Emission Components Research Articles

Modeling of Long-term Afterglow Counterparts to Gravitational Wave Events: The Full View of GRB 170817A

The arrival of gravitational wave astronomy and a growing number of time-domain-focused observatories are set to lead to an increasing number of detections of short gamma-ray bursts (GRBs) launched with a moderate inclination to Earth. Being nearby events, these are also prime candidates for very long-term follow-up campaigns and very long-baseline interferometry, which has implications for multi-messenger modeling, data analysis, and statistical inference methods applied to these sources. Here, we present a comprehensive modeling update that directly incorporates into afterglowpy astrometric observations of the GRB position, Poissonian statistics for faint sources, and modeling of a trans-relativistic population of electrons. We use the revolutionary event GW170817 to demonstrate the impact of these extensions both for the best-fit physics parameters and model selection methods that assess the statistical significance of additional late-time emission components. By including in our analysis the latest Chandra X-ray observations of GRB 170817A, we find only weak evidence (≲2σ) for a new emission component at late times, which makes for a slightly more natural fit to the centroid evolution and prediction for the external medium density.

Evaluating the Performance of Agricultural Tractor Engine using Cottonseed Oil Biodiesel

The energy demand has been significantly increasing around the world in the last century. Conventional fossil fuels as one of the sources has been highly demanded due to its negative environmental effect. The growing demand for energy stimulated the development of renewable and eco-friendly alternative energy sources. Produced from vegetable oils and animal fats, biodiesel is a renewable, sustainable, and biodegradable fuel. It can be used as an alternate fuel to conventional diesel (CD) in compression ignition (CI) engines. The Belarus 920 tractor, with a maximum output of 74.5kW, was put through a Power Take Off (PTO) test in this study to assess its performance and emission components when fueled with conventional petroleum diesel, B20, B50, and B100 of Cotton Seed Oil Biodiesel (CSOME). The performance results showed that the power and Break Thermal Efficiency (BTE) fell, while the BSFC improved, when the tractor was fueled with neat CSOME and its mixes.

Global Freight Transport Emissions Responsibility.

The transportation of freight by land, sea and air underpins the complex network of global trade in physical commodities. Greenhouse gas emissions from freight transportation are a significant component of global emissions and are predicted to grow in coming decades. However, the inclusion of freight transport in emissions accounts and environmental impact studies is often incomplete. Both data availability and difficulties in allocating freight emissions to specific commodity trades contributes to this. In this study, international freight movements by transport mode are estimated from the bottom-up by imputing global freight transport routes. Emissions are estimated from these freight movements and integrated with a global multiregional input-output model. This enables the calculation of carbon footprints that are complete with respect to freight emissions. We estimate that global freight transport emissions contributed 2.8 Gt CO2-equiv in 2012, or about 41% of total transport emissions. In general, freight footprints contribute about 9% to national emissions footprints. While trade in physical commodities (such as construction materials, food and fossil fuels) are associated with the largest embodied freight emissions, services (such as public administration, education and health) also require significant freight transport. Using a consumption-based allocation of freight transport emissions allows the decarbonisation of other sectors to be complementary to the decarbonisation of transport through reduction in demand, for example through material efficiency strategies. To drive decarbonisation in maritime transport it is critical to include bunker emissions in national emissions inventories, thereby completing the system boundary.

Chiral Organometallic Complexes Derived from Helicenic N-Heterocyclic Carbenes (NHCs): Design, Structural Diversity, and Chiroptical and Photophysical Properties.

ConspectusRecently, helicene derivatives have emerged as an important class of molecules with potential applications spanning over asymmetric catalysis, biological activity, magnetism, spin filtering, solar cells, and polymer science. To harness their full potential, especially as emissive components in circularly polarized organic light-emitting diodes (CP-OLEDs), generating structural chemical diversity and understanding the resulting photophysical and chiroptical properties are crucial. In this Account, we shed light on chemical engineering combining helicene and N-heterocyclic carbene (NHC) chemistries to create transition-metal complexes with unique architectures and describe their photophysical and chiroptical attributes. The σ-donating and π-accepting capabilities of the helically chiral π-conjugated NHCs endow the complexes with remarkable structural and electronic features. These characteristics manifest in phenomena such as chirality induction, very long-lived phosphorescence, and strong chiroptical signatures (electronic circular dichroism and circularly polarized luminescence).We describe the different classes of ligands primarily developed in our group by classifying them according to their connection between the helicenic moiety and the imidazole precursor. This connection is essential in determining the degree of π-conjugation and characterizing the emissive state. We comprehensively discuss 6-coordinate, 4-coordinate, and 2-coordinate complexes, delving into their structural nuances and examining how the interplay between metals and auxiliary ligands shapes their photophysical properties, with interpretations enriched by DFT calculations. Helicenes are known to promote intersystem crossing thanks to strong spin-orbit coupling, while metals offer robust frameworks leading to a variety of molecular architectures with specific topologies together with distinct excited-state properties. The electronic configurations and energy levels of the ligand and metal orbitals thus significantly modulate the photophysical and chiroptical behaviors of these complexes. In-depth analysis of chiroptical properties, notably electronic circular dichroism and circularly polarized luminescence, emphasizes the influence of different stereogenic elements on the chiroptical responses across various energy ranges with appealing "match-mismatch" effects. Finally, we describe future prospects of helicene NHCs, particularly in the context of emerging research on cost-effective and abundant transition metals for materials science and for photocatalysis. Indeed, the inherent long-lived MLCT, excited-state delocalization, structural rigidity, and intrinsic chirality of these complexes present intriguing avenues for future investigations.

Decomposition of Carbon Dioxide (CO2) Emissions in Hungary

Elevated levels of global greenhouse gases (GHGs), primarily produced through fossil fuel combustion, present environmental risks such as prolonged droughts, global warming, and catastrophic floods. Despite raising awareness and international efforts to combat climate change, fossil fuel and GHGs demand persists. At this juncture, this study investigates Hungary's transportation sector, a notable CO2 emitter. Using the Kaya Identity and Log Mean Divisia Index method, this study decomposes the primary components of CO2 emissions in Hungary's transport sectors from 2001-2021. This analysis is done in two decomposition levels, annual and periodic decomposition analysis for each of the five years starting from 2001. The analysis reveals that the economic activity effect ∆CGPE is the predominant driver of CO2 emissions, while the energy intensity effect ∆CEIE improvements have substantially mitigated these increases. Population changes affect ∆CPOPE, and the carbon emission intensity effect ∆CCEIE has had minimal impacts. The study provides insights and recommendations for policy and strategic interventions to reduce emissions and promote sustainable transportation practices in Hungary.

Source Profiles of VOCs for Different Types of Industrial Boilers in Sichuan, China

Seven different types of industrial boilers in Sichuan Province were selected to determine the VOC emission components and the source profiles of VOCs containing 115 components were established using Teflon sampling and GC-MS/FID analysis. The ozone formation potential （OFP） and emission factors of VOCs from different types of industrial boilers were analyzed. The results showed that the VOC components emitted from different types of industrial boilers were different. Oxygenated volatile organic compounds （OVOCs） and halogenated hydrocarbons were the major components of biomass boilers, with a total contribution rate of more than 60%. The primary VOC emission species included dichloromethane, ethylene, acetone, acetaldehyde, acetylene, and toluene. Halogenated hydrocarbons （50.7%） were the chief emission components of coal-fired boilers, followed by aromatic hydrocarbons and OVOCs. Dichloromethane, ethylene, acetaldehyde, ethyl acetate, and benzene hydrocarbon were the major VOC emission species. The emission of alkanes （59.7%） in natural gas boilers was prominent, particularly ethane and isopentane. The OFP values of VOC emissions from coal-fired, biomass, and natural gas industrial boilers were 6.1, 28.7, and 4.7 mg·m-3, respectively. Alkenes were the primary OFP contributors （35.1%-59.5%） in different types of industrial boilers. OVOCs （32.8%） in biomass boilers and aromatic hydrocarbons （43.0%） in coal-fired boilers also contributed significantly to OFP. The VOC emission factors of coal-fired, biomass, and natural gas industrial boilers in Sichuan Province were （17.3 ± 10.7） g·t-1, （90.6 ± 42.1） g·t-1, and 0.10 g·m-3, respectively. The VOC emission level of biomass boilers was higher than that of coal-fired boilers and VOC emission control could not be ignored.

Statistical estimation of full-sky radio maps from 21cm array visibility data using Gaussian Constrained Realisations

Abstract An important application of next-generation wide-field radio interferometers is making high dynamic range maps of radio emission. Traditional deconvolution methods like CLEAN can give poor recovery of diffuse structure, prompting the development of wide-field alternatives like Direct Optimal Mapping and m-mode analysis. In this paper, we propose an alternative Bayesian method to infer the coefficients of a full-sky spherical harmonic basis for a drift-scan telescope with potentially thousands of baselines, that can precisely encode the uncertainties and correlations between the parameters used to build the recovered image. We use Gaussian Constrained Realisations (GCR) to efficiently draw samples of the spherical harmonic coefficients, despite the very large parameter space and extensive sky-regions of missing data. Each GCR solution provides a complete, statistically-consistent gap-free realisation of a full-sky map conditioned on the available data, even when the interferometer’s field of view is small. Many realisations can be generated and used for further analysis and robust propagation of statistical uncertainties. In this paper, we present the mathematical formalism of the spherical harmonic GCR-method for radio interferometers. We focus on the recovery of diffuse emission as a use case, along with validation of the method against simulations with a known diffuse emission component.

SN 2021adxl: A luminous nearby interacting supernova in an extremely low-metallicity environment

SN 2021adxl is a slowly evolving, luminous, Type IIn supernova with asymmetric emission line profiles, similar to the well-studied SN 2010jl. We present extensive optical, near-ultraviolet, and near-infrared photometry and spectroscopy covering ∼1.5 years post discovery. SN 2021adxl occurred in an unusual environment, atop a vigorously star-forming region that is offset from its host galaxy core. The appearance of Lyα and O II, as well as the compact core, would classify the host of SN 2021adxl as a “Blueberry” galaxy, analogous to higher redshift, low-metallicity, star-forming dwarf “Green Pea” galaxies. Using several abundance indicators, we find a metallicity of the explosion environment of only ∼0.1 Z⊙, the lowest reported metallicity for a Type IIn SN environment. SN 2021adxl reaches a peak magnitude of Mr ≈ −20.2 mag and since discovery, SN 2021adxl has faded by only ∼4 magnitudes in the r band with a cumulative radiated energy of ∼1.5 × 1050 erg over 18 months. SN 2021adxl shows strong signs of interaction with a complex circumstellar medium, seen by the detection of X-rays, revealed by the detection of coronal emission lines, and through multi-component hydrogen and helium profiles. In order to further understand this interaction, we model the Hα profile using a Monte Carlo electron scattering code. The blueshifted high-velocity component is consistent with emission from a radially thin spherical shell resulting in the broad emission components due to electron scattering. Using the velocity evolution of this emitting shell, we find that the SN ejecta collide with circumstellar material of at least ∼5 M⊙ assuming a steady-state mass-loss rate of ∼4 − 6 × 10−3 M⊙ yr−1 for the first ∼200 days of evolution. SN 2021adxl was last observed to be slowly declining at ∼0.01 mag d−1, and if this trend continues, SN 2021adxl will remain observable after its current solar conjunction. Continuing the observations of SN 2021adxl may reveal signatures of dust formation or an infrared excess, similar to that seen for SN 2010jl.

Prospects for a survey of the galactic plane with the Cherenkov Telescope Array

Approximately one hundred sources of very-high-energy (VHE) gamma rays are known in the Milky Way, detected with a combination of targeted observations and surveys. A survey of the entire Galactic Plane in the energy range from a few tens of GeV to a few hundred TeV has been proposed as a Key Science Project for the upcoming Cherenkov Telescope Array Observatory (CTAO). This article presents the status of the studies towards the Galactic Plane Survey (GPS). We build and make publicly available a sky model that combines data from recent observations of known gamma-ray emitters with state-of-the-art physically-driven models of synthetic populations of the three main classes of established Galactic VHE sources (pulsar wind nebulae, young and interacting supernova remnants, and compact binary systems), as well as of interstellar emission from cosmic-ray interactions in the Milky Way. We also perform an optimisation of the observation strategy (pointing pattern and scheduling) based on recent estimations of the instrument performance. We use the improved sky model and observation strategy to simulate GPS data corresponding to a total observation time of 1620 hours spread over ten years. Data are then analysed using the methods and software tools under development for real data. Under our model assumptions and for the realisation considered, we show that the GPS has the potential to increase the number of known Galactic VHE emitters by almost a factor of five. This corresponds to the detection of more than two hundred pulsar wind nebulae and a few tens of supernova remnants at average integral fluxes one order of magnitude lower than in the existing sample above 1 TeV, therefore opening the possibility to perform unprecedented population studies. The GPS also has the potential to provide new VHE detections of binary systems and pulsars, to confirm the existence of a hypothetical population of gamma-ray pulsars with an additional TeV emission component, and to detect bright sources capable of accelerating particles to PeV energies (PeVatrons). Furthermore, the GPS will constitute a pathfinder for deeper follow-up observations of these source classes. Finally, we show that we can extract from GPS data an estimate of the contribution to diffuse emission from unresolved sources, and that there are good prospects of detecting interstellar emission and statistically distinguishing different scenarios.Thus, a survey of the entire Galactic plane carried out from both hemispheres with CTAO will ensure a transformational advance in our knowledge of Galactic VHE source populations and interstellar emission.

Flare-related plasma motions in the outer atmosphere of the RS CVn-type star II Peg

Analogous to solar flares, stellar flares are dramatic explosions in the atmosphere, which may be accompanied by prominence eruptions, coronal mass ejections (CMEs), and other forms of plasma motion. Based on time-resolved spectroscopic observations of the RS CVn-type star II Peg, we aim to search for the potential plasma motions associated with flares. In these observations, we detected part of the gradual decay phase of an optical flare, for which we find a lower limit on the energy of the H$ alpha $ line of $6.03 $ erg. Converting this H$ alpha $ energy, we find a bolometric white-light energy of $3.10 $ erg. Moreover, a secondary peak is also observed. After removing a quiescence reference, the H$ alpha $ residual shows an asymmetric behavior, including both a blueshifted and a redshifted emission component. The former component has a bulk velocity of about -180 km s$^ $ and extends its velocity to more than -350 km s$^ $. This phenomenon is likely caused by a prominence eruption event or a chromospheric evaporation process. The latter emission component has a bulk velocity of 130 to 70 km s$^ $ and extends its velocity to nearly 400 km s$^ $. We attribute the redshifted emission component to one or a combination of several possible scenarios: flare-driven coronal rain, chromospheric condensation, backward-directed prominence eruption close to the stellar limb, or falling material in a prominence eruption. The minimum masses of the moving plasmas resulting in the blueshifted and redshifted emission components are estimated to be $0.56 $ g and $1.74 $ g, respectively.

High‐Efficiency Circularly Polarized Luminescence Regulation of a Dye‐Doped Polymer Film by Acid/Aggregation

AbstractSmart materials with circularly polarized luminescence (CPL) tunable ability show great potential for advanced information storage and encryption. While an effective integration of high photoluminescence quantum yield (PLQY) and facile regulation of CPL property in thin films are of great significance, it is challenging due to the scarcity of suitable materials and complexity of systems. Herein, a novel acid‐responsive CPL tunable molecule is designed by combining an aggregation‐induced emission (AIE) component (TPE), an acid‐responsive luminophore (Rhodol), and a chiral aniline. Benefitting by the “AIE” effect of TPE and acid‐sensitive nature of Rhodol, the acidified molecule (S‐Rhodol‐TPE) exhibits a high PLQY even when doped in the polymer substrate at high concentrations. In addition, due to the fluorescence resonance energy transfer (FRET) process between TPE and Rhodol, the emission color of S‐Rhodol‐TPE can be easily regulated by the doped ratio and acidified degree of S‐Rhodol‐TPE in the polymer film. This work exhibits a unique approach to achieving smart CPL‐tunable films with high PLQYs and multiple emission color‐regulation properties, which can undoubtedly facilitate the progress of CPL tunable materials.

Rational design of narrowband deep blue MR-TADF dendrimers for high performance solution-processed all fluorescence white OLEDs

Developing solution-processable deep-blue multiple resonances thermally activated delayed fluorescence (MR-TADF) is a formidable challenge. Here, we using a convergent synthesis process successfully developed a series of MR-TADF dendrimers based on C=O/N resonant core (QAO). The alkyl chain alternate-linked functional dendrons not only ensure the narrow-band deep-blue emission but also enable the dendrimers with aggregation-induced emission enhancement (AIEE) properties, which efficiently mitigate the aggregation-induced exciton quenching (ACQ) and obnoxious spectral redshift broadening effect. Notably, the solution-processed deep blue MR-TADF OLEDs achieved a maximum external quantum efficiency (EQE) of 13.5 % and CIE of (0.15, 0.12) with an electroluminescence peak below 450 nm. Further using such dendrimer as a sensitizer for white OLEDs resulted in an optimized high EQE of 18.9 % and a high color-rendering index (CIR) of 81.1 for two and three optical components of white emissions, which are among the highest values of previously reported solution-processed all-fluorescence white OLEDs. This is the first attempt to construct white OLED based on an MR-TADF emitter and the satisfactory results indicate that the flexible dendron engineering strategy can effectively develop high-performance narrow band deep-blue MR-TADF for wide-color gamut display and high CIR white OLEDs.

Research and analysis of urban-rural residential carbon emissions in China

Residential carbon emissions are an important component of anthropogenic carbon emissions. a significant increase in residential carbon emissions has become a reality under the global urbanization process. In this context, this paper built a feature combination value model based on NPP-VIIRS nighttime light remote sensing data, and divided urban-rural areas through breakpoint analysis method and reference comparison method. Then, explored the characteristics and differences of residential carbon emissions and per capita residential carbon emissions in nine different levels of cities in 2019 from the perspective of urban-rural areas. The results indicate that the residential carbon emissions and per capita residential carbon emissions shows the spatial distribution characteristics of first tier cities>second tier cities>third tier cities. Among them, the residential carbon emissions in Beijing, Guangzhou, Nanjing, Taiyuan show a distribution pattern of urban>urban-rural fringe>rural. The residential carbon emissions in Shijiazhuang, Wuxi, Xiangyang, Zunyi, Huai’an show a distribution pattern of rural>urban-rural fringe>urban. The per capita residential carbon emissions of urban areas are relatively low, while the per capita residential carbon emissions of rural areas are relatively high, show a distribution pattern of rural>urban-rural fringe >urban. The results can help the Chinese government balance the needs of urban-rural development in different levels of cities, so as to formulate targeted carbon emission reduction policies and achieve low-carbon goals.

Incorporating Sb (III) and Bi (III) ions into Cs2AgNaInCl6 perovskite toward efficient white-light emission with high color rendering index

Single phosphor with efficient and high quality white-light emission is necessary for lighting applications. In this work, we report a double perovskite, Cs2AgNaInCl6 with Bi3+ and Sb3+ incorporation, which demonstrates excellent white-light properties including tunable emission component and correlated colour temperature (CCT). Using the broad-band emission of self-trapped excitons (STEs) associated with Bi3+ and Sb3+ in the Cs2AgNaInCl6 host, the blue and orange dual-band STEs emission located at 460 and 565 nm covers the entire visible range to achieve high-quality white light emission. The relative intensity of the dual emission components can be adjusted flexibly by modulating the doping ratio of Bi3+ and Sb3+. The dual STEs emission shares the same optimal excitation wavelength at 340 nm. The optimal sample of Bi3+ (1 %) and Sb3+ (10 %) codoped Cs2Ag0.1Na0.9InCl6 exhibits high color rendering index (CRI) of up to 93, and high photo-luminescence quantum yield (PLQY) of 76 %. This codoping in double perovskite approach represents a promising method for achieving high-quality white lighting application within a single phosphor.

Behavior of the Position and Ellipticity Angles at Polarization Mode Transitions in Pulsar Radio Emission

Polarization observations of radio pulsars show that abrupt transitions in the polarization vector’s position angle can be accompanied by large excursions in the vector’s ellipticity angle, suggesting the vector passes near the right or left circular pole of the Poincaré sphere. The behavior of the angles can be explained by a transition in dominance of the orthogonal polarization modes or a vector rotation caused by a change in the phase difference between the modes. Four polarization models are examined to quantify and understand the behavior of the angles at a mode transition: coherent polarization modes, partially coherent modes, incoherent modes with nonorthogonal polarization vectors, and incoherent orthogonal modes with an elliptically polarized emission component. In all four models, the trajectory of the mode transition on the Poincaré sphere follows the geodesic that connects the orientations of the mode polarization vectors. The results from the models can be similar, indicating that the interpretation of an observed transition within the context of a particular model is not necessarily unique. The polarization fraction of the emission and the average ellipticity angle depend upon the statistical character of the mode intensity fluctuations. The polarization fraction increases as the fluctuations increase. The excursion in ellipticity angle can be large when the mode intensities are quasi-stable and is suppressed when the intensity fluctuations are large.

New phase-construction phosphors ceramics for warm-white solid-state lighting: Orange-yellow-emitting (Lu,Gd)3(Sc,Al)5O12: Ce3+

Phosphor-converted white light-emitting diodes (pc-wLEDs) and phosphor-converted white laser diodes (pc-wLDs) are extensively utilized in lighting applications, with their quality and reliability heavily dependent on color converters. Recent progress in all-inorganic color converters, particularly phosphor ceramics (PCs), have markedly enhanced performance. However, due to the difficulty of managing emissive components, achieving warm white light with substantial red emission still remains challenging. In this work, a series of pure-phase Ce3+-activated garnet-structured solid-solution PCs, (Lu,Gd)3(Sc,Al)5O12: Ce (LGSAG: Ce), were fabricated using vacuum sintering technology for the first time. Through systematic analysis, it can be revealed that the addition of Gd3+ leads to a red shift in emission through changes in crystal-field splitting, whereas the inclusion of Sc3+ primarily focuses on improving the microstructure of the developed PCs. Particularly, the pc-wLED constructed from typical LGSAG: Ce PC generated significantly warmer light with a correlated color temperature (CCT) of 2916 K, compared to the 9557 K from LuAG: Ce PC. Meanwhile, under 40.0 W (15.7 W/mm2) blue laser excitation, the maximum luminous flux and luminescence efficiency of one typical LGSAG: Ce PG are 1172 lm and 29.3 lm/W, respectively. Therefore, the developed LGSAG: Ce PCs can show notable potential as color converters for future high-power warm-white solid-state lighting applications.

Ground-reflected light: The invariance principle and the effect of luminaire height, emission pattern, and non-uniform albedo

The weighted contribution of ground-reflected component of light emissions from artificial sources gradually increases as the transitioning from bad-shielded to modernized light sources with low or zero direct uplight takes place in cities or towns. In this work, we demonstrate that the modeling of reflected light on a large domain for Lambertian flat surfaces does not require information about the height of the light sources and directional distribution of photons their produce. This kind of "invariance principle" becomes invalid when the homogeneity condition for the surface albedo is violated. However, we have shown that an analytical solution exists also for position-dependent albedo and even for angle-dependent reflectance which is the effect we now include to the light pollution models for the first time. This effect is known from the observation of sunbeams entering uneven surfaces at different zenith angles. Here in analogy with that daylight model we derive formulae for ground surfaces illuminated by artificial lights located at different heights above the surrounding terrain.

The Intrinsic Correlations between Prompt Emission and X-ray Flares of Gamma-Ray Bursts

X-ray flare (XRF) is a common phenomenon in the X-ray afterglow of gamma-ray bursts (GRBs). Although it is commonly believed that XRFs may share a common origin with prompt emission, i.e., the “internal” origin, the origin of XRFs is still unknown. In this work, we compile a GRB sample containing 31 GRBs with a single XRF, a well-measured spectrum, and a redshift, and investigate the intrinsic properties and correlations between prompt emission and the XRFs of these events. We find that the distributions of main physical parameters of prompt emission and XRFs are basically log-normal. The median value of the rise time is shorter than the decay time for all flares, with a ratio of about 1:2, which is similar to the fast rise and exponential decay structure of prompt emission pulses. We also find that the prompt emission energy (Eiso) and peak luminosity (Liso) have tight correlations with XRF energy (EX,iso) and peak luminosity (LX,p), Eiso∝EX,iso0.74 (LX,p0.62) and Liso∝EX,iso0.85 (LX,p0.68). However, the durations of prompt emissions are independent of the temporal properties of XRFs. Furthermore, we also analyze the three-parameter correlations between prompt emissions and XRFs, and find that there are tight correlations among the XRF peak time (Tp,z), LX,p, and Eiso/Liso, LX,p∝Tp,z−1.08Eiso0.84 and LX,p∝Tp,z−1.09Liso0.71. Interestingly, these results are very similar to the properties of an X-ray plateau in GRBs, which indicates that X-ray flares and plateaus may have the same physical origin, and strongly supports that the two emission components originate from the late-time activity of the central engine.

International Trade Reshapes the Decoupling of Emissions from Economic Growth.

Efforts to stabilize the global climate change while also continuing human development depend upon "decoupling" economic growth from fossil fuel CO2 emissions. However, evaluations of such decoupling have typically relied on production-based emissions, which do not account for emissions embodied in international trade. Yet international trade can greatly change emissions accounting and reshape the decoupling between emissions and economic growth. Here, we evaluate decoupling of economic growth from different accounts of emissions in each of the 159 countries and analyze the drivers of decoupling. We find that between 1995 and 2015, although 29 countries exhibited strong decoupling of territorial emissions (growing economies and decreasing emissions), only 19 countries achieved economic growth while their consumption-based emissions decreased. Most developed countries have achieved decoupling of emissions related to domestic goods and services, but have not achieved decoupling of emissions related to imported goods and services. The U-test confirms that the domestic component of consumption-based emissions exhibits a stronger decoupling trend from gross domestic product (GDP) growth than consumption-based emissions, and emissions from imports continue to rise with GDP per capita without a corresponding decline, providing a statistical validation of the decoupling analysis. Moreover, in the countries where economic growth and consumption-based emissions are most decoupled, a key driver is decreasing emissions intensity due to technological progress─and especially reductions in the intensity of imported goods and services. Our results reveal the importance of assessing decoupling using consumption-based emissions; successful decoupling may require international cooperation and coordinated mitigation efforts of trading partners.

Rapid kilonova evolution: Recombination and reverberation effects

Kilonovae (KNe) are one of the fastest types of optical transients known, cooling rapidly in the first few days following their neutron-star merger origin. We show here that KN spectral features go through rapid recombination transitions, with features due to elements in the new ionisation state emerging quickly. Due to time-delay effects of the rapidly expanding KN, a ‘wave’ of these new features passing though the ejecta should be a detectable phenomenon. In particular, isolated line features will emerge as blueshifted absorption features first, gradually evolving into P Cygni features and then pure emission features. In this analysis, we present the evolution of individual exposures of the KN AT2017gfo observed with VLT/X-shooter, which together comprise X-shooter’s first epoch spectrum (1.43 days post-merger). The spectra of these ‘sub-epochs’ show a significant evolution across the roughly one hour of observations, including a decrease in the blackbody temperature and photospheric velocity. The early cooling is even more rapid than that inferred from later photospheric epochs and suggests that a fixed power-law relation between the temperature and time does not describe the data. The cooling constrains the recombination wave, where a Sr II interpretation of the AT2017gfo ∼1 μm feature predicts both a specific timing for the feature emergence and its early spectral shape, including the very weak emission component observed at about 1.43 days. This empirically indicates a strong correspondence between the radiation temperature of the blackbody and the ejecta’s electron temperature. Furthermore, this reverberation analysis suggests that temporal modelling is important for interpreting individual spectra and that higher-cadence spectral series, especially when concentrated at specific times, can provide strong constraints on KN line identifications and the ejecta physics. Given the use of such short-timescale information, we lay out improved observing strategies for future KN monitoring.