for the development of different types of pore throats are clarified. The studies show that there are four types of pore throats developed in the T3x4 of the western Sichuan depression, including primary intergranular pore-throats (>350 nm), residual intergranular pore-throats (75–350 nm), dissolution pore-throats (16–75 nm), and intercrystalline pore-throats (<16 nm), among which the homogeneity of dissolution pore-throats are the best, followed by residual intergranular pore-throats and intercrystalline pore-throats, and the primary intergranular pore-throats the most heterogeneous. The permeability has a better relationship with the proportion and fractal dimension of primary intergranular pore-throats and residual intergranular pore-throats of tight reservoir of the Xujiahe Formation. The relation-ship between porosity and the proportion and fractal dimension of primary intergranular pore-throats and dissolution pore-throats is better. Brittle minerals such as quartz and metamorphic debris, as well as early developed films of chlorite and illite mainly control the development of intergranular pore-throats. Potassium feldspar mainly controls the development of dissolution pore-throats, while sedimentary rock debris, volcanic debris, and kaolinite play a destructive role for all types of pore-throats. The high-quality reservoirs in the T3x4 are controlled by the development of primary intergranular pore throats and dissolution pore throats, and they are mainly developed in environments with strong hydrodynamic conditions, large rock grain sizes, high content of brittle minerals such as quartz and metamorphic debris, extensive development of chlorite and illite films, and low content of sedimentary rock debris, matrix, and cemented materials. This study is of guiding significance in clarifying the causes of heterogeneity in different types of pore-throat systems in tight sandstones and the formation mechanism of high-quality reservoirs in tight sandstones with high content of debris.

Crack evolution mechanism of stratified rock mass under different strength ratios and soft layer thickness: Insights from DEM modeling

Research on stratified rock masses, which are common geological formations, has primarily focused on their mechanical properties, while studies on crack evolution and microscopic damage mechanisms remain limited. This study addresses this gap by investigating the combined effects of strength ratios and soft layer thicknesses on the microcrack evolution mechanism of stratified rocks using the discrete element method (DEM). Through FISH language programming in the particle flow code (PFC), this study reveals the acoustic emission (AE) characteristics, crack initiation and propagation, damage degree, and final failure characteristics. The key findings are: (1) Higher strength ratios between the hard and soft components of stratified rocks make specimens more sensitive to increases in soft layer thickness. (2) Three types of AE events were identified: continuous active, intermittent active, and silent. (3) Cracks initiate at the interface between components and propagate along the interface into the rock matrix. The strength ratios determine the crack propagation path and the damage extent of the components. (4) The failure of stratified rocks is primarily controlled by the soft component. Crack connections typically form vertical and sub-vertical tensile failure planes in the hard component, and a shear failure surface with a “V”-shaped intersection in the soft component.

Modified approach to estimate effective porosity using density and neutron logging data in conventional and unconventional reservoirs

Porosity is a critical petrophysical parameter that governs storage capacity in reservoirs. Despite the introduction of various techniques to assess pore structure, the complexity of rock components and the wide range of pore types have led to limitations in accurately evaluating porosity, particularly in clay-dominant reservoirs. Discrepancies and inconsistencies remain among different analytical calculation methods. Determining porosity using neutron and density logs is especially challenging in the presence of clay minerals and hydrocarbon saturation, particularly gas. Gas saturation reduces rock density, while in clay-dominant formations, neutron logs often indicate excessively high porosity due to the water content in clays. The impact of clay-bound water on rock porosity is still not fully accounted for. This study proposes a modified method for estimating porosity in both conventional and unconventional reservoirs, addressing the effect of clay-bound water on porosity calculations. The proposed method incorporates the rock's composition through its response observed in the neutron and density logs. Analytical equations are formulated to account for the influence of clay-bound water on these logs, and porosity is estimated. To validate the methodology, it was applied to two wells in organic shale reservoirs and one well in a conventional reservoir. The proposed porosity estimation method produced results that closely aligned with previously established methods, demonstrating consistency across all three wells with minimal deviations. This method offers broad applicability for exploration and exploitation in both conventional and unconventional reservoirs.

Characteristics and formation of natural fractures in a silica-rich chalk, Coniacian Arnager Limestone Formation, Bornholm, Denmark.

Natural fractures are abundant and important components in many carbonate sedimentary rocks globally. In hydrocarbon and groundwater reservoirs of carbonate rocks they can form connected networks and thereby influence the permeability and f luid flow significantly. Outcrop studies of fractured carbonate rocks can provide an essential understanding of 3-dimensional fracture networks, thereby aiding in understanding fracture patterns and connectivity in subsurface carbonate reservoirs. The Arnager Limestone Formation is a naturally fractured silica-rich chalk of Coniacian age exposed in a coastal cliff on the island of Bornholm in the Baltic Sea (Denmark). This study examines the natural fractures in the Arnager Limestone Formation from a structural and geomechanical perspective. The Arnager Limestone Formation forms one, 12–20 m thick, main rock mechanical unit; bedding planes acts as weak interfaces and divides it into near-identical, cm- to dm-thick rock mechanical subuits. Flat-lying (horizontal) or low-angle dipping bedding-parallel fractures are intersected by two near-vertical or steeply dipping fracture systems, a major N–S-trending system and a less prominent W–E-trending fracture system. Rock mechanical analysis of the tensile strength and elastic moduli provides the foundation for discussing maximum burial depth of the Arnager Limestone Formation. The tensile strength gives information on the bedding-parallel fractures, which can have formed due to stress relief during uplift and erosion, possible accentuated by glacial processes. The near-vertical fracture sets are interpreted to have formed in response to tectonic movements.

Evidence of a 4.33 billion year age for the Moon’s South Pole–Aitken basin

AbstractThe Moon’s farside South Pole–Aitken (SPA) basin is the largest and oldest visible impact basin in the inner Solar System. Determining the timing of this catastrophic event is key to understanding the onset of the lunar basin-forming epoch, with implications for understanding the impact bombardment history of the inner Solar System. Despite this, the formation age of the SPA basin remains poorly constrained. Here we show that the chemical composition of the lunar meteorite Northwest Africa 2995 is in good agreement with lithologies exposed within the southern region of the SPA basin. Radiometric dating of a range of mineral and rock components in Northwest Africa 2995 yielded consistent dates of ~4.32–4.33 billion years old. We interpret these dates as the age of SPA basin formation, inferring that this event occurred ~120 million years before the formation of the main cluster of lunar impact basins between ~4.2 Ga and 3.8 Ga. This weakens support for a narrow period of lunar late heavy impact bombardment and also implies that the earliest formed impact basins on the Moon (that is, >4.33–4.5 Ga old) were erased either by the SPA impact itself when its formation caused massive resurfacing of the lunar surface or through other geological processes.

Effect of Primary/Artificial Interface on Dynamic Failure Behavior of Combined Coal and Rock: Monitoring by High-Speed Imaging and Scanning Electron Microscopy.

The instability of the primary coal and rock structure significantly impacts the safety of coal mining and construction. The complex coal-rock interface cannot be simplified as a smooth surface. To investigate the dynamic response of primary composite coal and rock (primary-CCR), we studied the impact of load, hydrostatic pressure, and interface type on the mechanical behavior and macro/micro failure characteristics using a separate Hopkinson bar, a high-speed camera, and a scanning electron microscope. The results indicate a linear relationship between the composite strength, impact toughness, and impact velocity of the two types of composite coal and rock. The mechanical behavior of the primary-CCR initially increases and then decreases with the rise of hydrostatic pressure (turning point: 10 MPa). There is a positive correlation between artificial combined coal-rock (artificial-CCR) and hydrostatic pressure. The dissipative energy of combined coal and rock increases linearly with impact velocity. Initially, the dissipative energy per unit fracture area increases with hydrostatic pressure, then decreases as pressure continues to rise. Additionally, an increase in impact load causes the energy dissipation inflection point to shift forward. The primary interface significantly reduces the energy threshold for instability failure, resulting in a transition from energy transfer to energy dissipation in rock components. This transition manifests as the failure of artificial combined coal and rock cracks, which develop into rock fragments at an impact velocity of 14 m/s. Furthermore, the change in section roughness of coal and rock correlates with the degree of macroscopic crack growth, following the order: coal > primary-CCR > artificial-CCR > rock.

Patterns distribution, concentrations and sources of radioactive elements from black sand in the Red Sea coast, Egypt

In Egypt, the distribution of black sand in various coastal regions has been readily apparent by thorough research. Unfortunately, these investigations did not measure radioactivity in black sand, particularly in the vicinity of the Red Sea. Gamma-ray spectroscopy was used to detect the naturally occurring radioactivity from 238U, 232Th, 40K, and 226Ra in black sand samples from eight locations along the Red Sea coast: Ras Elbehar, Gemsa, Hurghada Elahiaa, Hurghada Titanic, Safaga, Qusier Elsharm Alqbly, Gabal Alrosass, and Marsa Alam. The resultant data were interpolated to represent the spatial distribution. Additionally, the potential rocks sources of radionuclides were geologically mapped to elucidate the relationship between rock components and radioactivity. The results showed that 226Ra, 232Th and238U were higher at samples collected from Ras Elbehar, Hurghada Elahiaa and Hurghada Titanic compared to the other sites. On the other hand, 40K showed the lowest mean value (75.3 ± 3.8 Bq/kg) in Hurghada Titanic samples, while it peaked (563 ± 28 Bq/kg) in Qusier Elsharm Alqbly samples. The interpolated results show notable differences in radioactive amounts between the north and south, which are indicative of several environmental conditions and human activities. Alkaline syenite, syenogranite, older granites (tonalite and granodiorite), and minor acidic volcanic/metavolcanic rocks make up the upstream area of the basin area draining into, for example, the Ras Elbehar locality (highest activity concentrations for 238U (1596 ± 80 Bq/kg) and 226Ra (886 ± 44 Bq/kg)), while alkali-feldspar granite, schist, and shale rocks make up the mid-stream area. The findings provide a basis for scientific forecasting on the impact of synthetic or naturally occurring radioactive isotopes introduced into aquatic environments.

Titanite from the NYF-type pegmatites of Szklarska Poręba Huta quarry, Karkonosze granite massif, SW Poland

Titanite, an accessory mineral of pegmatite related to aplogranite, was identified in the Szklarska Poręba Huta quarry within the Karkonosze granite massif in Lower Silesia, Poland. It formed during pegmatitic to hydrothermal stages. Besides the isovalent substitution Sn → Ti, the chemical composition of the mineral is characterized by three coupled substitutions: (1) (Al, Fe, Sc)3+ + (OH, F)- → YTi + ZO, (2) XREE3+ + Y(Al, Fe, Sc)3+ →X)Ca2+ + YTi4+, and (3) (Al, Fe, Sc)3+ + (Nb, Ta)5+ → 2YTi. These substitutions are strongly dependent on the composition of the magma in terms of its Al2O3/TiO2 activity ratio, with the first one also influenced by the H2O/HF fugacity ratio. Fluorine, which induced the most common substitution (1), had its source in high-temperature F-bearing fluids released from rocks of the metamorphic envelope adjacent to the intruding granite. These fluids mobilized and transported various rock components (Sc, REE, Nb, Ta, etc.) among others in the form of fluoride complexes, enriching the aplogranite magma with some metallic elements. The substitution of Sn for Ti developed with decreasing temperature to the extent that in thin ore-mineralized quartz veins cutting aplogranite, titanite reaches Sn-bearing compositions up to the prevalence of Sn corresponding to malayaite.

Multiscale simulation of water/oil displacement with dissolved CO[formula omitted]: Implications for geological carbon storage and CO[formula omitted]-enhanced oil recovery

This study combines molecular and pore-scale simulations to enhance our understanding of water, carbon dioxide (CO2), and oil flow in a porous system for high-efficiency geological carbon storage and enhanced oil recovery. We use molecular dynamics simulations to study the variation of interfacial tension (IFT), viscosity, and contact angle across varying system CO2 concentrations. The study reveals that the IFT simulation accuracy in the three-component mixture system relates positively to the volume-to-interfacial area ratio, and IFT decreases with CO2 concentration. Oil–CO2 mixture viscosity decreases and shows an intersection with water viscosity as CO2 concentration increases. The contact angle on the hydrophobic surface of kaolinite first increases and then decreases with CO2 concentration, while the hydrophilic surface contact angle is not sensitive to the CO2 concentration. Visualizing CO2 density distribution reveals its accumulation at fluid–fluid and fluid–solid interfaces and the combined effect results in the highest CO2 density at contact-line regions. Meanwhile, the elevated CO2 density at fluid–fluid interfaces reduces IFT, contributing to the initial contact angle increase, while the CO2 density increase at fluids–solid surface explains the subsequent contact angle decrease. These findings are then upscaled into a core-scale system using lattice Boltzmann simulations. The results are summarized into a phase diagram, which reveals the non-monotonic variations of the initial–residual (I–R) curves across different CO2 concentrations, and the residual saturation overall decreases with CO2 concentration for high initial saturations. These findings underscore the critical roles of system CO2 concentration and rock components, particularly kaolinite clay minerals, in subsurface multiphase seepage confronted in geological carbon storage and CO2-enhanced oil recovery, highlighting the importance of digital rock physical chemistry.

Characterization of radon gas transmission rate in pore structures of different rock layers by radon daughters inversion calculation

Determining the transmission rate of radon gas in overburden strata is crucial for conducting a comprehensive study of radon gas's longitudinal and long-distance migration mechanisms. This study investigates the mineral components of rocks in the underground strata of the mining area using the X-ray diffraction method. Additionally, it examines the pore structure parameters of the rocks at different depths using the low-temperature nitrogen adsorption method. This research introduces an approach to inversion calculate the radon gas transmission rate through the activity ratio of radon's characteristic daughters based on the decay law and activity balance of 210Po and 210Pb daughters. In addition, it determines the transmission rates of radon gas in overlying strata at various depths through this method. The relationship between the rock's mineral composition and pore structure is investigated, and the effects of pore structure and mineral composition on the radon gas transmission rate are analyzed. The findings indicated that the pore structure exerts a dual impact on radon gas transport: macropores serve as channels for upward radon gas transport, while micropores offer most of the adsorption area. In contrast, the radon gas transmission rate is indirectly influenced by the mineral composition content associated with the medium's adsorption capacity and pore structure. In the studied lithologies, an increase in quartz content promotes radon gas transmission, while an increase in clay mineral content impedes it. Finally, the mechanisms of radon gas transport, daughter adsorption, and the impacts of rock pore structure and mineral composition on the radon transmission rate are discussed.

Review on CO2–Brine Interaction in Oil and Gas Reservoirs

Carbon neutrality has become a global common goal. CCUS, as one of the technologies to achieve carbon neutrality, has received widespread attention from academia and industry. After CO2 enters the formation, under the conditions of formation temperature and pressure, supercritical CO2, formation water, and rock components interact, which directly affects the oil and gas recovery and carbon sequestration efficiency. In this paper, the recent progress on CO2 water–rock interaction was reviewed from three aspects, including (i) the investigation methods of CO2 water–rock interaction; (ii) the variable changes of key minerals, pore structure, and physical properties; and (iii) the nomination of suitable reservoirs for CO2 geological sequestration. The review obtains the following three understandings: (1) Physical simulation and cross-time scale numerical simulation based on formation temperature and pressure conditions are important research methods for CO2 water–rock interaction. High-precision mineral-pore in situ comparison and physical property evolution evaluation are important development directions. (2) Sensitive minerals in CO2 water–rock interaction mainly include dolomite, calcite, anhydrite, feldspar, kaolinite, and chlorite. Due to the differences in simulated formation conditions or geological backgrounds, these minerals generally show the pattern of dissolution or precipitation or dissolution before precipitation. This differential evolution leads to complex changes in pore structure and physical properties. (3) To select the suitable reservoir for sequestration, it is necessary to confirm the sequestration potential of the reservoir and the later sequestration capacity, and then select the appropriate layer and well location to start CO2 injection. At the same time, these processes can be optimized by CO2 water–rock interaction research. This review aims to provide scientific guidance and technical support for shale oil recovery and carbon sequestration by introducing the mechanism of CO2 water–rock interaction, expounding the changes of key minerals, pore structure, and physical properties, and summarizing the sequestration scheme.

Features of ore-forming magma and fluid revealed by apatite and zircon geochemistry: A case study from the Huanggang skarn Fe-Sn deposit, NE China

The large-scale Huanggang Skarn Fe-Sn deposit is located in the southern part of the Great Xing’an Range (SGXR), NE China. The causative granitic rocks in the Huanggang ore district are characterized by consistently high SiO2 contents, low EuN/EuN* (0.02–0.24) and Sr/Y (0.2–1.9). The pre-ore granite porphyry and syn-ore syenogranite have been dated through zircon and monazite U-Pb dating at 144.6 ± 1.4 Ma and 138.6 ± 1.3 to 135.9 ± 0.8 Ma, respectively. The U-Pb dating of garnet from ore-associated skarn reveals that the mineralization was happened at 136.5 ± 1.3 Ma, which is consistent with the emplacement age of the ore-related syenogranite.Zircon geochemistry shows that the pre-ore granite porphyry has relatively low oxygen fugacity (average zircon Ce4+/Ce3+ = 14.74), whereas the syn-ore syenogranite is more oxidized (average zircon Ce4+/Ce3+ = 178.9). We suggest that the elevation of oxygen fugacity was most likely caused by degassing. The textural features indicate that apatite crystals from the pre-ore granite porphyry are magmatic in origin. In contrast, textural and chemical characteristics of apatite grains from syn-ore syenogranite reveal that they have been modified by hydrothermal fluids in different degrees. The apatite in both pre- and syn-ore granites display relatively high F and low Cl contents, and very low SO3 concentrations (i.e., <0.032 wt%), indicate extremely low content of S in the causative magma. Apatite from syn-ore syenogranite display more strong and variable enrichment of LREE relative to HREE compared to those from pre-ore granite porphyry. The extensive present of new REE mineral inclusions (monazite and xenotime) in the altered apatite suggests that the concentrations of Ca and Na must be low in the ore-forming fluid. Apatite from syn-ore syenogranite have higher concentrations of Mo, W, Zn, Sn, and Be than those from pre-ore granite porphyry.Combined with zircon and apatite geochemistry, and whole rock components of the ore-related granites in the Huanggang deposit, we propose that the ore-forming magma has undergone long-term evolution under relatively reduced conditions with extensive fractional crystallization of plagioclase. The reduced and S-poor evolved magma could have promoted the enrichment of Sn and prevented Fe from precipitating as sulfide. This study also reveals that the compositional characteristics of ore-forming fluid, such as the enrichment of ore-forming materials, could be revealed by altered apatite geochemistry.

Modulation of the Nogo signaling pathway to overcome amyloid-β-mediated neurite inhibition in human pluripotent stem cell-derived neurites.

JOURNAL/nrgr/04.03/01300535-202509000-00026/figure1/v/2024-11-05T132919Z/r/image-tiff Neuronal cell death and the loss of connectivity are two of the primary pathological mechanisms underlying Alzheimer's disease. The accumulation of amyloid-β peptides, a key hallmark of Alzheimer's disease, is believed to induce neuritic abnormalities, including reduced growth, extension, and abnormal growth cone morphology, all of which contribute to decreased connectivity. However, the precise cellular and molecular mechanisms governing this response remain unknown. In this study, we used an innovative approach to demonstrate the effect of amyloid-β on neurite dynamics in both two-dimensional and three-dimensional culture systems, in order to provide more physiologically relevant culture geometry. We utilized various methodologies, including the addition of exogenous amyloid-β peptides to the culture medium, growth substrate coating, and the utilization of human-induced pluripotent stem cell technology, to investigate the effect of endogenous amyloid-β secretion on neurite outgrowth, thus paving the way for potential future applications in personalized medicine. Additionally, we also explore the involvement of the Nogo signaling cascade in amyloid-β-induced neurite inhibition. We demonstrate that inhibition of downstream ROCK and RhoA components of the Nogo signaling pathway, achieved through modulation with Y-27632 (a ROCK inhibitor) and Ibuprofen (a Rho A inhibitor), respectively, can restore and even enhance neuronal connectivity in the presence of amyloid-β. In summary, this study not only presents a novel culture approach that offers insights into the biological process of neurite growth and inhibition, but also proposes a specific mechanism for reduced neural connectivity in the presence of amyloid-β peptides, along with potential intervention points to restore neurite growth. Thereby, we aim to establish a culture system that has the potential to serve as an assay for measuring preclinical, predictive outcomes of drugs and their ability to promote neurite outgrowth, both generally and in a patient-specific manner.

Characteristics and correlations of rock components, structure, and physical properties of deep clastic reservoirs in the LD-X area of Yinggehai basin, western South China Sea

Deep clastic rocks in the LD area of the western South China Sea have undergone complex and historical processes of burial, thermal evolution, and diagenesis. As important factors affecting the porosity and permeability, rock components and structures can exhibit pronounced differences with complex lithologies in the vertical direction. In this study, we used a comprehensive method to analyze the lithological characteristics through thin-section observation, scanning electron microscopy imaging, cathodoluminescence, back-scattered electron imaging (on microprobe)), X-ray diffraction patterns of clays, grain size measurement, porosity–permeability analyses, and special imaging logging. The clastic rocks in the study area are dominated by quartz, feldspar, and debris, with the main lithology being subfeldspathic sandstone. The fillings are dominated by carbonate cement, and the clays are mostly illite. The sandstone is mostly grain-supported, moderately rounded, and fine-to medium-grained with poor-medium sorting. Porosity values are mostly in the range of 5–15%, whereas permeability values are in the range of 0.05–10.00 mD. Porosity and permeability are positively correlated with the quartz and feldspar contents and grain size and negatively correlated with the rock debris and carbonate cementing materials and sorting coefficient. These different correlations indicate that the rock components are closely related to the physical properties of the reservoirs. Sandstones with better physical properties generally have higher compositional and structural maturities. On this basis, a conceptual model of the evolution of rock components, structure and physical properties in the LD area is developed. It is verified by the logging profile that rock grouping can reflect both the good and bad physical properties, while simultaneously indicating the development patterns of high-quality reservoirs in the study area.

In-situ mapping of monocrystalline regions on Mars

Elemental quantification instruments for planetary missions provide a capability for in-situ identification of mineral phases via stoichiometry, an essential step in petrological investigations. X-ray fluorescence (XRF) has been employed for this purpose by multiple generations of Mars rovers (i.e., Pathfinder, Spirit and Opportunity, Curiosity and Perseverance). The Planetary Instrument for X-ray Lithochemistry (PIXL) aboard Perseverance rasters a micro-focused X-ray beam to generate micron-mm-sized maps illustrating variations in elemental composition and allowing mission scientists to identify rock components (i.e., sedimentary grains, veins and igneous crystals). Energy-dispersive X-ray diffraction can also be detected with PIXL and can be used as an additional constraint on component boundaries, providing PIXL with the capability to map monocrystalline regions in-situ. Here we introduce and apply a new method where each diffraction peak is partitioned independently according to its energy, using the instrument geometry to inform consistent partitioning. Applying this method to datasets acquired from the Dourbes abrasion patch in the Séítah formation of Jezero crater, Mars, reveals monocrystalline regions that were hidden using previous methods. This application of the technique allows faster and more accurate visualization of petrographic textures in future PIXL datasets, in particular those with rock components that are not easily separable using stoichiometry alone.

Alkali Trace Elements Observed by MarSCoDe LIBS at Zhurong Landing Site on Mars: Quantitative Analysis and Its Geological Implications

AbstractMars Surface Composition Detector (MarSCoDe) is one of the important payloads carried by the Zhurong rover, China's first Mars exploration mission Tianwen‐1. The laser‐induced breakdown spectroscopy (LIBS) instrument of MarSCoDe is mainly used to detect major and trace elements on the surface of Mars. The quantitative analysis of alkali trace elements, namely lithium (Li), strontium (Sr), and rubidium (Rb), holds significance in unraveling the geological evolution of the Zhurong landing site. This study focuses on establishing univariate calibration models using MarSCoDe LIBS spectra from 84 samples tested in the ground laboratory. The accuracy of these models, within a few parts per million (ppm), was subsequently validated through the analysis of 12 onboard MarSCoDe Calibration Targets (MCCTs). With these models, Li, Sr, and Rb concentrations in the surface targets during the initial 300 sols (Martian days) traverse were determined. These concentrations ranged from 6 to 18, 106–628, and 22–87 ppm, respectively. Our results suggest that Li, Sr, and Rb are mainly related to the igneous rock components in the rocks and soils at the Zhurong landing site. The major secondary minerals in MarSCoDe scientific targets are likely small amounts of sulfates, which appear to have formed from the acidic weathering of recent surface brine. Clay minerals are likely either absent or very sparse in the scientific targets. The surface igneous materials at the landing site likely have originated from the most recent lava flow during the Amazonian epoch.

Control of Physical Properties by the Matching between Rock Components and Pore Structure in Shale Reservoirs of the Permian Lucaogou Formation, Jimusar Sag

Control of Physical Properties by the Matching between Rock Components and Pore Structure in Shale Reservoirs of the Permian Lucaogou Formation, Jimusar Sag

Experimental Analysis of the Mechanical Properties and Failure Behavior of Deep Coalbed Methane Reservoir Rocks

A comprehensive understanding of the mechanical characteristics of deep coalbed methane reservoir rocks (DCMRR) is crucial for the safe and efficient development of deep coalbed gas resources. In this study, the microstructural and mechanical features of the coal seam roof, floor, and the coal seam itself were analyzed through laboratory experiments. The impact mechanisms of drilling fluid and fracturing fluid hydration on the mechanical properties and failure behavior of coal seam rocks were investigated. The experimental results indicate that the main minerals in coal seams are clay and amorphous substances, with kaolinite being the predominant clay mineral component in coal seam rocks. The rock of the coal seam roof and floor exhibits strong elasticity and high compressive strength, while the rock in the coal seam section shows a lower compressive capacity with pronounced plastic deformation characteristics. The content of kaolinite shows a good correlation with the mechanical properties of DCMRR. As the kaolinite content increases, the strength of DCMRR gradually decreases, and deformability enhances. After immersion in drilling fluid and slickwater, the strength of coal seam rocks significantly decreases, leading to shear fracture zones and localized strong damage features after rock compression failure. The analysis of the mechanical properties of DCMRR suggests that the horizontal well trajectory should be close to the coal seam roof, and strong sealing agents should be added to drilling fluid to reduce the risk of wellbore collapse. Enhancing the hydration of slickwater is beneficial for the formation of a more complex fracture network in deep coalbed methane reservoir.

Tritium behavior in soil and mineral rock components used for plant cultivation

Immersion, percolation and tritium release experiments in peat and vermiculite soil samples were performed to analyze their behavior in this widely used medium for plant cultivation. Samples were immersed in tritiated water for 696 h and the isotope exchange capacity evaluated. A vertical flow regime was also considered with analysis for hydraulic conductivity to understand tritium mobility and therefore its availability. Peat soil showed a high tritium retention after percolation, but vermiculite seem to suppress its retention ability. The high moisture and organic content of peat enhanced its isotope exchange capacity. The falling head method was used to numerically evaluate the saturated hydraulic conductivity and outflow flux. Calculated isotope exchange capacity was 4.95×10-2 mol-T2O/g for peat and 3.38×10-2 mol-T2O/g for vermiculite. The tritium release experiment showed significant release of tritiated carbons in peat.

Efficiently reconstructing high-quality details of 3D digital rocks with super-resolution Transformer

Accurate pore-scale modeling demands high-quality digital rock images, which should possess a broad imaging field of view (FOV) and high resolution to characterize multi-scale rock components. However, achieving both conditions simultaneously is challenging due to hardware constraints. Super-resolution techniques can mitigate this issue by reconstructing high-resolution details from low-resolution images captured with a wide FOV. To reconstruct high-quality 3D digital rocks, we propose a novel Efficient Attention Super-Resolution Transformer (EAST) model. It integrates self-attention and channel attention mechanisms and undergoes structural optimization. Evaluation demonstrates that EAST achieves superior reconstruction quality with a 1.85 × speedup while reducing parameters by 78 % over the advanced model. Additionally, to tailor to the characteristics of digital rocks and the constrained dataset, we employ a hybrid loss function along with two data augmentation techniques. Visualizations reveal that EAST can resist noise and blur interference, highlighting valuable features such as pore edges and textures. Ultimately, we introduce an approach based on self-supervised fine-tuning to enhance the model robustness. Direct flow simulation verifies that the reconstructed results closely align with high-resolution images in terms of physical accuracy. EAST reduces the relative error of the absolute permeability by 18.5 % and 33 % over the Tricubic method on two external samples.