Unitized Reversible Fuel Cells (URFCs) combines the functionality of hydrogen fuel cells and water electrolyzers into a single device, offering high energy density for energy conversion and storage. However, their commercial viability is deterred by the high precious group metal (PGM) loadings. Conventional URFCs utilize 1 mg/cm2 of Pt and 1 mg/cm2 of IrO2 in the oxygen electrode, posing economic and sustainability challenges.This study investigates the performance and durability implications of minimizing PGM loadings in oxygen electrode which utilizes a mixture of IrO2 and Pt black to facilitate oxygen evolution and oxygen reduction reaction respectively. We also examine the effect of the porous transport layer (PTL) morphology and wettability on the URFC performance and durability. Accelerated stress test (AST) protocol was developed to evaluate the performance loss across both fuel cell and water electrolyzer mode of URFC operation. Additionally, this research provides a detailed characterization of loss in active area, change in catalyst layer structural, and PTL wettability offering insights into the degradation mechanism in URFCs.This study not only establishes a foundational benchmark for understanding the URFC performance and durability at low catalyst loadings but also highlights the critical need for strategic component selection and activation methods to enhance the system's overall efficiency and durability, marking a significant step towards the realization of more sustainable energy solutions.
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