In this paper, we contemplate addressing nonlinear problems involving complex symmetric Jacobian matrices. Firstly, we establish a parameter-free method called modified Newton–CAPRESB (MN–CAPRESB) method by harnessing the modified Newton method as the outer iteration and the CAPRESB (Chebyshev accelerated preconditioned square block) method as the inner iteration. Secondly, the local and semilocal convergence theorems of MN–CAPRESB method are proved under some conditions. Eventually, the numerical experiments of two kinds of complex nonlinear equations are presented to validate the feasibility of MN–CAPRESB method compared to other existing iteration methods.