Commercial Film Research Articles

Efficient synthesis of cellulose acetate through one-step homogeneous acetylation of cotton cellulose in binary ionic liquids

Cellulose acetate (CA) is an important cellulose derivative with a wide range of applications. To adopt a more efficient and environmentally friendly method to synthesize cellulose acetate, a binary ionic liquid mixture of 1-butyl-3-methylimidazole chloride salt (BmimCl) and 1-butyl-3-methyldihydroimidazole phosphate (BmimH2PO4) was used. Compared to the conventional methods, this approach didn't require pre-activation of cellulose and the process of homogeneous acetylation proceeded without a catalyst. By simply adjusting the reaction conditions, cellulose acetate with a degree of substitution (DS) in the range of 0.83–3.0 was produced by one-step homogeneous acetylation without hydrolysis. Furthermore, the cellulose acetate film produced by solvent casting exhibited smooth surface characteristics, 95 % transparency, and 57.9 MPa tensile strength. Therefore, this study highlights the importance of using binary ionic liquid mixtures for facile synthesis of cellulose acetate. Due to their excellent transparency and mechanical properties, newly synthesized cellulose acetate films could replace commercial films.

Unlocking superior preservation: The synergy of lignin and zeolite in chitosan-based composite films for perishable foods

Chitosan-based films are confronted with several technical challenges that impede their broad application in the preservation of perishable foods, such as suboptimal mechanical properties and insufficient antioxidant activity. In this work, we have introduced lignin (LG) and natural clinoptilolite zeolite (NCZ) into pure chitosan-based films to address the above limitations. The synergistic incorporation of LG and NCZ has endowed the composite films, designated as CTSLC, with a suite of enhanced attributes, including improved thermostability, enhanced UV-shielding capability and hydrophobicity, augmented antioxidant activity, refined gas selectivity, and bolstered mechanical properties. The enhancements in the antioxidant activity, gas selectivity, and mechanical properties of CTSLC are notably pronounced, reflecting a substantial advancement in their overall performance. These attributes surpass those of both pure chitosan-based film or commercial polyethylene film. Consequently, CTSLC could keep the freshness and appearance of strawberries and mangoes at least 60 hours and 10 days, respectively. The findings suggest that CTSLC has the potential to be a promising material for the preservation of perishable foods, offering a significant advancement in the field of food packaging and preservation technology.

Antibacterial and antioxidant supramolecular nanocomposite hydrogel dressings with angiogenesis and photo-thermal effect for multidrug‐resistant bacterial infected wound healing

Antioxidant, antibacterial and removable supramolecular nanocomposite hydrogel dressings with self-healing and tissue adhesiveness is highly anticipated for bacterial infected skin wound healing. A series of supramolecular nanocomposite hydrogels via quadruple hydrogen bond and coordination bonds (catechol-Cu) was developed based on ureidopyrimidinone-modified poly(glycerol sebacate)–co-poly(ethylene glycol)-g-catechol (PEGSDU) and mesoporous copper sulfide nanoparticle (CuS NPs) as antioxidative, antibacterial, removable and tissue-adhesive dressing to treat the MRSA-infected wound. The hydrogels exhibited good self-healing, free radical scavenging, photothermal sterilization performance, adhesiveness, and temperature-sensitive removability. In addition, the Cu2+ was able to be slowly released from the hydrogel, which can promote the proliferation and migration of fibroblasts. Hydrogels containing CuS NPs showed better wound repair efficiency than commercial TegadermTM films and hydrogels without CuS NPs in MRSA-infected skin wound, which was attributed to the good antibacterial property, improved collagen deposition, reduced inflammatory response, and improved new vessels formation, thereby significantly promoting the repair of wounds. In summary, this antioxidative and antibacterial supramolecular nanocomposite hydrogel dressing provide a new type of multi-functional dressing for the treatment of infected skin wounds.

Innovating a EVOH composite coating towards outstanding H2 barrier and anti-corrosion properties

Concerning the mitigating leakage and hydrogen-induced embrittlement during the conveyance of hydrogen (H2), we have developed an innovative dual-layer composite coating that exhibits exceptional hydrogen gas barrier properties and good resistance to corrosion. Using a bottom-top approach combining hot pressing with spin-coating techniques, the bottom Ethylene-vinyl alcohol copolymer (EVOH) layer with glass flakes (GF) serves as an effective hydrogen gas barrier and the top fluorosilicone resin (FSR) layer with composite nanofiller possesses good corrosion resistance, ensuring the functional integrity of the EVOH layer. The composite coating shows an exemplary low hydrogen gas transmission rate (H2 GTR) value of 2.858 cm3/(m2·24 h·0.1 MPa), representing a substantial decrease of 99.98 % compared to the FSR coating and 15 times more effective than commercial gas barrier films. Moreover, even after a 90-day immersion in 3.5 wt% NaCl solution, the coating maintains an impressive impedance at 0.01 Hz (|Z|0.01 Hz) of 1.0 × 1011 Ω·cm2. The composite coating is exposed to 2 MPa hydrogen for 7 days, and we find that it still sustains outstanding hydrogen gas barrier and anti-corrosion properties.

The Correlations between Microstructures and Color Properties of Nanocrystalline Cellulose: A Concise Review.

Cellulose nanocrystals (CNCs) are a green resource which can produce photonic crystal films with structural colors in evaporation-induced self-assembly; CNC photonic crystal films present unique structural colors that cannot be matched by other colored materials. Recently, the mechanisms of CNC photonic crystal films with a unique liquid crystal structure were investigated to obtain homogenous, stable, and even flexible films at a large scale. To clarify the mechanism of colorful CNC photonic crystal films, we briefly summarize the recent advances from the correlations among the preparation methods, microstructures, and color properties. We first discuss the preparation process of CNCs, aiming to realize the green application of resources. Then, the behavior of CNCs in the formation of liquid crystal phases is studied, considering the influence of the CNCs' size and shape, surface properties, and the types and concentrations of solvents. Finally, the film formation process of CNCs and the control of structural colors during the film formation are summarized, as well as the mechanisms of CNC photonic crystal films with full color. In summary, considering the above factors, obtaining reliable commercial CNC photonic crystal films requires a comprehensive consideration of the subsequent preparation processes starting from the preparation of CNCs.

Correlations between adhesion and molecular interactions at buried interfaces of model polymer systems and in commercial multilayer barrier films.

Sum frequency generation vibrational spectroscopy (SFG) was applied to characterize the interfacial adhesion chemistry at several buried polymer interfaces in both model systems and blown multilayer films. Anhydride/acid modified polyolefins are used as tie layers to bond dissimilar polymers in multilayer barrier structures. In these films, the interfacial reactions between the barrier polymers, such as ethylene vinyl alcohol (EVOH) or nylon, and the grafted anhydrides/acids provide covalent linkages that enhance adhesion. However, the bonding strengths vary for different polymer-tie layer combinations. Here, using SFG, we aim to provide a systematic study on four common polymer-tie interfaces, including EVOH/polypropylene-tie, EVOH/polyethylene-tie, nylon/polypropylene-tie, and nylon/polyethylene-tie, to understand how the adhesion chemistry varies and its impact on the measured adhesion. Our SFG studies suggest that adhesion enhancement is driven by a combination of reaction kinetics and the interfacial enrichment of the anhydride/acid, resulting in stronger adhesion in the case of nylon. This observation matches well with the higher adhesion observed in the nylon/tie systems in both lap shear and peel test measurements. In addition, in the polypropylene-tie systems, grafted oligomers due to chain scission may migrate to the interface, affecting the adhesion. These by-products can react or interfere with the barrier-tie chemistry, resulting in reduced adhesion strength in the polypropylene-tie system.

Two-step cathodic microwave electrodeposition for construction of Co9S3(OH)5@Ni(OH)2 hetero-structure as supercapacitor electrode materials

The preparation of two-phase electrode materials of Co9S8@Ni(OH)2 typically involves a laborious three-step process. In this study, a two-step cathode microwave electrochemical method was proposed for the fabrication of Co9S8@Ni(OH)2 electrode materials for supercapacitors, eliminating the need for precursor synthesis. This approach not only simplified the preparation process and saved time but also successfully produced a p-n heterostructure electrode material consisting of Co9S8@Ni(OH)2 phases, where the Co9S8 phase has a chemical formula of Co9S3(OH)5. This unique structure is capable of inducing an internal electrical field by facilitating the transfer of charge carriers from Co9S3(OH)5 to Ni(OH)2, thereby enhancing charge transfer kinetics. As a result, the electrode exhibited remarkable supercapacitive performance, achieving a high specific capacitance of 255.4 mAh g-1 (7.56 F cm-2) at 1 A g-1. Even at a 20-fold increase in charge/discharge current density, the specific capacitance remained high at 218.9 mAh g-1 (6.48 F cm-1), retaining 85.8 % of the initial capacity. Furthermore, the Co9S3(OH)6@Ni(OH)2 electrode materials demonstrated excellent durability, enduring 10000 cycles with a capacitance retention of 92.9 % of the initial value. An asymmetric supercapacitor constructed with Co9S3(OH)5@Ni(OH)2 as the anode and a commercial active carbon film as the cathode was able to power a red light diode continuously emitting light for up to 42 min.

Energy-efficient and directional preparation of cellulose nanosheets by one-pot surface modification assisted swelling method

The energy-intensive and time-consuming process required for disassembling natural materials into nanoblocks are the major obstacles for the practical applications of biopolymer nanomaterials. Herein, a one-pot, energy-efficient and directional preparation method for gently exfoliating cellulose into nanosheets was achieved by surface modification assisted swelling process. The resulting cellulose nanosheets (CNSs) exhibited diameters ranging from 100 to 480 nm and thicknesses of approximately 5 nm, with a maximum yield of 97.9 %. This method could be widely applicable to common cellulose raw materials. Contrary to other nanocellulose reported previously, CNSs could be dried and stored in solid state, and re-dispersed in aqueous phase, thereby convenient for storage and transportation. Cellulose nanosheets films (CNSFs) obtained from CNSs showed high transparencies (>90 %) and excellent gas barrier properties, especially for the water vapor permeability of only 0.0072×10−10 cm3 cm cm−2 s−1 Pa−1, which were superior to other cellulose based films. In the simulation experiment of dry food packaging, CNSF10 possessed remarkable water vapor and oxygen blocking capabilities comparable to commercial cling films and met the practical requirements. The preparing process of CNSs reported here had the advantages including easy implementation, energy efficiency, and environmentally friendliness, and expanded possibilities for large-scale and widespread utilization of nanocellulose.

Laser micro/nano structuring of three-dimensional porous gradient graphene: Advanced heater for antibacterial surfaces and ion-selective electrode for sweat sensing

The development of three-dimensional (3D) gradient porous graphene (GPG) patterns, leveraging the remarkable properties and unique structure of graphene, has garnered considerable attention owing to their excellent electrochemical and electrothermal performances. Among the numerous graphene synthesis methods, laser-induced graphene (LIG) stands out as an eco-friendly and practical approach for creating patterned graphene structures on commercial films, with synthetic details varying depending on the application. Unlike conventional LIG with uniform geometric characteristics, we developed an innovative approach for circular line-scribed ultraviolet (UV)-LIG patterning; these approaches utilize a high overlapping factor and low power to achieve uneven graphitization. A comprehensive analysis of the 3D GPG was conducted via specific surface area measurements, contact angle analyses, sheet resistance measurements, X-ray photoelectron spectroscopy, and Raman spectroscopy. These 3D GPG structures exhibit large surface areas, low sheet resistance, and superior ion transport, thus improving heater and ion-selective electrode (ISE) performances. The fabricated 3D GPG heaters were successfully applied to antibacterial surfaces, and the ISEs were applied in a sweat sensor was demonstrated owing to the remarkable combination of high surface area, low electrical resistance, and unique 3D porous structure.

Degradation of polyethylene terephthalate (PET) plastics by wastewater bacteria engineered via conjugation.

Wastewater treatment plants are one of the major pathways for microplastics to enter the environment. In general, microplastics are contaminants of global concern that pose risks to ecosystems and human health. Here, we present a proof-of-concept for reduction of microplastic pollution emitted from wastewater treatment plants: delivery of recombinant DNA to bacteria in wastewater to enable degradation of polyethylene terephthalate (PET). Using a broad-host-range conjugative plasmid, we enabled various bacterial species from a municipal wastewater sample to express FAST-PETase, which was released into the extracellular environment. We found that FAST-PETase purified from some transconjugant isolates could degrade about 40% of a 0.25 mm thick commercial PET film within 4 days at 50°C. We then demonstrated partial degradation of a post-consumer PET product over 5-7 days by exposure to conditioned media from isolates. These results have broad implications for addressing the global plastic pollution problem by enabling environmental bacteria to degrade PET.

Evaluation of a Commercial MoS2 Dry Film Lubricant for Space Applications

Molybdenum disulfide coatings, particularly Microseal 200-1, have been extensively used as dry film lubricants for actuating mechanisms in space applications. Although Microseal 200-1 has historically been a popular choice for space missions, recent assessments indicate a need for reexamination. This study evaluates sliding friction in air and dry gaseous nitrogen atmospheres at ambient temperatures with both linear reciprocating and rotary unidirectional tribo-tests. Measurements are performed for Microseal 200-1 applied on substrates and surface treatments commonly used in aerospace components, particularly stainless steel and a titanium alloy. Our findings indicate that the friction of stainless steel balls sliding on Microseal 200-1-coated disks is significantly influenced by the environment as well as the disk substrate material. The average friction coefficient ranges from 0.12 to 0.48 in air and from 0.04 to 0.41 in dry gaseous nitrogen, and the amount of friction is consistently much higher for the Microseal 200-1 on the stainless steel than on the titanium alloy. Microscopy and surface analyses, including scanning electron microscopy, energy-dispersive X-ray spectroscopy, and X-ray fluorescence, of the coatings on stainless steel substrates reveals that the coatings are sparse and relatively thin, likely a key factor contributing to their high friction. This insight underscores the substrate dependence of this widely used coating and highlights the importance of detailed tribological testing in accurately assessing the tribological performance of commercial dry film lubricants, a key step towards improving the reliability and effectiveness of actuating mechanisms for space applications.

Semiomical Analysis of 8 March World Women's Day Advertisements

Communication dates back to the beginning of human history, as far back as human history. Human beings have always sought ways to communicate with the people they live with and have developed various communication strategies. Signs, symbols and body language are as important and necessary as human verbal communication. Indicators try to make sense of what is intended to be explained by making it meaningful and concretizing it. Any sign embodies linguistic situations, thoughts, ideas and feelings. In this context, semiotics is used for analysis purposes in cases where any product, service or communication study is involved. Today, as a means of communication, indicators are used when companies want to create various/purposeful thoughts about the product or service in advertisements developed as a way of conveying messages to the consumer audience. The idea, subject, situation and/or event that is intended to be explained is tried to be concretized in people's minds by creating indicators. In this study, "What Would the World Be Like Without Women?" prepared by Gratis for March 8 International Women's Day. In order to understand what kind of messages Kılıoğlu wanted to send to the audience with the signs used in the "If There Were No Women" commercials made by Megaron companies for March 8, International Women's Day, an analysis was made with the semiotic analysis method and an evaluation was made based on the findings obtained. Commercial films express the place and importance of women in social life with strong visual and auditory indicators. Through semiotic analysis, an attempt has been made to analyze how these messages are created and transmitted.

A novel biodegradable film based on chicken gelatin and κ-carrageenan cross-linked with oxidized phenolic compounds.

Natural and renewable polymers are gradually replacing petroleum-based plastics, mostly as a result of environmental concerns. Moreover, upcycling industrial food waste into new added-value products is a creative approach that is crucial for cleaner and more sustainable manufacturing. The aim of this study was to obtain an environmentally friendly biodegradable film using a combination of k-carrageenan (KCAR) and chicken gelatin (CGEL), which obtained from poultry by-products. The effects of varying concentrations of KCAR (0-2%) on the physical, permeability, textural, thermal, and microstructural properties of CGEL/KCAR composite films were evaluated. The findings demonstrated that an increase in KCAR enhanced the lightness and opacity levels of the films. Water vapor permeability (WVP) values reduced as the KCAR concentration increased. The lowest WVP value (0.0012g.mm/h.m2.kpa) was seen in the treatment with 2% KCAR. Tensile strength (TS) values increased with increasing KCAR. The films' thermal stability was increased by the addition of KCAR. Microstructure assessments revealed a more compact and smooth structure in the KCAR-containing treatments, indicating improvements in WVP, thermal stability, and TS. Compared to the commercial cattle gelatin film, the CGEL film had higher TS and lower water solubility (WS). Overall, this study showed that the physical, mechanical, barrier and thermal and microstructural qualities of gelatin-based films may be enhanced by combining CGEL and KCAR to create an effective biodegradable film. Moreover, the comparison study between commercial cattle and chicken gelatin films revealed that cross-linked chicken gelatin films would be a suitable alternative for bovine gelatin films in the production of biodegradable film.

Green composites for sustainable food packaging: Exploring the influence of lignin-TiO2 nanoparticles on poly(butylene adipate-co-terephthalate)

Titanium dioxide (TiO2) is a common pigment used in food packaging to provide a transparent appearance to plastic packaging materials. In the present study, poly(butylene adipate-co-terephthalate) (PBAT) incorporated with lignin-TiO2 nanoparticles (L-TiO2) eco-friendly composite films was prepared by employing an inexpensive melting and hot-pressing technique. The P-L-TiO2 composite films have been studied using Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), scanning electron microscope (SEM), Thermogravimetric analysis (TGA), and Differential scanning calorimetry (DSC) analysis. The FTIR results and homogeneous, dense SEM images confirm the interaction of L-TiO2 with the PBAT matrix. It has also been found that the addition of L-TiO2 nanoparticles can increase the crystallinity, tensile strength, and thermal stability of PBAT. The addition of L-TiO2 increased the tensile strength and decreased the elongation at break of films. The maximum tensile strength of the film, achieved with 5 wt% L-TiO2, was 47.0 MPa, compared with 24.3 MPa for pure PBAT film. The composite film with 5 wt% L-TiO2 has outstanding oxygen and water vapor barrier properties. As the content of lignin-TiO2 increases, the antimicrobial activity of the composite films also increases; the percentage of growth of all the tested bacteria Staphylococcus aureus (S. aureus), and Escherichia coli (E. coli) is significantly reduced. Strawberries were packed to evaluate the suitability of produced composite films as packaging materials, as they effectively preserved pigments from accumulation and extended the shelf-life as compared to commercial polyethylene packaging film.

Improved moisture barrier and mechanical properties of rice protein/sodium alginate films for banana and oil preservation: Effect of the type and addition form of fatty acid

Attenuating the moisture sensitivity of hydrophilic protein/polysaccharide-based films without impairing other properties remains a challenge. Fatty acid dispersed in Pickering emulsion was proposed to overcome such issue. An increase in fatty acid chain length slightly reduced the water vapor permeability (WVP) of emulsion films. As the number of fatty acid double bonds increased from 0 to 1, the WVP of emulsion films was significantly decreased by 14.02% while mechanical properties were significantly enhanced. More hydrogen bonds and stronger electrostatic interactions in the presence of fatty acids were observed by molecular dynamics simulation. The weight loss of bananas coated with oleic acid-incorporated film-forming emulsion was 6.81% lower than that of uncoated group after 4 days, and the corresponding film was more effective to delay oil oxidation than the commercial polypropylene film, indicating that the film is a promising alternative to food coating and packaging material.

Commercial Environmental Education Films and Science Teaching

Commercial Environmental Education Films and Science Teaching

Expressions of a backlash: Challenging the story of success in Norwegian cinema of the 1980s and 1990s

Abstract In this article, we ask if there was a backlash against film feminism in Norway in the 1980s. In Norwegian film history, this decade is known as “the helicopter period” and is associated with a turn towards commercial genre film and classical dramaturgy. This has usually been narrated as a success story for Norwegian cinema. It is, however, also a decade connected to a loss of position for the women directors who had gained a footing in Norwegian cinema in the 1970s. We thus question the idea of progress associated with this decade in film history and propose avenues of investigation. We explore the loss of position of female directors by looking at film reception and film criticism. We further present and discuss a numerical breakdown of women directors and female lead characters in the 1980s and 1990s and point to thematic readings of the on-screen portrayal of women characters in this time span. We find evidence of aggression towards women and a disappearance of women’s film and argue that this points to an anti-feminist pushback in Norwegian cinema of the 1980s and 1990s.

BarbieThe Combination of Feminism and Commercial Film

With the continuous development of feminism in recent years, there have been many new manifestations in the field of culture and art. In 2023, the movie Barbie was released, which became a phenomenon of feminist artworks in the new era and triggered a wide discussion in society. This study explores the feminism embodied in Barbie through the analysis of the contents and characters in the movie. It provides new ideas and references for the combination of feminism and commercial film. By combining feminist and commercial films, Barbie has managed to spark a big debate on social issues while claiming the top spot at the 2023 box office. In terms of movie content, movie box office, movie reputation and so on, the movie Barbie is a very successful work. The success of Barbie undoubtedly provides a very new and good reference for the development of feminism in literary and artistic works. In today's still patriarchal world, feminism wants to have a better development in literary and artistic works, and the combination of feminism and commercial film models is a very effective means.

High-barrier, flexible, hydrophobic, and biodegradable cellulose-based films prepared by ascorbic acid regeneration and low temperature plasma technologies

Regenerated cellulose (RC) films are considered a sustainable packaging material that can replace non-degradable petroleum-based plastics. However, their susceptibility to water vapor and oxygen can limit their effectiveness in protecting products. This study introduces a novel approach for enhancing RC films to create durable, flexible, hydrophobic, high-barrier, and biodegradable packaging materials. By exploring the impact of ascorbic acid coagulation bath treatment and plasma-enhanced chemical vapor deposition (PECVD) on the properties of RC films, we found that the coagulation bath treatment facilitated the organized reconfiguration of cellulose chains, while PECVD applied a dense SiOx coating on the film surface. The results demonstrated a significant enhancement in water vapor and oxygen barrier properties of the composite film, almost reaching the level of commercial barrier films. Moreover, the composite film displayed exceptional biodegradability, fully degrading in soil within 35 days. Additionally, it showcased impressive mechanical strength, hydrophobic characteristics, and freshness preservation, positioning it as a valuable option for bio-based high-barrier packaging applications.

Development of bio-composite mulch film from cotton gin wastes: Study of pesticide residue and outdoor stability and degradation

Non-degradable plastic mulch films used in agriculture are polluting the environment by leaving residues and microplastics in the soil. They are also difficult to recycle due to contamination during their use. Biodegradable mulch films are needed as alternatives so that they can be used effectively during the growing season and later be ploughed to be degraded in soil. However, market-available so-called biodegradable mulch films are very slow to degrade in the natural environment and thus do not fit with crop rotation demands or annual cultivation. In this study, we have developed mulch films from cotton gin trash (CGT) and/or gin motes (GM) in combination with biodegradable polycaprolactone and demonstrated their effectiveness over 3 months in outdoor conditions. Both the stability and degradation behaviours of mulch film samples were observed when they were placed on top of the soil and buried in the soil, respectively. Pesticide residue analysis also was carried out on CGT powder to identify and quantify individual pesticides against a matrix of known pesticides. The mulch films prepared in this study showed comparable and stable mechanical properties compared to commercial biodegradable mulch film, though were much quicker to degrade when buried in the soil. No pesticides were detected in the CGT samples. The films produced were vapour-permeable and may be useful in practical agricultural settings by being able to maintain consistent soil moisture and allowing precipitation to penetrate gradually. The lab-scale production cost for the film was 98.8 AUD/kg, which could be lowered by integrating a continuous film line in large-scale production.