Commercial Sugar Research Articles

Development of a novel method based on extraction mediated by a semipermeable membrane to determine Cd and Cr in sugar by graphite furnace atomic absorption spectrometry

This work proposes a novel method to determine the Cd(II) and Cr(III) content in commercial sugar samples. It is based on the extraction of the analytes (as ammonium pyrrolidine dithiocarbamate complexes) into a semipermeable membrane device (SPMD) filled with CHCl3. After extraction, the SPMD was deployed and opened, and the analytes were recovered from the organic phase by back extraction with a 4.2 mol L−1 HNO3 solution. The analytes present in the acid extract were measured with graphite furnace atomic absorption spectrometry. Under optimized conditions, the limit of quantification of the method was 1.2 and 3.1 ng g−1 for Cd(II) and Cr(III), respectively. Twelve samples of different types of sugar were analyzed. In addition, a recovery test was performed to evaluate the accuracy of the method. The recovery percentage was 90 %–102 % for Cd(II) and 85.2 %–103 % for Cr(III).

3D Porous Edible Scaffolds from Rye Secalin for Cell-Based Pork Fat Tissue Culturing.

Cellular agriculture holds hope for a sustainable alternative to conventional meat, yet multiple technical challenges remain. These include the large-scale production of edible scaffolds and culturing methods for fat tissues, which are key to meat texture, flavor, and nutritional values. Herein. we disclose our method in the facile fabrication of sponge-like plant protein scaffolds by applying commercial sugar cubes as highly permeable templates. The prepared secalin scaffolds feature a high porosity of 85-90%, fully interconnected pores, and high water stability. The mechanical properties of scaffolds could be tuned by varying sugar-to-protein weight ratio and post-water annealing treatment. Moreover, murine preadipocytes (3T3-L1) and porcine adipose-derived stem cells (ADSCs) readily infiltrate, adhere, proliferate, and differentiate on the secalin scaffolds to develop a fat tissue morphology. A cultured fat tissue was produced by culturing porcine ADSCs for 12 days, which remarkably resembles conventional porcine subcutaneous adipose tissue in appearance, texture, flavor, and fatty acid profiles. The research demonstrates the great potential of sponge-like secalin scaffolds for cultured fat tissue production.

Techno-economic analysis of biomass value-added processing informed by pilot scale de-ashing of paper sludge feedstock

Paper sludge biomass represents an underutilized feedstock rich in pulped and processed cellulose which is currently a waste stream with significant disposal cost to industry for landfilling services. Effective fractionation of the cellulose from paper sludge presents an opportunity to yield cellulose as feedstock for value-added processes. A novel approach to cellulose fractionation is the sidehill screening system, herein studied at the pilot-plant scale. Composition analysis determined ash removal and carbohydrate retention of both sidehill and high-performance benchtop screening systems. Sidehill screening resulted in greater carbohydrates retention relative to benchtop screening (90% vs 66%) and similar ash removal (95% vs 98%). Techno-economic analysis for production of sugar syrup yielded a minimum selling price of $331/metric ton of sugar syrup including disposal savings, significantly less than a commercial sugar syrup without fractionation. Sensitivity analysis showed that screening conditions played a significant role in economic feasibility for cellulosic yield and downstream processes.

Acid hydrolysis of Solanum tuberosum periderm for accumulation of polyhydroxyalkanoates in Pseudomonas putida MTCC 2475.

Polyhydroxyalkanoates are a class of biodegradable, biocompatible polymers composed of polyesters of R-hydroxyalkanoic acids and deposited intracellularly by a variety of microorganisms which have potential to serve as alternative to commercial plastic. Bioplastics are gaining attention due to sustainability, biodegradability, biocompatibility, and lower carbon footprint. Nevertheless, the commercialization of PHA is predominantly hindered by the elevated production expenses arising primarily from the use of a pure sugar substrate. Our study has established a feasible method for bioplastic formation applying Pseudomonas putida MTCC 2475 and Solanum tuberosum periderm as a carbon source. To optimize the sugar yield response surface methodology was used, which released 69.34% ± 0.25% reducing sugar. PHA production experiments were performed in hydrolysate containing media as well as commercial sugar containing mineral salt media. After 48h of fermentation of using this sugar, a biomass concentration of 2.19 gL-1, with a PHA production of 0.60 gL-1 (28.71% ± 0.55%) was obtained which was comparatively similar with synthetic media (2.56 gL-1 cell dry weight and 29.97% ± 0.45% PHA). Furthermore, the monomers of PHA produced by hydrolysate were characterized using Gas chromatography-mass spectrometry, Fourier transform infrared spectroscopy, differential scanning calorimetry, and nuclear magnetic resonance. This investigation has identified three distinct monomers of medium-chain PHAs, namely, methyl 3-Hydroxydodecanoate, 3-Hydroxytetradecanoate, and Hexadecanoic acid 3-Hydroxy methyl esters. Hence this study concludes a sustainable production of bioplastics from S. tuberosum periderm waste.

Pineapple core from the canning industrial waste for bacterial cellulose production by Komagataeibacter xylinus

To address the high production cost associated with bacterial cellulose (BC) production using the Hestrin-Schramm (HS) medium, alternative agricultural wastes have been investigated as potential low-cost resources. This study aims to utilize pineapple core from pineapple canning industry waste as a carbon source to enhance the bacterial growth of Komagataeibacter xylinus and to characterize the physical and mechanical properties of the resulting BC. To assess growth performance, commercial sugar at concentrations of 0, 2.5, and 5.0 % (w/v) was incorporated into the medium. Fermentation was conducted under static conditions at room temperature for 5, 10, and 15 days. The structural and physical properties of BC were characterized using SEM, FTIR, XRD, and DSC. With the exception of crystallinity, BC produced from the pineapple core medium exhibited comparable characteristics to BC produced in the HS medium. These findings highlight the potential of utilizing pineapple core, a byproduct of the canning industry, as an economically viable nutrient source for BC production.

Green waste-derived compost (GWC) alleviates drought stress and promotes sugar beet productivity and biofortification

ABSTRACT Green waste-derived compost (GWC) is a valuable soil amendment for improving soil organic matter and decreasing waste products and potential pollutants. The study was carried out to evaluate the effect of GWC application on the yield and quality of sugar beet under deficit irrigation conditions using different irrigation systems. A field experiment was conducted using the commercial sugar beet variety Gazelle in sandy soil. Two doses (0 and 14 t ha−1) of GWC were applied to the soil. Three water deficiency levels (60, 80 and 100% of the soil field capacity) under either drip and sprinkler irrigation systems were applied. The application of 14 ton ha−1 of GWC resulted in the highest root and recoverable sugar yields, especially under the well-irrigated conditions under drip irrigation. Sugar beet root biofortification and juice quality were also significantly improved under drip irrigation in response to the application of 14 ton ha−1 of GWC by increasing sucrose content, quality index (Qz)% and recoverable sugar (RS)%. The application of GWC under drip irrigation enhanced water use efficiency for root (WUERY) and recoverable sugar yields (WUERSY), in particular under drip irrigation and water deficit conditions (60% of the soil field capacity). The soil physicochemical properties were significantly improved in response to the application of GWC. GWC application promoted the yield and biofortification of sugar beet by improving the soil physiochemical properties, and nutrient mobilization and uptake. The application of GWC is essential for sustainable sugar beet production and efficient irrigation water use in sandy soils.

Oral sugar and vasopressin: Possible alternative in the management of ovine pregnancy toxemia

Ovine pregnancy toxemia, a disease that affects adult ewes in the final stages of pregnancy and which is caused by a negative energy imbalance, requires the usage of dextrose substances for treatment. It has been proven that it is possible to induce reticular groove closure by means of an intravenous injection of lysine-vasopressin (LVP) at doses of 0.08 IU/kg B.W., which enables oral administration of glucose solutions that can be used in pregnancy toxemia therapy. The aim of this research is to compare the effectiveness of conventional treatment with i.v. glucose solution versus coadministration of LVP and a commercial sugar-water solution. This was administered orally to eight ewes to which we experimentally had provoked pregnancy toxemia by fasting. The use of commercial sugar, replacing other glucose solutions, could facilitate and cheapen the therapy for this disease significantly. The results obtained indicate that the joint administration of LVP and an oral solution of commercial sugar produce a noteworthy increase in glycaemia, which has a longer effect over time despite being less marked than with i.v. administration of glucose solution. Therefore, it could be used in the therapy of this disease. Besides, it is also able to normalize other parameters used to evaluate energy metabolism in ewes during the days of the trial.

Production of sugars from mixed hardwoods for use in the synthesis of sugar fatty acid esters catalyzed by immobilized‐stabilized derivatives of Candida antarctica lipase B

AbstractThe synthesis of sugar fatty acid esters (SFAEs) from lignocellulosic biomass and oleic acid (C18:1) was catalyzed by immobilized‐stabilized derivatives of Candida antarctica lipase B in a methyl ethyl ketone medium. After steam‐explosion pretreatment of mixed hardwoods and enzymatic hydrolysis at 15%wt solids, xylose and glucose were purified/concentrated to a mass ratio of ~3 to 1. These lignocellulosic sugars were superior to commercial sugars as the carbohydrate source for the esterification reaction in terms of sugar conversions. The highest conversions were obtained using 1.5% w/v of Novozyme 435 (N435, uncoated) as the biocatalyst for the synthesis of SFAEs. Coating the N435 with polyethyleneimine (PEI) prevented enzyme leakage into the reaction medium and produced 35% and 50% higher xylose and glucose conversions to SFAEs, respectively, at the same enzyme loading. After six 24 h reuse cycles with the PEI‐coated N435, xylose conversion decreased by 44%, while a 65% reduction in xylose conversion was observed with the uncoated lipase. Mass spectrometry analysis confirmed the production of xylose and glucose mono‐ and di‐esters. Our purified product presented an emulsion capacity (EC) close to that of a commercial sugar ester and the ECs of the xylose oleate, laurate, and palmitate synthesized in previous studies. © 2023 The Authors. Biofuels, Bioproducts and Biorefining published by Society of Industrial Chemistry and John Wiley & Sons Ltd.

Impact of Commercial Sugar as a Substrate in Single-Chamber Microbial Fuel Cells to Improve the Energy Production with Bioremediation of Metals

Microbial fuel cells (MFCs) have emerged as a viable method for bioremediation of toxic metals while also producing energy. In this paper, we examine the issue of organic substrate as a source of metabolism for microbe growth in MFC, as well as its significance for metal ion degradation in tandem with energy production. This study focused on the use of commercial sugar as an organic substrate in a single-chamber MFC. The MFC was operated for 27 days, with the highest voltage of 150 mV achieved on day 12, and toxic metal bioremediation efficiencies of 89%, 76.45%, and 89.45% for Pb2+, Cd2+, and Hg2+, respectively. Every 24 hours, the organic substrate (sugar solution) was fed into the cell. This study’s mechanism of metal ion degradation and electron transport is also thoroughly described. In addition, some future views have been highlighted.

Water use efficiency responses to fluctuating soil water availability in contrasting commercial sugar beet varieties.

Many areas of sugar beet production will face hotter and drier summers as the climate changes. There has been much research on drought tolerance in sugar beet but water use efficiency (WUE) has been less of a focus. An experiment was undertaken to examine how fluctuating soil water deficits effect WUE from the leaf to the crop level and identify if sugar beet acclimates to water deficits to increase WUE in the longer term. Two commercial sugar beet varieties with contrasting upright and prostrate canopies were examined to identify if WUE differs due to contrasting canopy architecture. The sugar beet were grown under four different irrigation regimes (fully irrigated, single drought, double drought and continually water limited) in large 610 L soil boxes in an open ended polytunnel. Measurements of leaf gas exchange, chlorophyll fluorescence and relative water content (RWC) were regularly undertaken and stomatal density, sugar and biomass yields and the associated WUE, SLW and Δ13C were assessed. The results showed that water deficits generally increase intrinsic (WUEi) and dry matter (WUEDM) water use efficiency but reduce yield. Sugar beet recovered fully after severe water deficits, as assessed by leaf gas exchange and chlorophyll fluorescence parameters and, except for reducing canopy size, showed no other acclimation to drought, and therefore no changes in WUE or drought avoidance. Spot measurements of WUEi, showed no differences between the two varieties but the prostrate variety showed lower Δ13C values, and traits associated with more water conservative phenotypes of a lower stomatal density and greater leaf RWC. Leaf chlorophyll content was affected by water deficit but the relationship with WUE was unclear. The difference in Δ13C values between the two varieties suggests traits associated with greater WUEi may be linked to canopy architecture.

Evaluating the Potential of Newly Developed Energy Cane Clones for First- and Second-Generation Ethanol Production

The rapid increases in fuel ethanol demand and food security concerns have driven the need for diverse feedstocks in the ethanol production process. Energy cane is an energy crop that is an ideal sustainable biofuel feedstock. The present study evaluated ethanol production of the juice and bagasse of two newly developed energy cane clones, TByEFC08-0035 and TByEFC10-0004. The results of the chemical composition analyses of the juice and bagasse samples revealed that the two energy cane clones contained high contents of both sucrose (15.36–17.95%) and fiber (13.44–24.16%). The maximum ethanol concentrations from the juice on a laboratory scale (87.10 g/L) and on an agronomic scale (1211.76 kg/ha) were recorded for TByEFC10-0004 fermented with a new isolate Kluyveromyces marxianus SJT83, whereas the maximum ethanol concentrations from bagasse on a laboratory scale (9.81 g/L) and on an agronomic scale (790.68 kg/ha) were reached with TByEFC08-0035 fermented with Scheffersomyces shehatae TTC79. The total ethanol yields from the juice and bagasse samples per cultivation area of both energy cane clones were in the range 1294.23–1469.14 kg/ha, being 1.70–1.93 and 1.08–1.23 times higher than the control energy cane Biotec2 variety and the commercial sugar cane Khon Kaen3 variety, respectively. This study revealed the potential of the energy cane clones TByEFC08-0035 and TByEFC10-0004 currently being developed as sugar and lignocellulose substrates for first- and second-generation ethanol industry applications.

Mechanical Properties of Sugar Beet Roots under Impact Loading Conditions.

Root damages due to mechanical impacts result in deterioration in commercial sugar beet quality. In order to determine the mechanical characteristics of roots, a stand equipped with a pendulum enabling impact investigations of whole beets was used. The roots were stored in a monitored environment for up to 5 days (temperature 15 ± 2 °C, 40 ± 2%). During the tests, the beets were struck against a flat steel resistant surface with the velocities Vimp = 0.5, 1.0 and 1.5 m·s-1. The measurements of local root curvatures in three chosen impact areas and the deformation (dmax) allowed modelling of the volume of contact (CV) by means of the ellipsoid cap. These investigations enabled the determination of the relations between the maximal impact force, Fmax, the impact energy, Eimp, and the absorbed energy, Eabs, as well as the contact volume and impact velocity, taking into account the root storage time, St. It was found that the maximal impact force increased with increasing impact velocity and decreased with the storage time for each group of roots. With increasing velocity, there were also increases in the following: impact energy, absorbed energy, contact volume and maximal deformation, as well as absorbed energy, referred to as the mass Eabs-v from Vimp. The mean values of the stresses (σmax), being the quotients of the impact force (Fmax) and the surface area of the ellipsoid cap base (ABE), were 0.81-1.17 MPa, 1.064-1.59 MPa and 1.45-1.77 MPa for the velocities of 0.5, 1.0 and 1.5 m·s-1, respectively. It was confirmed that the statistical significance of the mentioned parameters changes depending on the impact velocity.

Green synthesis of templated porous carbons

AbstractPorous carbon materials such as activated carbons are widely used industrially for the purposes of purification, decolourization, deodorization, and gas storage, among others. Routes for the synthesis of these materials employing templates have increasingly attracted attention due to the ease of manipulating the characteristics of the final product. In the present work, a simple synthesis method was applied for the production of highly porous carbon materials using commercial sugar as the carbon source, Aerosil silica as a template, and deionized water. The synthesis procedure was as follows: (I) Gel formation; (II) carbonization of the gels; (III) removal of the silica template; (IV) activation. The materials were characterized by N2 and CO2 physisorption, Raman spectroscopy, X‐ray diffraction, Fourier‐transform infrared spectroscopy (FTIR), scanning electron microscopy, and thermogravimetric analysis. The aging time had an important influence on the specific area and porosity of the material, with physisorption analysis revealing a high specific area and pore volume. The activation procedures further contributed to significantly increasing the specific area (up to 1158 m2 g−1) and pore volume (up to 1.65 cm3 g−1). The X‐ray diffractograms and Raman spectra identified the formation of semi‐crystalline structures in the material, with the presence of a random distribution of graphite and graphene oxide, in addition to amorphous carbon. FTIR analysis showed the presence of bands corresponding to aromatic groups. The results demonstrated that it was possible to obtain materials with excellent potential for use in different industrial sectors using simple raw materials and a technique that is easy to reproduce.

Productivity of sugar beet in various crop rotations of the Left Bank Forest-Steppe with organo-mineral fertilizer

Aim. To establish the influence of the structure, recruitment and placement of field crops in different rotations on the general productivity, yield and quality of sugar beets in particular. The research was carried out in the subzone of unstable moisture of the Left Bank Forest-Steppe of Ukraine on typical low-humus chernozem of the Panfil Research Station of the Institute of Agriculture of the National Academy of Sciences. Methods. The technology of growing agricultural crops in the experiment is generally accepted and recommended for the research area. Chemical plant protection agents were used to produce competitive commercial sugar beet products. Results. The results of research carried out in a long-term stationary field experiment, which was established in 2001, to study crop rotations on typical chernozems of unstable moisture in the Left Bank Forest Steppe, convincingly indicate that during the 2016−2020 research period, the 8-field crop rotation turned out to be the most rational in this zone saturated with 62.5 % grain, 25 % fodder and 12.5 % technical crops: perennial legumes – winter wheat – sugar beets – corn for grain – corn for agriculture – winter triticale – spring wheat – spring barley for organic-mineral intensification systems (by-products of the predecessor + N100 P100 K100 for sugar beets). Conclusions. The yield of sugar beets, which were grown after winter wheat, as a precursor and a corresponding set of crop rotations, was in the range of: 50.86–53.21 t/ha, while the sugar harvest was at the level of – 13.5–13.7 t/ha. The economic efficiency of growing sugar beets in the structure of multi – rotational crop rotations is: conditionally net profit – 70.67–75.05 thousand UAH/ha with a high level of profitability – 338–362 %.

Biosynthesis of bacterial cellulose nanofibrils in black tea media by a symbiotic culture of bacteria and yeast isolated from commercial kombucha beverage

Bacterial cellulose has drawn the attention for its unique properties and applications including; medicine, pharmacy, food, agricultural, textile and electronics. The present study focused on the production of bacterial cellulose nanofibrils (BCNF) from black tea as cost effective alternative medium in addition to study the effect of gamma radiation on BCNF properties. A symbiotic culture of bacteria and yeast (SCOBY) were isolated from commercial Kombucha beverage and were identified as Acinetobacterlowffii and Candida krusei, respectively. The symbiotic culture was used for production of BCNF on Hestrin-Schramm (HS), black tea (BT) and modified BT media. BCNF was purified (0.5 N NaOH) and quantified by dry weight, yield and productivity determination. Characterization and effect of gamma radiation (5–25 kGy) on BCNF were studied using Scanning Electron Microscope (SEM), Fourier transform infrared (FTIR) and X-Ray Diffraction (XRD). The highest BCNF production was achieved using BT medium with 0.2% tea and 6.0% commercial sugar (with dry weight 4.77–4.61 g/l and productivity 68.14% and 65.85%, respectively). Supplementation of BT medium with 1% ethanol, 0.27% Na2HPO4 and 0.5% yeast extract individually, enhanced the BCNF production (7.85, 6.84 and 5.73 g/l), respectively. FTIR spectrum of BCNF from sugared water (SW), HS and BT showed similar structure with high purity. As a conclusion, gamma irradiation has no effect on the BCNF structure while showed different effects on its crystallinity index and size with the different doses. The changes in CrI were ranged between (17 and 23.5%), while the crystallinity size (Cs) was affected by gamma irradiation in a positive relationship where the crystalline size was decreased (33%) by exposure to 5 kGy then increased by increasing the dose of radiation reaching 25.7% at 25 kGy. SEM graphs showed the morphology of microbial culture and its symbiotic relationship in addition to the ultrafine structure of non-irradiated and irradiated BCNF.Graphical abstract

3D Composite PDMS/MWCNTs Aerogel as High-Performing Anodes in Microbial Fuel Cells

Porous 3D composite materials are interesting anode electrodes for single chamber microbial fuel cells (SCMFCs) since they exploit a surface layer that is able to achieve the correct biocompatibility for the proliferation of electroactive bacteria and have an inner charge transfer element that favors electron transfer and improves the electrochemical activity of microorganisms. The crucial step is to fine-tune the continuous porosity inside the anode electrode, thus enhancing the bacterial growth, adhesion, and proliferation, and the substrate's transport and waste products removal, avoiding pore clogging. To this purpose, a novel approach to synthetize a 3D composite aerogel is proposed in the present work. A 3D composite aerogel, based on polydimethylsiloxane (PDMS) and multi-wall carbon nanotubes (MWCNTs) as a conductive filler, was obtained by pouring this mixture over the commercial sugar, used as removable template to induce and tune the hierarchical continuous porosity into final nanostructures. In this scenario, the granularity of the sugar directly affects the porosities distribution inside the 3D composite aerogel, as confirmed by the morphological characterizations implemented. We demonstrated the capability to realize a high-performance bioelectrode, which showed a 3D porous structure characterized by a high surface area typical of aerogel materials, the required biocompatibility for bacterial proliferations, and an improved electron pathway inside it. Indeed, SCMFCs with 3D composite aerogel achieved current densities of (691.7 ± 9.5) mA m-2, three orders of magnitude higher than commercial carbon paper, (287.8 ± 16.1) mA m-2.

Soft Multifunctional Porous Sponge Sensor for Pressure and Strain Using Liquid Metal/Polydimethylsiloxane with Silver-Nanowire-Coated Composite.

Compression and tension sensors with a porous structure have attracted attention recently. Porous sponge sensors have the advantage of a wide deformation range owing to their structural characteristics. In this study, a porous sponge structure was prepared by absorbing polydimethylsiloxane (PDMS) into the matrix of porous commercial sugar cubes. A conductive network was formed by coating the outside of the sponge skeleton with silver nanowires (AgNWs), which have a high aspect ratio. In addition, a liquid metal (LM), which does not directly form an electrical network but changes from zero-dimensional to one-dimensional under an external force was introduced into this porous sponge structure. The effects of the LM on the sensor sensitivity to pressure and strain were analyzed by comparing the electrical resistance changes of PDMS/AgNW and LM/PDMS/AgNW sponge sensors under tension and pressure. This study shows that the use of a porous structure and an LM may be useful for future wearable sensor design.

Emulsifying activity of commercial sugar beet pectins with aromatic and aliphatic oils

Commercial sugar beet pectin (SBP), 1.5% (w/v), was emulsified with three structurally different oils at 15% (w/v), aromatic limonene, aliphatic medium chain triglycerides (MCT), and aliphatic rice bran oil (RBO). Stability of RBO emulsified with four commercial pectins was determined. Emulsions had volume-based diameter, (D4,3 values) ≤ 2 μm at day 0. Emulsions made with limonene showed the largest particle size increase from day 0 to day 1 (≤3.34 μm) and reached 10 μm by day 9. Emulsions made with MCT had similar (p>0.05) particle sizes between day 1 and day 30 (≤3.83 μm); emulsions made with RBO had similar (p>0.05) particle sizes throughout the entire study (≤3.77 μm). Light microscopy images reflected similar trends as particle size data. Emulsions prepared with RBO were fitted following the Power-Law model and displayed shear-thinning behavior with a flow behavior index of 0.940 or 0.894 at day 0 and 30, respectively. Emulsions prepared with four commercial pectins and RBO had similar particle size and light microscopy, but consistency index was higher and more shear thinning after 30 days in two pectins. Commercial beet pectins had similar protein content, degree of esterification, molecular weight and surface hydrophobicity. Galacturonic acid content and neutral sugar content varied between pectins. Particle size, light microscopy and rheological parameters show variability in SBP emulsion stability with aromatic and different aliphatic oils. For emulsions prepared with a single oil, RBO, emulsion stability varies between different lots of pectin that is not predicted by typical specifications of commercial SBP.

Emulsification mechanism of persimmon pectin with promising emulsification capability and stability

The influence of processing factors and surrounding environment stress on persimmon pectin (PP) prepared emulsion was compared with commercial sugar beet and citrus pectins. The results showed that although PP-stabilized emulsion was sensitive to salt ions, it had stronger resistance against high temperature, freeze-thawing, thermal cycling, and accelerated centrifugation than commercial sugar beet and citrus pectins. To reveal its potential emulsifying mechanism, multi-techniques including triple-phase contact angle evaluation, adsorption layer characterization, and super-resolution imaging of emulsions were employed. Results showed that PP had a high triple-phase contact angle of 83°, endowing it with balanced hydrophobicity and interfacial adsorption. The polystyrene latex particles (PS) model analysis showed that PP exhibited the highest adsorption layer thickness. Moreover, the quartz crystal microbalance with dissipation monitoring (QCM-D) analysis suggested that PP formed a thicker interfacial film and higher adsorption mass and viscoelasticity. The cryogenic-scanning electron micromorphology (Cryo-SEM) revealed a “3D-network” structure around the oil droplets was formed by PP, further enhancing elastic interface film and effectively preventing the flow of the oil droplets. Overall, PP exerted excellent emulsifying capability and stability through multi-layer adsorption. The results suggested that PP exhibited a promising emulsification potential and could be developed as a novel polysaccharide emulsifier in the food industry. • The emulsion prepared by PP exhibited higher resistance against environmental stress than that of commercial pectins. • PP exerted promising emulsification properties via multi-layer adsorption on the interface. • 3D-structure around the oil droplets formed by PP effectively prevented oil droplets flow.

Toward abiotic sugar synthesis from CO2 electrolysis

Toward abiotic sugar synthesis from CO2 electrolysis