The detection of flame ion current is a promising approach in fully premixed combustion. However, how to control the excess air coefficient (α) by ion current still needs an effective method. For this reason, the application of natural gas (12T), hydrogen-doped 12T (12T-H) and dimethyl ether (DME) in fully premixed combustion is experimentally studied in this paper. The emission characteristics of NOx, CO and CO2 from fully premixed condensing gas boilers (FPCGB) were analyzed. The detection voltage generated by the flame ion current is used to monitor the NOx emissions of different gas types. A novel combustion control method based on flame ion current is proposed. The results show that hydrogen addition can reduce NOx, CO and CO2 emissions of 12T. The highest NOx emission is observed at a hydrogen volume ratio (HVR) of 15 % in the experiment. The detection voltage gradually decreases with increasing HVR. The CO2 of DME is always lower than 12T. When α exceeds 1.21, 1.31 and 1.12, respectively, DME exhibits higher values in NOx, CO and detection voltage compared to that of 12T. In addition, two combustion characteristic values are identified and proposed for combustion feedback control. The peak voltage (Up) can be used as a parameter to identify the type of gas. The emission voltage (Ue) can be used to determine whether the NOx emission concentration exceeds the 40 ppm threshold.
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