Complete Redistribution Research Articles

Binding of Gold(III) from Solutions by the [Ag6{S2CN(CH2)6}6] Cluster: Synthesis, Thermal Behavior, and Self-Organization of the Supramolecular Structure of the Double Complex [Au{S2CN(CH2)6}2]2[AgCl2]Cl\xb72CHCl3 (Role of Secondary Au\u22c5\u22c5\u22c5Cl, Ag\u22c5\u22c5\u22c5S, and Cl\u22c5\u22c5\u22c5Cl Interactions)

The capability of silver(I) cyclo-hexamethylenedithiocarbamate to concentrate gold(III) from solutions characterized by a high level of salinity (5.15 M NaCl) into the solid phase has been established. The double chloroform-solvated Au(III)–Ag(I) complex [Au{S2CN(CH2)6}2]2[AgCl2]Cl·2CHCl3 (I) was preparatively isolated as an individual form of binding of [AuCl4]– anions. The composition of the ionic structural units of compound I indicates that gold(III) binding from a solution to the solid phase is accompanied by the complete redistribution of the HmDtc ligands between the coordination spheres of Ag(I) and Au(III). Complex I characterized by IR spectroscopy, simultaneous thermal analysis, and X-ray structure analysis (CIF file CCDC no. 2051654) exhibits the supramolecular structure containing two oppositely charged pseudo-polymeric subsystems. Complex cations [Au{S2CN(CH2)6}2]+ and anions [AgCl2]– (in a ratio of 2 : 1) form a complicatedly organized cation-anionic pseudo-polymeric ribbon ({[Au(HmDtc)2]⋅⋅⋅[AgCl2]⋅⋅⋅[Au(HmDtc)2]}+)n due to secondary interactions Ag⋅⋅⋅S (3.2613 Å) and Au⋅⋅⋅Cl (3.2765 Å). The pseudo-polymeric ribbon consists of two rows of cations and a row of anions. The outer-sphere chloride ions combine the solvate chloroform molecules by two equivalent hydrogen bonds Cl⋅⋅⋅H–C yielding anion-molecular triads [Cl3CH⋅⋅⋅Cl⋅⋅⋅HCCl3]–, which are involved in the formation of the supramolecular ribbon due to the secondary Cl⋅⋅⋅Cl interactions (3.4058 Å) between the nonequivalent chlorine atoms of the nearest solvate molecules. The study of the thermal behavior of complex I makes it possible to determine the character of thermolysis and conditions for the quantitative regeneration of bound gold.

Influence of calcination temperature of acidic ammonium salts of phosphotungstic acid on their composition and properties

The effect of the calcination temperature on the structure and properties of acidic ammonium salt (NH4)2HPW12O40 was studied. The absence of the influence of the calcination temperature of the samples on their particle size distribution, thermal stability and water content was shown. In the investigated range from 300 to 450 ​°C, a nonmonotonic change in the specific surface area and proton-conducting properties is observed depending on the calcination temperature. Calcination at a temperature other than optimal leads to a decrease in the specific surface area and proton conducting properties. A lower temperature is probably not enough for a complete redistribution of protons and ammonium ions; and an increase in the calcination temperature above optimal one entails the compaction of the salt crystallites.

Overall spatiotemporal dynamics of greenhouse gasses and oxygen in two subtropical reservoirs with contrasting trophic states

The impact of cultural eutrophication on carbon cycling in subtropical reservoirs was assessed using high-resolution measurements of dissolved gas concentration, atmospheric exchange, and uptake/production rates of methane, carbon dioxide, and oxygen. Seasonal measurements were performed in two reservoirs that pertain to the same hydrological basin but are drastically different in terms of allochthonous carbon input. These results were used to feed a mass balance model, from which a large number of overall parameters were determined to explicitly describe the dynamics and spatial attributes of the carbon cycle in the reservoirs. A single graphical representation of each reservoir was created to facilitate an overall appraisal of the carbon cycle. The impact of cultural eutrophication was profound and resulted in a complete redistribution of how the various bioprocesses participated in the methane, carbon dioxide, and oxygen cycles. Among several identified impacts of eutrophication, it was observed that while eutrophication triggered increased methane production, this effect was followed by a similar increase in methane emissions and methanotrophic rates, while gross primary production was depleted.

The Effects of Three-dimensional Radiative Transfer on the Resonance Polarization of the Ca i 4227 Å Line

Abstract The sizable linear polarization signals produced by the scattering of anisotropic radiation in the core of the Ca i 4227 Å line constitute an important observable for probing the inhomogeneous and dynamic plasma of the lower solar chromosphere. Here we show the results of a three-dimensional (3D) radiative transfer complete frequency redistribution investigation of the line’s scattering polarization in a magnetohydrodynamical 3D model of the solar atmosphere. We take into account not only the Hanle effect produced by the model’s magnetic field but also the symmetry breaking caused by the horizontal inhomogeneities and macroscopic velocity gradients. The spatial gradients of the horizontal components of the macroscopic velocities produce very significant forward scattering polarization signals without the need of magnetic fields, while the Hanle effect tends to depolarize them at the locations where the model’s magnetic field is stronger than about 5 G. The standard 1.5D approximation is found to be unsuitable for understanding the line’s scattering polarization, but we introduce a novel improvement to this approximation that produces results in qualitative agreement with the full 3D results. The instrumental degradation of the calculated polarization signals is also investigated, showing what we can expect to observe with the Visible Spectro-Polarimeter at the upcoming Daniel K. Inouye Solar Telescope.

Self-Similar Solutions in the Theory of Nonstationary Radiative Transfer in Spectral Lines in Plasmas and Gases

Radiative transfer (RT) in spectral lines in plasmas and gases under complete redistribution of the photon frequency in the emission-absorption act is known as a superdiffusion transport characterized by the irreducibility of the integral (in the space coordinates) equation for the atomic excitation density to a diffusion-type differential equation. The dominant role of distant rare flights (Lévy flights, introduced by Mandelbrot for trajectories generated by the Lévy stable distribution) is well known and is used to construct approximate analytic solutions in the theory of stationary RT (the escape probability method is the best example). In the theory of nonstationary RT, progress based on similar principles has been made recently. This includes approximate self-similar solutions for the Green’s function (i) at an infinite velocity of carriers (no retardation effects) to cover the Biberman–Holstein equation for various spectral line shapes; (ii) for a finite fixed velocity of carriers to cover a wide class of superdiffusion equations dominated by Lévy walks with rests; (iii) verification of the accuracy of above solutions by comparison with direct numerical solutions obtained using distributed computing. The article provides an overview of the above results with an emphasis on the role of distant rare flights in the discovery of nonstationary self-similar solutions.

Political Activism and the Provision of Dynamic Incentives: Growing the Pie in the Battle for Redistribution

AbstractThis paper studies the determination of income taxes in a dynamic setting with human capital accumulation. The goal is to understand the factors that support an outcome without complete redistribution, given a majority of relatively poor agents and the inability to commit to future taxes. All agents agree ex ante that limiting tax and transfers is beneficial but a majority favours large redistribution, ex post, at the time of the vote. In a political influence game, group activism limits the support for expropriatory taxation and preserves incentives. In some cases, the outcome corresponds to the optimal allocation under commitment.

Binding of Gold(III) from Solutions by Tetranuclear Lead(II) Dipropyldithiocarbamate [Pb4{S2CN(C3H7)2}8] and Chemisorption Synthesis of the Double Ionic Polymer Complex ([Au{S2CN(C3H7)2}2][PbCl3] · 0.5CH3–C6H5)n: Heteronuclear ( 13 C, 15 N) CP-MAS NMR, Structural Organization, and Construction Principles of Cationic and Anionic Polymer Chains

Solid-state 13C and 15N CP-MAS NMR data adequately reflected the presence of four nonequivalent PrDtc ligands in the tetranuclear lead(II) N,N-dipropyldithiocarbamate (PrDtc), [Pb4{S2CN(C3H7)2}8] (I); the spin–spin coupling constants 3J(15N–207Pb) for the ligands were estimated. It was shown by 13C MAS NMR that the chemisorption binding of AuCl3 from a solution in 2M HCl using lead(II) dipropyldithiocarbamate is accompanied by complete redistribution of the PrDtc ligands from Pb(II) to Au(III) coordination sphere; this gives the double complex of [Au{S2CN(C3H7)2}2][PbCl3] (II). Upon crystallization from an acetone–toluene mixture (3 : 1), this complex was isolated as the solvated form ([Au{S2CN(C3H7)2}2][PbCl3] ⋅ 1/2CH3C6H5)n (IIa), which was characterized by X-ray diffraction (CIF file CCDC no. 1978947). The cationic part of the complex is represented by non-centrosymmetric gold(III) complex ions, [Au{S2CN(C3H7)2}2]+, which are combined by pairs of nonequivalent Au···S secondary bonds, thus forming supramolecular pseudo-polymer chain ([Au{S2CN(C3H7)2}2]+)n. The 1D polymeric trichloroplumbate(II) anion, {[Pb(μ2-Cl)3]–}n, acts as the counter-ion. The C–H···Cl hydrogen bonds between the anionic and cationic chains lead to formation of channels in the crystal lattice, which are occupied by solvating toluene molecules.

Modeling Mg ii during Solar Flares. II. Nonequilibrium Effects

Abstract To extract the information that the Mg ii NUV spectra (observed by the Interface Region Imaging Spectrograph) carry about the chromosphere during solar flares, and to validate models of energy transport via model–data comparison, forward modeling is required. The assumption of statistical equilibrium (SE) is typically used to obtain the atomic level populations from snapshots of flare atmospheres, due to computational necessity. However, it is possible that relying on SE could lead to spurious results. We compare solving the atomic level populations via SE versus a nonequilibrium (NEQ) time-dependent approach. This was achieved using flare simulations from RADYN alongside the minority species version MS_RADYN from which the time-dependent Mg ii atomic level populations and radiation transfer were computed in complete frequency redistribution. The impacts on the emergent profiles, lightcurves, line ratios, and formation heights are discussed. In summary we note that NEQ effects during flares are typically important only in the initial stages and for a short period following the cessation of the energy injection. An analysis of the timescales of ionization equilibrium reveals that for most of the duration of the flare, when the temperatures and densities are sufficiently enhanced, the relaxation timescales are short (τ relax < 0.1 s), so that the equilibrium solution is an adequate approximation. These effects vary with the size of the flare, however. In weaker flares, effects can be more pronounced. We recommend that NEQ effects be considered when possible but that SE is sufficient at most stages of the flare.

Enhancing Throughput of Optimum Channel in Ofdm Based Full Duplex Communication

The efficient use of radio facilities in cellular networks is essential and being widely studied. This letter sees a cellular relay system where various user couples perform trans-directional interaction via various relays relying on Orthogonal Frequency-Division Multiplexing (OFDM) communication.. Joint implementation of route and transmit allocation, along with subcarrier coupling, subcarrier distribution as well as relay choice, for complete output redistribution is identified as a combination estimation issue.. Using a graph conceptual strategy, we can efficiently fix the problem in exponential time by converting it into a Optimum Adjusted Bipartite Tracking (MWBM) issue. Simulation experiments are conducted to assess the complete throughput of the network versus transmitting energy per node and the number of relay nodes. Carrier frequency offset causes a number of impairments including attenuation and rotation of each of the subcarriers and intercarrier interference (ICI) between carrier frequency offset causes a number of impairments including attenuation and rotation of each of the subcarriers and intercarrier interference (ICI) between subcarriers. In the mobile radio environment, the relative movement between transmitter and receiver causes doppler frequency shifts, in addition, the carriers can never be perfectly synchronized. These random frequency errors in OFDM system distort orthogonality between subcarriers and thus intercarrier interference (ICI) occurs. A Number of methods have been developed to reduce this sensitivity to frequency offset

Income inequality and carbon consumption: Evidence from Environmental Engel curves

I investigate the relationship between income inequality and the carbon dioxide (CO2) content of consumption. I quantify the CO2 content of household expenditure using input-output analysis and estimate Environmental Engel curves (EECs) which describe the income–emissions relationship. Using EECs for the United States between 1996 and 2009, I decompose the change in CO2 over time and the distribution of emissions across households. In both cases, income is an important driver of household carbon. Finally, I describe a potential “equity-pollution dilemma”—progressive income redistribution may raise the demand for aggregate greenhouse gas emissions. I estimate that transfers raise emissions by 5.1% at the margin and by 2.3% under complete redistribution.

Semi-empirical model atmospheres for the chromosphere of the sunspot penumbra and umbral flashes

Context. The solar chromosphere and the lower transition region are believed to play a crucial role in the heating of the solar corona. Models that describe the chromosphere (and the lower transition region), accounting for its highly dynamic and structured character are, so far, found to be lacking. This is partly due to the breakdown of complete frequency redistribution (CRD) in the chromospheric layers and also because of the difficulty in obtaining complete sets of observations that adequately constrain the solar atmosphere at all relevant heights. Aims. We aim to obtain semi-empirical model atmospheres that reproduce the features of the Mg II h&k line profiles that sample the middle chromosphere with focus on a sunspot. Methods. We used spectropolarimetric observations of the Ca II 8542 Å spectra obtained with the Swedish 1 m Solar Telescope and used NICOLE inversions to obtain semi-empirical model atmospheres for different features in and around a sunspot. These were used to synthesize Mg II h&k spectra using the RH1.5D code, which we compared with observations taken with the Interface Region Imaging Spectrograph (IRIS). Results. Comparison of the synthetic profiles with IRIS observations reveals that there are several areas, especially in the penumbra of the sunspot, where most of the observed Mg II h&k profiles are very well reproduced. In addition, we find that supersonic hot down-flows, present in our collection of models in the umbra, lead to synthetic profiles that agree well with the IRIS Mg II h&k profiles, with the exception of the line core. Conclusions. We put forward and make available four semi-empirical model atmospheres. Two for the penumbra, reflecting the range of temperatures obtained for the chromosphere, one for umbral flashes, and a model representative of the quiet surroundings of a sunspot.

The range of normative surface skin temperature changes in adolescents: prospective multicenter study.

We aimed to establish a normative range of surface skin temperature (SST) changes due to blood redistribution in adolescents and to register the time needed for complete postural change-related blood redistribution. The healthy volunteers (age 15-18, n = 500, M 217, F 283) were recruited for this prospective multicenter study. The volunteers were asked to keep one extremity down and another extremity up in supine rest, sitting with straight legs, and upright rest. We obtained temperature readings being taken from the tips of the middle fingers and temperature readings from the tips of the first toes at the ambient temperature of 25 °C and 30 °C. The control group consisted of a 100 of adult volunteers. The resting temperature of the middle fingers for a sitting participant was 28.6 ± 0.8 °C. The physiological change of this temperature during body position changes was 4.5 ± 1.1 °C and for most of the participants remained within the 26.5-31.5 °C range at 25 °C. For the toe, physiological skin temperature range was 25.5-33 °C. At 30 °C, these ranges were 27-33 °C for the fingers and 27-34 °C for the toes. On average, 2-3 min were needed for such temperature changes. At normal room temperature, the SST of thermoneutral adolescents may vary within a range of approximately 5 °C only due to the blood redistribution in the body. This range is specific for each person due to individual peculiarities of the vasomotor activity. This normative range of SSTs should be taken into account during investigations of thermoregulation.

Distribution of Load Forces in Hollow Core Slabs of Precast Solid Floor Supported on Bearing Walls

The need to cut construction cost of residential and public buildings and provide them with a free and transformable planning structure during their operation cause interest in building wall systems with a large step of bearing walls. In order to reduce labor inputs and increase rate of construction in such building load-bearing system it is also necessary to maximize the use of large-sized prefabricated products and minimize consumption of in-situ concrete. In this case prefabricated products should be substituted according to the conditions of local (regional) construction industry base and volume of in-situ concrete must be sufficient to ensure a complete redistribution of internal forces between elements of the bearing system under load. As for the described bearing wall system of a multi-storey building the paper presents a flat precast solid floor formed by hollow-core slabs and monolithic crossbars supported by load-bearing walls. The hollow-core slabs supported at the ends on cast-in-place crossbars in the planes of bearing walls are arranged in dense groups between cast-in-place braced cross-beams. Dense contacts between overlapping elements are fixed by internal bonds. New data on distribution of forces in floor elements under the action of a vertical load have been obtained on the basis of full-scale tests and existing theoretical assumptions. It has been established that due to this load reactive thrust forces ensuring an operation of every hollow-core slab group in the floor as an effective solid plate supported along the contour have been originated in the floor plane along two main axes. Calculation of the reactive thrust forces makes it possible more accurately to assess a load-bearing capacity and rigidity of the precast solid floor and to increase a step of bearing walls up to 8 m and more while having hollow-core slabs with a thickness of 220 mm.

A simplified method for evaluation of brittle crack arrest toughness of steels in scaled-down bending tests

The wide-plate crack arrest test under tensile load for characterizing the brittle crack arrest toughness of high strength shipbuilding steel requires high economical cost and long lead-time, so there is still a substantial industry need for the simplified evaluation using the scaled-down specimen. The alternative method using a single edge-notched bending specimen, which assumes the complete load redistribution during the crack propagation, was recently proposed. However, it was confirmed that the results obtained using this method exhibited a low correlation with the arrest toughness obtained using the wide-plate tests. A new scaled-down version of the crack arrest test under bending load and a series of simplified evaluation based on the dynamic elasto-plastic FEA were introduced to characterize the crack arrest performance of the two types of steel plates in this investigation. The specimen is a single edge-notched tapered plate subjected to a three-point bending load in an isothermal environment. The geometry was selected so that the dynamic crack driving force calculated using FEA decreases monotonically with the crack propagation. For adopting a simplistic analytical approach considering the dynamic effect, the dynamic FEA simulation assumed the constant crack velocity and flat crack front and output the opening stress distributed ahead of the growing crack. The experimentally obtained values of the arrested crack length and the analytically obtained transition curves of the dynamic SIF were employed to characterize the crack arrest performance of the two steels. The results obtained using the simplified method developed in this investigation exhibited a high correlation with the arrest toughness obtained using the wide-plate crack arrest test.

Non-thermal hydrogen Lyman line and continuum emission in solar flares generated by electron beams

Aims. Hydrogen Lyman continuum emission is greatly enhanced in the impulsive kernels of solar flares, with observations of Lyman lines showing impulsive brightening and both red and blue wing asymmetries, based on the images with low spatial resolution. A spate of proposed instruments will study Lyman emission in more detail from bright, impulsive flare kernels. In support of new instrumentation we aim to apply an improved interpretation of Lyman emission with the hydrodynamic radiative code, HYDRO2GEN, which has already successfully explained Hαemission with large redshifts and sources of white light emission in solar flares. The simulations can interpret the existing observations and propose observations in the forthcoming missions.Methods. A flaring atmosphere is considered to be produced by a 1D hydrodynamic response to injection of an electron beam, defining depth variations of electron and ion kinetic temperatures, densities, and macro-velocities. Radiative responses in this flaring atmosphere affected by the beams with different parameters are simulated using a fully non-local thermodynamic equilibrium (NLTE) approach for a five-level plus continuum model hydrogen atom with excitation and ionisation by spontaneous, external, and internal diffusive radiation, and by inelastic collisions with thermal and beam electrons. Integral radiative transfer equations for all optically thick transitions are solved using the L2 approximation simultaneously with steady state equations.Results. During a beam injection in the impulsive phase there is a large increase of collisional ionisation and excitation by non-thermal electrons that strongly (by orders of magnitude) increases excitation and the ionisation degree of hydrogen atoms from all atomic levels. These non-thermal collisions combined with plasma heating caused by beam electrons lead to an increase in Lyman line and continuum radiation, which is highly optically thick. During a beam injection phase the Lyman continuum emission is greatly enhanced in a large range of wavelengths resulting in a flattened distribution of Lyman continuum over wavelengths. After the beam is switched off, Lyman continuum emission, because of its large opacity, sustains, for a very long time, the high ionisation degree of the flaring plasma gained during the beam injection. This leads to a long enhancement of hydrogen ionisation, occurrence of white light flares, and an increase of Lyman line emission in cores and wings, whose shapes are moved closer to those from complete redistribution (CRD) in frequencies, and away from the partial ones (PRD) derived in the non-flaring atmospheres. In addition, Lyman line profiles can reflect macro-motions of a flaring atmosphere caused by downward hydrodynamic shocks produced in response to the beam injection reflected in the enhancements of Ly-line red wing emission. These redshifted Ly-line profiles are often followed by the enhancement of Ly-line blue wing emission caused by the chromospheric evaporation. The ratio of the integrated intensities in the Lyαand Lyβlines is lower for more powerful flares and agrees with reported values from observations, except in the impulsive phase in flaring kernels which were not resolved in previous observations, in which the ratio is even lower. These results can help observers to design the future observations in Lyman lines and continuum emission in flaring atmospheres.

Fractional Differential Model of Resonant Transfer of Excitations in Plasma

The most crucial feature of excitation transfer in low-temperature plasma forming the physical basis for operation of contemporary lighting devices is participation of resonant photons in the process. The widely used approximation of complete frequency redistribution assumes independence of the emitted photon frequency from frequency of the absorbed one. Averaged over frequency distribution in a resonance line, the natural transfer equation with the exponential kernel becomes the equation with an inverse power kernel, which in case of an infinite homogeneous medium is asymptotically equivalent to the Laplace equation of non-integer (fractional) order, considered in this article.

Doppler Frequency Redistribution upon Coherent Photon Emission by Atoms in an Optically Dense Medium

The problem of transfer of line radiation in sodium vapor under photoexcitation by laser radiation of a resonance line with wavelength λ = 589.6 nm is numerically solved. The influence of Doppler frequency shifts on photon emission coherent in the atomic reference system is taken into account in the formation of an emission line profile using the model of partial frequency redistribution. In the case of a small optical thickness of a medium τ0 ≤ 1, the Doppler frequency redistribution in the laboratory reference system yields higher intensity values in the emission line profile core in comparison with the model of complete frequency redistribution. For an optically dense medium, thermal motion of atoms leads to an increase of reabsorption in the emission line core, and intensity increases in the line wings as compared to the complete redistribution model. The dependence of the Holstein trapping factor on optical thickness is closer to the analytic dependence than the complete redistribution model. This is explained by the fact that the frequencies of emitted photons in the laboratory reference system fall into the spectral profile core, which increases the effects of resonance radiation trapping in a dense medium.

Maxwell-Boltzmann versus non-ergodic events in the velocity distribution of water molecules evaporated from protonated water nanodroplets.

Measurement of velocity distributions of evaporated water monomers from small mass- and energy-selected protonated water clusters allows probing the extent of thermalization after excitation of these ultimately small nanodroplets. Electronic excitation of a molecule in the cluster is here induced by a single collision with an argon atom in the keV energy range. The measured velocity distributions of the departing neutral molecules exhibit bimodal shapes with a lower-velocity part consistent with a complete redistribution of the deposited energy in the entire cluster and a higher-velocity contribution corresponding to evaporation before complete energy redistribution. Statistical molecular dynamics calculations reproduce the bimodal shape of the velocity distributions by assuming an initial spreading of the excitation energy among all modes, thereby reproducing the lower velocity contribution of the distribution. By contrast, assuming the deposited energy to be initially localized among the modes of a single molecule leads to calculated distributions with two components whose shape is in accordance with the experimental results. The characteristics and the relative abundance of these two contributions in the velocity distributions obtained are presented and discussed as a function of the number of molecules (n = 2-10) in the ionized nanodroplet H+(H2O) n .

Achieving dispersed fine soft Bi particles and grain refinement in a hypermonotectic Al–Bi alloy by severe plastic deformation and annealing

The present work revealed that equal-channel angular pressing (ECAP) deformation combined with appropriate annealing could represent as an efficient route to modify immiscible as-cast microstructure of a monotectic Al–8Bi alloy by a complete redistribution of immiscible Bi particles and grain refinement of alloy matrix. Especially, we found that the mean size of Bi particles in the 4-pass ECAPed Al–8Bi sample decreases after annealing at 200 °C for 8 h, due to inverse coarsening driven by the reduction of elastic energy and interfacial energy induced by morphology change and spatial distribution of Bi particles.

The organization of genome duplication is a critical determinant of the landscape of genome maintenance

Genome duplication is essential for cell proliferation, and the mechanisms regulating its execution are highly conserved. These processes give rise to a spatiotemporal organization of replication initiation across the genome, referred to as the replication program. Despite the identification of such programs in diverse eukaryotic organisms, their biological importance for cellular physiology remains largely unexplored. We address this fundamental question in the context of genome maintenance, taking advantage of the inappropriate origin firing that occurs when fission yeast cells lacking the Rad3/ATR checkpoint kinase are subjected to replication stress. Using this model, we demonstrate that the replication program quantitatively dictates the extent of origin de-regulation and the clustered localization of these events. Furthermore, our results uncover an accumulation of abnormal levels of single-stranded DNA (ssDNA) and the Rad52 repair protein at de-regulated origins. We show that these loci constitute a defining source of the overall ssDNA and Rad52 hotspots in the genome, generating a signature pattern of instability along the chromosomes. We then induce a genome-wide reprogramming of origin usage and evaluate its consequences in our experimental system. This leads to a complete redistribution of the sites of both inappropriate initiation and associated Rad52 recruitment. We therefore conclude that the organization of genome duplication governs the checkpoint control of origin-associated hotspots of instability and plays an integral role in shaping the landscape of genome maintenance.