Complex Estuarine System Research Articles

Salinity Response to Seasonal Runoff in a Complex Estuarine System (Cochin Estuary, West Coast of India)

ABSTRACT Vinita, J.; Shivaprasad, A.; Revichandran, C.; Manoj, N.T.; Muraleedharan, K.R., and Binzy, J., 2015. Salinity response to seasonal runoff in a complex estuarine system (Cochin estuary, west coast of India). The hydrographic conditions in Cochin estuary are investigated using longitudinal measurements of salinity profiles during a 1-year period. The estuary transformed from salt wedge conditions during the wet season to a partially or well-mixed state during the dry season. During high runoff months (June–September) and moderate runoff months (October–December and May), the salinity structure is a strong function of variations in river runoff, and the estuary responds coherently to episodic inputs of freshwater. However, during the period from January to April, the dependence of the salinity field on runoff was weakened by axial diffusivity. The salt transport was a balance between seaward flux induced by river runoff and tidally induced diffusive landward flux. The latter dominated in almost all...

Detection of water quality parameters in Hangzhou Bay using a portable laser fluorometer

A field, light-weight laser fluorometer based on the method of laser induced fluorescence was developed for water quality monitoring. The basic instrument configuration uses a high pulse repetition frequency microchip laser, a confocal reflective fluorescent probe and a broadband hyperspectral micro spectrometer; it weights only about 1.7kg. Simultaneous estimates of three important water quality parameters, namely, chlorophyll a (chl-a), colored dissolved organic matter (CDOM), and total suspended matter (TSM) measured by the laser fluorometer were observed to agree well with those measured by traditional methods (0.27–0.84μgL−3 chl-a, R2=0.88; 0.104–0.295m−1 CDOM absorption, R2=0.90; and 59.8–994.9mgL−3 TSM, R2=0.86) in Hangzhou Bay water. Subsequently, distribution and characteristics of CDOM and chl-a laser fluorescence in Hangzhou Bay were analyzed, which will enhance our understanding of biogeochemical processes in this complex estuarine system at high-resolution, high-frequency and long-term scale.

Molecular characterization of Pseudo-nitzschia community structure and species ecology in a hydrographically complex estuarine system (Puget Sound, Washington, USA)

Species within the toxic marine diatom genus Pseudo-nitzschia coexist in coastal and estuarine waters globally and are difficult to distinguish by microscopy. Here, we describe a sensitive, high throughput PCR-based Automated Ribosomal Intergenic Spacer Analysis (ARISA) approach to determine the relative abundance of Pseudo-nitzschia species within natural communities over space and time. The method was quantitatively validated using simplified mixtures of DNA or ITS1 standards from isolates of P. pungens, P. multiseries, and P. delicatissima. Relative abundance calculations based on ARISA profiles from these mixtures reflected input ratios, with minor deviations resulting from intraspecific variability. ARISA was used to identify and quantify at least eight species within Puget Sound and the eastern Strait of Juan de Fuca, Washington, USA: P. americana, P. australis/P. seriata, P. cuspidata, P. delicatissima, P. fraudulenta, P. fryxelliana, P. multiseries, and P. pungens; genotypes corresponding to P. pungens var. pungens and P. pungens var. cingulata were identified by environmental sequencing. The different species were significantly correlated with physical (temperature, salinity), biological (chlorophyll a fluorescence, oxygen), and/or chemical (ammonium, nutrient ratios) factors. The ability to determine shifts in the relative abundance of Pseudo-nitzschia species over spatial and temporal scales relevant to dispersion and selection facilitates dissection of the varied mechanisms driving vertical and horizontal species distribution patterns in hydrographically complex systems.

Damming deltas: A practice of the past? Towards nature-based flood defenses

There is extensive experience in adaptive management of exposed sandy coastlines through sand nourishment for coastal protection. However, in complex estuarine systems, coastlines are often shortened through damming estuaries to achieve desired safety levels. The Dutch Deltaworks illustrate that this approach disrupts natural sediment fluxes and harms ecosystem health, which negatively affects derived ecosystem services, such as freshwater availability and mussel and oyster farming. This heavily impacts local communities and thus requires additional maintenance and management efforts. Nevertheless, the discussion on coastline shortening keeps surfacing when dealing with complex coastal management issues throughout the world. Although adaptive delta management accompanied by innovative approaches that integrate coastal safety with ecosystem services is gaining popularity, it is not yet common practice to include adaptive pathways, a system-based view and ecosystem knowledge into coastal management projects. Here, we provide a first attempt to integrate ecosystem-based flood risk reduction measures in the standard suite of flood risk management solutions, ranging from structural to non-structural. Additionally, for dealing with the dynamic and more unpredictable nature of ecosystems, we suggest the adaptive delta management approach that consists of flexible measures, measurable targets, monitoring and intervention, as a framework for embedding ecosystem-based alternatives for flood risk mitigation in the daily practice of engineers and coastal planners.

Nursery systems for Patagonian grenadier off Western Patagonia: large inner sea or narrow continental shelf?

Abstract Niklitschek, E. J., Secor, D., Toledo, P., Valenzuela, X., Cubillos, L., and Zuleta, A. 2014. Nursery systems for Patagonian grenadier off Western Patagonia: large inner sea or narrow continental shelf? – ICES Journal of Marine Science, 71: 374–390. Adjacent to Chile's long and narrow continental shelf, the Patagonian Inner Sea (PES) is among the largest and most complex estuarine systems in the world. The PES harbours high concentrations of juveniles and adults of important groundfishes, which spawn within or in near proximity to it. A dominant view is that recruitment primarily originates here rather than in adjacent coastal regions. We used otolith stable isotopes to evaluate the relative contribution of several PES and continental shelf regions to recruitment of Patagonian grenadier, one of the most abundant groundfishes in the area. Seawater chemistry confirmed that δ13C and δ18O differentiated these nursery and feeding regions. Estimated recruitments from PES nurseries to adult feeding regions were important (10–35%), but lower than dominant contributions from shelf nurseries (64–85%). Stable isotope differences within otoliths indicated, however, that most adults had previously used PES habitats as subadults. Adults exhibited stronger homing to feeding habitats in the PES than to shelf regions, suggestive of seasonal site fidelity or partial migration behaviours. The proximity of principal spawning areas to the bifurcation of the West Wind Drift Current may cause large interannual and decadal variations in larvae transport and the relative contribution of different shelf and PES nurseries to recruitment.

A Modeling Study of the Potential Water Quality Impacts from In-Stream Tidal Energy Extraction

To assess the effects of tidal energy extraction on water quality in a simplified estuarine system, which consists of a tidal bay connected to the coastal ocean through a narrow channel where energy is extracted using in-stream tidal turbines, a three-dimensional coastal ocean model with built-in tidal turbine and water quality modules was applied. The effects of tidal energy extraction on water quality were examined for two energy extraction scenarios as compared with the baseline condition. It was found, in general, that the environmental impacts associated with energy extraction depend highly on the amount of power extracted from the system. Model results indicate that, as a result of energy extraction from the channel, the competition between decreased flushing rates in the bay and increased vertical mixing in the channel directly affects water quality responses in the bay. The decreased flushing rates tend to cause a stronger but negative impact on water quality. On the other hand, the increased vertical mixing could lead to higher bottom dissolved oxygen at times. As the first modeling effort directly aimed at examining the impacts of tidal energy extraction on estuarine water quality, this study demonstrates that numerical models can serve as a very useful tool for this purpose. However, more careful efforts are warranted to address system-specific environmental issues in real-world, complex estuarine systems.

Total Maximum Daily Load Criteria Assessment Using Monitoring and Modeling Data

AbstractApplications of Total Maximum Daily Load (TMDL) criteria for complex estuarine systems like Chesapeake Bay have been limited by difficulties in estimating precisely how changes in input loads will impact ambient water quality. A method to deal with this limitation combines the strengths of the Chesapeake Bay's Water Quality Sediment Transport Model (WQSTM), which simulates load response, and the Chesapeake Bay Program's robust historical monitoring dataset. The method uses linear regression to apply simulated relative load responses to historical observations of water quality at a given location and time. Steps to optimize the application of regression analysis were to: (1) determine the best temporal and spatial scale for applying the WQSTM scenarios, (2) determine whether the WQSTM method remained valid with significant perturbation from calibration conditions, and (3) evaluate the need for log transformation of both dissolved oxygen (DO) and chlorophyll a (CHL) datasets. The final method used simple linear regression at the single month, single WQSTM grid cell scale to quantify changes in DO and CHL resulting from simulated load reduction scenarios. The resulting linear equations were applied to historical monitoring data to produce a set of “scenario‐modified” DO or CHL concentration estimates. The utility of the regression method was validated by its ability to estimate progressively increasing attainment in support of the 2010 Chesapeake Bay TMDL.

Modelling of tide and surge elevations in the Solent and surrounding waters: The importance of tide–surge interactions

A regional two-dimensional hydrodynamic model using the MIKE-21 software and data from a pre-operational forecasting system of the English Channel is described and applied to the Solent–Southampton Water estuarine system. The regional model was able to predict surge heights with a root mean squared error (RMSE) accuracy of 0.09 m during a three month hindcast in the winter of 2009, comparing closely with accuracy assessments from other independent systems. However, consistent underprediction of tidal harmonic constituent amplitudes was present throughout the region leading to errors in the prediction of the total water level elevations. Despite the complex nature of the Solent tidal regime, interpolation of tidal elevations from harmonic analysis at fixed tide gauge locations was shown to be effective in reducing this uncertainty at gauged and un-gauged sites. The degree to which tide–surge interactions were taking place was examined. Of particular interest was the quantification of the sensitivity of the predicted surge to the levels of uncertainty expected in the prediction of the tide within a complex nearshore region such as the Solent. The tide–surge interaction during three surge events was shown to be greatest in the Western Solent and Southampton Waters regions, where the tidal uncertainty was greatest. Interaction between the tide and surge resulted in a change of up to 0.3 m (11%) in the predicted total peak water level when the surge was added to the harmonic analysis-based tidal prediction. Despite the significant effect of removing the tide–surge interactions, tests indicated that the error in tidal range expected in the regional models tidal prediction altered the prediction of the surge only enough to induce changes in peak total water elevations by up to 0.03 m during an event on 10th March 2008. The findings suggest that the current tidal predictions in complex estuarine systems, such as the Solent, are of high enough quality to reproduce the majority of the tide–surge interactions taking place and that the error in the surge due to uncertainties in the predicted tide are expected to be relatively small.

Shoreline Change along Sheltered Coastlines: Insights from the Neuse River Estuary, NC, USA

Coastlines are constantly changing due to both natural and anthropogenic forces, and climate change and associated sea level rise will continue to reshape coasts in the future. Erosion is not only apparent along oceanfront areas; shoreline dynamics in sheltered water bodies have also gained greater attention. Additional estuarine shoreline studies are needed to better understand and protect coastal resources. This study uses a point-based approach to analyze estuarine shoreline change and associated parameters, including fetch, wave energy, elevation, and vegetation, in the Neuse River Estuary (NRE) at two contrasting scales, Regional (whole estuary) and Local (estuary partitioned into eight sections, based on orientation and exposure). With a mean shoreline-change rate of –0.58 m yr−1, the majority (93%) of the NRE study area is eroding. Change rates show some variability related to the land-use land-cover classification of the shoreline. Although linear regression analysis at the Regional Scale did not find significant correlations between shoreline change and the parameters analyzed, trends were determined from Local Scale data. Specifically, erosion rates, fetch, and wave exposure increase in the down-estuary direction, while elevation follows the opposite trend. Linear regression analysis between mean fetch and mean shoreline-change rates at the Local Scale provide a first-order approach to predict shoreline-change rates. The general trends found in the Local Scale data highlight the presence of underlying spatial patterns in shoreline-change rates within a complex estuarine system, but Regional Scale analysis suggests shoreline composition also has an important influence.

Peracarid assemblages of Zostera meadows in an estuarine ecosystem (O Grove inlet, NW Iberian Peninsula): spatial distribution and seasonal variation

The Galician rias are singular and complex estuarine systems of great economic importance. Seagrasses are key elements of the ecosystem and favor the maintenance of high species diversity in benthic communities. Nevertheless, the ecological role of seagrass meadows in the Galician rias has been only partially assessed. Peracarid crustaceans are an important component of soft-bottom faunas and have great importance for the structure of benthic assemblages. In this work, species diversity, patterns of distribution and seasonal fluctuations of peracarids (Crustacea, Peracarida) are studied in estuarine sediments colonized by two species of Zostera (Z. marina and Z. noltii) at the O Grove inlet (Ria de Arousa, Galicia, NW Iberian Peninsula). The spatial distribution of peracarid assemblages was characterized by high numerical dominances due to a few species, particularly tanaidaceans. The temporal study at a Z. marina meadow showed a strongly seasonal pattern defined by great fluctuations of the amphipod population, the latter being the dominant group in abundance and number of species. The highest numbers of species and individuals were observed in September, with minimum values in March. Analyses pointed out a high correlation among the granulometric features of the studied bottoms and the faunistic attributes. Nevertheless, the presence of the seagrasses should influence in a major way the hydrodynamic and sedimentary features of the habitat and utterly the spatial and temporal patterns observed in the peracarid assemblage in the O Grove inlet.

Wetland‐estuarine‐shelf interactions in the Plum Island Sound and Merrimack River in the Massachusetts coast

Wetland‐estuarine‐shelf interaction processes in the Plum Island Sound and Merrimack River system in the Massachusetts coast are examined using the high‐resolution unstructured grid, finite volume, primitive equations, coastal ocean model. The computational domain covers the estuarine and entire intertidal area with a horizontal resolution of 10–200 m. Driven by five tidal constituents forcing at the open boundary on the inner shelf of the eastern coast of the Gulf of Maine, the model has successfully simulated the 3‐D flooding/drying process, temporal variability, and spatial distribution of salinity as well as the water exchange flux through the water passage between the Plum Island Sound and Merrimack River. The model predicts a complex recirculation loop around the Merrimack River, shelf, and Plum Island Sound. During the ebb tide, salt water in the Plum Island Sound is injected into the Merrimack River, while during flood tide, a significant amount of the freshwater in the Merrimack River is forced into Plum Island Sound. This water exchange varies with the magnitude of freshwater discharge and wind conditions, with a maximum contribution of ∼30%–40% variability in salinity over tidal cycles in the mouth of the Merrimack River. Nonlinear tidal rectification results in a complex clockwise residual recirculation loop around the Merrimack River, shelf, and Plum Island Sound. The net water flux from Plum Island Sound to the Merrimack River varies with the interaction between tide, river discharge, and wind forcing. This interaction, in turn, affects the salt transport from this system to the shelf. Since the resulting water transport into the shelf significantly varies with the variability of the wind, models that fail to resolve this complex estuarine and shelf system could either overestimate or underestimate the salt content over the shelf.

Regulation of feeding mode by the sand dollar Dendraster excentricus in a shallow estuarine habitat

The sand dollar Dendraster excentricus is a facultative suspension feeder, which is relatively rare within the Order Clypeasteroida. Field studies of regulation of its feeding mode have been mostly conducted in exposed coastal habitats, where they are typically observed in an inclined position and oriented parallel to each other during suspension feeding. Physical (current speed and direction, reduction of drag and lift) and biological factors (increased efficiency of capture of particulates, and density) have been associated with regulation of its feeding mode in exposed coastal systems. We simultaneously measured the role of physical and biological factors in regulating the selection mode for feeding under varying tidal conditions in a shallow estuary in Baja California, Mexico. We used photographic records and direct sampling in fixed plots to determine the relationship between feeding behavior and environmental conditions. Current direction and speed, tidal level, density and content of organic matter in the water column and sediments were measured with respect to feeding mode (prone or inclined) and orientation relative to prevailing currents during spring and neap tides. Multiple regression analysis indicated that the percentage of inclined sand dollars was strongly and positively correlated only with tidal level at the densities found in the estuary (mean < 180 individuals m − 2 ); there was no relationship with current velocity, density, and organic matter content of the water. The prone position, indicative of deposit feeding, was largely limited to low tidal levels. We used circular statistics to determine whether the orientation of inclined sand dollars was correlated with current direction and speed. Sand dollars were only oriented parallel to the prevailing currents during the strongest currents of spring tides (> 20 cm s − 1 ). We did not observe the predominant oral:aboral configuration found in exposed coastal systems, which may be attributed to the relatively low densities of sand dollars in the exposed coastal environment (30–180 individuals m − 2 ), compared to protected coastal habitats (up to 1000 individuals m − 2 ). Our results suggest that regulation of the feeding mode of sand dollars in shallow and hydrodynamically complex estuarine systems differs from the feeding mode found in exposed coastal environments.

Spatial Variation in the Marine Radiocarbon Reservoir Effect Throughout the Scottish Post-Roman to Late Medieval Period: North Sea Values (500–1350 BP)

The marine radiocarbon reservoir effect (MRE) occurs as a spatially and temporally dependent variable owing to localized changes in oceanic water composition. This study investigates ΔR values (deviations from the global average MRE whose ΔR = 0) during the period 500–1350 BP for the east coast of Scotland, where a complex estuarine system exists that drains into the semi-enclosed North Sea basin. Due to the availability of suitable archaeological samples, the data set has a distinct Medieval focus that spans the area from Aberdeen in the north to East Lothian in the south. Many of the ΔR values are not significantly different from 0 (the global average), but there are occasional excursions to negative values (max –172 ± 20) indicating the presence of younger water. These values show greater variability compared to other published data for this general region, suggesting that considerable care must be taken when dating marine derived samples from archaeological sites on the east coast of Scotland.

Development of a preliminary relative risk model for evaluating regional ecological conditions in the Delaware River Estuary, USA

Effective environmental management and restoration of urbanized systems such as the Delaware River Estuary requires a holistic understanding of the relative importance of various stressor-related impacts throughout the watershed, both historical and ongoing. To that end, it is important to involve as many stakeholders as possible in the management process and to develop a system for sharing of scientific data and information, as well as effective technical tools for evaluating and disseminating the data needed to make management decisions. In this study, we describe a preliminary assessment that was undertaken to evaluate the relative risks for the variety of stressors currently operating within the Delaware Estuary using a relative risk model (RRM) framework. This model was constructed using existing data and information on the ecological conditions and stressors in the main-stem Delaware River below the head of tide at Trenton, New Jersey, USA. A large database was developed with pertinent data from a variety of library, scientific, and regulatory sources. Data were compiled, reviewed, and characterized before development of the Estuary-specific RRM. Our primary goals and objectives in developing this preliminary RRM for the Estuary were to 1) determine if the RRM framework can be adapted to a large complex estuarine system such as the Delaware River, 2) identify the issues associated with adapting the model framework to the various management issues and regional areas/habitats of the River, 3) help identify data needs and potential refinements that might be needed to more specifically quantify relative stressor risks in various areas and habitats of the Estuary to better inform future management goals/actions by Stakeholders. The key conclusions of our preliminary assessment are 1) a diverse suite of stressors is likely affecting the ecological conditions of the Delaware Estuary, 2) chemical (toxicants/contaminants) and physical (sedimentation, habitat loss) stressors were found to be on par with regards to their ranking, and 3) the RRM, in its current form, made it difficult to effectively balance the inequality in the sizes of the study subareas considered in the assessment. Management objectives and related research activities should focus on collecting the necessary data and information to further refine the RRM and assess the relative impacts of these stressors at various scales in the Estuary. By having such a framework and tool available, we believe that stakeholders within the Delaware River watershed will be able to make more informed and risk-based management decisions regarding restoration options for the Estuary.

Low-frequency sea-level change in Chesapeake Bay: Changing seasonality and long-term trends

Long-term sea-level variability in Chesapeake Bay is examined from long tide gauge records in order to assess the influence of climate factors on sea-level changes in this complex estuarine system. A time series decomposition method based on autoregression is applied to extract flexible seasonal and low-frequency components from the tide gauge records, allowing to analyse long-term sea-level variability not only by estimating linear trends from the records, but also by examining fluctuations in seasonal and long-term patterns. Long-term sea-level variability in Chesapeake Bay shows considerable decadal variability. At the annual scale, variability is mainly determined by atmospheric factors, specifically atmospheric pressure and zonal wind, but no systematic trends are found in the amplitude of the annual cycle. On longer time scales, precipitation rate, a proxy for river discharge, is the main factor influencing decadal sea-level variability. Linear trends in relative sea-level heights range from 2.66 ± 0.075 mm/year (at Baltimore) to 4.40 ± 0.086 mm/year (at Hampton Roads) for the 1955–2007 period. Due to the gentle slope of most of the bay margin, a sea-level increase of this magnitude poses a significant threat in terms of wetland loss and consequent environmental impacts.

A Differential Pressure Instrument with Wireless Telemetry for In-Situ Measurement of Fluid Flow across Sediment-Water Boundaries

An instrument has been built to carry out continuous in-situ measurement of small differences in water pressure, conductivity and temperature, in natural surface water and groundwater systems. A low-cost data telemetry system provides data on shore in real time if desired. The immediate purpose of measurements by this device is to continuously infer fluxes of water across the sediment-water interface in a complex estuarine system; however, direct application to assessment of sediment-water fluxes in rivers, lakes, and other systems is also possible. Key objectives of the design include both low cost, and accuracy of the order of ±0.5 mm H2O in measured head difference between the instrument's two pressure ports. These objectives have been met, although a revision to the design of one component was found to be necessary. Deployments of up to nine months, and wireless range in excess of 300 m have been demonstrated.

Stochastic Event-Based Approach to Generate Concurrent Hourly Mean Sea Level Pressure and Wind Sequences for Estuarine Flood Risk Assessment

The determination of the annual exceedence probability (AEP) of extreme water levels in complex estuarine systems is an important and challenging issue in flood management. Extreme estuarine levels are caused by the combined effects of river flows, local winds, and coastal ocean levels. This paper describes a stochastic, event-based approach for generating concurrent hourly mean sea level pressure (MSLP) and wind speed, which are needed in a larger project to derive stochastic hourly river flows, winds, and coastal ocean levels to drive a hydrodynamic model for estuarine flood level simulation. The minimum MSLP versus rainfall and maximum wind speed versus rainfall relationships for the extreme flood events at the daily time scale are first used to generate minimum daily MSLP and maximum daily wind speed using a nonparametric resampling method. The generated minimum daily MSLP and maximum daily wind speed are then used to scale concurrent hourly MSLP and wind speed sequences resampled from the historical ...

Hyperspectral Sensing for Assessing Nearshore Water Quality Conditions of Hudson/Raritan Estuary

This study addresses the use of remote sensing hyperspectral data acquired by NASA/Airborne Visible Infra Red Imaging Spectrometer (AVIRIS) to estimate concentrations of optical water quality parameters in the Hudson/Raritan Estuary of New York-New Jersey. Hudson/Raritan estuary is a complex estuarine system where tidal and wind-driven currents are modified by freshwater discharges from the Hudson, Raritan, Hackensack, and Passaic rivers. Hypersectral (high resolution) remote sensing data offers unique advantages for the study of recurrent hydrological phenomena on regional and local scales. The paper describes the bio-optical water quality model constructed linking the water constituent concentrations to (i) the inherent optical properties (IOPs), using the specific inherent optical properties (SIOP), and (ii) to the subsurface light levels. Generation of accurate reflecta nce R(0) from radiance recorded by the AVIRIS is the key parameter for input into inverse modeling for estimation of constituent concent rations. In conjunction with bio-optical model, the linear matrix inversion technique is used for retrieval of estuarine water constituents in terms of chlorophyll, colored dissolved organic matter and inorganic material. The long term goal is to establish a monitoring/management system for retrieval of estuarine water constituents using remotely sensed data. Such efforts are complementary to the development of spectral library for detec tion/identification of harmful algal blooms (HABs) causing eutrophication and pollutions in the world’s coastal and estuarine waters. Results of AVIRIS data analyses in forms of thematic maps of concentrations of water quality parameters can be integrated into the Geographic Information Systems (GIS) of the estuary. GIS is a computer-based geospatial database which can be used as a management tool for monitoring of water quality conditions of the estuary.

Retrieval of marine water constituents from AVIRIS data in the Hudson/Raritan Estuary

This paper reports on the validation of bio‐optical models in estuarine and nearshore (case 2) waters of New Jersey–New York to retrieve accurate water leaving radiance spectra and chlorophyll concentration from the NASA Airborne Visible Infrared Imaging Spectrometer (AVIRIS) data complemented with in situ measurements. The study area—Hudson/Raritan Estuary—is a complex estuarine system where tidal and wind‐driven currents are modified by freshwater discharges from the Hudson, Raritan, Hackensack, and Passaic rivers. Over the last century the estuarine water quality has degraded, in part due to eutrophication, which has disrupted the pre‐existing natural balance, resulting in phytoplankton blooms of both increased frequency and intensity, increasing oxygen demand and leading to episodes of hypoxia. During 1999–2001 data acquisitions by NASA AVIRIS field measurements were obtained to establish hydrological optical properties of the Hudson/Raritan Estuary: (1) concurrent above‐ and below‐surface spectral irradiance; (2) sampling for laboratory determination of inherent optical properties; and (3) concentrations of optically‐important water quality parameters. We used a bio‐optical model based on Gordon et al. to predict the sub‐surface irradiance reflectance from optically important water constituents. Modelling of reflectance is a prerequisite for processing remote sensing data to desired thematic maps for input into the geographical information system (GIS) for use as a management tool in water quality assessment. A Radiative Transfer Code—MODTRAN‐4—was applied to remove the effects of the atmosphere so as to infer the water leaving radiance from the AVIRS data. The results of this procedure were not satisfactory, therefore an alternative approach was tested to directly correct the AVIRIS image using modelled spectra based on measured optical characteristics. The atmospherically corrected AVIRIS ratio image was used to calculate a thematic map of water quality parameters (i.e. chlorophyll‐a) concentration, which subsequently were integrated into a GIS for management of water quality purposes.

A Review of Factors Influencing Measurements of Decadal Variations in Metal Contamination in San Francisco Bay, California

This review summarizes some of the principal results of systematic measurements of trace metal concentrations throughout San Francisco Bay that began in 1989, and that have yielded insights on the factors controlling temporal and spatial variations of those concentrations on seasonal to decadal time scales. Pronounced seasonal variation in some metal concentrations is associated with gradients in the system's hydrology and the diagenetic remobilization of metals from benthic sediments. Additional temporal variation is associated with interannual differences in hydrologic flushing (e.g., ENSO cycles) and episodic storm events. While intra- and inter-annual variabilities complicate assessments of long-term variations in metal concentrations, recent analyses using stable lead isotopic composition distributions and time-series models have deconvoluted decadal changes in lead and silver concentrations in the estuary. Decadal variations in concentrations of other contaminant metals (e.g., mercury) are now being characterized, as well as projections of future concentrations of other metals of concern (e.g., copper). These historic assessments and projections of trace metal variations attest to the importance of long-term, systematic monitoring programs to quantify past and future impacts on water quality in San Francisco Bay and other complex estuarine systems.