Combustion Of Agricultural Biomass Research Articles

Performance of Corn Cob Combustion in a Low-Temperature Fluidized Bed

This study investigates the combustion of agricultural biomass rich in alkali elements in the fluidized bed. The experiments were performed with smashed corn cob in a 500 kW fluidized bed combustor which was designed for work under low bed temperatures (650–700 °C). During the experiments, the formed compounds from corn cob combustion were measured by sampling particulate matter, and mineral compositions were determined. Also, the temperature profile of the FBC was established. It was determined that the emissions of K and Na elements from the FBC increased from 4 to 7.3% and from 1.69 to 3%, respectively, changing the bed temperature from 650 to 700 °C. Though alkali emissions are reduced at a 650 °C bed temperature, CO emissions are higher by about 50% compared to the case of 700 °C. The addition of 3% of dolomite reduced the pollutant emissions and alkali emissions as well. Potassium content decreased by about 1% and 4%, respectively, at the bed temperatures of 650 °C and 700 °C. The NOx emissions were less than 300 mg/m3 and did not exceed the limit for medium plants regarding DIRECTIVE (EU) 2015/2193. During extended experiments lasting 8 h, no agglomeration of the fluidized bed was observed. Moreover, the proposed configuration of the FBC and its operational parameters prove suitable for facilitating the efficient combustion of agricultural biomass.

Dynamic investigation on potassium migration and transformation during biochar combustion and its correlation with combustion reactivity

For agricultural biomass combustion, K migration and transformation is a key factor affecting boiler operation and reaction characteristics. In this study, dynamic K migration and transformation characteristics during rice straw char combustion process under different O2 concentrations were studied using chemical fractionation analysis (CFA), X-ray diffraction (XRD) and scanning electron microscopy coupled with energy dispersive X-ray (SEM-EDX). Furthermore, the correlation between K migration/transformation and char combustion reactivity was discussed. The results showed that most of K in rice straw char was H2O-soluble K. And the main forms of H2O-soluble K and insoluble K are KCl and KAlSi3O8, respectively. As reaction proceeded, the contents of H2O-soluble K and insoluble K decreased but those of NH4Ac-soluble K and HCl-soluble K increased. Most of the released K is H2O-soluble K. H2O-soluble K would be transformed into NH4Ac-soluble K and HCl-soluble K, and some insoluble K would be transformed into H2O-soluble K. The increase of O2 concentration would stimulate the transformation of H2O-soluble K into NH4Ac-soluble K, HCl-soluble K and released K. However, the reaction to form K-aluminosilicate was hardly found during the combustion process at 400 ℃. Ultimately, it is found that H2O-soluble K is the key occurrence form K affecting the combustion characteristics of rice straw char.

Ash Transformation during Fixed-Bed Combustion of Agricultural Biomass with a Focus on Potassium and Phosphorus

In this study, ash transformation during fixed-bed combustion of different agricultural opportunity fuels was investigated with a special focus on potassium (K) and phosphorus (P). The fuel pellets were combusted in an underfed fixed-bed pellet burner. Residual ashes (bottom ash and slag) and particulate matter were collected and characterized by scanning electron microscopy–energy-dispersive X-ray spectroscopy, X-ray diffraction, inductively coupled plasma, and ion chromatography. The interpretation of the results was supported by thermodynamic equilibrium calculations. For all fuels, almost all P (>97%) was found in residual-/coarse ash fractions, while K showed different degrees of volatilization, depending on fuel composition. During combustion of poplar, which represents Ca–K-rich fuels, a carbonate melt rich in K and Ca decomposed into CaO, CO2, and gaseous K species at sufficiently high temperatures. Ca5(PO4)3OH was the main P-containing crystalline phase in the bottom ash. For wheat straw and grass, representing Si–K-rich fuels, a lower degree of K volatilization was observed than for poplar. P was found here in amorphous phosphosilicates and CaKPO4. For wheat grain residues, representing P–K-rich fuels, a high degree of both K and P retention was observed due to the interaction of K and P with the fuel-bed constituents, i.e., char, ash, and slag. The residual ash was almost completely melted and rich in P, K, and Mg. P was found in amorphous phosphates and different crystalline phases such as KMgPO4, K2CaP2O7, K2MgP2O7, and K4Mg4(P2O7)3. In general, the results therefore imply that an interaction between ash-forming elements in a single burning fuel particle and the surrounding bed ash or slag is important for the overall retention of P and K during fuel conversion in fixed-bed combustion of agricultural biomass fuels.

Polycyclic aromatic hydrocarbons emission from cigar burner combustion system and comparison of their content in fly ashes

Agricultural biomass is considered a preferred RES in Serbia because of its availability and suitability to limit the use of fossil fuel resources and reduce GHG emissions. Therefore, constant work has been done to develop technologies that enable its utilization for energy purposes. As an example of these efforts, in the Agricultural Corporation PKB, the soybean straw cigarette-type combustion system has been applied for greenhouse heating for over a decade. However, many volatile and semivolatile organic compounds are emitted directly into the atmosphere or concentrated in ash particles during agricultural biomass combustion. Since some of the emitted compounds, such as polycyclic aromatic hydrocarbons (PAHs), are toxic, monitoring their concentrations in fly ash is recommended. Literature data regarding PAHs content in agricultural biomass ashes are insubstantial, especially in Serbia. For that purpose, PAHs contents in the cyclone and stack fly ashes of soybean straw were investigated and compared. In addition, the emission factors, toxicity, carcinogenicity and benzo[a]pyrene equivalence concentrations were determined and used to estimate the potential environmental impact of these ashes. As a result, stack ash has been shown to have a higher potential environmental risk than cyclone ash. Hence, an assessment of using soybean straw as a feed fuel in a real cigarette-type combustion plant regarding PAHs emission is given. These results provide important information for optimizing combustion conditions and assisting the local entities in managing air pollution and control policies in Serbia.

The effect of torrefaction, slow, and fast pyrolysis on the single particle combustion of agricultural biomass and lignite coal at high heating rates

The present paper studies single particle combustion of olive residue (OR), almond shell (AS), and Tunçbilek lignite (TL) and their thermal pre-treated particles in a vertical wire mesh reactor (WMR) setup. Pre-treatment of the fuels was done via torrefaction, slow, and fast pyrolysis. The particles with different masses were heated to 1000 °C by radiation with a heating rate of 900 °C/s. The combustion process was recorded with a high-speed camera. The time analysis demonstrated that the particle mass and size did not affect ignition delay time; however, slow pyrolysis had a significant effect on the ignition delay time. The ignition delay time was significantly increased for the chars produced from slow pyrolysis compared to raw and other heat-treated particles for all fuels. Burnout times of all fuels increased proportionally with particle mass. Fast and slow pyrolysis generally increased the char combustion and burnout times. The average burnout times for fast and slow pyrolyzed biochars were ∼20 s and ∼29 s, respectively, while those of raw biomass were ∼9 s. The average burnout times for fast and slow pyrolyzed lignite particles was ∼20 s and ∼53 s, respectively, while those of raw lignite was ∼19 s, when 2 mg particles were compared. Fast pyrolyzed biomass particles had similar burnout times compared to those of raw TL particles. This depicts the potential of co-firing TL with biomass chars produced from fast pyrolysis.

Estimation of Field-Level NOx Emissions from Crop Residue Burning Using Remote Sensing Data: A Case Study in Hubei, China

Crop residue burning is the major biomass burning activity in China, strongly influencing the regional air quality and climate. As the cultivation pattern in China is rather scattered and intricate, it is a challenge to derive an accurate emission inventory for crop residue burning. In this study, we proposed a remote sensing-based method to estimate nitrogen oxide (NOx) emissions related to crop residue burning at the field level over Hubei, China. The new method considers differences in emission factors and the spatial distribution for different crop types. Fire radiative power (FRP) derived from moderate-resolution imaging spectroradiometer (MODIS) was used to quantify NOx emissions related to agricultural biomass combustion. The spatial distribution of different crops classified by multisource remote sensing data was used as an a priori constraint. We derived a new NOx emission database for Hubei from 2014 to 2016 with spatial resolution of 1 × 1 km. Significant seasonal patterns were observed from the NOx emission database. Peak NOx emission occurring in October was related to the residue burning in late autumn harvesting. Another peak was observed between January and April, which was due to the frequent burning of stubble before spring sowing. Our results were validated by comparing our emission inventory with geostationary satellite observations, previous studies, global fire emission database (GFED), NO2 vertical column densities (VCDs) from ozone monitoring instrument (OMI) satellite observations, and measurements from environmental monitoring stations. The comparisons showed NOx emission from GFED database was 47% lower than ours, while the evaluations from most of the statistical studies were significantly higher than our results. The discrepancies were likely related to the differences of methodology and data sources. The spatiotemporal variations of NOx emission in this study showed strong correlations with NO2 VCDs, which agreed well with geostationary satellite observations. A reasonable correlation between in situ NO2 observations and our results in agricultural regions demonstrated that our method is reliable. We believe that the new NOx emission database for crop residue burning derived in this study can potentially improve the understanding of pollution sources and can provide additional information for the design of pollution control measures.

Effects of process parameters on the physicochemical properties of corn stalk hydrochar and the removal of alkali and alkaline earth metals

The advantages of the direct combustion of agricultural biomass for power generation are restricted due to the drawbacks of this biomass and the deep peak shaving trend. Hydrothermal carbonization can improve the physical and thermochemical properties of raw materials. Corn stalk samples were selected as the research object in this study. Corn stalk hydrochars were prepared with reaction pressures of 0–3 MPa, reaction temperatures of 160–240 °C, and residence times of 1–10 h. The effects of the process parameters on the physicochemical properties of hydrochar and on the removal of alkali and alkaline earth metals (AAEMs) were studied by measuring the hydrochar mass, energy yield, product composition, morphology, as well as the removal efficiency of AAEMs. The results indicated that the corn stalk hydrochar had higher mass and energy yields than the raw corn stalk. X-ray diffraction showed that the carbon content in the hydrochar was greater than that in raw corn stalk. Scanning electron microscopy showed that the reaction temperature played a more significant role in the hydrothermal carbonization process than the reaction pressure and residence time.

Ash Transformation during Single-Pellet Combustion of Agricultural Biomass with a Focus on Potassium and Phosphorus

In this study, ash transformation and release of critical ash-forming elements during single-pellet combustion of different types of agricultural opportunity fuels were investigated. The work focus ...

Understanding the origin of carbonaceous aerosols during periods of extensive biomass burning in northern India.

Post-harvest crop residue burning is extensively practiced in North India, which results in enhanced particulate matter (PM) concentrations. This study explores the PM2.5 (particulate matter with aerodynamic diameter≤2.5μm) emissions during various time periods (pre-monsoon, monsoon, and post-monsoon) over the biomass burning source region in Beas, Punjab. The PM2.5 concentrations during the pre-monsoon period (106-458μgm-3) and the post-monsoon period (184-342μgm-3) were similar but much higher than concentrations during the monsoon season (23-95μgm-3) due to enhanced wet deposition. However, the carbonaceous aerosol fraction in PM2.5 was nearly double in the post-monsoon season (∼27%) than the pre-monsoon period (∼15%). A higher contribution of secondary organic carbon (SOC) observed during the pre-monsoon season can be attributed to enhanced photochemical activity in dry conditions. Stable carbon isotope ratio (δ13C value) of ambient PM allowed elucidation of contributing sources. δ13CTC correlation with SOC during post-monsoon and pre-monsoon periods suggests significant influence of secondary formation processes during both time periods. The concentrations of carbon fractions in sampled sources and aerosols suggests contribution of biofuels, resulting in enhanced PM concentration at this location. δ13CTC values of pre- and post-monsoon samples show dominance of freshly emitted aerosols from local sources. Impact of biomass and biofuel combustion was also confirmed by biomass burning K+BB tracer, indicating that major agriculture residue burning occurred primarily during nighttime. C3 plant derived aerosols dominated at the sampling location during the entire sampling duration and contributed significantly during the pre-monsoon season. Whereas, both fossil fuel and C3 plant combustion contributed to the total mass of carbonaceous aerosols during the post-monsoon and monsoon seasons.

P-Based Additive for Reducing Fine Particulate Matter Emissions during Agricultural Biomass Combustion

To understand the influence of P-containing compounds on particulate matter (PM) emissions from the combustion of agricultural residues, the combustion of cornstalk was performed with the addition ...

Effectiveness of Bamboo Biochar Combined with Compost and NPK Fertilizer to Improved Soil Quality and Corn Yield

Biochar is a carbon-rich material produced from incomplete combustion of agricultural biomass through pyrolysis process. Bamboo biochar can increase soil carbon content, improve soil fertility and restore the degraded soil. Previously we found that bamboo-biochar was effective to improve maize yield with an optimum dosage 10.52 t ha-1 biochar. Here, we examined the effectiveness of bamboo-biochar combined with compost and NPK fertilizer to improved soil quality and crop yield. In this experiment, we used a randomized block design (RBD) with two factors, three replications. The first factor was biochar dosage (four levels), namely without biochar, biochar dosage 5.26 t ha-1, biochar dosage 10.52 t ha-1, biochar dosage 15.78 t ha-1. The second factor is the type of fertilizer with four types, namely: without fertilizer, compost, NPK, and compost+NPK. The results showed that biochar dosage 10.52 t ha-1 combined with compost+NPK could increase P and K availability, increase total soil microbes, and improved soil quality to be very good with soil quality rating value 18. The biochar dosage 10.52 t ha-1 combined with compost+NPK gave the dry weight seed-corn highest of 12.84 tons per hectare that increased 38.61% when compared with without biochar and with compost+NPK. The highest yield 12.84 tons of the dry weight of seed-corn per hectare provides the highest effectiveness-agronomic value 119.69% and feasibility of corn crop farming in drylands value 1.27.

Combustion of Agricultural Biomass - Issues and Solutions

Combustion of Agricultural Biomass - Issues and Solutions

Gaseous emissions during agricultural biomass combustion in a 50 kw moving step grate boiler

Gaseous emissions during agricultural biomass combustion in a 50 kw moving step grate boiler

Characteristics of Particulate Matter Emitted from Agricultural Biomass Combustion

In this work, the emission of particulate matter (PM) from combustion of agricultural biomass was investigated in comparison to woody biomass. The mechanism of PM emission was studied by means of mass-based particle size distributions (PSDs), inorganic elemental component analysis and morphology at variant combustion temperatures, and different biomass feedstocks. The mass-based PSDs of PM10 of cotton stalk, rice husk, and camphor wood exhibit a bimodal distribution, while that of corn stalk exhibits a unimodal distribution. The emission of PM10 of agricultural biomass is much higher than that of woody biomass, and it is mainly composed of PM1, in which Na and K are enriched as alkali metal chloride and sulfide. On the other hand, Mg and Ca are enriched as the main inorganic compounds in PM1–10 for woody biomass. A higher combustion temperature is favorable for the formation of fine PM particles against a reduction of PM10. PM1 and PM1–10 formation mechanisms are different for different biomass feedstocks...

CO2 adsorption on agricultural biomass combustion ashes

Carbon capture and storage has become an alternative means of confronting global warming. Further research and development into adequate and low-cost materials is required for CO2 adsorption technologies.Samples of fly ash, bottom ash and their respective pellets, produced from wheat bran combustion, were characterized and tested to assess their capacity for CO2 adsorption at different temperatures. Neither the ashes nor their pellets were subject to prior thermochemical activation.The bottom ash sample and its pellets showed a higher adsorption capacity for the majority of the temperatures studied. The pelletized bottom ash reached the maximum adsorption capacity (0,07 mmol CO2/g), followed by the non-pelletized bottom ash (0,06 mmol CO2/g); both at an adsorption temperature of 25°C.CO2 adsorption of bottom ash, from the combustion of wheat bran (agricultural biomass), by a physical adsorption mechanism was demonstrated whereas with the fly ash sample, CO2 adsorption by both physical and chemical adsorption mechanisms was identified.

Comparison of the gaseous and particulate matter emissions from the combustion of agricultural and forest biomasses

The aim of this study was to compare gaseous and particulate matter (PM) emissions from the combustion of agricultural (switchgrass, fast-growing willow and the dried solid fraction of pig manure) and forest (wood mixture of Black Spruce and Jack Pine) biomasses in a small-scale unit (17.58kW). Concentrations of CO2, CO, CH4, NO2, NH3, N2O, SO2, HCl, and H2O were measured by Fourier transform infrared spectroscopy and converted into emission rates. Opacity was also evaluated and particulates were sampled. Results showed significantly higher emissions of SO2, NO2 and PM with the combustion of agricultural biomass compared to the forest biomass. However, further studies should be carried out so regulations can be adapted in order to permit the combustion of agricultural biomass in small-scale combustion units.

Adsorption Characteristics of Methylene Blue on Activated Carbon from Rice Husk Ash by Chemical-Thermal Process

The production of functional activated carbon (AC) prepared from cheap agricultural biomass combustion residue rice husk ash (RHA) has been utilized as the adsorbent for the removal of Methylene Blue from an aqueous solution was examined in this study. The RHA was subjected to a chemical pretreatment by ZnCl2, followed by carbonization in a muffle. The experimental data were analyzed by the Freundlich models of adsorption. Equilibrium data fitted well with the Freundlich model. The rates of adsorption were found to conform to the pseudo-second-order kinetics with good correlation.

Furnace for biomass combustion – Comparison of model with experimental data

As one of the most easily accessible renewable energy resources, straw can be burned to provide heat energy. In this paper, results of theoretical and experimental research conducted under the proceedings of mathematical – numerical modeling of turbulent reacting flows has been presented. Two-dimensional turbulent flow model with homogeneous chemical reactions has been developed. The proposed model has been analyzed on the example of adiabatic combustion chamber for combustion of agricultural biomass. Turbulent flow is considered using time averaging Navier–Stokes equations that are closed by k–ε turbulence model. Calculations based on the proposed models were conducted using commercial CFD package FLUENT 6.3.26. For the purposes of experimental research, measurements of fluid flow and thermal parameters, such as continuous measurement of temperature in different points in the workspace furnace, air flow, flue gas flow, continual analysis of combustion products as well as setting heat and material balance, were carried out. Comparative analysis of the results of experiments and calculations indicate satisfactory agreement between the model and experiment.

Development of the boiler for combustion of agricultural biomass by products

Republic of Serbia consumes about 15 million tons of equivalent oil per year (Mtoe). At the same time potential of the renewable energy sources is about 3,5 Mtoe/year. Main renewable source is biomass, with its potential of about 2,6 Mtoe/year, and 60% of the total biomass source is of agricultural origin. Mainly, that type of biomass is collected, transported and stored in form of bales. At the same time in one of the largest agricultural companies in Serbia (PKB) there are over 2000 ha of soya plantations, and also 4000 t/year of baled soya straw available, none of which being used for energy purposes. Therefore, efforts have been made in the Laboratory for Thermal Engineering and Energy of the "Vinca" Institute to develop a technology for utilizing bales of various sizes and shapes for energy production. Satisfactory test results of the 1 MW experimental facility - low CO levels and stable thermal output - led to the building-up of a 1.5 MW soya straw bales-fired hot water boiler, with cigarette type of combustion, for the purposes of greenhouse and office heating in the PKB. Further more, achieving good results in exploitation of that hot water boiler, the next step is building up the first combined heat and power (electricity) production facility (CHP), which will use agricultural biomass as a fuel, in Serbia.